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At least 1,279 records · Page 71

Accurate and reliable thermochemistry by data analysis of complex thermochemical networks using Active Thermochemical Tables: the case of glycine thermochemistry

Active Thermochemical Tables (ATcT) were successfully used to resolve the existing inconsistencies related to the thermochemistry of glycine, based on statistically analyzing and solving a thermochemical network that includes >3350 chemical species interconnected by nearly 35 000 thermochemically-relevant determinations from experiment and high-level theory. Here, the current ATcT results for the 298.15 K enthalpies of formation are −394.70 ± 0.55 kJ mol −1 for gas phase glycine, −528.37 ± 0.20 kJ mol −1 for solid α-glycine, −528.05 ± 0.22 kJ mol −1 for β-glycine, −528.64 ± 0.23 kJ mol −1 for γ-glycine, −514.22 ± 0.20 kJ mol −1 for aqueous undissociated glycine, and −470.09 ± 0.20 kJ mol −1 for fully dissociated aqueous glycine at infinite dilution. In addition, a new set of thermophysical properties of gas phase glycine was obtained from a fully corrected nonrigid rotor anharmonic oscillator (NRRAO) partition function, which includes all conformers. Corresponding sets of thermophysical properties of α-, β-, and γ-glycine are also presented.

Active Thermochemical Tables↗

The triple binary star EQ Tau with an active component

New photometric data of EQ Tau observed in 2010 and 2013 are presented. Light curves obtained in 2000 and 2004 by Yuan and Qian and 2001 by Yang and Liu, together with our two newly determined sets of light curves, were analyzed using the Wilson-Devinney code. The five sets of light curves exhibit very obvious variations, implying that the light curves of EQ Tau show a strong O'Connell effect. We found that EQ Tau is an A-type shallow contact binary with a contact degree of f = 11.8%; variable dark spots on the primary component of EQ Tau were also observed. Using 10 new times of minimum light, together with those collected from the literature, the orbital period change of EQ Tau was analyzed. We found that its orbital period includes a secular decrease (dP/dt = –3.63 × 10{sup –8} days yr{sup –1}) and a cyclic oscillation (A {sub 3} = 0.0058 days and P {sub 3} = 22.7 yr). The secular increase of the period can be explained by mass transfer from the more massive component to the less massive one or/and angular momentum loss due to a magnetic stellar wind. The Applegate mechanism cannot explain the cyclic orbital period change. A probable transit-like event was observed in 2010. Therefore, the cyclic orbital period change of EQ Tau may be due to the light time effect of a third body.

79 ASTRONOMY AND ASTROPHYSICS↗

Identification of Program Signatures from Cloud Computing System Telemetry Data

Malicious cloud computing activity can take many forms, including running unauthorized programs in a virtual environment. Detection of these malicious activities while preserving the privacy of the user is an important research challenge. Prior work has shown the potential viability of using cloud service billing metrics as a mechanism for proxy identification of malicious programs. Previously this novel detection method has been evaluated in a synthetic and isolated computational environment. In this paper we demonstrate the ability of billing metrics to identify programs, in an active cloud computing environment, including multiple virtual machines running on the same hypervisor. The open source cloud computing platform OpenStack, is used for private cloud management at Pacific Northwest National Laboratory. OpenStack provides a billing tool (Ceilometer) to collect system telemetry measurements. We identify four different programs running on four virtual machines under the same cloud user account. Programs were identified with up to 95% accuracy. This accuracy is dependent on the distinctiveness of telemetry measurements for the specific programs we tested. Future work will examine the scalability of this approach for a larger selection of programs to better understand the uniqueness needed to identify a program. Additionally, future work should address the separation of signatures when multiple programs are running on the same virtual machine.

Nichols, Nicole M.↗

Solar Flare Activity from 2006 to 2016 according to Data from the PAMELA and ARINA Spectrometers

In the period from 2006 to 2016, experiments based on the use of the PAMELA and ARINA spectrometers and aimed at detecting cosmic rays were performed on board the RESURS-DK1 satellite. Although the main goal of these experiments was to study the galactic component of cosmic rays, the instruments in question also detected, over a broad energy range, solar particles accelerated in powerful explosive processes on the Sun (solar flares). A list of solar events in which the PAMELA and ARINA spectrometers detected, in various years of their operation, an increase in the intensities of fluxes of solar protons whose energies were above 45 MeV is presented among other things.

79 ASTRONOMY AND ASTROPHYSICS↗

Data for Reshaping the 2-Pyrone Synthase Active Site for Chemoselective Biosynthesis of Polyketides

Engineering enzymes with novel reactivity and applying them in metabolic pathways to produce valuable products are quite challenging due to the intrinsic complexity of metabolic networks and the need for high in vivo catalytic efficiency. Triacetic acid lactone (TAL), naturally generated by 2-pyrone synthase (2PS), is a platform molecule that can be produced via microbial fermentation and further converted into value-added products. However, these conversions require extra synthetic steps under harsh conditions. We herein report a biocatalytic system for direct generation of TAL derivatives under mild conditions with controlled chemoselectivity by rationally engineering the 2PS active site and then rewiring the biocatalytic pathway in the metabolic network of E. coli to produce high-value products, such as kavalactone precursors, with yields up to 17 mg/L culture. Computer modeling indicates sterics and hydrogen-bond interactions play key roles in tuning the selectivity, efficiency, and yield.

Conversion↗

State Spotlight on Resilience: The Michigan Public Service Commission and Data Informed Accountability

Resilience activities are an emerging area within regulatory utility policy. As resilience frameworks develop, many Public Utility Commissions (PUCs) are looking to initiate resilience activities and have identified enhancing grid reliability as a practical starting point. Reliability describes the grid’s ability to deliver electricity steadily and without interruptions under normal or “blue sky” conditions. Reliability is measured using industry standard metrics such as outage frequency (SAIFI) and outage duration (SAIDI). Resilience is broader, reflecting the grid’s ability to both withstand and recover from disruptions, particularly those caused by extreme events such as severe storms. A reliable grid minimizes routine disruptions; a resilient grid ensures the system can recover quickly when disruptions occur, preventing them from escalating into widespread or prolonged crises.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Living on a Flare: Relativistic Reflection in V404 Cyg Observed by NuSTAR during Its Summer 2015 Outburst

We present first results from a series of NuSTAR observations of the black hole X-ray binary V404 Cyg obtained during its summer 2015 outburst, primarily focusing on observations during the height of this outburst activity. The NuSTAR data show extreme variability in both the flux and spectral properties of the source. This is partly driven by strong and variable line-of-sight absorption, similar to previous outbursts. The latter stages of this observation are dominated by strong flares, reaching luminosities close to Eddington. During these flares, the central source appears to be relatively unobscured and the data show clear evidence for a strong contribution from relativistic reflection, providing a means to probe the geometry of the innermost accretion flow. Based on the flare properties, analogies with other Galactic black hole binaries, and also the simultaneous onset of radio activity, we argue that this intense X-ray flaring is related to transient jet activity during which the ejected plasma is the primary source of illumination for the accretion disk. If this is the case, then our reflection modeling implies that these jets are launched in close proximity to the black hole (as close as a few gravitational radii), consistent with expectations for jet launching models that tap either the spin of the central black hole, or the very innermost accretion disk. Our analysis also allows us to place the first constraints on the black hole spin for this source, which we find to be a{sup ∗}>0.92 (99% statistical uncertainty, based on an idealized lamp-post geometry).

79 ASTRONOMY AND ASTROPHYSICS↗

NSSFC: VAS assessment activities

Vertical atmospheric sounder data were evaluated. Basic work thus far has been directed toward evaluating, over the in near real time to determine the instrument's ability to detect regions with potential for severe storm development. A real time hourly water vapor loop 16 hours daily provides data to monitor position and trends of mid and upper level meteorological features. Because water vapor is more uniform than clouds, the water vapor images improve the ability to monitor certain atmospheric features such as jets, shortwaves, vorticity centers, and subsidence zones. Additional products to be evaluated include a version of the split window developed by NASA and cloud drift winds generated from three hourly sequenced CO2 VAS channels. A technique also under evaluation at NSSFC provides hail size potential based on VAS sounding data. Part of a planned upgrade to CSIS linking the 9600 baud phone line to one of the CSIS CPUs to allow access to VAS data via CSIS.

Anthony, R. W.↗

The interpretation of crustal dynamics data in terms of plate interactions and active tectonics of the Anatolian Plate and surrounding regions in the Middle East

The primary effort in this study during the past year has been directed along two separate lines: (1) expanding finite element models to include the entire Anatolian plate, the Aegean Sea and the Northeastern Mediterranean Sea, and (2) investigating the relationship between fault geometry and earthquake activity for the North Anatolian and similar strike-slip faults (e.g., San Andreas Fault). Both efforts are designed to provide an improved basis for interpreting the Crustal Dynamics measurements NASA has planned for this region. The initial phases of both investigations have been completed and the results are being prepared for publication. These investigations are described briefly.

Toksoz, M. Nafi↗

The interpretation of crustal dynamics data in terms of plate interactions and active tectonics of the Anatolian Plate and surrounding regions in the Middle East

The long term objective of this project is to interpret NASA's Crustal Dynamics measurements (SLR) in the Eastern Mediterranean region in terms of relative plate motions and intraplate deformation. The approach is to combine realistic modeling studies with an analysis of available geophysical and geological observations to provide a framework for interpreting NASA's measurements. This semi-annual report concentrates on recent results regarding the tectonics of Anatolia and surrounding regions from ground based observations. Also briefly reported on is progress made in using GPS measurements to densify SLR observations in the Eastern Mediterranean.

Toksoz, M. Nafi↗

IRAS observations of active galactic nuclei

IRAS data has been analyzed for 35 radio galaxies and 42 radio-loud quasars, using the coadded survey database. The detection rate is 50 percent with more than 40 percent detected in more than one band. Quasars generally have smooth energy spectra over four or five decades in frequency, consistent with incoherent synchrotron emission from 1 cm to 1 micron. Radio galaxies by contrast have discontinuous spectra, with a large range in the spectral index at IRAS wavelengths. The energy budget shows that the majority of the power per unit bandwidth emerges in the infrared (1-100 microns). The fraction of bolometric luminosity emitted in the infrared is 20-30 percent for the quasars and 40-60 percent for the radio galaxies.

Impey, Chris↗

The interpretation of crustal dynamics data in terms of plate interactions and active tectonics of the Anatolian Plate and surrounding regions in the Middle East

The long-term objective of this project is to interpret NASA's Crustal Dynamics measurements (SLR) in the Eastern Mediterranean region in terms of relative plate movements and intraplate deformation. The approach is to combine realistic modeling studies with analysis of available geophysical and geological observations to provide a framework for interpreting NASA's measurements. This semi-annual report concentrates on recent results regarding the tectonics of Anatolia and surrounding regions from ground based observations. Also reported on briefly is progress in the use of the Global Positioning System to densify SLR observations in the Eastern Mediterranean. Reference is made to the previous annual report for a discussion of modeling results.

Toksoz, M. Nafi↗

The Interpretation of Crustal Dynamics Data in Terms of Plate Interactions and Active Tectonics of the Anatolian Plate and Surrounding Regions in the Middle East

During the past 6 months, efforts were concentrated on the following areas: (1) Continued development of realistic, finite element modeling of plate interactions and associated deformation in the Eastern Mediterranean; (2) Neotectonic field investigations of seismic faulting along the active fault systems in Turkey with emphasis on identifying seismic gaps along the North Anatolian fault; and (3) Establishment of a GPS regional monitoring network in the zone of ongoing continental collision in eastern Turkey (supported in part by NSF).

Toksoz, M. Nafi↗

CDDIS Support of IGS LEO Activities

The Crustal Dynamics Data Information System (CDDIS) has served as a global data center for the International GPS Service (IGS) since its start in June 1992, providing on-line access to data from over 175 sites on a daily and hourly basis. This paper will present an overview about the current status of the CDDIS GPS data and products archive with a look to the future support of LEO (Low Earth Orbiting missions), including the archive of high-rate data and on-board GPS receiver data.

Noll, Carey E.↗