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At least 1,279 records · Page 71

Composite materials with self-regulated infrared emissivity and environment responsive fibers

A composite fabric having self-regulating Infrared emissivity includes meta fibers formed with optical nanostructures and an environment (temperature and/or moisture) responsive mechanism configured to adjust a relative disposition between the optical structures to control the electromagnetic coupling therebetween, thus regulating the infrared emissivity of the composite fabric to maintain a user of the fabric in a temperature/moisture comfort zone. The environment responsive mechanism may include a temperature responsive polymer layer on the fiber capable of expansion/shrinkage depending on the applied temperature, or a moisture responsive fiber changing its shape depending on the moisture level to affect spacing between the optical nanostructures.

Wang, Yuhuang↗

Hybrid Bio-Based Composites: Enabling Cellulose Nanofiber (CNF) Incorporation into Composites via Macroscale Natural Fiber Carriers

Cellulose nanofibers (CNFs) have significant potential in composites as additives to improve mechanical properties, melt rheology, and more. However, agglomeration of CNFs is a key challenge in composite melt processing as obtaining nano-level dispersion of CNFs often requires cost- and energy-intensive processes (e.g., solvent exchange or freeze drying) due to the strong hornification tendencies of CNF. Herein, we avoid these challenges by using a natural fiber carrier method to integrate CNF into thermoplastic composites. Fibers are co-dried to create a hybrid fiber feedstock for compounding in which natural fibers are decorated with dispersed nanofibers. The hybridized fibers result in up to a 24% increase in tensile strength and up to a 35% increase in Young’s modulus compared to composites only containing natural fibers. The lignocellulosic nanofibers are found to outperform their purely cellulosic counterpart, which is theorized to be due to either an increased propensity for fibrillation of the lignocellulosic fibers or the increased hydrophobicity of the fibers due to the presence of lignin. Surface analysis of fiber feedstocks, via streaming potential measurements and dynamic light scattering (DLS), confirmed a significant change in the feedstock hydrophobicity before and after hybridization. While mild additions of CNF (1 wt.% on the macroscale fiber) do not impact the composite melt viscosity, the viscosity is found to increase at higher CNF loadings (5 wt.% on the macroscale fiber), indicating its utility as a rheology modifier. Lastly, use of these materials as novel feedstocks for medium-scale additive manufacturing in high-fidelity part production was demonstrated.

bio-based↗

An Algorithm for Characterization of Fiber Aggregation in Composite Microstructures

Composite structures are susceptible to localized flaws, or variability, that drive global failure. To capture this variance, a multiscale model needs to be introduced that not only accurately represents the statistical nature of the composite microstructure but is also efficient. At the microscale, fiber aggregation creates local stress concentrations, where failure is likely to occur sooner than expected. A method of rapid microstructure generation, in conjunction with cluster characterization, is examined to develop accurate reproductions of 2D composite cross-sections. Parameterization of shape and size of fiber clusters is used to characterize representative volume elements. The discrete element method is used to generate pseudo-microstructures. The clustering parameters from the pseudo- and actual microstructure arrangements (obtained from micrographs) can be compared to determine the validity of the representative volume element generated with the discrete element method. Results show a promising approach to evaluating randomness of fiber distributions and how to accurately recreate microstructures for strength analysis.

Carbon fiber↗

The role of rapid solidification processing in the fabrication of fiber reinforced metal matrix composites

Advanced composite processing techniques for fiber reinforced metal matrix composites require the flexibility to meet several widespread objectives. The development of uniquely desired matrix microstructures and uniformly arrayed fiber spacing with sufficient bonding between fiber and matrix to transmit load between them without degradation to the fiber or matrix are the minimum requirements necessary of any fabrication process. For most applications these criteria can be met by fabricating composite monotapes which are then consolidated into composite panels or more complicated components such as fiber reinforced turbine blades. Regardless of the end component, composite monotapes are the building blocks from which near net shape composite structures can be formed. The most common methods for forming composite monotapes are the powder cloth, foil/fiber, plasma spray, and arc spray processes. These practices, however, employ rapid solidification techniques in processing of the composite matrix phase. Consequently, rapid solidification processes play a vital and yet generally overlooked role in composite fabrication. The future potential of rapid solidification processing is discussed.

Locci, Ivan E.↗

Low-velocity impact resistance and failure characteristics of all thermoplastic woven polymer-fiber-reinforced plastic composites

This study addresses the impact performances of recyclable composites made of all thermoplastic polymer-fiber-reinforced plastics (PFRPs), where the reinforcing fibers and matrix are made of thermoplastic polymers. Three woven PFRPs systems were evaluated, including polypropylene fibers, polypropylene matrix, and high-density polyethylene matrix. In low-velocity impact scenario with an impactor speed of less than 6 m/s, our results demonstrate the energy absorption capabilities of the flat laminate PFRPs compared to woven carbon fiber-reinforced plastics (CFRPs) and aluminum alloy 5052. For the systems studied, the PFRPs can reach the specific energy absorption 89% to 115% of the CFRPs. Even compared with the aluminum alloy 5052, the PFRPs can reach up to 97%. We investigate the failure morphologies of the PFRPs using X-ray µCT scans. They reveal the PFRPs’ unique ductile failure morphologies compared to common CFRPs. In addition, we heal the perforated region in the PFRPs by applying the manufacturing process identical to the initial curing process. The healed panels are perforated again, and they recovered 30% to 38% of their original specific energy absorption, a recovery not achievable with CFRPs. This study provides valuable experimental results, and concrete insights into the potential applications of recyclable PFRPs in various engineering fields. It emphasizes their excellent energy-absorbing capability and repairability.

CFRPs↗

Generic composite flywheel designs

Fiber reinforced composites belong to a new class of materials and allow great flexibility in flywheel design. The most efficient flywheel may no longer have the classic Stodola taper and indeed, may not even be round. Some of the flywheel designs that have been developed in the past are discussed. Although choice of material, mounts and service requirements often dictate the final design choice for a particular application, the composite flywheels in this paper are classified within a geometric framework, a simple stress analysis of a circular disk is carried out.

Steele, R. S.↗

Integrating helicoid channels for passive control of fiber alignment in direct-write 3D printing

3D printing of fiber-reinforced composites has been receiving increasing attention as an efficient additive approach enabling lightweight, functional, and high-performance components required for industrial applications. The properties of fiber composites significantly depend on internal microstructures, including fiber orientation, distribution, and degree of alignment. Although multiple strategies have been introduced for controlling the fiber composites microstructures, these strategies are mostly active approaches relying on additional control of mechatronics parts, external forces, or intentionally introduced unstable flows inside narrow nozzles. These methods suffer from higher risk of nozzle clogging and requiring extra parts in 3D printing. Here, we introduce helicoid channels into extrusion system as a passive approach to control the fiber alignment without any additional moving parts in direct-write 3D printing. The helicoid channels automatically guide the composite inks and align fibers before flowing into narrow nozzle space, avoiding clogging and improving printability. The analyses indicate that both helicoid surface to volume ratio and helix angle affect the pre-alignment of fibers, leading to tunable mechanical properties of printed fiber-reinforced composites with increased stiffness and strength up to 77.6% and 47.8%, respectively.

36 MATERIALS SCIENCE↗

Sapphire reinforced alumina matrix composites

Unidirectionally reinforced A1203 matrix composites have been fabricated by hot pressing. Approximately 30 volume % of either coated or uncoated sapphire fiber was used as reinforcement. Unstabilized ZrO2 was applied as the fiber coating. Composite mechanical behavior was analyzed both after fabrication and after additional heat treatment. The results of composite tensile tests were correlated with fiber-matrix interfacial shear strengths determined from fiber push-out tests. Substantially higher strength and greater fiber pull-out were observed for the coated fiber composites for all processing conditions studied. The coated fiber composites retained up to 95% and 87% of their as-fabricated strength when heat treated at 14000C for 8 or 24 hours, respectively. Electron microscopy analysis of the fracture surfaces revealed extensive fiber pull-out both before and after heat treatment.

Jaskowiak, Martha H.↗

Molecular Dynamics Modeling of Carbon Nanotube Composite Fracture Using ReaxFF

Carbon nanotube (CNT) fiber reinforced composites with specific tensile strengths and moduli approaching those of aerospace grade carbon fiber composites have recently been reported. This achievement was enabled by the emerging availability of high N/tex yarns in kilometer-scale quantities. While the production of this yarn is an impressive advance, its strength is still much lower than that of the individual CNTs comprising the yarn. Closing this gap requires understanding load transfer between CNTs at the nanometer dimensional scale. This work uses reactive molecular dynamics simulations to gain an understanding at the nanometer scale of the key factors that determine CNT nanocomposite mechanical performance, and to place more realistic upper bounds on the target properties. While molecular dynamics simulations using conventional force fields can predict elastic properties, the ReaxFF reactive forcefield can also model fracture behavior because of its ability to accurately describe bond breaking and formation during a simulation. The upper and lower bounds of CNT composite properties are investigated by comparing systems composed of CNTs continuously connected across the periodic boundary with systems composed of finite length CNTs. These lengths, effectively infinite for the continuous tubes and an aspect ratio of 13 for the finite length case, result from practical limitations on the number of atoms that can be included in a simulation. Experimentally measured aspect ratios are typically on the order of 100,000, so the calculated results should represent upper and lower limits on experimental mechanical properties. Finally, the effect of various degrees of covalent crosslinking between the CNTs and amorphous carbon matrix is considered to identify the amount of CNT-matrix covalent bonding that maximizes overall composite properties.

Jensen, Benjamin D.↗

One-step Tape Casting of Composites via Slurry on Fiber

A process by which metal matrix composites can be made was presented. The process involves putting a powder slurry on fibers to make a precursor green tape. These green tapes are cut, stacked and hot pressed to form the fully dense composite. A computer program was presented which enables complete quantification and control of the process. Once some easily obtained properties of the slurry and its behavior are determined (such as the shrinkage from the wet to green state, and the density of the green tape) modification of the fiber spacing and blade height give the maker precise control of fiber volume fraction, and fiber architecture in the composite. The process was shown to be accurate and flexible through the production of a wide variety of volume fraction fiber composites made from a wide variety of fibers and powders. The most time consuming step of the tape casting process (other than hot pressing) was winding the fiber on the drum. The tape casting techniques developed resulted in high quality metal matrix composites, with ultimate tensile strength in the range of 215 ksi (1477 MPa), a strain at failure of 1.15 percent, and in fatigue at room temperature 0 to 120 ksi, n = 0.3 Hz, a 4-ply Ti-24Al-11Nb/SCS-6, 32 vol% fiber tape cast composite lasted 202,205 cycles with a maximum strain on the 100th cycle of 0.43 percent.

deGroh, Henry C., III↗

Thermal-conductivity measurements of tungsten-fiber-reinforced superalloy composites using a thermal-conductivity comparator

The thermal conductivity (TC) of tungsten-fiber-reinforced superalloys was determined for two composite systems by using a thermal conductivity standard from the National Bureau of Standards and a comparator and technique developed for that purpose. The results were compared with TC data for the nickel-base alloy MAR-M200. The technique lends itself to applications involving thin specimens, such as thin-walled turbine blades. The TC's of the composite systems were considerably higher in both the longitudinal and transverse directions than that of the monolithic superalloys used as the matrices.

Westfall, L. J.↗

Elucidating the impact of fiber source on polypropylene/hemp composite performance for the automotive industry

Given their high strength-to-weight ratio, there is an ever-increasing volume of plastics being used in the automotive industry as plastics aid in the charge to lightweight vehicles for improved fuel efficiency. However, these plastics are often landfilled at their end-of-life, which has given rise to the demand for sustainable materials and waste management alternatives compared to purely synthetic systems. Natural fiber composites have been explored as a viable material option to reduce the environmental impact of plastic use in automobiles while simultaneously ensuring the part performance is not sacrificed. Herein, we explored the use of hemp/polypropylene (PP) composites in which US-sourced hemp is compared to internationally sourced and industrially available hemp. There appears to be a minimal impact on the composite properties regardless of fiber sourcing, and the addition of a natural filler to the PP matrix results in up to a 367% increase in Young's modulus, 126% increase in heat deflection temperature, and comparable water uptake performance. It should be noted that the natural filler addition does increase density by up to 13% due to the higher density of natural fibers compared to the low-density PP matrix. A modified rule of mixtures calculation revealed that the composite materials produced in this study demonstrated good agreement with analytical modeling. Finally, a screening analysis was performed exploring the transportation of hemp fibers, and the results build a strong case for regionalized manufacturing of automotive parts.

Hubbard, Amber M. [Oak Ridge National Laboratory (↗

An Advanced Meso-Scale Peridynamic Modeling Technology using High-Performance Computing for Cost-Effective Product Design and Testing of Carbon Fiber Reinforced Polymer Composites in Light-weight Vehicles

We study a peridynamic composite modeling technology based on the discontinuous Galerkin finite element method, implemented in the commercial LS-DYNA software, for modeling and prediction of failure in carbon fiber reinforced polymer composites. The proposed technology is developed for the material failure analysis at the meso-scale, which provides the prevailing fiber-matrix interaction mechanism, without adoption of the representative volume element method and thus avoiding complicated numerical calibration procedures. Three types of experimental tests—in-plane coupon test, out-of-plane coupon test, and a component crash test—are simulated in a high-performance computing environment to assess the performance of the proposed peridynamic composite modeling technology.

36 MATERIALS SCIENCE↗

Film/Adhesive Processing Module for Fiber-Placement Processing of Composites

An automated apparatus has been designed and constructed that enables the automated lay-up of composite structures incorporating films, foils, and adhesives during the automated fiber-placement process. This apparatus, denoted a film module, could be used to deposit materials in film or thin sheet form either simultaneously when laying down the fiber composite article or in an independent step.

Hulcher, A. Bruce↗

Determining Fiber Orientation in Graphite-Reinforced Composites

Orientation of fibers in graphite-fiber-reinforced plastics easily determined with new method. Materials scientists thus ensure that fibers, usually not visible after graphite/plastic composite has been cured, properly oriented in test specimens and test results accurately represent the characteristics of composite. Method based on fact that continuous graphite fibers embeded in cured polymer matrix actually parallel conductors. Thus, resistance measured across laminate is at minimum when probes of ohmmeter connected to opposite ends of fibers.

Daniels, J. G.↗

Moisture effects on the high-temperature strength of fiber-reinforced resin composites.

Under NAS 8-27435, the Convair Aerospace Division of General Dynamics and their subcontractor, Hercules Incorporated, have conducted studies on the effects of moisture on the properties of fiber-reinforced resin composites and on the epoxy resins presently used in advanced composites. Data are presented on the resins and composites subjected to varying time/temperature/humidity or time/temperature/water-boil exposures. The effects of moisture on matrix, reinforcement, and fiber/resin interface are discussed and supported by experimental test data.

Hertz, J.↗

Environmental Aging of Scotch-Weld(TradeMark) AF-555M Structural Adhesive in Composite to Composite Bonds

Fiber reinforced resin matrix composites have found increased usage in recent years. Due to the lack of service history of these relatively new material systems, their long-term aging performance is not well established. In this study, adhesive bonds were prepared by the secondary bonding of Scotch-Weld(TradeMark) AF-555M between pre-cured adherends comprised of T800H/3900-2 uni-directional laminate. The adherends were co-cured with wet peel-ply for surface preparation. Each bond-line of single-lap-shear (SLS) specimen was measured to determine thickness and inspected visually for voids. A three-year environmental aging plan for the SLS specimens at 82 C and 85% relative humidity was initiated. SLS strengths were measured for both controls and aged specimens at room temperature and 82 C. The aging results of strength retention and failure modes to date are reported.

Hou, Tan-Hung↗

Rate dependent constitutive models for fiber reinforced polymer composites

A literature survey was conducted to assess the state-of-the-art in rate dependent constitutive models for continuous fiber reinforced polymer matrix composite (PMC) materials. Several recent models which include formulations for describing plasticity, viscoelasticity, viscoplasticity, and rate-dependent phenomenon such as creep and stress relaxation are outlined and compared. When appropriate, these comparisons include brief descriptions of the mathematical formulations, the test procedures required for generating material constants, and details of available data comparing test results to analytical predictions.

Gates, Thomas S.↗