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At least 1,279 records · Page 71
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

The stability of H/V spectral ratios from noise measurements in Armutlu Peninsula (Turkey)

The horizontal to vertical spectral ratio (H/V) method has been successfully using in order to estimate the fundamental resonance frequency of the sedimentary cover, its thickness and amplification factor since at least 3 decades. There are numerous studies have been carried out on the stability of the H/V spectral ratios. Almost all studies showed that fundamental frequency is stable even measurements are repeated at different times. From this point of view, the results will show us an approach whether the stations are suitable for accurate estimate of earthquake studies and engineering purposes or not. Also we want to see if any effects of the amplification factor changing on the seismograms for Armutlu Seismic Network (ARNET) even though seismic stations are established far away from cultural noise and located on hard rock sites. It has been selected one hour recorded data of all stations during the most stationary times. The amplification and resonant frequency variations of H/V ratio were calculated to investigate temporal stability in time. There is a total harmony in fundamental frequencies values and H/V spectral ratio values in time-lagged periods. Some stations shows secondary minor peaks in high frequency band due to a shallow formation effect or cultural noises around. In the east side of the area ILYS station shows amplitude peak in lower fundamental frequency band from expected. This could compose a high amplification in lower frequencies and so that yield less reliable results in local earthquakes studies. By the experimental results from ambient noise analysis, it could be worked up for relocation of one station.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

A Universal Seeding Strategy to Synthesize Single Atom Catalysts on 2D Materials for Electrocatalytic Applications

Abstract Single‐atom catalysts (SACs) are attracting significant attention due to their exceptional catalytic performance and stability. However, the controllable, scalable, and efficient synthesis of SACs remains a significant challenge. Herein, a new and versatile seeding approach is reported to synthesize SACs supported on different 2D materials such as graphene, boron nitride (BN), and molybdenum disulfide (MoS 2 ). This method is demonstrated on the synthesis of Ni, Co, Fe, Cu, Ag, Pd single atoms as well as binary atoms of Ni and Cu codoped on 2D support materials with the mass loading of single atoms in the range of 2.8–7.9 wt%. In particular, the applicability of the new seeding strategy in electrocatalysis is demonstrate on nickel SACs supported on graphene oxide (SANi‐GO), exhibiting excellent catalytic performance for electrochemical CO 2 reduction reaction with a turnover frequency of 325.9 h −1 at a low overpotential of 0.63 V and high selectivity of 96.5% for CO production. The facile, controllable, and scalable nature of this approach in the synthesis of SACs is expected to open new research avenues for the practical applications of SACs.

Zhao, Shiyong↗
DOE OSTI2018

Computational screening of organic polymer dielectrics for novel accelerator technologies

The use of infrared lasers to power accelerating dielectric structures is a developing area of research. Within this technology, the choice of the dielectric material forming the accelerating structures, such as the photonic band gap (PBG) structures, is dictated by a range of interrelated factors including their dielectric and optical properties, amenability to photo-polymerization, thermochemical stability and other target performance metrics of the particle accelerator. In this direction, electronic structure theory aided computational screening and design of dielectric materials can play a key role in identifying potential candidate materials with the targeted functionalities to guide experimental synthetic efforts. In an attempt to systematically understand the role of chemistry in controlling the electronic structure and dielectric properties of organic polymeric materials, here we employ empirical screening and density functional theory (DFT) computations, as a part of our multi-step hierarchal screening strategy. Our DFT based analysis focused on the bandgap, dielectric permittivity, and frequency-dependent dielectric losses due to lattice absorption as key properties to down-select promising polymer motifs. In addition to the specific application of dielectric laser acceleration, the general methodology presented here is deemed to be valuable in the design of new insulators with an attractive combination of dielectric properties.

47 OTHER INSTRUMENTATION↗
DOE OSTI2013

Klystron-like cavity with mode transformation for high-harmonic terahertz gyrotrons

A novel cavity scheme of a gyrotron is proposed and investigated. As it provides low Ohmic losses and high mode selectivity, it can be especially prospective for realization in gyrotrons operating in the THz frequency range. Numerical simulations show that it allows three-fold increase in the efficiency of the low-relativistic 500 GHz fourth-harmonic gyrotron as compared to conventional two-section scheme with modes transformation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Dipole-bound excited states and resonant photoelectron imaging of phenoxide and thiophenoxide anions

We report photodetachment and resonant photoelectron-imaging studies of cryogenically cooled phenoxide (C 6 H 5 O – ) and thiophenoxide (C 6 H 5 S – ) anions. In a previous study, a dipole-bound excited state was observed for C 6 H 5 O – at 97 cm –1 below the detachment threshold. Eight resonant photoelectron spectra were obtained via excitations to eight vibrational levels of the dipole-bound state (DBS) followed by autodetachment. In this paper, we present a complete photodetachment spectrum of C 6 H 5 O – covering a spectral range 2600 cm –1 above the detachment threshold and revealing nine additional vibrational resonances of the DBS. We also report the first observation of a dipole-bound excited state for C 6 H 5 S – , 39 cm –1 below its detachment threshold of 18 982 cm –1 . Photodetachment spectroscopy covering a spectral range 1500 cm –1 above the threshold reveals twelve vibrational resonances for the DBS of C 6 H 5 S – . By tuning the detachment laser to the vibrational resonances in the DBS of C 6 H 5 O – and C 6 H 5 S – , we obtain highly non-Franck-Condon resonant photoelectron spectra, as a result of mode-selectivity and the Δv = –1 propensity rule for vibrational autodetachment. Five new fundamental vibrational frequencies are obtained for the ground state of the C 6 H 5 O ( X 2 B 1 ) radical. Intramolecular inelastic scattering is observed in some of the resonant photoelectron spectra, leading to the excitation of the Franck-Condon-inactive lowest-frequency bending mode (ν 20 ) of C 6 H 5 O. The first excited state of C 6 H 5 O ( A 2 B 2 ) is observed to be 0.953 eV above the ground state. Twelve resonant photoelectron spectra are obtained for C 6 H 5 S – , allowing the measurements of seven fundamental vibrational frequencies of the C 6 H 5 S radical, whereas the non-resonant photoelectron spectrum exhibits only a single Franck-Condon active mode. The current study again demonstrates that the combination of photodetachment spectroscopy and resonant photoelectron spectroscopy is a powerful technique to obtain vibrational information about polar radical species.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Characterizing the best cosmic telescopes with the millennium simulations

Certain configurations of massive structures projected along the line of sight (LOS) maximize the number of detections of gravitationally lensed z ∼ 10 galaxies. We characterize such LOSs with the étendue σ{sub μ}, the area in the source plane magnified over some threshold μ. We use the Millennium I and Millennium XXL cosmological simulations to determine the frequency of high σ{sub μ} beams on the sky, their properties, and efficient selection criteria. We define the best beams as having σ{sub μ>3} > 2000 arcsec{sup 2}, for a z ∼ 10 source plane, and predict 477 ± 21 such beams on the sky. The total mass in the beam and σ{sub μ>3} are strongly correlated. After controlling for total mass, we find a significant residual correlation between σ{sub μ>3} and the number of cluster-scale halos (>10{sup 14} M {sub ☉} h {sup –1}) in the beam. Beams with σ{sub μ>3} > 2000 arcsec{sup 2}, which should be best at lensing z ∼ 10 galaxies, are 10 times more likely to contain multiple cluster-scale halos than a single cluster-scale halo. Beams containing an A1689-like massive cluster halo often have additional structures along the LOS, including at least one additional cluster-scale (M {sub 200} > 10{sup 14} M {sub ☉} h {sup –1}) halo 28% of the time. Selecting beams with multiple, massive structures will lead to enhanced detection of the most distant and intrinsically faint galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Metal Amorphous Nanocomposite Soft Magnetic Material-Enabled High Power Density, Rare Earth Free Rotational Machines [Metal Amorphous Nanocomposite (MANC) Soft Magnetic Material (SMM) Enabled High Power Density, Rare Earth Free Rotational Machines]

Metal amorphous nanocomposites (MANCs) are promising soft magnetic materials (SMMs) for power electronic applications offering low power loss at high frequency and maintaining a relatively high flux density. While applications in certain motor designs have been recently modeled, their widespread application awaits scaled manufacturing of MANC materials and proliferation of new higher speed motor designs. A hybrid motor design based on permanent magnets and doubly salient stator and rotor is reported here to develop a compact (a factor of 10 smaller than currently possible in Si steels), high-speed (>1 kHz, electrical), high-power (>2.5 kW) motor by incorporating low loss (<10 W/kg at 1 kHz) MANCs such as recently reported Fe-Ni-based alloys. A feature of this motor design is flux focusing from the permanent magnet allowing use of lower energy permanent magnet chosen from among non-rare earth containing compositions and attractive due to constraints posed by rare earth criticality. A 2-D finite element analysis model reported here indicates that a 2.5 kW hybrid motor may be built with a permanent magnet with a 0.4 T remanence at a rotor speed of 6000 rpm. At a magnetic switching frequency of 1.4 kHz, the core loss may be limited to <3 W by selecting an appropriate MANC SMM. The projected efficiency exceeds 96% not including power loss in the controller. Under full load conditions, the flux density distributions for the SMM stay predominantly <1.3 T, the saturation magnetization of optimized FeNi-based MANC alloys. As a result, the maximum demagnetizing field in the permanent magnet is less than 2.2 × 10 5 A/m sustainable, for example, with a high-grade hard ferrite magnet.

42 ENGINEERING↗
DOE OSTI2018

Distributed Control Strategy to Achieve Synchronized Operation of an Islanded MG

To seamlessly transition a microgrid (MG) from islanded to grid-connected mode, it is necessary to synchronize the magnitude, frequency, and phase of the MG voltage to the voltage of the main grid. In this paper, we present a distributed control strategy to achieve synchronized operation of an islanded MG supported by multiple controllable distributed generators (DGs). The proposed method utilizes pinning-based consensus algorithm to ensure explicit coordination between magnitude, frequency and phase angle regulation, while ensuring proportional power sharing. System frequency is regulated by all the DGs in proportion to their capacity, while a selected DG eliminates the phase and magnitude regulation errors. Controller design criteria is based on small-signal stability analysis. Here, the proposed control strategy is implemented in hardware controllers and its effectiveness is demonstrated using a real-time hardware-in-the-loop MG testbed.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2016

Genomic resolution of a cold subsurface aquifer community provides metabolic insights for novel microbes adapted to high CO 2 concentrations

As in many deep underground environments, the microbial communities in subsurface high-CO 2 ecosystems remain relatively unexplored. Current research based on single-gene assays revealed a remarkable variety of organisms from little studied phyla in Crystal Geyser (Utah, USA), a site where deeply sourced CO 2 -saturated fluids are erupted at the surface. To provide genomic resolution of the metabolisms of these organisms, we used a novel metagenomic approach to recover 227 high-quality genomes from 150 microbial species affiliated with 46 different phylum-level lineages. Bacteria from two novel phylum-level lineages have the capacity for CO 2 fixation. Analyses of carbon fixation pathways in all studied organisms revealed that the Wood-Ljungdahl pathway and the Calvin-Benson-Bassham Cycle occurred with the highest frequency, whereas the reverse TCA cycle was little used. We infer that this, and selection for form II RuBisCOs, are adaptions to high CO 2 -concentrations. Yet, many autotrophs can also grow mixotrophically, a strategy that confers metabolic versatility. The assignment of 156 hydrogenases to 90 different organisms suggests that H 2 is an important inter-species energy currency even under gaseous CO 2 -saturation. As a whole, metabolic analyses at the organism level provided insight into the biochemical cycles that support subsurface life under the extreme condition of CO 2 saturation.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Search for Infrasound Signals in InSight Data Using Coupled Pressure/Ground Deformation Methods

The unprecedented quality and sampling rate of seismometer and pressure sensors of the InSight Mars mission allow us to investigate infrasound through its pressure and ground deformation signals. This study focuses on compliance effects induced by acoustic waves propagating almost horizontally close to the surface. The compliance of acoustic waves is first estimated using the compliance estimates from pressure perturbations moving at wind speed. Then, a marker of compliance events is used to detect events of ground deformation induced by pressure variations, in three frequency bands from 0.4 to 3.2 Hz, from InSight sol 180 to 690. Additional selection criteria are imposed on the detected events to focus on acoustic waves and to remove various noise sources (e.g., wind effects or seismometer artifacts). After an automated selection, the visual inspection of the records allows us to validate two infrasound candidates that cannot be related to pressure perturbations moving at wind speed nor to known noise sources. For our highest quality infrasound candidate, the relation between this event and a convective vortex occuring 10 s later is tested. The azimuth of the vortex position at the time of infrasound detection is not consistent with the arrival azimuth of the suspected infrasound inferred from the polarization of seismometer records, thus the link between these two phenomena cannot be demonstrated. Further investigations would require a better understanding of wind-related noise impacting InSight sensors and of the effects of lateral variations of subsurface mechanical properties on the ground deformations induced by atmospheric pressure variations.

58 GEOSCIENCES↗
DOE OSTI2017

Simulations of the Fe K α Energy Spectra from Gravitationally Microlensed Quasars

The analysis of the Chandra X-ray observations of the gravitationally lensed quasar RX J1131−1231 revealed the detection of multiple and energy-variable spectral peaks. The spectral variability is thought to result from the microlensing of the Fe K α emission, selectively amplifying the emission from certain regions of the accretion disk with certain effective frequency shifts of the Fe K α line emission. In this paper, we combine detailed simulations of the emission of Fe K α photons from the accretion disk of a Kerr black hole with calculations of the effect of gravitational microlensing on the observed energy spectra. The simulations show that microlensing can indeed produce multiply peaked energy spectra. We explore the dependence of the spectral characteristics on black hole spin, accretion disk inclination, corona height, and microlensing amplification factor and show that the measurements can be used to constrain these parameters. We find that the range of observed spectral peak energies of QSO RX J1131−1231 can only be reproduced for black hole inclinations exceeding 70° and for lamppost corona heights of less than 30 gravitational radii above the black hole. We conclude by emphasizing the scientific potential of studies of the microlensed Fe K α quasar emission and the need for more detailed modeling that explores how the results change for more realistic accretion disk and corona geometries and microlensing magnification patterns. A full analysis should furthermore model the signal-to-noise ratio of the observations and the resulting detection biases.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

The Atacama Cosmology Telescope: Microwave Intensity and Polarization Maps of the Galactic Center

Herein we present arcminute-resolution intensity and polarization maps of the Galactic center made with the Atacama Cosmology Telescope. The maps cover a 32 deg 2 field at 98, 150, and 224 GHz with |l| ≤ 4°, |b| ≤ 2°. We combine these data with Planck observations at similar frequencies to create coadded maps with increased sensitivity at large angular scales. With the coadded maps, we are able to resolve many known features of the Central Molecular Zone (CMZ) in both total intensity and polarization. We map the orientation of the plane-of-sky component of the Galactic magnetic field inferred from the polarization angle in the CMZ, finding significant changes in morphology in the three frequency bands as the underlying dominant emission mechanism changes from synchrotron to dust emission. Selected Galactic center sources, including Sgr A*, the Brick molecular cloud (G0.253+0.016), the Mouse pulsar wind nebula (G359.23-0.82), and the Tornado supernova remnant candidate (G357.7-0.1), are examined in detail. These data illustrate the potential for leveraging ground-based cosmic microwave background polarization experiments for Galactic science.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1977

Multiple rate digital command detection system with range clean-up capability

A multi-rate digital command system is disclosed which uses the composite signal of a mu-type ranging system as a subcarrier to transmit range codes and data from a station to a receiver where the range codes are sequentially phase modulated on a subcarrier of frequency by one of its own subharmonics and data is phase modulated on a selected ranging component. A range cleanup loop in a spacecraft locks the phase of a locally generated reference component to a received ranging component and retransmits the component to a ground station. When the inverse phase of a ranging component is received and detected, the cleanup loop is modified to demodulate phase modulated command symbols while continuing tracking the same ranging component. The command symbol rate is coherently related to the ranging signal component bit rate.

Lesh, J. R.↗
NASA NTRS1980

Scannable beam forming interferometer antenna array system

An antenna array is described which comprises three interferometer pairs of antenna elements with selected spacings made to form a single beam which is readily scannable. All spatial frequencies generated by a signal and intercepted by the array are derived from a signal processing technique applied to the array. The array samples space in the spatial frequency domain while the signal processing technique utilizes real time convolution of functions in the spectral frequency domain. Summation of the appropriate spatial frequencies is equilvalent to a Fourier transform operation, yielding the location of the signal source in space. Resolution and freedom from interference of the interferometer system is equal to that of a fully filled array of the same aperture size containing element spacings of one half wavelength. An antenna array system comprising four antenna elements forming six interferometer pairs with a resolution equal to that of a sixteen element array with spacings of one half wavelength is described, as well as other multiples of one quarter wavelength of partial multiples of a wave length.

Kaiser, J. A., Jr.↗
NASA NTRS1979

Implicit finite-difference simulations of steady and unsteady transonic flows

Implicit methods for several fluid dynamic formulations have been developed and applied to steady-state and low-frequency transonic flows. The basic steps involved in the construction of implicit schemes include: selection of linearly stable accurate implicit difference operators, time-linearization of nonlinear terms, and approximate factorization of the implicit operators into easily solved systems of equations. The proposed schemes are found very efficient for the simpler formulations.

Ballhaus, W. F.↗
NASA NTRS1984

Space station orbit selection

Architecture and operations with respect to a permanent manned space facility are being studied, and basic modules of such a space station could be in orbit by 1992. A manned space station in low-earth orbit (LEO) represents a transportation node between the Space Shuttle and orbital transfer vehicles which together comprise a total space transportation system. The present investigation has the objective to examine the trades between performance and operational requirements of a space transportation system which affect space station orbit selection. Factors influencing the trades and selection process include launch vehicle and orbital transfer vehicle (OTV) delivery performance, vehicle launch frequency and windows, station drag characteristics, drag-makeup propulsion, and minimum orbital lifetime requirements.

Talay, T. A.↗