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At least 1,279 records · Page 71

Use of ground-based telescopes in determining the composition of the surfaces of solar system objects

Recent evidence suggests that the way that the surfaces of the solar system objects reflect solar radiation is controlled by the composition and mineralogy of the surface materials. The way sunlight is reflected from the surface as a function of wavelength, i.e., the spectral reflectance, is the most important property. Laboratory efforts to use ground-based optical telescope measurements to determine the composition of the surfaces of the solar system objects are reviewed.

Mccord, T. B.↗

Reproducibility of PMR-15 graphite polymide material

Investigation was made into the reproducibility of PMR polyimide/graphite prepreg reinforcement and the influence of these variabilities on processing characteristics and final composite properties. The purpose of these investigations was to establish specification controls and limits of acceptance/rejection on incoming materials. Prepreg samples were chemically analyzed and the results compared to the processing and property results of the resulting composites. The findings from these comparisons are discussed.

Hoggatt, J. T.↗

Synthesis of improved phenolic resins

Twenty seven addition cured phenolic resin compositions were prepared and tested for their ability to give char residues comparable to state-of-the-art phenolic resins. Cyanate, epoxy, allyl, acrylate, methacrylate and ethynyl derivatized phenolic oligomers were investigated. The novolac-cyanate and propargyl-novolac resins provided anaerobic char yields at 800 C of 58 percent. A 59 percent char yield was obtained from modified epoxy novolacs. A phosphonitrilic derivative was found to be effective as an additive for increasing char yields. The novolac-cyanate, epoxy-novolac and methacrylate-epoxy-novolac systems were investigated as composite matrices with Thornel 300 graphite fiber. All three resins showed good potential as composite matrices. The free radical cured methacrylate-epoxy-novolac graphite composite provided short beam shear strengths at room temperature of 93.3 MPa (13.5 ksi). The novolac-cyanate graphite composite produced a short beam shear strength of 74 MPa (10.7 ksi) and flexural strength of 1302 MPa (189 ksi) at 177 C. Air heat aging of the novolac-cyanate and epoxy novolac based composites for 12 weeks at 204 C showed good property retention.

Delano, C. B.↗

Composite components on commercial aircraft

Flight experience gained with numerous composite aircraft structures is discussed. Both commercial transports and helicopters are included. Design concepts with significant mass savings and appropriate inspection and maintenance procedures are among the factors considered. Also, a major NASA/U.S. industry technology program to reduce fuel consumption of commercial transport aircraft through the use of advanced composites is described, including preliminary results. Ground and flight environmental effects on the composite materials used in the flight service programs are also discussed.

Dexter, H. B.↗

NASA service experience with composite components

NASA Langley has been active in sponsoring flight service programs with advanced composites during the past decade. A broad data base and confidence in the durability of composite structures are being developed. Flight service experience is reported for more than 140 composite aircraft components with up to 8 years service and almost two million successful component flight hours. Composite components are being evaluated on Boeing, Douglas, and Lockheed transport aircraft. Components are currently under development for service evaluation on Bell and Sikorsky helicopters. Design concepts and inspection and maintenance results are reported for components currently in service. Components under development in the NASA Aircraft Energy Efficiency (ACEE) program are discussed. Results of flight, outdoor ground, and controlled laboratory environmental tests on composite materials used in the flight service programs are also presented.

Dexter, H. B.↗

Design Allowables Test Program, Celion 3000/PMR-15 and Celion 6000/PMR-15, Graphite/Polyimide Composites

A design allowables test program was conducted on Celion 3000/PRM-15 and Celion 6000/PMR-15 graphite/polyimide composite to establish material performance over a 116 K (-250 F) to 589 K (600 F) temperature range. Effects of aging, thermal cycling and moisture were also evaluated. Tension, compression and in plane shear properties were determined for uniaxial, pseudoisotropic and +45 laminates. Test results show sufficient strength and stiffness to substantiate graphite/polyimide composites as an acceptable structural material for high temperature structural applications.

Cushman, J. B.↗

Petrology of ALHA 81005, the first lunar meteorite

The meteorite thought to be best described as a lunar highland regolith breccia from a non-KREEPy region. The controversy that remains as to the most likely source region is discussed. It is noted that several large lunar nearside craters have been proposed (Ostertag and Ryder, 1983). After finding a very-low-titanium (VLT) mare basalt clast in a thin section of ALHA 81005, Treiman and Drake (1983) have suggested that this constrains the source to being near a region with VLT basalt. It is pointed out, however, that the unexplored far side of the moon cannot be ruled out. Most of the lithic clasts that are abundant in the meteorite are members of the anorthosite-norite-troctolite highland suite. It is noted that plagioclase compositions in lithic clasts and single grains are calcic (An94-98).

Simon, S. B.↗

Prediction of Combustion Gas Deposit Compositions

Demonstrated procedure used to predict accurately chemical compositions of complicated deposit mixtures. NASA Lewis Research Center's Computer Program for Calculation of Complex Chemical Equilibrium Compositions (CEC) used in conjunction with Computer Program for Calculation of Ideal Gas Thermodynamic Data (PAC) and resulting Thermodynamic Data Base (THDATA) to predict deposit compositions from metal or mineral-seeded combustion processes.

Kohl, F. J.↗

Test method development for structural characterization of fiber composites at high temperatures

Test methods used for structural characterization of polymer matrix composites can be applied to glass and ceramic matrix composites only at low temperatures. New test methods are required for tensile, compressive, and shear properties of fiber composites at high temperatures. A tensile test which should be useful to at least 1000 C has been developed and used to characterize the properties of a Nicalon/glass composite up to the matrix limiting temperature of 600 C. Longitudinal and transverse unidirectional composite data are presented and discussed.

Mandell, J. F.↗

Retarding potential analyzer research

Studies were continued in the areas of ionospheric electrodynamics, plasma irregularities, and ion-neutral coupling. The spectral characteristics of structure in the ion concentration and the electric field at high latitudes were examined. It was found that in the region of velocity shears the relationship between the slopes of the two spectra are dependent on the existence of large field-aligned currents and apparently large ionospheric conductivity gradients. The relationship between the Joule dissipation and the locally measured value of the ion temperature were studied by examining the horizontal ion drift velocity. The importance of ion-neutral coupling was investigated in additional studies involving the nature of the coupling at high latitude boundaries and during times of magnetic disturbances. Much of this behavior can be modeled using globular circulation models. In order to study the storm time response of the thermosphere the global ion convection pattern was derived from DE-2 measurements and used as input in a circulation model. The calculated variables of neutral velocity and composition and temperature were compared with measurements to validate the technique.

Hanson, W. B.↗

Mantle heterogeneity and crustal recycling in Archean granite-greenstone belts - Evidence from Nd isotopes and trace elements in the Rainy Lake area, Superior Province, Ontario, Canada

Crustal evolution in the Rainy Lake area, Ontario is studied in terms of geochemical characteristics. The Nd isotope data are examined for heterogeneity of the Archean mantle, and the Sm/Nd depletion of the mantle is analyzed. The Nd isotope systematics of individual rock suites is investigated in order to understand the difference between crust and mantle sources; the precursors and petrogenetic processes are discussed. The correlation between SiO2 content and Nd values is considered. Rapid recycling of crustal components, which were previously derived from depleted mantle sources, is suggested based on the similarity of the initial Nd isotopic composition for both mantle-derived and crustally-derived rocks.

Shirey, Steven B.↗

Materials development for precision segmented reflector applications

The requirements developed to guide the selection of current and future materials for precision segmented reflectors are presented along with a list of desirable properties. Some potential candidate materials including modified fiber reinforced organic matrix composites as well as carbon/carbon composites, graphite/glass composites, and metal matrix composites are identified. It is noted that in the near term, it is likely that modified fiber reinforced organic matrix composites have good applicability. In the longer term, materials such as carbon/carbon composites, graphite/glass composites and metal matrix composites may provide the best mix of properties.

Coulter, Daniel R.↗

Thermal History Of PMRs Via Pyrolysis-Gas Chromatography

Pyrolysis-gas chromatography (PY-GC) useful as analytical technique to determine extents of cure or postcure of PMR-15 polyimides and to lesser extent, cumulative thermal histories of PMR-15 polyimides exposed to high temperatures. Also applicable for same purposes to other PMR polyimides and to composite materials containing PMR polyimides. Valuable in reducing costs and promoting safety in aircraft industry by helping to identify improperly cured or postcured PMR-15 composite engine and airframe components and helping to identify composite parts nearing ends of their useful lives.

Gluyas, Richard E.↗

Cometary coma chemical composition (C4) mission

Cometary missions are of enormous fundamental importance for many different space science disciplines, including exobiology. Comets are presumed relics of the earliest, most primitive material in the solar nebula and are related to the planetesimals. They undoubtedly provided a general enrichment of volatiles to the inner solar system (contributing to atmospheres and oceans) and may have been key to the origin of life. A Discovery class, comet rendezvous mission, the Cometary Coma Chemical Composition (C4) Mission, was selected for further study by NASA earlier this year. The C4 Mission is a highly focused and usefully-limited subset of the Cometary Rendezvous Asteroid Flyby (CRAF) Mission, concentrating exclusively on measurements which will lead to an understanding of the chemical composition and make-up of the cometary nucleus. The scientific goals of the Cometary Coma Chemical Composition (C4) Mission are to rendezvous with a short-period comet and (1) to determine the elemental, chemical, and isotopic composition of the nucleus and (2) to characterize the chemical and isotopic nature of its atmosphere. Further, it is a goal to obtain preliminary data on the development of the coma (dust and gas composition) as a function of time and orbital position.

Carle, G. C.↗

Rare-Earth Garnets and Perovskites for Space-Based ADR Cooling at High T and Low H

Future NASA satellite detector systems must be cooled to the 0.1 K temperature range to meet the stringent energy resolution and sensitivity requirements demanded by mid-term astronomy missions. The development of adiabatic demagnetization refrigeration (ADR) materials that can efficiently cool from the passive radiative cooling limit of approx. 30 K down to sub-Kelvin under low magnetic fields (H less than or equal to 3 T) would represent a significant improvement in space-based cooling technology. Governed by these engineering goals, our efforts have focused on quantifying the change in magnetic entropy of rare-earth garnets and perovskites. Various compositions within the gadolinium gallium iron garnet solid solution series (GGIG, Gd3Ga(5-x)Fe(x)O12, 0.00 less than or equal to X less than or equal to 5.00) and gadolinium aluminum perovskite (GAP, GdAlO3) have been synthesized via an organometallic complex approach and confirmed with powder x-ray diffraction. The magnetization of the GGIG and GAP materials has been measured as a function of composition (0.00 less than or equal to X less than or equal to 5.00), temperature (2 K less than or equal to T less than or equal to 30 K) and applied magnetic field (0 T less than or equal to H less than or equal to 3 T). The magnetic entropy change (DeltaS(sub mag)) between 0 T and 3 T was determined from the magnetization data. In the GGIG system, DeltaS(sub mag) was compositionally dependent; Fe(sup 3+) additions up to X less than or equal to 2.44 increased DeltaS(sub mag) at T > 5 K. For GAP, DeltaS(sub mag) was similar to that of GGIG, X = 0.00, both in terms of magnitude and temperature dependence at T > 10 K. However, the DeltaS(sub mag) of GAP at T < 10 K was less than the endmember GGIG composition, X = 0.00, and exhibited maximum approx. 5 K.

King, T. T.↗