Materials and Platforms for the Optical Detection of Rare Earth Elements
Poster describing sensing materials and platforms for detection economically critical metals from unconventional sources such as acid mine drainage.
photoluminescence↗
SEARCH · Engineering Papers
Results for “site detection”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Air quality impacts from the development of unconventional oil and gas well pads: Air toxics and other volatile organic compounds
Unconventional oil and natural gas development (UOGD) has expanded rapidly across the United States in recent decades and raised concerns about associated air quality impacts. While significant effort has been made to quantify methane emissions, relatively few observations have been made of Volatile Organic Compounds (VOCs), especially during drilling and completion of new wells. Extensive air monitoring during development of several large, multi-well pads in Broomfield, Colorado, in the Denver-Julesburg Basin, provides a novel opportunity to examine changes in local air toxics and other VOC concentrations during well drilling and completions and production. These operations offer an especially useful case to study as several management practices were implemented to reduce emissions (e.g., electrified, grid-powered drill rigs and closed loop fluid handling systems to reduce truck traffic and limit fluid handling on the pad). With simultaneous measurements of methane and 50 VOCs from October 2018 to December 2022 at as many as 19 sites near well pads, in adjacent neighborhoods, and at a more distant reference location, we identify impacts from each phase of well development and production. Use of weekly, time-integrated canisters, a Proton Transfer Reaction Mass Spectrometer (PTR-MS), continuous photoionization detectors (PID) to trigger canister collection upon detection of VOC-rich plumes, and an instrumented vehicle, provided a powerful suite of measurements to characterize both transient plumes and longer-term changes in air quality. Prior to the start of well development, VOC gradients were small across Broomfield. Once drilling commenced, concentrations of oil and gas (O&G) related VOCs, including alkanes and aromatics, increased around active well pads. Concentration increases were clearly apparent during certain operations, including drilling, coil tubing/millout operations, and production tubing installation. Emissions of C 8 –C 10 n-alkanes during drilling operations highlighted the importance of VOC emissions from synthetic drilling mud chosen to reduce odor impacts. More than 90 samples were collected of transient plumes. Using composition measurements, meteorological data, and information about well pad activities, these plumes were connected with specific UOGD operations including drilling, flowback, and production equipment maintenance. The chemical signatures of these plumes differed by operation type (e.g., C 8 –C 10 n-alkanes constituted a larger fraction of measured VOCs in drilling-related plumes). Concentrations of individual, oil and gas-related VOCs in these plumes were often several orders of magnitude higher than in background air, with maximum ethane and benzene concentrations of 79,600 and 819 ppbv, respectively. Because these plumes typically impact a monitoring site for just several minutes, they are easily missed by slower-responding instruments. Study measurements highlight future emission mitigation opportunities during UOGD operations, including better control of emissions from shakers that separate drill cuttings from drilling mud, production separator maintenance operations, and periodic emptying of sand cans during flowback operations.
54 ENVIRONMENTAL SCIENCES↗
Monitoring of Dust Devil Tracks Around the InSight Landing Site, Mars, and Comparison With In Situ Atmospheric Data
The NASA InSight mission on Mars is a unique opportunity to study atmospheric processes both from orbit and in situ observations. We use post-landing high-resolution satellite images to monitor dust devil activity during the first 8 months of the mission. We perform mapping and semiautomatic detection of newly formed dust devil tracks and analyze their characteristics (sizes, azimuths, distances, and directions of motion).We find a large number of tracks appearing shortly after landing, followed by a significant decrease of activity during late winter, then a progressive increase during early spring. New tracks are characterized by dark linear, to slightly curvilinear, traces ranging from a few to more than 10 m wide. Tracks are oriented in the ambient wind direction, according to measurements made by InSight's meteorological sensors. The systematic analysis of dust devil tracks is useful to have a better understanding of atmospheric and aeolian activity around InSight.
C. Perrin↗
Site Selection for Mars Exopaleontology in 2001
The microbial fossil record encompasses a wide range of information, including cellular remains, stromatolites, biofabrics, trace fossils, biominerals and chemofossils. The preservation of fossils is strongly influenced by the physical, chemical and biological factors of the environment which, acting together, ultimately determine the types of information that will be captured and retained in the rock record. The critical factor in assessing the suitability of a site for a microbial fossil record is the paleoenvironment. The reconstruction of ancient sedimentary environments usually requires the integration of a wide variety of geological information, including the shape, geometry and internal structure of sedimentary deposits, their mineralogy, and geochemistry. For Mars, much of our knowledge about past environments is based on orbital imaging of geomorphic features. This evidence provides an important context and starting point for site selection. However, our knowledge of the martian surface is quite limited, and a major goal of the upcoming exploration effort is to reconstruct the history of Martian volatiles, climate, and hydrology as a context for the exploration for past or present life. Mineralogical mapping from orbit will be an important key in this effort. In exploring for evidence of past life, terrestrial experience suggests that the long-term preservation of biological information as fossils occurs under a fairly narrow range of geological conditions that are well known to paleontologists (1). In detrital sedimentary systems, microbial fossilization is favored by rapid burial in fine-grained, clay-rich sediments. In chemical sedimentary systems, preservation is enhanced by rapid entombment in fine-grained chemical precipitates. For long term preservation, host rocks must be composed of stable minerals that resist chemical weathering, and which form an impermeable matrix and closed chemical system that can protect biosignatures from alteration during subsequent diagenetic change or metamorphism. In this context, host rocks composed of highly ordered, chemically-stable mineral phases, like silica (forming cherts) or phosphate (forming phosphorites), are especially favored. Such lithologies tend to have very long crustal residence times and (along with carbonates and shales), are the most common host rocks for the Precambrian microfossil record on Earth. If we assume that a subsurface hydrosphere has been present throughout martian history, then life could have originated there at any time, perhaps emerging at the surface periodically when climate changes, induced by external forcing or endogenous processes (e.g. volcanism), allowed liquid water to exist at the surface. The recent discovery of subsurface chemolithoautotrophic organisms which are capable of synthesizing organic substrates from C02 and H2 liberated from the aqueous weathering of basalt, is especially. relevant as a model for martian life. While a subsurface habitable zone may yet exist on Mars, access to such environments will likely require drilling to depths of several kilometers. Given the technological challenge of deep drilling, this is unlikely to occur prior to human missions. So, even if there is extant life on Mars today in subsurface habitats, it may be much easier to find its fossil counterparts in ancient deposits exposed at the surface. In exploring for a fossil record in subsurface environments on Mars there are several geological situations that may provide access to the appropriate materials. These include 1) ejecta from impact craters, 2) talus slopes, debris flows or alluvial fans developed below the walls of deep canyons, and 3) the deposits of outflood channels. Examples of aqueous mineral deposits of formed in subsurface environments that could harbor a microbial fossil record include such things as cements in detrital sedimentary rocks, low temperature diagenetic minerals deposited in veins, or filling vesicles in volcanic rocks, and hydrothermal deposits formed below the upper temperature limit for life (about 160 degrees C). There are many sites within the present latitudinal constraints for the 2001 mission (15 deg S to 30 deg N) that meet these requirements. But the practical problem with these kinds of deposits is that they tend to be disseminated, making up only a small percentage of a host rock. Even with mineralogical information provided by the Thermal Emission Spectrometer (TES) presently in orbit around Mars, predicting their occurrence ahead of time may be quite difficult. The deposits of surficial aqueous sedimentary systems are likely to provide the largest targets for site selection in 2001. Of these, the deposits of hydrothermal systems (subaerial and subaqueous thermal springs) have been discussed previously. It is likely that hydrothermal systems were widespread on Mars early in its history and a number of common geo-tectonic settings on Mars are likely to have hosted hydrothermal activity. Most of these are represented within the latitudinal constraints presently identified for 2001. However, the deposits of surface spring systems are likely to be difficult to find as well. On Earth, exposure areas for hydrothermal spring mounds are typically a few square kms, less than a single TES pixel. But such deposits may be quite abundant within some volcanic terrains, It is estimated, for example, that between 15-20% of the floor of Yellowstone caldera is covered by thermal spring deposits. In such abundances, subaerial sinters could well be detected by TES. Where exposed, the shallow subsurface portions of these systems may be quite a lot larger (perhaps tens of square kms), although (as noted above) mineralization may be finely disseminated in the basement rock, making remote detection more difficult. Paleolake Basins. There are a large number of potential paleolake basins on Mars (inclusive of impact craters and volcanic calderas) that have been previously identified using Viking images. Most of these lie in the southern highlands beyond the l5 deg S constraint for 2001. However, deposits of paleolakes may offer the largest and most easily identified exopaleontological targets from orbit. Based on a variety of arguments, some workers have suggested that there was once an ancient ocean on the northern plains, and some sites of interest (potential shoreline terraces) fall within the 30 deg N constraint. From a paleontological standpoint the most interesting places of this type are terminal paleolake basins which are likely to have been both saline and alkaline. Models by Schaefer suggest such environments could be widespread on Mars. The conditions in terminal lake basin settings favor widespread chemical sedimentation, an important condition for microbial fossilization. Important lithological targets for a microbial fossil record in terminal lake basins include spring-deposited carbonates, shoreline cements, a wide variety of evaporite minerals and fine-grained detrital sediments including shales, marls, and water-lain volcanic ash deposits. In developing a strategy to explore for ancient hydrothermal deposits on Mars, we can learn from the methods that have been developed by explorationists to explore for economic mineral deposits on Earth. Due to their simple mineralogy, hydrothermal deposits can often be detected using remote sensing methods. Common thermal spring mineral assemblages include silica, carbonate, and various metallic oxides and sulfides. But there are also a number of diagnostic silicate minerals, including clays, formed by the hydrothermal alteration of country rocks. These hydrothermal minerals have characteristic spectral signatures that could be detected from Mars orbit using high resolution infrared remote sensing methods. In playa lake settings, evaporite deposits often form a predictable "bull's eye" pattern with carbonates being deposited in marginal basin areas, and sulfates and halides occurring progressively more basinward. The floors of some impact craters on Mars, such as "White Rock" and Bequeral Crater (see Oxia Palus NE, Site 148), have floor deposits that could be evaporites, inclusive of carbonates. Evaporite minerals possess characteristic spectral signatures in the infrared and could similarly be identified from Mars orbit using high resolution remote sensing methods. Clearly, utilization of TES data will be important for optimizing site selection for Exopaleontology, and every effort should be made to benefit from that data before a final decision is made.
Farmer, Jack↗
Integrating risk assessment methods for carbon storage: A case study for the quest carbon capture and storage facility
This paper documents how tools developed by the National Risk Assessment Partnership (NRAP) complement the Bowtie risk assessment approach through the demonstration of a risk-based Area of Review (AoR) determination for the Quest Carbon Capture and Storage (CCS) facility near Edmonton, Alberta with the NRAP Open-Source Integrated Assessment Model (NRAP Open-IAM). The Bowtie risk assessment for the Quest CCS site was developed by Shell Canada Ltd., who operates the asset on behalf of the Athabasca Oil Sand Project — a joint venture, owned by Canadian Natural Resources Ltd, Chevron Canada and Shell Canada Ltd. The Quest Bowtie treats site risk comprehensively – considering a large set of technical and project risks (e.g., operational risks, above ground infrastructure, public perception, etc.). NRAP tools, methods, and analyses are focused on quantitative assessment of subsurface technical risks. NRAP-Open-IAM was used to evaluate potential groundwater impacts at the Quest site, i.e., a sufficient change above background groundwater quality levels to be measurable, should CO 2 and/or brine leak from the reservoir via a faulty and/or compromised wellbore. Our results show there is a low potential for groundwater impact and support a further reduction (from ~460 to 100 km 2 ) to the established AoR for the Quest site. Integrating both approaches early in the site characterization period could significantly benefit commercial-scale projects by drastically reducing the region over which leakage risks (e.g., legacy wells) need to be evaluated, i.e., the AoR. This is especially true for brownfield sites, which could contain hundreds to thousands of legacy wells. Further, basing monitoring network design on those regions where impacts are most likely to occur has the potential to facilitate more efficient deployment of monitoring technologies and improve the likelihood of detecting a leak should one occur.
58 GEOSCIENCES↗
Synthesis and Quantum Metrology of Metal-Organic Framework-Coated Nanodiamonds Containing Nitrogen Vacancy Centers
ACS Spring 2022 National Meeting, Virtual, March 20-24, 2022
Shugayev, Roman↗
Observations of the Large Magellanic Cloud in high-energy gamma rays
The LMC provides a valuable site to study gamma-ray production, intensity, and distribution in an external galaxy. Using 4 weeks of data from the Energetic Gamma Ray Experiment Telescope (EGRET) aboard the Compton Gamma Ray Observatory, high-energy gamma-ray emission was detected for the first time from the LMC region. These gamma rays are believed to be produced primarily through the interaction of cosmic rays with interstellar matter. Hence, combined with a knowledge of the interstellar matter distribution, they can provide a direct measure of the cosmic-ray density in an external galaxy. The results obtained from EGRET observations indicate that the level of cosmic rays in the LMC is comparable to that in our Galaxy. The integrated flux above 100 MeV is (1.9 +/- 0.4) x 10 exp -7 photons/(sq cm s). The measured flux suggests a cosmic-ray density level consistent with that expected from a quasi-stable equilibrium model. This is the first detection of a normal galaxy outside the Milky Way in high-energy gamma rays.
Sreekumar, P.↗
Observations by the Mars 1994 orbiter and possible correlations with Mars Pathfinder
The Mars '94 spacecraft will still be operational when Mars Pathfinder begins its observations. While it will probably not be possible to detect the lander directly, the terrain, including the landing error ellipse, can be covered in high resolution (10 m) in various color bands. The stereo capability of the high resolution camera will provide a three-dimensional terrain map. The landing site of Pathfinder could possibly be chosen so that correlated observations of IMP and the remote sensing instruments onboard Mars '94 may be possible. We will discuss this scenario based on the presently adopted Mars '94 orbit and resulting enhancements stemming from correlations of data obtained by both spacecraft.
Keller, H. Uwe↗
A View of the Lunar Interior Through Lunar Laser Range Analysis
Laser ranges between observatories on the Earth and retroreflectors on the Moon started in 1969 and continue to the present. Recent range accuracies are 2 cm while earliest ranges are an C, order of magnitude less certain. Four retroreflectors are ranged: three located at the Apollo 11, 14, and 15 sites and one on the Lunakhod 2 rover. Accurate analysis of the range data determines a number of lunar science parameters. The lunar interior variables include a fluid core parameter. The Lunar Laser Ranging effort is reviewed elsewhere. Many parameters are detected through their influence on rotation. Also detected are solid-body tides and accurate selenocentric reflector locations. Determined through the rotation are moment-of-inertia differences, gravitational harmonics, potential Love number, and dissipation effects due to tides and molten core. The rotation of the Moon is not at its minimum energy state; some recently active process has caused free librations. The moment differences contributed to the recent improvement of the Moon's moment of inertia from the Lunar Prospector gravity field. The Love numbers provide bulk elastic properties. Future possibilities for measurement include oblateness of the core-mantle boundary and core moment. A study of dissipation signatures in the rotation determines tidal Q vs. frequency and concludes that the Moon has a molten core. At 1 month the tidal Q is 37 and at 1 yr it is 60. The core radius is < or = 352 km for Fe and < or = 374 km for the Fe-FeS eutectic. The core detection exceeds 3x its uncertainty. The spin of the core is not aligned with the spin of the mantle and torque arises from the velocity difference at the boundary. Yoder's turbulent boundary layer theory is used to compute the radii. The present heat generation from tides and core interaction is minor compared to radiogenic heating. The heating for ancient times is more interesting. Peale and Cassen investigated lunar tidal heating while the lunar orbit expanded due to tides on Earth. Their calculations predate the measurement of Q and should be multiplied by 3.45 to match the lunar-laser-determined Love number and monthly Q. Tidal-heating computations depend on how fast the lunar orbit evolved and whether the tidal dissipation is localized. Neither is known, but plausible assumptions lead to early central region temperature increases of several hundred degrees. Most of the energy is deposited early in the Moon's history. The turbulent boundary layer theory allows a prediction of energy dissipated at the core-mantle boundary during orbit evolution. Under the assumption that the properties of the early core are the same as at present, the energy dissipated by core-mantle interaction is about the same as for tidal dissipation, but it is deposited in a smaller volume. This source of energy is capable of promoting convection in an early fluid core and driving a dynamo. This is a transient phase with a duration depending on the rate of orbit evolution. Plausible assumptions lead to a duration of a few hundred million years. Thus, the remnant magnetization of many lunar rocks is compatible with a brief global magnetic field powered by dynamical energy dissipation. Analysis of the lunar laser ranges is providing information on lunar geophysics. Future data will improve accuracies of present solution parameters, and several more interior effects should be detectable.
Williams, J. G.↗
Major Volatiles from MSL SAM Evolved Gas Analyses: Yellowknife Bay Through Lower Mount Sharp
The Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments on the Mars Science Laboratory (MSL) analysed several subsamples of <150 μm fines from five sites at Gale Crater. Three were in Yellowknife Bay: the Rocknest aeolian bedform ("RN") and drilled Sheepbed mudstone from sites John Klein ("JK") and Cumberland ("CB"). One was drilled from the Windjana ("WJ") site on a sandstone of the Kimberly formation investigated on route to Mount Sharp. Another was drilled from the Confidence Hills ("CH") site on a sandstone of the Murray Formation at the base of Mt. Sharp (Pahrump Hills). Outcrops are sedimentary rocks that are largely of fluvial or lacustrine origin, with minor aeolian deposits.. SAM's evolved gas analysis (EGA) mass spectrometry detected H2O, CO2, O2, H2, SO2, H2S, HCl, NO, and other trace gases, including organic fragments. The identity and evolution temperature (T) of evolved gases can support CheMin mineral detection and place constraints on trace volatile-bearing phases or phases difficult to characterize with XRD (e.g., X-ray amorphous phases). They can also give constraints on sample organic chemistry. Here, we discuss trends in major evolved volatiles from SAM EGA analyses to date.
McAdam, A. C.↗
2005 AG20/20 Annual Review
Topics covered include: Implementation and Validation of Sensor-Based Site-Specific Crop Management; Enhanced Management of Agricultural Perennial Systems (EMAPS) Using GIS and Remote Sensing; Validation and Application of Geospatial Information for Early Identification of Stress in Wheat; Adapting and Validating Precision Technologies for Cotton Production in the Mid-Southern United States - 2004 Progress Report; Development of a System to Automatically Geo-Rectify Images; Economics of Precision Agriculture Technologies in Cotton Production-AG 2020 Prescription Farming Automation Algorithms; Field Testing a Sensor-Based Applicator for Nitrogen and Phosphorus Application; Early Detection of Citrus Diseases Using Machine Vision and DGPS; Remote Sensing of Citrus Tree Stress Levels and Factors; Spectral-based Nitrogen Sensing for Citrus; Characterization of Tree Canopies; In-field Sensing of Shallow Water Tables and Hydromorphic Soils with an Electromagnetic Induction Profiler; Maintaining the Competitiveness of Tree Fruit Production Through Precision Agriculture; Modeling and Visualizing Terrain and Remote Sensing Data for Research and Education in Precision Agriculture; Thematic Soil Mapping and Crop-Based Strategies for Site-Specific Management; and Crop-Based Strategies for Site-Specific Management.
Ross, Kenton W.↗
Detection of a Space Capsule Entering Earth’s Atmosphere with Distributed Acoustic Sensing (DAS)
On 24 September 2023, the Origins, Spectral Interpretation, Resource Identification, and Security-Regolith Explorer sample return capsule (SRC) entered Earth’s atmosphere after successfully collecting samples from an asteroid. The known trajectory and timing of this return provided a rare opportunity to strategically instrument sites to record geophysical signals produced by the capsule because it travelled at hypersonic speeds through the atmosphere. For this work, we deployed two distributed acoustic sensing (DAS) interrogators to sample over 12 km of surface-draped fiber-optic cables, as well as six collocated seismometer-infrasound sensor pairs, spread across two sites near Eureka, Nevada. This campaign-style rapid deployment is the first reported recording of an SRC re-entry with any distributed fiber-optic sensing technology. The DAS interrogators recorded an impulsive arrival with an extended coda which had features that were similar to recordings from both the seismometers and infrasound sensors. While the signal-to-noise ratio of the DAS data was lower than the seismic-infrasound data, the extremely dense spacing of fiber-optic sensors allowed for more phases to be clearly distinguished and the visualization of the continuous transformation of the wavefront as it impacted the ground. Unexpectedly, the DAS recordings contain less low-frequency content than is present in both the seismic and infrasound data. The deployment conditions strongly affected the recorded DAS data; in particular, we observed that fiber selection and placement exert strong controls on data quality.
58 GEOSCIENCES↗
Operational Focused Data Analytics for Optimizing Radiation Portal Monitor-Based Nuclear Smuggling Detection Systems at Global Ports of Entry
The National Nuclear Security Administration’s Office of Nuclear Smuggling Detection and Deterrence has deployed a fleet of radiation portal monitors (RPMs) across the world at global ports of entry including seaports, airports, and land border crossings. These RPMs are integrated into radiation detection systems (RDS) that also include fixed cameras, optical character recognition (OCR) systems, primary scanning systems (e.g., X-ray or gamma-ray), and secondary scanning systems (e.g., spectroscopic radiation portal monitors, portable radiation detection systems). The data from these sensing technologies is collected at the Central Alarm Station (CAS) where servers and computers reside to control and operate the system. Operators utilize the data collected by the CAS and declared cargo information to make decisions on how to respond to an alarm.This work explores the use of CAS-located data, looking at both the sensor data streams and operator inputs, to perform analysis which supports customs and border protection agencies to improve training capability and operational effectiveness. We focus on analyzing site level effectiveness and behavior by rolling up CAS-located data collected from individual occurrences. To-date, more than 15 sites (e.g., seaports, airports, border crossings) have been analyzed in this manner with the goal of understanding system operations to verify effectiveness and recommend potential improvements. This work first aims to provide background information on relevant CAS-located data sources and our current operational system analytics process including example results. After summarizing our current analytic techniques, we discuss how the future data analytics systems can provide key benefits to improving operational performance while minimizing the burden these detection systems place on operators.
Kuhn, Michael↗
SHADOZ (Southern Hemisphere ADditional OZonesondes): An Ozonesonde Network for Satellite Validation, Climatology and Modeling
In the past 5 years, new tropical ozone data products have been developed from TOMS and other satellites, During this period, global chemical-transport models have been used for ozone assessment studies. However, there has been a lack of independent ozone profiles in the tropics for evaluation of the data sets and models. In 1998, NASA's Goddard Space Flight Center, Wallops Flight Facility and NOAA's CMDL (Climate Monitoring and Diagnostics Lab), began a 2-year project to collect a consistent data set by augmenting ozonesonde launches at southern hemisphere tropical sites The measurements are available to the scientific community at a single electronic location - the SHADOZ website at NASA/Goddard: http://code9l6.gsfc.nasa.gov/Data services/Shadoz/shadoz hmpg2.html. Stations in SHADOZ include four islands in the Pacific: Fiji, Tahiti, San Cristobal (Galapagos) and American Samoa. Two sites are at and in the Atlantic: Natal (Brazil) and Ascension Island. Three other sites span Africa (Nairobi and Irene, South Africa) and the Indian Ocean (Reunion Island and Watukosek in Java, Indonesia). All SHADOZ sites are using ECC-type sondes, with the conversion from JMD sondes at Java in 1999, but there are variations in sonde preparation technique and data processing. During the 1998-1999 period, more than 550 sondes were incorporated into the SHADOZ data base. Examples from these measurements illustrate the tropical wave-one pattern in total ozone which is easily detectable by satellite. They also show that the wave-one pattern appears to be in the troposphere, as assumed in creating the modified-residual tropospheric ozone data product from TOMS. SHADOZ will add data from intensive field campaigns from time to time. Recent contributions to the SHADOZ archive are from the INDOEX (Indian Ocean Experiment January-March 1999)sondes at the Maldives (5N, 73E) and 27 sondes on the US NOAA oceanographic vessel, the FIN Ronald H Brown between Virginia (US) and Mauritius via CapeTown, during a cruise in January and February 1999. In 2000, as part of the SAFARI-2000 experiment and a validation project called Southern African Validation for EOS (SAVE), enhancement of ozonesonde launches at Irene (South Africa) will extend the data set from this site beyond the 1998-1999 period.
Thompson, Anne M.↗
Lithium thiostannate spinels: air-stable cubic semiconductors.
Lithium chalcogenide materials have been studied less than other alkali metal analogs and are of interest as ion conductors and semiconductors capable of thermal neutron detection. Herein, we describe the structural, thermal, magnetic, electronic, and ionic properties of a new family of cubic lithium thiospinels Li2MSn3S8 (M = Mg, Fe, Mn, Ni, Co) and Li1.66CuSn3.33S8. All compounds crystallize in the Fd (3) over barm space group and exhibit site occupancy disorder with Sn and M on the octahedral site for M = Mg, Fe, Mn, Ni, Co. The Li1.66CuSn3.33S8 compound also exhibits occupancy disorder on the tetrahedral sites between Li and Cu, as well as on the octahedral sites between Li and Sn. We demonstrate the ability to tune the physical properties of the compounds by changing their composition. By tuning the identity of the transition metal in the structure, the optical band gaps can vary between 0.91(2) and 2.19(2) eV, and electrical resistivities between 2.8 x 10(3) Omega-cm and 2.2 x 10(7)Omega-cm can be achieved. Density functional theory calculations for Li2MgSn3S8 and Li1.66CuSn3.33S8 suggest that both materials have indirect band gaps and significantly dispersive conduction bands. A bandwidth dispersion of 0.75 and 0.70 eV along the Gamma -> M direction in the conduction band are predicted for Li2MgSn3S8 and Li1.66CuSn3.33S8, respectively, with an electron effective mass of 0.49 and 0.55 m(e) at the Gamma point. The hole effective mass in the valence band is calculated to be 1.25 me at the M point and 0.75 me at the L point for Li2MgSn3S8 and Li1.66CuSn3.33S8, respectively. The ionic/electronic conductivity of each compound was determined using AC electrochemical impedance spectroscopy.
Quintero, Michael A.↗
Application of remote sensing in the determination of water quality in Nebraska reservoirs
In June, July, and August, 1975, ground truth was collected from Lake McConaughy, a 35,000 acre reservoir in western Nebraska, coincident with the overflights of LANDSAT. Water samples were collected on six different dates and analyzed for turbidity, suspended solids, and chlorophyll, parameters which had correlated well with CCT reflectances. The correlations and regressions reported were derived from data obtained on only three of the six sampling dates. The radiance values from each of the four spectral bands were printed out in the form of a map of Lake McConaughy. Reflectances in the various bands were then obtained from the map at the appropriate sampling sites. The dependent variables chlorophyll, suspended solids, and turbidity were compared to the independent variables - reflectances in the four bands - by regression analysis. Both multiple and univariate regressions were examined. It is concluded that CCT's from LANDSAT can be used to detect and quantify the water quality parameters suspended solids, turbidity, and chlorophyll.
Hergenrader, G. L.↗
Patterns of vegetation in the Owens Valley, California
Spectral characteristics of semi-arid shrub communities were examined using Airborne Imaging Spectrometer (AIS) data collected in the tree mode on 23 May 1985. Mesic sites with relatively high vegetation density and distinct zonation patterns exhibited greater spectral signature variations than sites with more xeric shrub communities. Spectral signature patterns were not directly related to vegetation density or physiognomy, although spatial maps derived from an 8-channel maximum likelihood classification were supported by photo-interpreted surface features. In AIS data, the principal detected effect of shrub vegetation on the alluvial fans is to lower reflectance across the spectrum. These results are similar to those reported during a period of minimal physiological activity in autumn, indicating that shadows cast by vegetation canopies are an important element of soil-vegetation interaction under conditions of relatively low canopy cover.
Ustin, S. L.↗
Assessment of AVIRIS data from vegetated sites in the Owens Valley, California
Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were acquired from the Bishop, CA area, located at the northern end of the Owens Valley, on July 30, 1987. Radiometrically-corrected AVIRIS data were flat-field corrected, and spectral curves produced and analyzed for pixels taken from both native and cultivated vegetation sites, using the JPS SPAM software program and PC-based spreadsheet programs. Analyses focussed on the chlorophyll well and red edge portions of the spectral curves. Results include the following: AVIRIS spectral data are acquired at sufficient spectral resolution to allow detection of blue shifts of both the chlorophyll well and red edge in moisture-stressed vegetation when compared with non-stressed vegetation; a normalization of selected parameters (chlorophyll well and near infrared shoulder) may be used to emphasize the shift in red edge position; and the presence of the red edge in AVIRIS spectral curves may be useful in detecting small amounts (20 to 30 pct cover) of semi-arid and arid vegetation ground cover. A discussion of possible causes of AVIRIS red edge shifts in respsonse to stress is presented.
Rock, B. N.↗