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At least 1,279 records · Page 71
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

NEUTRON-CAPTURE ELEMENT ABUNDANCES IN MAGELLANIC CLOUD PLANETARY NEBULAE

We present near-infrared spectra of 10 planetary nebulae (PNe) in the Large and Small Magellanic Clouds (LMC and SMC), acquired with the FIRE and GNIRS spectrometers on the 6.5 m Baade and 8.1 m Gemini South Telescopes, respectively. We detect Se and/or Kr emission lines in eight of these objects, the first detections of n -capture elements in Magellanic Cloud PNe. Our abundance analysis shows large s -process enrichments of Kr (0.6–1.3 dex) in the six PNe in which it was detected, and Se is enriched by 0.5–0.9 dex in five objects. We also estimate upper limits to Rb and Cd abundances in these objects. Our abundance results for the LMC are consistent with the hypothesis that PNe with 2–3 M {sub ⊙} progenitors dominate the bright end of the PN luminosity function in young gas-rich galaxies. We find no significant correlations between s -process enrichments and other elemental abundances, central star temperature, or progenitor mass, though this is likely due to our small sample size. We determine S abundances from our spectra and find that [S/H] agrees with [Ar/H] to within 0.2 dex for most objects, but is lower than [O/H] by 0.2–0.4 dex in some PNe, possibly due to O enrichment via third dredge-up. Our results demonstrate that n -capture elements can be detected in PNe belonging to nearby galaxies with ground-based telescopes, allowing s -process enrichments to be studied in PN populations with well-determined distances.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

High Order Finite Difference Methods with Subcell Resolution for Stiff Multispecies Discontinuity Capturing

Here, we extend the high order finite-difference method with subcell resolution (SR) in [34] for two-species stiff one-reaction models to multispecies and multireaction inviscid chemical reactive flows, which are significantly more difficult because of the multiple scales generated by different reactions. For reaction problems, when the reaction time scale is very small, the reaction zone scale is also small and the governing equations become very stiff. Wrong propagation speed of discontinuity may occur due to the underresolved numerical solution in both space and time. The present SR method for reactive Euler system is a fractional step method. In the convection step, any high order shock-capturing method can be used. In the reaction step, an ODE solver is applied but with certain computed flow variables in the shock region modified by the Harten subcell resolution idea. Several numerical examples of multispecies and multireaction reactive flows are performed in both one and two dimensions. Studies demonstrate that the SR method can capture the correct propagation speed of discontinuities in very coarse meshes.

65M06↗
NASA NTRS2011

Multi-Body Capture to Low-altitude Circular Orbits at Europa

For capture to a 200-km circular orbit around Europa, millions of different points along the orbit are simulated in the Jupiter-Europa Restricted 3-Body Problem. The transfers exist as members of families of trajectories, where certain families consistently outperform the others. The trajectories are not sensitive to changes in inclination for the final circular orbit. The top performing trajectories appear to follow the invariant manifolds of L2 Lyapunov orbits for capture into a retrograde orbit, and in some cases saving up to 40% of the from the patched 2-body problem. Transfers are attached to the current nominal mission for NASA's Jupiter-Europa Orbiter, where the total cost is roughly 100 m/s less than the baseline mission.

Jupiter-Europa Orbiter (JEO)↗
DOE OSTI2014

Advanced computational tools for optimization and uncertainty quantification of carbon capture processes

Advanced multi-scale modeling and simulation has the potential to dramatically reduce development time, resulting in considerable cost savings. The Carbon Capture Simulation Initiative (CCSI) is a partnership among national laboratories, industry and universities that is developing, demonstrating, and deploying a suite of multi-scale modeling and simulation tools. One significant computational tool is FOQUS, a Framework for Optimization and Quantification of Uncertainty and Sensitivity, which enables basic data submodels, including thermodynamics and kinetics, to be used within detailed process models to rapidly synthesize and optimize a process and determine the level of uncertainty associated with the resulting process. The overall approach of CCSI is described with a more detailed discussion of FOQUS and its application to carbon capture systems.

Carbon capture↗
DOE OSTI2015

Gamma-Ray Emission Spectra as a Constraint on Calculations of 234,236,238 U Neutron-Capture Cross Sections

Neutron capture cross sections in the “continuum” region (>≈1 keV) and gamma-emission spectra are of importance to basic science and many applied fields. Careful measurements have been made on most common stable nuclides, but physicists must rely on calculations (or “surrogate” reactions) for rare or unstable nuclides. Calculations must be benchmarked against measurements (cross sections, gamma-ray spectra, and <Γ γ >). Gamma-ray spectrum measurements from resolved resonances were made with 1 - 2 mg/cm 2 thick targets; cross sections at >1 keV were measured using thicker targets. The results show that the shape of capture cross section vs neutron energy is not sensitive to the form of the strength function (although the magnitude is); the generalized Lorentzian E1 strength function is not sufficient to describe the shape of observed gamma-ray spectra; MGLO + “Oslo M1” parameters produces quantitative agreement with the measured 238 U(n,γ) cross section; additional strength at low energies (~ 3 MeV) -- likely M1-- is required; and careful study of complementary results on low-lying giant resonance strength is needed to consistently describe observations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2017

Hybrid Encapsulated Ionic Liquids for Post-Combustion Carbon Dioxide (CO 2 ) Capture

Ionic liquids (ILs) and Phase Change Ionic Liquids (PCILs) are excellent materials for selective removal of carbon dioxide from dilute post-combustion streams. However, they are typically characterized as having high viscosities, which impairs their effectiveness due to mass transfer limitations, caused by the high viscosities. In this project, we are examining the benefits of encapsulating ILs and PCILs in thin polymeric shells to produce particles of approximately 100 to 600 µm in diameter that can be used in a fluidized bed absorber. The particles are produced by microencapsulation of the ILs and PCILs in CO 2 -permeable polymer shells. Here we report on the encapsulation of the IL and PCIL materials, thermodynamic testing of the encapsulated materials, mass transfer measurements in both a fluidized bed and a packed bed, determination of the effect of impurities (SO 2 , NO x and water) on the free and encapsulated IL and PCIL, recyclability of the CO 2 uptake, selection and synthesis of kg quantities of the IL and PCIL, identification of scale-up methods for encapsulation and production of a kg quantity of the PCIL, construction and shakedown of the laboratory scale unit to test the encapsulated particles for CO 2 capture ability and efficiency, use of our mass transfer model to predict mass transfer and identify optimal properties of the encapsulated particles, and initial testing of the encapsulated particles in the laboratory scale unit. We also show our attempts at developing shell materials that are resistant to water permeation. Overall, we have shown that the selected IL and PCIL can be successfully encapsulated in polymer shells and the methods scaled up to production levels. The IL/PCIL and encapsulated IL/PCIL react irreversibly with SO 2 and NO x so the CO 2 capture unit would need to be placed after the flue gas desulfurization and NO x reduction units. However, the reaction with CO 2 in the presence of water is completely reversible. Therefore, it is not necessary to exclude water from the capsules. Mass transfer in the fluidized and packed beds confirm that the fluidized bed arrangement is preferred and that the mass transfer can be predicted accurately by the rate based model that we have developed. Absorption and desorption experiments in the laboratory scale unit show good uptake and recyclability.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Amine-incorporated porous polymer networks (PPNs) as sorbents for post-combustion CO2 capture

The Zhou group has long been interested in the development of CO2 capture sorbents, having investigated both metal-organic frameworks (MOFs) and porous polymer networks (PPNs). In this work, we have begun an investigation of a new generation of PPN based sorbents. These PPN sorbents are low cost alternatives to expensive MOF sorbents, while achieving the low heats of adsorption necessary for economic CO2 capture.

post-combustion carbon capture, porous polymer net↗
DOE OSTI2022

Promoting Domestic and International Consensus - Program Area 1: Carbon Capture & Storage & Clean Energy Systems

This is the Final Report for the U.S. Department of Energy Cooperative Agreement DE-FE-0024159, Promoting Domestic and International Consensus on Fossil Energy Technologies: Carbon Capture and Storage and Clean Energy Systems carried out by the United States Energy Association. It is a compendium of each quarterly report submitted over the 7-year period of the agreement accounting for all accomplishments, including major activities, significant results, major findings or conclusions, key outcomes or other achievements. Changes in approach or aims, and reasons for those changes, are included as well as any problems or delays and actions taken and planned to resolve them. It also summarizes budget statuses and any changes in key personnel throughout the life of the agreement. Originally planned for 5 years, the agreement was extended twice through back-to-back no-cost extensions, one to enable full completion of tasks critical to the program’s success and the other due to the Covid-19 Pandemic. The goals of the program were to provide increased knowledge regarding Carbon, Capture, and Storage (CCS) and Clean Energy Systems (CES) to Industry and Government decision makers, technology developers, educators, policymakers, environmental and other stakeholders, and the public by sharing research, technologies, and best practices with domestic and international partners. Increasing such knowledge was key to the other goals of the program of building of a broad consensus among domestic and international decision makers, stakeholders, and the public to take action to support and implement CCS and CES technologies and systems to ensure clean, secure, and affordable energy while enhancing environmental protection. The program accomplished these goals through a series of activities including hosting of conferences and workshops, in-person briefings, virtual webinars, reports and white papers, and keeping stakeholders informed of industry happenings through email distribution lists. It is the belief of the authors of this report, that these activities can be considered to have been successful in their goals.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2012

An early deployment strategy for carbon capture, utilisation, and storage

This report describes the current use of CO2 for EOR, and discusses potential expansion of EOR using CO2 from power plants. Analysis of potential EOR development in the USA, where most current CO2-based EOR production takes place, indicates that relatively low cost, traditional sources of CO2 for EOR (CO2 domes and CO2 from natural gas processing plants) are insufficient to exploit the full potential of EOR. To achieve that full potential will require use of CO2 from combustion and gasification systems, such as fossil fuel power plants, where capture of CO2 is more costly. The cost of current CCUS systems, even with the revenue stream for sale of the CO2 for EOR, is too high to result in broad deployment of the technology in the near term. In the longer term, research and development may be sufficient to reduce CO2 capture costs to a point where CCUS would be broadly deployed. This report describes a case study of conditions in the USA to explore a financial incentive to promote early deployment of CCUS, providing a range of immediate benefits to society, greater likelihood of reducing the long-term cost of CCUS, and greater likelihood of broad deployment of CCUS and CCS in the long term. Additionally, it may be possible to craft such an incentive in a manner that its cost is more than offset by taxes flowing from increased domestic oil production. An example of such an incentive is included in this report.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2025

Techno-Economic Analysis of Sorbent-Based Direct Air Capture Informed by EPC Input and Recent Technological Advancements

Direct air capture (DAC) technology has been developing at an accelerated rate. Independent, comprehensive, and transparent techno-economic analyses (TEAs) of DAC technologies are required to inform future development. NETL is publishing an update to the 2022 sorbent-based DAC case study report. This manuscript highlights select TEA results that will be presented in the upcoming NETL report. The analysis considers three sorbent-based DAC system configurations (direct steam temperature swing, indirect steam temperature swing, and direct steam temperature/vacuum swing) and two scenarios for providing the required electricity and steam (stand-alone system with a combined heat and power plant generating the required steam and electricity, and a purchased power case utilizing an electric boiler). Detailed sensitivity analyses are included and highlight the impact of external market factors, sorbent performance, and economies of scale. The potential for cost reductions by opting for temperature vacuum swing adsorption is highlighted. More detailed background and TEA results will be presented in the upcoming NETL report titled “Direct Air Capture Case Studies: Sorbent System (Revision 1)”.

carbon dioxide removal↗
DOE OSTI2018

Chlorophyll Fluorescence Better Captures Seasonal and Interannual Gross Primary Productivity Dynamics Across Dryland Ecosystems of Southwestern North America

Satellite remote sensing provides unmatched spatiotemporal information on vegetation gross primary productivity (GPP). Yet understanding of the relationship between GPP and remote sensing observations and how it changes with factors such as scale, biophysical constraint, and vegetation type remains limited. This knowledge gap is especially apparent for dryland ecosystems, which have characteristic high spatiotemporal variability and are under–represented by long–term field measurements. Here we utilize an eddy covariance (EC) data synthesis for southwestern North America in an assessment of how accurately satellite–derived vegetation proxies capture seasonal to interannual GPP dynamics across dryland gradients. We evaluate the enhanced vegetation index, solar–induced fluorescence (SIF), and the photochemical reflectivity index. We find evidence that SIF is more accurately capturing seasonal GPP dynamics particularly for evergreen–dominated EC sites and more accurately estimating the full magnitude of interannual GPP dynamics for all dryland EC sites. Furthermore, these results suggest that incorporation of SIF could significantly improve satellite–based GPP estimates.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Dry and Wet CO 2 Capture from Milk‐Derived Microporous Carbons with Tuned Hydrophobicity

Abstract Pore size distribution and surface chemistry of bio‐derived (milk) microporous dominated carbon “MDC” is synergistically tuned, allowing for promising carbon capture in a dry CO 2 atmosphere and in mixed H 2 O–CO 2 . The capture capacity is attributed to the synergy of a large total surface area with an ultramicroporous and microporous texture (e.g., S tot 1889 m 2 g −1 , S mic 1755 m 2 g −1 , S ultra 1393 m 2 g −1 ), and a high content of nitrogen and oxygen heteroatom moieties (e.g., 5 at% N, 10.5 at% O). Tailored two‐step low‐temperature pyrolysis‐chemical activation is employed to take advantage of the intrinsic properties of the precursor, allowing for this unusual textural properties‐heteroatoms combination. For example, tested at 1 bar and 295 or 273 K, MDCs adsorb up to 22.0 and 29.4 wt% CO 2 , respectively. MDCs are also tailored to be hydrophobic, with CO 2 /H 2 O adsorption selectivity even after prolonged cycling. Maximum working capacities of 10.8 wt% for pure CO 2 and 3.5 wt% for a flue gas simulant (15% CO 2 , 85% N 2 ) are measured using temperature swing adsorption with dynamic purge gases, while being minimally affected by humid conditions. This work is directly aligned with the United Nation’s Sustainable Development Goal 13, take urgent action to combat climate change and its impacts.

Pokrzywinski, Jesse↗
DOE OSTI2017

Capture and coding of industry and occupation measures: Findings from eight National Program of Cancer Registries states

Background Although data on industry and occupation (I&O) are important for understanding cancer risks, obtaining standardized data is challenging. This study describes the capture of specific I&O text and the ability of a web‐based tool to translate text into standardized codes. Methods Data on 62 525 cancers cases received from eight National Program of Cancer Registries (NPCR) states were submitted to a web‐based coding tool developed by the National Institute for Occupational Safety and Health for translation into standardized I&O codes. We determined the percentage of sufficiently analyzable codes generated by the tool. Results Using the web‐based coding tool on data obtained from chart abstraction, the NPCR cancer registries achieved between 48% and 75% autocoding, but only 12‐57% sufficiently analyzable codes. Conclusions The ability to explore associations between work‐related exposures and cancer is limited by current capture and coding of I&O data. Increased training of providers and registrars, as well as software enhancements, will improve the utility of I&O data.

Freeman, MaryBeth B.↗
DOE OSTI2017

Highly Efficient Carbon Monoxide Capture by Carbanion‐Functionalized Ionic Liquids through C‐Site Interactions

Abstract A novel method for the highly efficient and reversible capture of CO in carbanion‐functionalized ionic liquids (ILs) by a C‐site interaction is reported. Because of its supernucleophilicity, the carbanion in ILs could absorb CO efficiently. As a result, a relatively high absorption capacity for CO (up to 0.046 mol mol −1 ) was achieved under ambient conditions, compared with CO solubility in a commonly used IL [Bmim][Tf 2 N] (2×10 −3 mol mol −1 ). The results of quantum mechanical calculations and spectroscopic investigation confirmed that the chemical interaction between the C‐site in the carbanion and CO resulted in the superior CO absorption capacities. Furthermore, the subsequent conversion of captured CO into valuable chemicals with good reactivity was also realized through the alkoxycarbonylation reaction under mild conditions. Highly efficient CO absorption by carbanion‐functionalized ILs provides a new way of separating and converting CO.

Tao, Duan‐Jian↗
DOE OSTI2014

Easily Regenerable Solid Adsorbents Based on Polyamines for Carbon Dioxide Capture from the Air

Adsorbents prepared easily by impregnation of fumed silica with polyethylenimine (PEI) are promising candidates for the capture of CO2 directly from the air. These inexpensive adsorbents have high CO2 adsorption capacity at ambient temperature and can be regenerated in repeated cycles under mild conditions. Despite the very low CO2 concentration, they are able to scrub efficiently all CO2 out of the air in the initial hours of the experiments. The influence of parameters such as PEI loading, adsorption and desorption temperature, particle size, and PEI molecular weight on the adsorption behavior were investigated. The mild regeneration temperatures required could allow the use of waste heat available in many industrial processes as well as solar heat. CO2 adsorption from the air has a number of applications. Removal of CO2 from a closed environment, such as a submarine or space vehicles, is essential for life support. The supply of CO2-free air is also critical for alkaline fuel cells and batteries. Direct air capture of CO2 could also help mitigate the rising concerns about atmospheric CO2 concentration and associated climatic changes, while, at the same time, provide the first step for an anthropogenic carbon cycle.

Goeppert, A↗
DOE OSTI2023

High-Performance CO 2 Capture from Air by Harnessing the Power of CaO- and Superbase-Ionic-Liquid-Engineered Sorbents

Direct air capture (DAC) of CO 2 by solid porous materials represents an attractive “negative emission” technology. However, state-of-the-art sorbents based on supported amines still suffer from unsolved high energy consumption and stability issues. For this work, taking clues from the CO 2 interaction with superbase-derived ionic liquids (SILs), high-performance and tunable sorbents in DAC of CO 2 was developed by harnessing the power of CaO- and SIL-engineered sorbents. Deploying mesoporous silica as the substrate, a thin CaO layer was first introduced to consume the surface-OH groups, and then active sites with different basicities (e. g., triazolate and imidazolate) were introduced as a uniformly distributed thin layer. The as-obtained sorbents displayed high CO 2 uptake capacity via volumetric (at 0.4 mbar) and breakthrough test (400 ppm CO 2 source), rapid interaction kinetics, facile CO 2 releasing, and stable sorption/desorption cycles. Operando diffuse reflectance infrared Fourier transformation spectroscopy (DRIFTS) analysis under simulated air atmosphere and solid-state NMR under 13 CO 2 atmosphere demonstrated the critical roles of the SIL species in low-concentration CO 2 capture. The fundamental insights obtained in this work provide guidance on the development of high-performance sorbents in DAC of CO 2 by leveraging the combined advantages of porous solid scaffolds and the unique features of CO 2 -philic ionic liquids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Underlying Roles of Polyol Additives in Promoting CO2 Capture in PEI/Silica Adsorbents

Solid-supported amines having low molecular weight branched poly(ethylenimine) (PEI) physically impregnated into porous solid supports are promising adsorbents for CO2 capture. Co-impregnating short-chain poly(ethylene glycol) (PEG) together with PEI alters the performance of the adsorbent, delivering improved amine efficiency (AE, mol CO2 sorbed / mol N) and faster CO2 uptake rates. To uncover the physical basis for this improved gas capture performance, we probed the distribution and mobility of the polymers in the pores via small angle neutron scattering (SANS), solid-state NMR, and molecular dynamic (MD) simulation studies. SANS and MD simulations reveal that PEG displaces wall-bound PEI, making amines more accessible for CO2 sorption. Solid-state NMR and MD simulation suggest intercalation of PEG into PEI domains, separating PEI domains and reducing amine-amine interactions, providing potential PEG-rich and amine-poor interfacial domains that bind CO2 weakly via physisorption while providing facile pathways for CO2 diffusion. Contrary to a prior literature hypothesis, no evidence is obtained for PEG facilitating PEI mobility in solid supports. Instead, the data suggest that PEG chains coordinate to PEI, form larger bodies with reduced mobility compared to PEI alone. We also demonstrate promising CO2 uptake and desorption kinetics at varied temperatures, given by favorable amine distribution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗