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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,261 records · Page 70
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

A surface crack in shells under mixed-mode loading conditions

The present consideration of a shallow shell's surface crack under general loading conditions notes that while the mode I state can be separated, modes II and III remain coupled. A line spring model is developed to formulate the part-through crack problem under mixed-mode conditions, and then to consider a shallow shell of arbitrary curvature having a part-through crack located on the outer or the inner surface of the shell; Reissner's transverse shear theory is used to formulate the problem under the assumption that the shell is subjected to all five moment and stress resultants.

Joseph, P. F.↗
NASA NTRS2016

Low Temperature Rhombohedral Single Crystal SiGe Epitaxy on c-plane Sapphire

Current best practice in epitaxial growth of rhombohedral SiGe onto (0001) sapphire (Al2O3) substrate surfaces requires extreme conditions to grow a single crystal SiGe film. Previous models described the sapphire surface reconstruction as the overriding factor in rhombohedral epitaxy, requiring a high temperature Al-terminated surface for high quality films. Temperatures in the 850-1100 C range were thought to be necessary to get SiGe to form coherent atomic matching between the (111) SiGe plane and the (0001) sapphire surface. Such fabrication conditions are difficult and uneconomical, hindering widespread application. This work proposes an alternative model that considers the bulk sapphire structure and determines how the SiGe film nucleates and grows. Accounting for thermal expansion effects, calculations using this new model show that both pure Ge and SiGe can form single crystal films in the 450-550 C temperature range. Experimental results confirm these predictions, where x-ray diffraction and atomic force microscopy show the films fabricated at low temperature rival the high temperature films in crystallographic and surface quality. Finally, an explanation is provided for why films of comparable high quality can be produced in either temperature range.

Duzik, Adam J.↗
DOE OSTI2022

CO 2 Hydrogenation to Methanol over Inverse ZrO 2 /Cu(111) Catalysts: The Fate of Methoxy under Dry and Wet Conditions

Understanding the surface chemistry of CH 3 O species is essential for the production of methanol by CO 2 hydrogenation over Cu-based heterogeneous catalysts, as it facilitates the rational design of more efficient conversion processes. Recent research has identified inverse ZrO 2 /Cu catalysts as highly active and selective systems for the transformation of CO 2 to methanol with a performance that can be better than that of commercial Cu/ZnO catalysts. Here, we employed synchrotron-based ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and calculations based on density functional theory (DFT) to understand the fate of CH 3 O groups under dry and wet environments. AP-XPS spectra revealed that under CO 2 hydrogenation conditions, formate and methoxy are two key intermediates to produce methanol. Furthermore, there are three different types of reactive sites on the surface: One is active for methoxy adsorption, which is stable and responsible for the methanol synthesis; Another one transforms CO 2 into CO; and a third one is active for CO 2 and methoxy dissociation, leading to C and methane formation. The theoretical calculations indicate that CH 3 OH readily dissociates to CH 3 O species following a highly exothermic (ΔE = -20.99 kcal/mol) and barrierless process. The water produced by the reverse water-gas shift reaction (CO 2 + H 2 → H 2 O + CO) can prevent the decomposition of CH 3 O species. We discovered that by introducing a tiny amount of water vapor (2 × 10 -6 Torr) into the reaction chamber, the energy barrier for the reaction CH 3 O(ads) + H(ads) → CH 3 OH(gas) is dramatically reduced. AP-XPS and computational modelling showed that water is quite capable of extracting adsorbed methoxy to form gaseous methanol. With this in mind, one could boost the methanol selectivity by adding appropriate amounts of water or steam, which is an inexpensive and feasible solution for industrial operations.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Electromagnetic scattering by coated convex surfaces and wedges simulated by approximate boundary conditions

Asymptotic/high-frequency solutions are developed for analyzing the non-specular scattering mechanisms associated with coated convex surfaces and edges simulated by approximate boundary conditions. In particular, the standard impedance boundary conditions (SIBC's) and the second order generalized impedance boundary conditions (GIBC's) are employed for a characterization of the edge diffraction, creeping wave, and surface diffracted wave contributions. To study the creeping wave and surface diffracted wave mechanisms, rigorous UTD (uniform geometrical theory of diffraction) diffraction coefficients are developed for a convex coated cylinder simulated with SIBC's and GIBC's. The ray solutions obtained remain valid in the transition region and reduce uniformly to those in the deep lit and shadow regions. A uniform asymptotic solution is also presented for observations in the close vicinity of the cylinder. The diffraction coefficient for a convex cylinder are obtained via a generalization of the corresponding ones of the circular cylinder. To validate the asymptotic/high-frequency solution, integral equations are derived for both E and H-polarization and solved numerically using the method of moments. Results are presented for a single and three layered coated convex cylinder. Some insights are also provided on the accuracy of the employed GIBC's versus SIBC's for application to curved surfaces. To characterize the scattering by impedance wedges illuminated at skew incidence, diffraction coefficients are derived from an approximate solution of the governing functional difference equations. This solution exactly recovers the known ones for an impedance half plane or an arbitrary wedge at normal incidence, and to validate it for other wedge angles, a moment method code was used. Finally, to test the usefulness of the approximate skew incidence impedance wedge diffraction coefficient for three dimensional structures, equivalent currents are derived in the context of the physical theory of diffraction (PTD) for a finite length impedance wedge of arbitrary internal angles. These are incorporated in a standard general purpose PTD code and results are presented for a number of different impedance structures.

Syed, H. H.↗
NASA NTRS1988

Navier-Stokes structure of merged layer flow on the spherical nose of a space vehicle

Hypersonic merged layer flow on the forepart of a spherical surface of a space vehicle has been investigated on the basis of the full steady-state Navier-Stokes equations using slip and temperature jump boundary conditions at the surface and free-stream conditions far from the surface. The shockwave-like structure was determined as part of the computations. Using an equivalent body concept, computations were carried out under conditions that the Aeroassist Flight Experiment (AFE) Vehicle would encounter at 15 and 20 seconds in its flight path. Emphasis was placed on understanding the basic nature of the flow structure under low density conditions. Particular attention was paid to the understanding of the structure of the outer shockwave-like region as the fluid expands around the sphere. Plots were drawn for flow profiles and surface characteristics to understand the role of dissipation processes in the merged layer of the spherical nose of the vehicle.

Jain, A. C.↗
NASA NTRSDate not supplied

Advancing Dust Tolerant Mechanisms for a Sustained Exploration of the Moon

Introduction: “I think dust is probably one of our greatest inhibitors to a nominal operation on the Moon. I think we can overcome other physio-logical or physical or mechanical problems except dust.”– Gene Cernan, Apollo 17 Technical Debrief The Apollo missions revealed the impact of lu-nar dust on mechanisms. Lunar dust particles are jagged and electrostatically charged, giving them the ability to bind or damage mechanisms and alter thermal properties. Reports documented clogged equipment and jammed mechanisms in every mission, regardless of surface duration, as well as clogged mechanisms in the Extravehicular Mobility Suit (EMS), including zippers, wrist and hose locks, faceplates, and sunshades [1-2]. Several astronauts remarked they could not have sustained surface activity much longer because clogged joints would have frozen up completely [2]. Effective dust mitigation strategies are need-ed to support longer duration stays on the lunar surface [3-4]. State of the Art: Technology for mechanisms able to operate in dusty enviroments is advancing rapidly due to the needs of both Mars rovers and the Artemis program. Vacuum-tight connectors are essential for spacesuits and habitats, and their performance can be dependent on cleaning technologies, which have proven difficult on the lunar surface. Several TRL 3-5 technologies are undergoing tests with the expectation to reach TRL 6 within 1-2 years. Some mechanisms will be infused and tested on the VIPER (Volatiles Inves-tigating Polar Exploration Rover) mission planned for mid-2020s. NASA Funded Efforts: NASA has recognized the need for dust tolerant mechanisms, and has partnered with industry to advance the state-of-the-art. At NASA GRC, KSC, and JSC, the Dust Tolerant Mechanisms Project is working to devel-op advanced actuator seals for rotary joints and rotary bearing technologies for long-term sus-tained operation in lunar dust environments. An-other NASA project at NASA GRC, partnered with GSFC, JPL, and KSC is Motors for Dusty & Ex-treme Cold Environments (MDECE). MDECE is developing an unheated magnetically-geared mo-tor that can operate continuously for a long dura-tion at an ambient temperature of -243 ºC (33 K). NASA GRC has the capability to characterize the effects of dust on seals, mechanisms, and other mating surfaces and components under lunar conditions [5]. Through the SBIR/STTR program, NASA has funded several companies to advance dust toler-ant mechanisms via the Dust Tolerant Mecha-nisms sub-topic with applications in surface mobil-ity, spacesuits, connectors, joints, and more. LSIC and Community Efforts: The Lunar Surface Innovation Consortium (LSIC) Dust Miti-gation focus group has fostered collaborations across NASA, industry, and academia to develop solutions that minimizes the impact of lunar dust on robotic and human systems. Community ef-forts have included topical meetings on dust tol-erant mechanisms, featured technology presenta-tions, and feedback to NASA on potential gaps and needs. Testing: In 2021, NASA released NASA-STD-1008 [6]. This NASA Technical Standard estab-lishes minimum requirements and provides guid-ance for testing systems and hardware to be ex-posed to dust in planetary environments. The standard has specific sections dedicated to Mechanisms Testing (e.g. bearings, gears) as well as Seals and Mating Surfaces Testing (e.g. hatches, docking systems). Gaps and Needs: NASA is tracking dust tol-erant mechanisms as a gap in a cross-directorate analysis of capability areas needed to enable fu-ture human space-flight architectures. Two high-priority gap areas include additional facilities for testing mechanisms in lunar-surface conditions, and a better understanding of vulnerabilities to the smallest, nanometer-scale dust particles. Conclusion: Understanding and mitigating lu-nar dust is critical to successful, sustained opera-tions on the lunar surface – whether autonomous or otherwise. This presentation will discuss both the state-of-the-art and open needs in lunar dust tolerant mechanisms, technology impacts, mitiga-tion approaches, testing, LSIC community efforts, and more. References: [1] Gaier, J. R. (2020). The Im-pact of Dust on Lunar Surface Equipment During Apollo. Lunar Dust 2020. [2] GRC, & Gaier, J. R. (2005). The Effects of Lunar Dust on EVA Sys-tems During the Apollo Missions. [3] Johansen, M. R. (2020). An Update on NASA’s Lunar Dust Mitigation Strategy. Lunar Dust 2020. [4] ASI, CSA, ESA, JAXA, & NASA. (2016). Dust Mitiga-tion Gap Assessment Report. [5] Jimenez, N. et al (2022), LPSC Abstract 2572. [6] NASA-STD-1008, 2021.

J I Nunez↗
NASA NTRS1975

An X-ray photoelectron spectroscopy study of nickel and nickel-base alloy surface alterations in simulated hot corrosion conditions with emphasis on eventual application to turbine blade corrosion

The spectra of the pure metals tested and their oxides were used to analyze the patterns obtained for various superalloys. The quantitative results for two superalloys revealed differences between the surface compositions and their behavior under different conditions of oxidation. The following results occurred during the hot corrosion of samples in the presence of Na2So4: a lack of Ti migration; strong effects on Cr; and, a higher speed of alteration of superalloys.

Mateescu, G. D.↗
DOE OSTI2021

Power Plant Testing of Ultrasonic Measurements of Temperature Distributions and Heat Fluxes to Heat Exchange Surfaces

Extreme environmental conditions are common in energy conversion applications, in which the most hardened insertion sensors often do not perform reliably for long. On the other hand, ultrasonic measurements can be acquired noninvasively, with sensitive components kept away from the damaging environment. We have previously developed the ultrasonic method for measuring the spatial distribution of temperatures in solid materials applicable when large thermal gradients are present. In the developed approach, we use the echogenically segmented ultrasound propagation path, structured to contain engineered or naturally occurring echogenic features, to produce a train of echoes in response to an external pulse of ultrasonic excitation. This paper outlines the testing results of this approach applied to the temperature distribution measurements to a waterwall of a 500 MW power-plant utility boiler. The validation results obtained over the prolonged power plant test show that the estimated temperature profile is correctly captured, and the measurement accuracy can be comparable with traditional insertion sensors, such as thermocouples. Overall, the testing has confirmed that the developed approach has matured to become an attractive alternative to conventional sensing in solving challenging problems of long-term temperature measurements in extreme environments. Heat fluxes and thermal stresses in the structure can then be characterized noninvasively using the measured temperature distribution as the basis.

Walton, Kenneth↗
NASA NTRS1973

Earth physics, overview

Satellite applications in earth and ocean dynamic studies are considered for: earthquake hazard assessment and alleviation; prediction of general ocean circulation, surface currents, and heat transport; monitoring of transient phenomena of the ocean surface, such as sea state and wave conditions, wind-surface interactions and storm searches; and refinement of the global geoid, the gravity and magnetic fields of the earth.

Vonbun, F. O.↗
NASA NTRS2016

LS3MIP (v1.0) Contribution to CMIP6: The Land Surface, Snow and Soil Moisture Model Intercomparison Project Aims, Setup and Expected Outcome.

The Land Surface, Snow and Soil Moisture Model Intercomparison Project (LS3MIP) is designed to provide a comprehensive assessment of land surface, snow, and soil moisture feedbacks on climate variability and climate change, and to diagnose systematic biases in the land modules of current Earth System Models (ESMs). The solid and liquid water stored at the land surface has a large influence on the regional climate, its variability and predictability, including effects on the energy, water and carbon cycles. Notably, snow and soil moisture affect surface radiation and flux partitioning properties, moisture storage and land surface memory. They both strongly affect atmospheric conditions, in particular surface air temperature and precipitation, but also large-scale circulation patterns. However, models show divergent responses and representations of these feedbacks as well as systematic biases in the underlying processes. LS3MIP will provide the means to quantify the associated uncertainties and better constrain climate change projections, which is of particular interest for highly vulnerable regions (densely populated areas, agricultural regions, the Arctic, semi-arid and other sensitive terrestrial ecosystems).The experiments are subdivided in two components, the first addressing systematic land biases in offline mode (LMIP, building upon the 3rd phase of Global Soil Wetness Project; GSWP3) and the second addressing land feedbacks attributed to soil moisture and snow in an integrated framework (LFMIP, building upon the GLACE-CMIP blueprint).

atmospheric temperature↗
DOE OSTI2023

Electropolishing Study on Nitrogen-doped Niobium Surface

The nitrogen doping (N-doping) process is applied to niobium (Nb) superconducting cavities to enhance their quality factors. The N-doping is followed by an electropolishing process that provides the final surface of the cavities. A controlled EP process is necessary to get the benefit of N-doping and achieve a high accelerating gradient. We have performed electropolishing of N-doped Nb surface under various conditions to understand their impact on the surface. A modified EP process was developed to obtain a smooth pit-free surface.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1986

DE-2 mass spectrometer observations relevant to the Shuttle glow

A comparison of satellite mass spectrometer data from Dynamics Explorer-2 and Atmosphere Explorer-C and -D provides new evidence supporting the hypothesis that NO2 is the source of the observed continuum glow near ram-facing surfaces of the Space Shuttle. Surface reactions of thermospheric N and O in mass spectrometer ion sources produce NO and NO2 in amounts highly dependent on surface temperature and composition, with direct exposure of ion source surfaces to rammed gas a necessary condition for the production of large amounts of NO2. Initial orbit data indicate that a period of surface conditioning is necessary before these odd nitrogen molecules can be produced efficiently.

Engebretson, M. J.↗
NASA NTRS2002

Stochastic Estimation and Non-Linear Wall-Pressure Sources in a Separating/Reattaching Flow

Simultaneous wall-pressure and PIV measurements are used to study the conditional flow field associated with surface-pressure generation in a separating/reattaching flow established over a fence-with-splitter-plate geometry. The conditional flow field is captured using linear and quadratic stochastic estimation based on the occurrence of positive and negative pressure events in the vicinity of the mean reattachment location. The results shed light on the dominant flow structures associated with significant wall-pressure generation. Furthermore, analysis based on the individual terms in the stochastic estimation expansion shows that both the linear and non-linear flow sources of the coherent (conditional) velocity field are equally important contributors to the generation of the conditional surface pressure.

Naguib, A.↗
NASA NTRS2002

Soil Moisture and Snow Cover: Active or Passive Elements of Climate

A key question is the extent to which surface effects such as soil moisture and snow cover are simply passive elements or whether they can affect the evolution of climate on seasonal and longer time scales. We have constructed ensembles of predictability studies using the NCAR CCM3 in which we compared the relative roles of initial surface and atmospheric conditions over the central and western U.S. in determining the subsequent evolution of soil moisture and of snow cover. Results from simulations with realistic soil moisture anomalies indicate that internal climate variability may be the strongest factor, with some indication that the initial atmospheric state is also important. Model runs with exaggerated soil moisture reductions (near-desert conditions) showed a much larger effect, with warmer surface temperatures, reduced precipitation, and lower surface pressures; the latter indicating a response of the atmospheric circulation. These results suggest the possibility of a threshold effect in soil moisture, whereby an anomaly must be of a sufficient size before it can have a significant impact on the atmospheric circulation and climate. Results from simulations with realistic snow cover anomalies indicate that the time of year can be crucial. When introduced in late winter, these anomalies strongly affected the subsequent evolution of snow cover. When introduced in early winter, however, little or no effect is seen on the subsequent snow cover. Runs with greatly exaggerated initial snow cover indicate that the high reflectivity of snow is the most important process by which snow cover can impact climate, through lower surface temperatures and increased surface pressures. The results to date were obtained for model runs with present-day conditions. We are currently analyzing runs made with projected forcings for the 21st century to see if these results are modified in any way under likely scenarios of future climate change. An intriguing new statistical technique involving 'clustering' is developed to assist in this analysis.

Oglesby, Robert J.↗
NASA NTRS2005

Numerical Investigation of Flow in an Over-Expanded Nozzle with Porous Surfaces

A new porous condition has been implemented in the PAB3D solver for simulating the flow over porous surfaces. The newly-added boundary condition is utilized to compute the flow field of a non-axisymmetric, convergent-divergent nozzle incorporating porous cavities for shock-boundary layer interaction control. The nozzle has an expansion ratio (exit area/throat area) of 1.797 and a design nozzle pressure ratio of 8.78. The flow fields for a baseline nozzle (no porosity) and for a nozzle with porous surfaces (10% porosity ratio) are computed for NPR varying from 2.01 to 9.54. Computational model results indicate that the over-expanded nozzle flow was dominated by shock-induced boundary-layer separation. Porous configurations were capable of controlling off-design separation in the nozzle by encouraging stable separation of the exhaust flow. Computational simulation results, wall centerline pressure, mach contours, and thrust efficiency ratio are presented and discussed. Computed results are in excellent agreement with experimental data.

Elmiligui, Alaa↗
NASA NTRS2006

Numerical Investigation of Flow in an Over-expanded Nozzle with Porous Surfaces

A new porous condition has been implemented in the PAB3D solver for simulating the flow over porous surfaces. The newly-added boundary condition is utilized to compute the flow field of a non-axisymmetric, convergent-divergent nozzle incorporating porous cavities for shock-boundary layer interaction control. The nozzle has an expansion ratio (exit area/throat area) of 1.797 and a design nozzle pressure ratio of 8.78. The flow fields for a baseline nozzle (no porosity) and for a nozzle with porous surfaces (10% porosity ratio) are computed for NPR varying from 2.01 to 9.54. Computational model results indicate that the over-expanded nozzle flow is dominated by shock-induced boundary-layer separation. Porous configurations are capable of controlling off-design separation in the nozzle by encouraging stable separation of the exhaust flow. Computational simulation results, wall centerline pressure, mach contours, and thrust efficiency ratio are presented and discussed. Computed results are in excellent agreement with experimental data.

Abdol-Hamid, Khaled S.↗