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At least 1,279 records · Page 71

Durability Study of a High-Pressure Common Rail Fuel Injection System Using Lubricity Additive-Dosed Gasoline-Like Fuel—Improved Endurance with Upgraded Hardware

Gasoline compression ignition (GCI) is a promising combustion technology that can help the commercial transportation sector achieve operational flexibility and meet upcoming criteria pollutant regulations. However, high-pressure fuel injection systems (>1000 bar) are needed to enable GCI and fully realize its benefits compared to conventional diesel combustion. This work is a continuation of previous durability studies that identified three key technical risks after running gasoline-like fuel through a heavy-duty, common rail injection system: (i) cavitation damage to the inlet check valve of the high-pressure pump, (ii) loss of injector fueling capacity, (iii) cavitation erosion of the injector nozzle holes. Upgraded hardware solutions were tested on a consistent 400- to 800-hour NATO durability cycle with the same gasoline-like fuel as previous studies. The upgraded pump showed no signs of abnormal wear or cavitation damage to the inlet check valve. In contrast to previous studies, there were no signs of pump performance degradation observed after 400 hours of testing. Material selection and design upgrades were also made to the injector which, only showed a 6.5% loss in fueling capacity after 800 hours of durability testing compared to 49.3% previously. Finally, geometric nozzle hole features such as higher inlet radius of curvature and higher K-factor were found to correlate with reduced cavitation erosion. However, mitigation of eccentric radial needle motion (i.e., wobble) is likely needed to further suppress cavitation. In general, the results from this study indicate there are viable hardware-based solutions for improving the endurance of high-pressure systems when running with gasoline-like fuel.

33 ADVANCED PROPULSION SYSTEMS↗

Pioneer imaging photopolarimeter optical system.

The imaging photopolarimeter aboard the Pioneer 10 spacecraft en route to the vicinity of Jupiter is described. This instrument is capable of moderate resolution spin-scan imaging and high precision polarimetric and photometric mapping of Jupiter in red and blue light. The field of view can be selectively changed from 0.50 mrad square to 40 mrad square to accommodate resolution and radiance combinations ranging from the zodiacal background to that of Jupiter. Optical materials were chosen to survive, with minimum degradation, the rigors of a nearly 2-year journey to Jupiter including transit through the Jovian trapped radiation belts. The optics are described in detail, and the operational system is outlined. The procedures for preflight and in-flight calibration are described, and some performance characteristics and preliminary flight results are presented.

Pellicori, S. F.↗

Sublimation behavior of silicon nitride /Si3N4/ coated silicon germanium /SiGe/ unicouples

For the Multi-Hundred Watt (MHW) Radioisotope Thermoelectric Generator (RTG), the silicon germanium unicouples are coated with silicon nitride to minimize degradation mechanisms which are directly attributable to material sublimation effects. A program is under way to determine the effective vapor suppression of this coating as a function of temperature and gas environment. The results of weight loss experiments, using Si3N4 coated hot shoes (SiMo), operating over a temperature range from 900 C to 1200 C, are analyzed and discussed. These experiments were conducted both in high vacuum and at different pressures of carbon monoxide (CO) to determine its effect on the coating. Although the results show a favorable vapor suppression at all operating temperatures, the pressure of the CO and the thickness of the coating have a decided effect on the useful lifetime of the coating.

Stapfer, G.↗

Silicon materials task of the low cost solar array project, part 2

Purity requirements for solar cell grade silicon material was developed and defined by evaluating the effects of specific impurities and impurity levels on the performance of silicon solar cells. Also, data was generated forming the basis for cost-tradeoff analyses of silicon solar cell material. Growth, evaluation, solar cell fabrication and testing was completed for the baseline boron-doped Czochralski material. Measurements indicate Cn and Mn seriously degrade cell performance, while neither Ni nor Cu produce any serious reduction in cell efficiency.

Hopkins, R. H.↗

On the origin of Luna 24 basalts and soils

Analyses of fine-grained very low titanium (VLT) basalt from the Luna 24 drill core suggest that a single homogeneous magma is represented by the sample. In particular, the small variation in MgO contents of the fine-grained basalt, together with the tight clustering of the compositions of brown glasses (which may be pyroclastic equivalents of the VLT basalt), provides evidence for the single-magma hypothesis. The high-Mg component in the soil samples, though not obviously explainable in petrographic terms, may be derived from material similar to olivine vitrophyre and its degraded products, or from some other high-Mg VLT basalt.

Ryder, G.↗

Boron-containing organosilane polymers and ceramic materials thereof

The present invention relates to organic silicon-boron polymers which upon pyrolysis produce high-temperature ceramic materials. More particularly, it relates to the polyorganoborosilanes containing -Si-B- bonds which generate high-temperature ceramic materials (e.g., SiC, SiB4, B4C) upon thermal degradation. The process for preparing these organic silicon-boron polymer precursors are also part of the invention.

Riccitiello, Salvatore R.↗

Passivation of high temperature superconductors

The surface of high temperature superconductors such as YBa2Cu3O(7-x) are passivated by reacting the native Y, Ba and Cu metal ions with an anion such as sulfate or oxalate to form a surface film that is impervious to water and has a solubility in water of no more than 10(exp -3) M. The passivating treatment is preferably conducted by immersing the surface in dilute aqueous acid solution since more soluble species dissolve into the solution. The treatment does not degrade the superconducting properties of the bulk material.

Vasquez, Richard P.↗

Chemical compatibility of cartridge materials

The objectives were to determine the chemical compatibility of titanium-zirconium-molybdenum (TZM) with GaAs and CdZnTe, and Inconel with HgCdTe and HgZnTe. At the present time, no other studies regarding the compatibility of these crystal components and their respective cartridge materials have been performed. This study was to identify any possible problems between these materials to insure proper containment of possibly hazardous fumes during crystal growth experiments. In this study, the reaction zone between the materials was studied and the amount of degradation to the system was measured. Detailed results are presented.

Ambrose, Bryan↗

A high specific power solar array for low to mid-power spacecraft

UltraFlex is the generic term for a solar array system which delivers on-orbit power in the 400 to 6,000 watt per wing sizes with end-of-life specific power performance ranging to 150 watts-per-kilogram. Such performance is accomplished with off-the-shelf solar cells and state-of the-art materials and processes. Much of the recent work in photovoltaics is centered on advanced solar cell development. Successful as such work has been, no integrated solar array system has emerged which meets NASA's stated goals of 'increasing the end-of-life performance of space solar cells and arrays while minimizing their mass and cost.' This issue is addressed; namely, is there an array design that satisfies the usual requirements for space-rated hardware and that is inherently reliable, inexpensive, easily manufactured and simple, which can be used with both advanced cells currently in development and with inexpensive silicon cells? The answer is yes. The UltraFlex array described incorporates use of a blanket substrate which is thermally compatible with silicon and other materials typical of advanced multi-junction devices. The blanket materials are intrinsically insensitive to atomic oxygen degradation, are space rated, and are compatible with standard cell bonding processes. The deployment mechanism is simple and reliable and the structure is inherently stiff (high natural frequency). Mechanical vibration modes are also readily damped. The basic design is presented as well as supporting analysis and development tests.

Jones, P. Alan↗

Combustion of PTFE: The effects of gravity on ultrafine particle generation

The objective of this project is to obtain an understanding of the effect of gravity on the toxicity of ultrafine particle and gas phase materials produced when fluorocarbon polymers are thermally degraded or burned. The motivation for the project is to provide a basic technical foundation on which policies for spacecraft health and safety with regard to fire and polymers can be formulated.

McKinnon, Thomas↗

Prediction of Degraded Strength in Composite Laminates with Matrix Cracks

Composite laminated materials are becoming increasingly important for aerospace engineering. As the aerospace industry moves in this direction, it will be critical to be able to predict how these materials fail. While much research has been done in this area, both theoretical and experimental, the field is still new enough that most computer aided design platforms have not yet incorporated damage prediction for laminate materials. There is a gap between the level of understanding evident in the literature and what design tools are readily available to engineers. The work reported herein is a small step toward filling that gap for NASA engineers. A computer program, LAMDGRAD, has been written which predicts how some of the materials properties change as damage is incurred. Specifically, the program calculates the Young's moduli E(sub x) and E(sub y) the Poisson's ratio v(sub xy) and the shear modulus G(sub xy) as cracks developing the composite matrix. The changes in the Young's moduli are reported both as a function of mean crack separation and in the form of a stress-versus-strain curve. The program also calculates the critical strain for delamination growth and predicts the strain at which a quarter-inch diameter delaminated area will buckle. The stress-versus-strain predictions have been compared to experiment for two test structures, and good agreement has been found in each case.

Kime, Yolanda J.↗

Thermal Effects on the Bearing Behavior of Composite Joints

Thermal effects on the pin-bearing behavior of an IM7/PET15 composite laminate are studied comprehensively. A hypothesis presents factors influencing a change in pin-bearing strength with a change in temperature for a given joint design. The factors include the change in the state of residual cure stress, the material properties, and the fastener fit with a change in temperature. Experiments are conducted to determine necessary lamina and laminate material property data for the IM7/PET15 being utilized in this study. Lamina material properties are determined between the assumed stress free temperature of 460 F down to -200 F. Laminate strength properties are determined for several lay-ups at the operating temperatures of 350 F, 70 F, and -200 F. A three-dimensional finite element analysis model of a composite laminate subject to compressive loading is developed. Both the resin rich layer located between lamina and the thermal residual stresses present in the laminate due to curing are determined to influence the state of stress significantly. Pin-bearing tests of several lay-ups were conducted to develop an understanding on the effect of temperature changes on the pin-bearing behavior of the material. A computational study investigating the factors influencing pin-bearing strength was performed. A finite element model was developed and used to determine the residual thermal cure stresses in the laminate containing a hole. Very high interlaminar stress concentrations were observed two elements away from the hole boundary at all three operating temperatures. The pin-bearing problem was modeled assuming a rigid frictionless pin and restraining only radial displacements at the hole boundary. A uniform negative pressure load was then applied to the straight end of the model. A solution, where thermal residual stresses were combined with the state of stress due to pin-bearing loads was evaluated. The presence of thermal residual stresses intensified the interlaminar stresses predicted at the hole boundary in the pin-bearing problem. This dissertation shows that changes in material properties drives pin-bearing strength degradation with increasing temperature.

Walker, Sandra Polesky↗

Effects of Space Environments: Techniques and Lessons from Selected Flight Experiments

Data describing long-term materials performance under exposure to space environments has accumulated gradually over the past four decades. The authors present here selected results from several previous flight experiments and operational spacecraft, and a few examples from a current flight experiment. As examples of environmental effects on materials, analysis of Gortex samples from the Passive Optical Sample Assembly II (POSA II) experiment on the MIR-Shuttle docking module will be described. Results from a previous evaluation of radiation on silverized Teflon from over ten individual satellites will be summarized. Several examples of contamination effects on materials properties will be presented. These include outgassing of solar arrays onto nearby surfaces of the POSA I experiment and contamination of certain surfaces of the Long Duration Exposure Facility (LDEF). Results from experiments with silicone contamination on satellites in geosynchronous orbit will be compared with measurements on the Solar Maximum satellite and the LDEF. A number of techniques are being attempted to extend the range of exposure conditions present on selected experiments. Use of focusing concentrators on the Effect of Space Environments on Materials (ESEM), POSA, and Materials International Space Station Experiment (MISSE) will be described. A technique for obtaining time-resolved data from a passive materials experiment will be described. The status of an on-going materials flight experiment, MISSE, will be reported. Finally, the authors will draw some conclusions about the current state of knowledge relating to materials chosen for spacecraft applications. Understanding of degradation mechanisms, state of predictive models, and the need to strengthen model inputs will be discussed.

Golden, J. L.↗

New Endcaps for Improved Oxidation Resistance in PMR Polyimides

A polyimide is a polymer composed of alternating units of diamine and dianhydride, linked to each other via an imide bond. PMR polyimides, commonly used in the aerospace industry, are generally capped at each end by an endcap (such as the nadic endcap used in PMR 15) which serves a double function: (1) it limits the number of repeating units and, hence, the average molecular weight of the various polymer chains (oligomers), thereby improving processibility; (2) Upon further treatment (curing), the endcap crosslinks the various oligomer strands into a tough heat-resistant piece. It is this very endcap, so important to processing, that accounts for much of the weight loss in the polymer on aging in air at elevated temperatures. Understanding this degradation provides clues for designing new endcaps to slow down degradation, and prolong the lifetime of the material.

Frimer, Aryeh A.↗

Reevaluation of Tetrahydrophthalic Anydrides as Endcaps for Improved Oxidation Resistance in Addition to Polyimides

A polyimide is a polymer composed of alternating units of diamine and dianhydride, linked to each other via an imide bond. PMR polyimides, commonly used in the aerospace industry, are generally capped at each end by an endcap (such as the nadic endcap used in PMR 15) which serves a double function: (1) it limits the number of repeating units and, hence, the average molecular weight of the various polymer chains (oligomers), thereby improving processibility; (2) Upon further treatment (curing), the endcap crosslinks the various oligomer strands into a tough heat-resistant piece. It is this very endcap, so important to processing, that accounts for much of the weight loss in the polymer on aging in air at elevated temperatures. Understanding this degradation provides clues for designing new endcaps to slow down degradation, and prolong the lifetime of the material.

Frimer, Aryeh A.↗