Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Polar system modeling”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,279 records · Page 71

A Microphysically-based Approach to Inferring Porosity, Grain Size, and Dust Abundance in the Seasonal Caps from Atmospherically-corrected TES Spectra

One of the highlights of the TES observations in the polar regions has been the identification of a "cryptic" region in the south where CO2 appears to be in the form of a solid slab rather than a fluffy frost. While the exact mechanism(s) by which the cryptic region is formed are still subject of some debate, it appears certain that a type of rapid metamorphism related to the high volatility of CO2 ice is involved. The high volatility of CO2 ice under martian conditions has several Solar System analogs (N2 on Triton and Pluto, SO2 on Io), thus making the martian cryptic region somewhat less cryptic and certainly non-unique among planetary objects. In an endmember scenario, both the formation and the spectral properties of the cryptic region (and of other areas in the seasonal caps) can be quantitatively modeled by considering sintering of an ensemble of quasi-spherical CO2 grains. This model includes the special case of instanteneous slab formation, which occurs when the grains are sufficiently small (in the submicron range) so that their sintering timescale is short relative to the deposition timescale (a situation analogous to the "sintering" of water droplets falling into a pond).

Eluszkiewicz, J.↗

Deactivating Emission in Azulene via Solvent-Induced (Anti)Aromaticity

Anti-Kasha emission is a coveted feature in optoelectronics, with promise in areas such as imaging, sensing, and the production of white-light LEDs via dual-photon emission. Despite being a rare feature in organic systems, anti-Kasha emission is readily observed in the deceptively simple molecule azulene, which possesses two bright singlet states in the UV–visible spectrum and readily emits from the S 2 state. With dominant anti-Kasha emission and decades of synthetic study, azulene is a perfect candidate for novel material fabrication; however, large gaps persist in understanding the photophysics of even the simple parent compound. These range from competing, experimentally unverified models of azulene reactivity and aromaticity to the unexplained deactivation of anti-Kasha emission in a host of azulene derivatives. Herein, we use fluorescence and transient absorption spectroscopies to explore the detailed solvent dependence of azulene photophysics. We discover a tunable reduction in the S 2 lifetime via weak complexation with aromatic solvents. Interestingly, our results are independent of polarity, highlighting the primacy of peripherally delocalized 10-π Hückel aromaticity over zwitterionic character. When the dipolar character is enhanced through chemical functionalization, we observe even greater sensitivity to solvent aromaticity and more rapid quenching, revealing the role of conical intersections in azulenes with zwitterionic excited states. Overall, this work provides essential mechanistic insight into the photophysics of azulene and reveals a simple new approach to control the excited-state aromaticity and anti-Kasha emission in this class of materials.

Absorption↗

An illustration of the complexity of continent formation

It was pointed out that a consensus may be emerging in crustal growth models, considering the clustering of most growth curves and their uncertainties. Curves most distant from this clustering represent models involving extensive recycling of continental material back into the mantle, but the author wondered if geochemical signatures for this would be recognizable considering the lack of evidence from seismic tomography for discrete mantle reservoirs, and the likelihood of core-mantle interaction based on recent high pressure experiments. Unreactivated Archean rocks represent only 2 percent of present continental area, and the author was uncomfortable about basing inferences on what the early Earth was like on such a small amount of information. He feels that the hypothesis of continental assembly that needs testing is that of banging together of island arcs, such as in Indonesia today. As an example of how complex this process can be, the author described the geology of the Caribbean arc system, which shows evidence for reversals of subduction polarity, numerous collisional events, and substantial strike-slip movements. It seemed unlikely to the author that Archean examples would have been less complicated.

Burke, Kevin↗

Lunar Scout Two spacecraft gravity experiment

Measurement of the gravity field of the Moon has a high science priority because of its implications for the internal structure and thermal history of the Moon, and it has a high priority for future exploration activities because of the influence of lunar gravity on spacecraft navigation and orbit maintenance. The current state of knowledge in the lunar gravity field (and the uncertainty in the knowledge) is based primarily on data accumulated from the Lunar Orbiter and Apollo programs. Data are sparse and emphasize the equatorial band (+/- 30 deg) on the near side of the Moon. There are no tracking data on the far side and only the Lunar Orbiter 5 provides a small amount of high inclination data. A host of gravity models developed from different combinations of tracking data have large discrepancies in their predictions of spacecraft motion and orbit lifetimes. There are also large disagreements in the Mercator projections of the gravity acceleration from each model, especially on the far side, where the contours tend to have no obvious relationship with the local topography. The science and engineering requirements for global gravity field mapping will be satisfied with continuous radio metric tracking of Lunar Scout 1 in a low polar orbit using the Deep Space Network and Lunar Scout 2 in a high elliptical orbit. The gravity field of the Moon will be mapped during the Scout Program using a two spacecraft concept. In the two spacecraft concept, one spacecraft is placed in a high altitude eccentric orbit while the second spacecraft is in a low altitude polar orbit. The gravity experiment requires a radio frequency that will permit two-way Doppler tracking between the spacecraft and the Deep Space Network (DSN). Both spacecraft carry NASA standard transponder systems for data transmission to Earth as well as for tracking and orbit determination. Data sufficient to produce a gravity field map could be acquired within one month with this system.

Cheng, Andrew F.↗

Transonic Dynamics Tunnel Force and Pressure Data Acquired on the HSR Rigid Semispan Model

This report describes the aerodynamic data acquired on the High Speed Research Rigid Semispan Model (HSR-RSM) during NASA Langley Transonic Dynamics Tunnel (TDT) Test 520 conducted from 18 March to 4 April, 1996. The purpose of this test was to assess the aerodynamic character of a rigid high speed civil transport wing. The wing was fitted with a single trailing edge control surface which was both steadily deflected and oscillated during the test to investigate the response of the aerodynamic data to steady and unsteady control motion. Angle-of-attack and control surface deflection polars at subsonic, transonic and low-supersonic Mach numbers were obtained in the tunnel?s heavy gas configuration. Unsteady pressure and steady loads data were acquired on the wing, while steady pressures were measured on the fuselage. These data were reduced using a variety of methods, programs and computer systems. The reduced data was ultimately compiled onto a CD-ROM volume which was distributed to HSR industry team members in July, 1996. This report documents the methods used to acquire and reduce the data, and provides an assessment of the quality, repeatability, and overall character of the aerodynamic data measured during this test.

Schuster, David M.↗

Weather Prediction Improvement Using Advanced Satellite Technology

We discuss in this paper some of the problems that exist today in the fall utilization of satellite data to improve weather forecasts and we propose specific recommendations to solve them. This discussion can be viewed as an aspect of the general debate on how best to organize the transition from research to operational satellites and how to evaluate the impact of a research instrument on numerical weather predictions. A method for providing this transition is offered by the National Polar-Orbiting Operational Environmental Satellite System (NPOESS) Preparatory Project (NPP). This mission will bridge the time between the present NOAA and Department of Defense (DOD) polar orbiting missions and the initiation of the converged NPOESS series and will evaluate some of the Earth Observing System (EOS) instruments as appropriate for operational missions. Thus, this mission can be viewed as an effort to meet the operational requirements of NOAA and DOD and the research requirements of NASA. More generally, however, it can be said that the process of going from the conception of new, more advanced instruments to their operational implementation and full utilization by the weather forecast communities is not optimal. Instruments developed for research purposes may have insufficient funding to explore their potential operational capabilities. Furthermore, instrument development programs designed for operational satellites typically have insufficient funding for assimilation algorithms needed to transform the satellite observations into data that can be used by sophisticated global weather forecast models. As a result, years often go by before satellite data are efficiently used for operational forecasts. NASA and NOAA each have unique expertise in the design of satellite instruments, their use for basic and applied research and their utilization in weather and climate research. At a time of limited resources, the two agencies must combine their efforts to work toward common goals of full utilization of satellite data. This is a challenge that requires the assimilation of myriad new data into increasingly sophisticated numerical forecast models that run on increasingly sophisticated computer systems. In section II, we briefly outline the impact of satellite data on the quality of the National Centers for Environmental Prediction (NCEP) forecasts. In section III, we describe the present status of the utilization of satellite data in NCEP models and the challenges that lie ahead. In section IV, we propose solutions whose goals are summarized in section V.

Einaudi, Franco↗

Overview of NASA's Carbon Monitoring System Flux-Pilot Project

NASA's space-based observations of physical, chemical and biological parameters in the Earth System along with state-of-the-art modeling capabilities provide unique capabilities for analyses of the carbon cycle. The Carbon Monitoring System is developing an exploratory framework for detecting carbon in the environment and its changes, with a view towards contributing to national and international monitoring activities. The Flux-Pilot Project aims to provide a unified view of land-atmosphere and ocean-atmosphere carbon exchange, using observation-constrained models. Central to the project is the application of NASA's satellite observations (especially MODIS), the ACOS retrievals of the JAXA-GOSAT observations, and the "MERRA" meteorological reanalysis produced with GEOS-S. With a primary objective of estimating uncertainty in computed fluxes, two land- and two ocean-systems are run for 2009-2010 and compared with existing flux estimates. An transport model is used to evaluate simulated CO2 concentrations with in-situ and space-based observations, in order to assess the realism of the fluxes and how uncertainties in fluxes propagate into atmospheric concentrations that can be more readily evaluated. Finally, the atmospheric partial CO2 columns observed from space are inverted to give new estimates of surface fluxes, which are evaluated using the bottom-up estimates and independent datasets. The focus of this presentation will be on the science goals and current achievements of the pilot project, with emphasis on how policy-relevant questions help focus the scientific direction. Examples include the issue of what spatio-temporal resolution of fluxes can be detected from polar-orbiting satellites and whether it is possible to use space-based observations to separate contributions to atmospheric concentrations of (say) fossil-fuel and biological activity

Pawson, Steven↗

Probing the antiknock effect of anisole through an ignition, speciation and modeling study of its blends with isooctane

In order to unravel the reaction pathways relevant to anisole co-oxidation within a fuel blend, a detailed study of isooctane/anisole blends was performed with the ULille RCM. Ignition delays as well as mole fraction profiles were measured during a two-stage ignition delay using sampling and GC techniques. These results are used to validate a kinetic model developed from ab initio calculations for the most relevant rate constants which included H-atom abstraction reactions from anisole, and reactions on the potential energy surfaces of methoxyphenyl + O 2 and anisyl + O 2 . Pressure dependent rate constants were computed for the methoxyphenyl + O 2 and anisyl + O 2 reactive systems using master equation code analysis. The new kinetic model shows good agreement with the experimental data. Dual brute-force sensitivity analysis was performed, on both first- and second-stages of ignition, allowing the identification of the most important reactions in the prediction of both ignition delays. It was observed that while pure anisole does not show NTC behavior, a 60/40 isooctane/anisole blend displays such behavior, as well as two-stage ignition. This suggests anisole addition may not be as beneficial to knock resistance as expected from its high octane number. The kinetic modeling results demonstrate the importance of H-abstraction reactions both from the methoxy group and from the aryl ring in ortho-position and the addition of the resultant radicals to O2, mostly leading to the formation of polar or non-aromatic products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Topological and nematic superconductivity mediated by ferro-SU(4) fluctuations in twisted bilayer graphene

We propose an SU(4) spin-valley-fermion model to investigate the superconducting instabilities of twisted bilayer graphene (TBG). In this approach, bosonic fluctuations associated with an emergent SU(4) symmetry, corresponding to combined rotations in valley and spin spaces, couple to the low-energy fermions that comprise the flat bands. These fluctuations are peaked at zero wave vector, reflecting the “ferromagnetic-like” SU(4) ground state recently found in strong-coupling solutions of microscopic models for TBG. Focusing on electronic states related to symmetry-imposed points of the Fermi surface, dubbed here “valley hot-spots” and “van Hove hot-spots,” we find that the coupling to the itinerant electrons partially lifts the huge degeneracy of the ferro-SU(4) ground state manifold, favoring intervalley order, spin-valley coupled order, ferromagnetic order, spin-current order, and valley-polarized order, depending on details of the band structure. Here, these fluctuations, in turn, promote attractive pairing interactions in a variety of closely competing channels, including a nodeless f-wave state, a nodal i-wave state, and topological d+id and p+ip states with unusual Chern numbers 2 and 4, respectively. Nematic superconductivity, although not realized as a primary instability of the system, appears as a consequence of the near-degeneracy of superconducting order parameters that transform as one-dimensional and two-dimensional irreducible representations of the point group D 6 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The EOS Data and Information System (EOSDIS)

The Earth Observing System (EOS) is the centerpiece of NASA's Mission to Planet Earth initiative. It is a pivotal part of the U.S. Global Change Research Program and hence of the international effort to understand global change and the increasing demands of human activity. EOS consists of a space-based observing system, a Data and Information System (EOSDIS) and a scientific research program. The space component consists of two series of polar-orbiting spacecraft, the first scheduled for launch in 1998, that will collect data for 15 years. EOS is completing its conceptual design phase and is preparing to enter the design phase with the selection and construction of the instruments for the first platform. EOSDIS will allow researchers to quickly and easily access data about the Earth system. Development of EOSDIS has already begun; it will support research and analysis with existing data. Geophysical and biological products will be created from the satellite data to be used to a broad range of the scientific community. NASA has also committed to providing smaller missions - called Earth Probes - dedicated to near-term observations of specific Earth processes. The scientific research program was initiated in 1990, with funding for 28 interdisciplinary teams, to begin development of models that will use EOS data and define the data requirements from the instruments, nine facility instruments and their science teams, 23 instrument investigations and definition studies for a synthetic-aperture radar.

Dozier, J.↗

Root gravitropism: an experimental tool to investigate basic cellular and molecular processes underlying mechanosensing and signal transmission in plants

The ability of plant organs to use gravity as a guide for growth, named gravitropism, has been recognized for over two centuries. This growth response to the environment contributes significantly to the upward growth of shoots and the downward growth of roots commonly observed throughout the plant kingdom. Root gravitropism has received a great deal of attention because there is a physical separation between the primary site for gravity sensing, located in the root cap, and the site of differential growth response, located in the elongation zones (EZs). Hence, this system allows identification and characterization of different phases of gravitropism, including gravity perception, signal transduction, signal transmission, and curvature response. Recent studies support some aspects of an old model for gravity sensing, which postulates that root-cap columellar amyloplasts constitute the susceptors for gravity perception. Such studies have also allowed the identification of several molecules that appear to function as second messengers in gravity signal transduction and of potential signal transducers. Auxin has been implicated as a probable component of the signal that carries the gravitropic information between the gravity-sensing cap and the gravity-responding EZs. This has allowed the identification and characterization of important molecular processes underlying auxin transport and response in plants. New molecular models can be elaborated to explain how the gravity signal transduction pathway might regulate the polarity of auxin transport in roots. Further studies are required to test these models, as well as to study the molecular mechanisms underlying a poorly characterized phase of gravitropism that is independent of an auxin gradient.

Non-NASA Center↗

Magnetism and finite-temperature effects in UZr 2 : A density functional theory analysis

The structure and the thermophysical properties of d-UZr 2 are investigated using 0 K density functional theory and ab initio molecular dynamics (AIMD). Modeling the true paramagnetic state of this intermetallic compound has been challenging using first-principles calculations. For the first time, we find that the generalized gradient approximation method without applying an on-site Coulomb interaction term (Hubbard U) can result in a ground state that is antiferromagnetic (AFM). We believe that this weak AFM ground state is the closest to the real paramagnetic state. We found that structure optimization at finite temperatures using AIMD is necessary to achieve this ground state instead of the non-magnetic and ferromagnetic states previously reported in the literature. Our findings indicate that applying the Hubbard U on uranium f-orbitals in this metallic system is unnecessary and not recommended, as it leads to a large overestimation of the volume and introduces an unphysical strong spin polarization. Finally, our approach results in atomic volume, thermal expansion, and heat capacities that have strong agreement with experiments.

36 MATERIALS SCIENCE↗

Characteristics and kinetics of laser-pumped Ti:sapphire oscillators

The experimental performance of a gain-switched Ti:sapphire laser oscillator pumped by a frequency-doubled Q-switched Nd:YAG laser system is presented for a variety of operating conditions. A theoretical model developed for this oscillator predicts well its performance. The observed curved input-output energy plots for the oscillator result from the kinetics of gain switching and fluorescence decay during the gain buildup period. Fluorescence decay also produces observed oscillator thresholds higher than those normally predicted by the standard gain-equals-loss condition. Gain-switched parasitic modes, with a higher threshold but shorter round-trip time than the resonator mode, cause the resonator mode to oscillate only over a finite range of pump energies. Spectroscopic investigations show that the Ti:sapphire cross-section spectrum is well fit by a Poisson distribution, giving a peak cross section of 3 x 10 to the -19th sq cm for the pi polarization.

Eggleston, John M.↗

Improving Forecast Skill by Assimilation of AIRS Temperature Soundings

AIRS was launched on EOS Aqua on May 4, 2002, together with AMSU-A and HSB, to form a next generation polar orbiting infrared and microwave atmospheric sounding system. The primary products of AIRS/AMSU-A are twice daily global fields of atmospheric temperature-humidity profiles, ozone profiles, sea/land surface skin temperature, and cloud related parameters including OLR. The AIRS Version 5 retrieval algorithm, is now being used operationally at the Goddard DISC in the routine generation of geophysical parameters derived from AIRS/AMSU data. A major innovation in Version 5 is the ability to generate case-by-case level-by-level error estimates delta T(p) for retrieved quantities and the use of these error estimates for Quality Control. We conducted a number of data assimilation experiments using the NASA GEOS-5 Data Assimilation System as a step toward finding an optimum balance of spatial coverage and sounding accuracy with regard to improving forecast skill. The model was run at a horizontal resolution of 0.5 deg. latitude X 0.67 deg longitude with 72 vertical levels. These experiments were run during four different seasons, each using a different year. The AIRS temperature profiles were presented to the GEOS-5 analysis as rawinsonde profiles, and the profile error estimates delta (p) were used as the uncertainty for each measurement in the data assimilation process. We compared forecasts analyses generated from the analyses done by assimilation of AIRS temperature profiles with three different sets of thresholds; Standard, Medium, and Tight. Assimilation of Quality Controlled AIRS temperature profiles significantly improve 5-7 day forecast skill compared to that obtained without the benefit of AIRS data in all of the cases studied. In addition, assimilation of Quality Controlled AIRS temperature soundings performs better than assimilation of AIRS observed radiances. Based on the experiments shown, Tight Quality Control of AIRS temperature profile performs best on the average from the perspective of improving Global 7 day forecast skill.

Susskind, Joel↗

Assimilating GCOM-W AMSR2 Radiance Data in Future GEOS Reanalysis

Surface and atmospheric radiation are being measured by space-borne conical scanning microwave radiometers with high accuracy and spatial resolution since 1980s'. These radiometers include Special Sensor Microwave Imager (SSM/I) onboard various NOAA's polar-orbiting satellites, Special Sensor Microwave Imager Sounder (SSMIS) onboard Defense Meteorological Satellite Program (DMSP) satellites, and Advanced Microwave Scanning Radiometer for EOS (AMSR-E), Advanced Microwave Scanning Radiometer 2 (AMSR2), Tropical Rainfall Measurement Mission (TRMM) Microwave Imager (TMI), and Global Precipitation Measurement (GPM) Microwave Imager (GMI) onboard NASA and JAXA's satellites. Atmospheric temperature, humidity, clouds, and precipitation are retrieved using brightness temperature data at frequencies between 22 GHz – 183 GHz. Some of the brightness temperature and retrieved rain rate data made by these imagers are assimilated in NASA Global Modelling and Assimilation Office (GMAO)'s weather and climate data sets including the Modern-Era Retrospective analysis for Research and Applications (MERRA) and its version 2 (MERRA-2) data sets. However, those radiance data are assimilated with the Goddard Earth Observing System model, version 5 (GEOS-5) only in clear-sky conditions. Recently, we started assimilate GPM/GMI radiance data with GEOS-5's atmospheric data assimilation system GSI under all-sky conditions in order to have better constraints in analyzed hydrological properties. GMAO plans to assimilate more microwave radiometers' brightness temperature data in its analyses. In this talk, we will discuss TMI and AMSR2 data's impact in temperature, humidity, clouds and precipitation under all-sky conditions in future GEOS reanalysis.

Jin, Jianjun↗

Direct Measurement of the Selective Microwave-Induced Heating of Agglomerates of Dipolar Molecules: The Origin of and Parameters Controlling a Microwave Specific Superheating Effect

Agglomerates of polar molecules in nonpolar solvents are selectively heated by microwave radiation. The magnitude of the selective heating was directly measured by using the temperature dependence of the intensities of the Stokes and anti-Stokes bands in the Raman spectra of p-nitroanisole (pNA) and mesitylene. Under dynamic heating conditions, a large apparent temperature difference (ΔT) of over 100 °C was observed between the polar pNA solute and the nonpolar mesitylene solvent. This represents the first direct measurement of the selective microwave heating process. The magnitude of the selective microwave heating was affected by the properties of the agglomerated pNA. As the concentration of the pNA increases, the magnitude of the selective heating of the pNA was observed to decrease. This is explained by the tendency of the pNA dipoles to orient in an antiparallel fashion in the aggregates as measured by the Kirkwood g value, which decreased with increasing concentration. This effect reduces the net dipole moment of the agglomerates, which decreases the microwave absorption. After the radiation was terminated, the effective temperature of the dipolar molecules returned slowly to that of the medium. The slow heat transfer was modeled successfully by treating the solutions as a biphasic solvent/solute system. Based on modeling and the fact that the agglomerate can be heated above the boiling temperature of the solvent, an insulating layer of solvent vapor is suggested to form around the heated agglomerate, slowing convective heat transfer out of the agglomerate. Furthermore, this is an effect unique to microwave heating.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ground testing in a simulated auroral environment

Shuttle polar orbit missions are being planned in which astronaut extravehicular activities (EVA) will eventually include external operations or repair and refurbishment of satellites. Recent satellite data and model calculations show that significant spacecraft charging and differential charging occurs in that environment and could endanger equipment and personnel involved in the EVA. These spacecraft charging events take place in response to an intense flux of high energy electrons accompanied by a large drop in the ambient plasma density. The extent of which the auroral environment can be simulated in a large vacuum chamber are determined so that conditions which lead to significant charging and discharging may be observed and controlled. A large chamber would be required in order to simulate the effects of an aurora-like, large cross-section, energetic electron precipitation on a target system the size of an astronaut with a life support system. The precipitating electrons can be simulated with an array of multipactor sources and the background ionization produced by the beam can be limited to the range of the auroral density if the chamber pressure is not significantly above 1 x .000001 Torr. Some small chamber work has shown that the plasma in the beam will diffuse radially at a rate determined by the Bohm diffusion coefficient.

Mcintyre, Bernard↗

VIPER: Systems Integration Status

NASA’s Artemis Program plans to return humans to the Moon for an extended stay. To do so will require substantial resources to sustain that continued human presence, including continuous supplies delivered from the Earth. Given the expense and complexity of resource deliveries from Earth, if some resources were indigenously available, substantial logistical savings could be available by “living off the land”, wherever possible. The LCROSS[1] , LRO and other missions have confirmed the presence of resources such as water-ice and other volatiles in lunar polar regions, so the next step is to understand the scientific nature and physical distribution of those candidate resources. Those local volatiles could be processed into propellants and human life-supporting needs, reducing risk of maintaining a permanent human presence on the Moon. The Volatiles Investigating Polar Exploration Resource (VIPER) is a surface mobility scientific platform, designed to spend ~100 days mapping and surveying four different Ice Stability Regions to understand the scientific nature and distribution of water and other volatiles. VIPER will also provide scientific mineralogical context of the lunar regolith, such as the presence of silicon and light metals in lunar regolith, providing a composite picture of resource availability and sustainment. This paper will discuss the latest systems-level integration activities by the VIPER team, following our initial introduction to this mission at IAC2021[2] . The VIPER team successfully passed its Systems Integration Review (SIR) in late-2022, and in early 2023, began system-level surface segment (rover) flight hardware assembly. VIPER is managed within NASA’s Science Mission Directorate (SMD), utilizing the Commercial Lunar Payload Services (CLPS) lunar delivery model with partner, Astrobotic, Inc.

VIPER↗