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NASA NTRS1982

Stratospheric aerosols - Observation and theory

Important chemical and physical roles of aerosols are discussed, and properties of stratospheric aerosols as revealed by experimental data are described. In situ measurements obtained by mechanical collection and scattered-light detection yield the overall size distribution of the aerosols, and analyses of preserved aerosol precursor gases by wet chemical, cryogenic and spectroscopic techniques indicate the photochemical sources of particle mass. Aerosol chemical reactions including those of gaseous precursors, those in aqueous solution, and those on particle surfaces are discussed, in addition to aerosol microphysical processes such as nucleation, condensation/evaporation, coagulation and sedimentation. Models of aerosols incorporating such chemical and physical processes are presented, and simulations are shown to agree with measurements. Estimates are presented for the potential aerosol changes due to emission of particles and gases by aerospace operations and industrial consumption of fossil fuels, and it is demonstrated that although the climatic effects of existing levels of stratospheric aerosol pollution are negligible, potential increases in those levels might pose a future threat.

Turco, R. P.↗

NASA NTRS1996

Theoretical Studies of the HO/HO2 Catalytic Cycle for Ozone Destruction

Recently it has been determined that the HO/HO2 catalytic cycle accounts for nearly one-half of the total ozone depletion in the lower stratosphere. The catalytic cycle is: (1) HO + O3 yields HO2 + O2; (2) HO2 + O3 yields HO + O2 + O2. The net reaction is 2O3 yields 3O2. The rate limiting step in this process is the reaction of HO2 with ozone. There is a problem extending the experimental measurement of the rate of this reaction over the range 233-400 K down to stratospheric temperatures of 210-220 K. Therefore we have undertaken a project to determine the temperature dependence of the rate constant for this reaction in the low temperature region. The first step in this project, which is described in this poster, is the determination of the relevant potential energy surfaces. The calculations use CASSCF/derivative methods to define the pathways followed by CASSCF/ACPF to determine the energetics. The HO + O3 reaction is found to proceed through an HO4 complex, which is unstable with respect to HO2 + O2. The HO2 +O3 reaction is more complex. One pathway, which has been characterized, is the formation of an HO5 complex which decomposes to HO3 + O2 and subsequently to HO + O2 + O2. Another pathway, which is believed to also play a role, is hydrogen abstraction to give O2 + HO3 and subsequent decomposition of HO3 to HO + O2. Isotopic labeling experiments indicate that the later pathway is dominant. However, so far attempts to locate the saddle point for this pathway have not been successful. We have also characterized the potential energy surfaces for a number of species involved in these reactions, including HO3 and triplet O4. The triplet O4 species is probably involved in the reaction of vibrationally excited O2 with ground state O2 leading to O3 + O. The latter reaction is believed to be important as an additional source of stratospheric ozone.

Walch, Stephen P.↗

NASA NTRS2023

Accessing Icy Worlds Using Lattice Confinement Fusion (LCF) Fast Fission

Exploring the oceans of icy moons and planets requires a robust robotic probe powered by an energy source that can operate under icy world ocean conditions and be self-contained. We propose a non-fissile, compact, scalable nuclear energy source to electrically power untethered, autonomous probes to melt or bore through icy world crusts. The probe can be used for planetary (i.e. Pluto, lunar (i.e., Europa), or asteroid exploration (i.e. Ceres) where ice caps are encountered. This new approach may yield a variable output fission power source with a higher performance than 238Pu and a non-fissile alternative to a highly enriched uranium (HEU) core. This approach saves uranium enrichment expense, and both HEU and 238Pu security and launch safety costs. The reactor will produce electrical power with thermal waste heat to melt through the ice crust with possible sonic assistance. This NIAC funded proposal and presentation will introduce the hybrid fusion-fission reactor concept applied to the Saturnian moon, Enceladus, explore the potential for and benefits of this new type of nuclear reactor, and discuss applying this new technology.

Icy Worlds↗

NASA NTRS1981

Design model for the baffle aperture region of a hollow cathode thruster

A current balance on the main discharge chamber of an electron bombardment thruster is carried out. It is shown that the discharge current is the sum of the net cathode emission current, the beam current, and the ion current to cathode potential surfaces. Measurements of ion currents outside the virtual anode surface in a SERT II divergent magnetic field thruster show that relatively few ions cross this surface. This implies that ions are directed preferentially toward the anode and cathode pole pieces. A simple theoretical model useful as an aid in the design of the baffle aperture region of a hollow cathode equipped thruster is developed. The electron diffusion process through the aperture is modeled in accordance with the Bohm diffusion theory. The model is shown to yield consistent results for a given thruster geometry over substantial changes in operating conditions. The model's design usefulness is limited by a factor of two uncertainty observed over different thruster/cathode region geometries and by the accuracy to which the plasma parameters required as inputs to the model can be specified.

Brophy, J. R.↗

NASA NTRS1996

Propulsion Selection for 85kft Remotely Piloted Atmospheric Science Aircraft

This paper describes how a 3 stage turbocharged gasoline engine was selected to power NASA's atmospheric science unmanned aircraft now under development. The airplane, whose purpose is to fly sampling instruments through targeted regions of the upper atmosphere at the exact location and time (season, time of day) where the most interesting chemistry is taking place, must have a round trip range exceeding 1000 km, carry a payload of about 500 lb to altitudes exceeding 80 kft over the site, and be able to remain above that altitude for at least 30 minutes before returning to base. This is a subsonic aircraft (the aerodynamic heating and shock associated with supersonic flight could easily destroy the chemical species that are being sampled) and it must be constructed so it will operate out of small airfields at primitive remote sites worldwide, under varying climate and weather conditions. Finally it must be low cost, since less than $50 M is available for its development. These requirements put severe constraints on the aircraft design (for example, wing loading in the vicinity of 10 psf) and have in turn limited the propulsion choices to already-existing hardware, or limited adaptations of existing hardware. The only candidate that could emerge under these circumstances was a propeller driven aircraft powered by spark ignited (SI) gasoline engines, whose intake pressurization is accomplished by multiple stages of turbo-charging and intercooling. Fortunately the turbocharged SI powerplant, owing to its rich automotive heritage and earlier intensive aero powerplant development during WWII, enjoys in addition to its potentially low development costs some subtle physical advantages (arising from its near-stochiometric combustion) that may make it smaller and lighter than either a turbine engine or a diesel for these altitudes. Just as fortunately, the NASA/industry team developing this aircraft includes the same people who built multi-stage turbocharged SI powerplants for unmanned military spyplanes in the early 1980's. Now adapting hardware developed for reconaissance at 65-70 kft to the interests of atmospheric science at 80-90 kft, their efforts should yield an aero powerplant that pushes the altitude limits of subsonic air breathing propulsion.

Bents, David J.↗

NASA NTRS1974

Geological evaluation and applications of ERTS-1 imagery over Georgia

ERTS-1 70mm and 9 x 9 film negatives are being used by conventional and color enhancement methods as a tool for geologic investigation. Geologic mapping and mineral exploration by conventional methods is very difficult in Georgia. Thick soil cover and heavy vegetation cause outcrops of bed rock to be small, rare and obscure. ERTS imagery, and remote sensing in general have helped delineate: (1) major tectonic boundaries; (2) lithologic contacts; (3) foliation trends; (4) topographic lineaments; and (5) faults. The ERTS-1 MSS imagery yields the greatest amount of geologic information on the Piedomont, Blue Ridge, and Valley and Ridge Provinces of Georgia where topography is strongly controlled by the bedrock geology. ERTS imagery, and general remote sensing techniques, have provided us with a powerful tool to assist geologic research; have significantly increased the mapping efficiency of our field geologists; have shown new lineaments associated with known shear and fault zones; have delineated new structural features; have provided a tool to re-evaluate our tectonic history; have helped to locate potential ground water sources and areas of aquifer recharge; have defined areas of geologic hazards; have shown areas of heavy siltation in major reservoirs; and by its close interval repetition, have aided in monitoring surface mine reclamation activities and the environmental protection of our intricate marshland system.

Pickering, S. M.↗

NASA NTRS2012

Free-Mass and Interface Configurations of Hammering Mechanisms

A series of free-mass designs for the ultrasonic/ sonic driller/corer (USDC) has been developed to maximize the transfer of energy from the piezoelectric transducer through the horn to the bit, as well as to minimize potential jamming. A systematic development was made producing novel designs of free-mass configurations where the impact force is spread across a minimal area maximizing the impact on the bit. The designed free masses were made to operate at high temperatures (500 C) as on Venus, and they can be made to operate at extremely low temperature, too. In normal operation, the free mass bounces between the horn and the bit, impacting both repeatedly. The impact stress profile, maximum stress, contact time duration, and the required yielding stress for the materials of the free mass, bit, and horn are all affected by the contact area. A larger contact area results in lower stress in the contact region, and avoids yielding of the materials. However, before the excitation voltage is applied to the transducer, the horn, free mass, and the bit are pressed together. Larger contact area results in a stronger coupling of the bit to the horn transducer, which greatly changes the vibration characteristics of the transducer, and makes the USDC difficult to start. To obtain optimum performance, a catalog of free-mass designs is required, allowing maximum flexibility during trade-off for these conflicting contact area requirements. For this purpose, seven different designs were conceived: point contacts, circular contacts, point/circular contacts, line contacts, ring contacts, line/ring contacts, and dashed line contacts. Besides point/circular and line/ring contacts, the free mass can be designed as any of the above shapes. Depending on the ratio of the diameter to the height, and the free-mass retention method used (the cup or rod), the free mass can be configured with one or more sliding surfaces on the outside or inside diameter surface or both. Matching horn tips and free mass may also offer some utility in maximizing the stress pulse.

Bao, Xiaoqi↗

NASA NTRSDate not supplied

Bionutrients-1: Utilizing Genomics and Transcriptomics to Assess the Reliability of Microorganisms for In Situ Nutrient Production on Long Duration Missions

The resupply of current long-duration crewed missions to the ISS relies on ground-launched supplies. As NASA looks toward Mars, ground-based resupply will no longer be an option. Critical nutrients, including vitamin C, vitamin K, folate, and thiamin, degrade during long-term storage, and regular consumption of these nutrients is essential for astronaut health. Another challenge of current food systems is the difficulty of consuming sufficient calories when subsisting on the limited flavors of freeze-dried food, which can lead to weight loss. The inclusion of microorganism-based food systems could alleviate both concerns. For example, the fermentation of rehydrated milk into yogurt with microorganisms genetically incorporating genes to produce critical vitamins would allow for both in situ production of nutrients and a fresh food product with additional flavor profiles. In comparison to plant food production, microorganisms require less flight infrastructure. The BioNutrients-1 mission is demonstrating viability of microbial fermentation food production in microgravity and testing the reliability of this approach for long-duration missions lacking resupply. While the BioNutrients-1 mission includes the collection of multiple phenotypic measurements, this status update will focus on the processing of samples for genomics and transcriptomics analyses as well as the planned analysis pipelines. First, the BioNutrients-1 mission seeks to identify microorganisms capable of surviving long-duration storage at ambient temperatures while maintaining genetic fidelity. To achieve this, nine commonly employed microbial species were stored at ambient temperatures in Stasis Packs on the ISS for five years. The viability and mutation rates will be measured at multiple time points for both flown and ground control samples. From an omics perspective, the changes in the bulk rates of point mutations and genetic rearrangements across the Stasis Pack species during the five years of storage will be determined, providing valuable insights into the potential of these microorganisms for long-duration space missions. Second, the BioNutrients-1 mission is characterizing the impact of microgravity on fermentation. Two strains of the yeast Saccharomyces cerevisiae, each encoding antioxidants (β-carotene or zeaxanthin) were flown to ISS for storage and fermentation within simplified bioreactors (Production Packs). The impact of microgravity on the expression of the antioxidant production genes and general metabolic genes will be determined using RNA sequencing. Ultimately, the transcriptome data will be compared to phenotypic measurements, such as the antioxidant yield, end-state biomass, and the production of EtOH, to determine the impacts of microgravity and long-term storage on microbial fermentation. The findings from this research will be instrumental in understanding the challenges and opportunities of microorganism-based food systems in space missions.

BioNutrients↗

NASA NTRS1975

Fully unsteady subsonic and supersonic potential aerodynamics for complex aircraft configurations with applications to flutter

A general formulation is presented for the analysis of steady and unsteady, subsonic and supersonic aerodynamics for complex aircraft configurations. The theoretical formulation, the numerical procedure, the description of the program SOUSSA (steady, oscillatory and unsteady, subsonic and supersonic aerodynamics) and numerical results are included. In particular, generalized forces for fully unsteady (complex frequency) aerodynamics for a wing-body configuration, AGARD wing-tail interference in both subsonic and supersonic flows as well as flutter analysis results are included. The theoretical formulation is based upon an integral equation, which includes completely arbitrary motion. Steady and oscillatory aerodynamic flows are considered. Here small-amplitude, fully transient response in the time domain is considered. This yields the aerodynamic transfer function (Laplace transform of the fully unsteady operator) for frequency domain analysis. This is particularly convenient for the linear systems analysis of the whole aircraft.

Tseng, K.↗

NASA NTRS1972

Evaluation of the pulse-contour method of determining stroke volume in man.

The pulse-contour method for determining stroke volume has been employed as a continuous rapid method of monitoring the cardiovascular status of patients. Twenty-one patients with ischemic heart disease and 21 patients with mitral valve disease were subjected to a variety of hemodynamic interventions. The pulse-contour estimations, using three different formulas derived by Warner, Kouchoukos, and Herd, were compared with indicator-dilution outputs. A comparison of the results of the two methods for determining stroke volume yielded correlation coefficients ranging from 0.59 to 0.84. The better performing Warner formula yielded a coefficient of variation of about 20%. The type of hemodynamic interventions employed did not significantly affect the results using the pulse-contour method. Although the correlation of the pulse-contour and indicator-dilution stroke volumes is high, the coefficient of variation is such that small changes in stroke volume cannot be accurately assessed by the pulse-contour method. However, the simplicity and rapidity of this method compared to determination of cardiac output by Fick or indicator-dilution methods makes it a potentially useful adjunct for monitoring critically ill patients.

Alderman, E. L.↗

NASA NTRS1983

The constancy of G and other gravitational experiments

Recent solar system experimental tests of the general relativity theory are reviewed. The solar system data set available at the Harvard-Smithsonian Center for Astrophysics is first reviewed. Investigations of the secular variation of G in the solar system are discussed; recent analyses using Viking data yield G-dot/G of less than 3 x 10 to the -11th/yr. The present data set will make it possible to distinguish between competitive theories. Shapiro's time-delay effect has provided the most stringent solar system test of general relativity. The effect has been measured to be consistent with the predictions of the theory to within an uncertainty of 0.1 percent. Tests which can be performed in the near future, including the measurement of relativistic effects due to the square of the solar potential and the detection of the Lense-Thirring effect, are discussed.

Reasenberg, R. D.↗

NASA NTRS1987

Positron annihilation gamma rays from novae

The potential for observing annihilation gamma rays from novae is investigated. These gamma rays, a unique signature of the thermonuclear runaway models of novae, would result from the annihilation of positrons emitted by beta(+)-unstable nuclei produced near the peak of the runaway and carried by rapid convection to the surface of the nova envelope. Simple models, which are extensions of detailed published models, of the expansion of the nova atmospheres are evolved. These models serve as input into investigations of the fate of nearby Galactic fast novae could yield detectable fluxes of electron-positron annihilation gamma rays produced by the decay of N-13 and F-18. Although nuclear gamma-ray lines are produced by other nuclei, it is unlikely that the fluxes at typical nova distances would be detectable to present and near-future instruments.

Leising, Mark D.↗

NASA NTRS1991

Nondestructive Structural Damage Detection in Flexible Space Structures Using Vibration Characterization

Spacecraft are susceptible to structural damage over their operating life from impact, environmental loads, and fatigue. Structural damage that is not detected and not corrected may potentially cause more damage and eventually catastrophic structural failure. NASA's current fleet of reusable spacecraft, namely the Space Shuttle, has been flown on several missions. In addition, configurations of future NASA space structures, e.g. Space Station Freedom, are larger and more complex than current structures, making them more susceptible to damage as well as being more difficult to inspect. Consequently, a reliable structural damage detection capability is essential to maintain the flight safety of these structures. Visual inspections alone can not locate impending material failure (fatigue cracks, yielding); it can only observe post-failure situations. An alternative approach is to develop an inspection and monitoring system based on vibration characterization that assesses the integrity of structural and mechanical components. A methodology for detecting structural damage is presented. This methodology is based on utilizing modal test data in conjunction with a correlated analytical model of the structure to: (1) identify the structural dynamic characteristics (resonant frequencies and mode shapes) from measurements of ambient motions and/or force excitation; (2) calculate modal residual force vectors to identify the location of structural damage; and (3) conduct a weighted sensitivity analysis in order to assess the extent of mass and stiffness variations, where structural damage is characterized by stiffness reductions. The approach is unique from other existing approaches in that varying system mass and stiffness, mass center locations, the perturbation of both the natural frequencies and mode shapes, and statistical confidence factors for structural parameters and experimental instrumentation are all accounted for directly.

Ricles, James M.↗

NASA NTRS2009

Superconducting Hot-Electron Submillimeter-Wave Detector

A superconducting hot-electron bolometer has been built and tested as a prototype of high-sensitivity, rapid-response detectors of submillimeter-wavelength radiation. There are diverse potential applications for such detectors, a few examples being submillimeter spectroscopy for scientific research; detection of leaking gases; detection of explosive, chemical, and biological weapons; and medical imaging. This detector is a superconducting-transition- edge device. Like other such devices, it includes a superconducting bridge that has a low heat capacity and is maintained at a critical temperature (T(sub c)) at the lower end of its superconducting-transition temperature range. Incident photons cause transient increases in electron temperature through the superconducting-transition range, thereby yielding measurable increases in electrical resistance. In this case, T(sub c) = 6 K, which is approximately the upper limit of the operating-temperature range of silicon-based bolometers heretofore used routinely in many laboratories. However, whereas the response speed of a typical silicon- based laboratory bolometer is characterized by a frequency of the order of a kilohertz, the response speed of the present device is much higher characterized by a frequency of the order of 100 MHz. For this or any bolometer, a useful figure of merit that one seeks to minimize is (NEP)(tau exp 1/2), where NEP denotes the noise-equivalent power (NEP) and the response time. This figure of merit depends primarily on the heat capacity and, for a given heat capacity, is approximately invariant. As a consequence of this approximate invariance, in designing a device having a given heat capacity to be more sensitive (to have lower NEP), one must accept longer response time (slower response) or, conversely, in designing it to respond faster, one must accept lower sensitivity. Hence, further, in order to increase both the speed of response and the sensitivity, one must make the device very small in order to make its heat capacity very small; this is the approach followed in developing the present device.

Karasik, Boris↗

NASA NTRS2017

Developing a Robust, Interoperable GNSS Space Service Volume (SSV) for the Global Space User Community

For over two decades, researchers, space users, Global Navigation Satellite System (GNSS) service providers, and international policy makers have been working diligently to expand the space-borne use of the Global Positioning System (GPS) and, most recently, to employ the full complement of GNSS constellations to increase spacecraft navigation performance. Space-borne Positioning, Navigation, and Timing (PNT) applications employing GNSS are now ubiquitous in Low Earth Orbit (LEO). GNSS use in space is quickly expanding into the Space Service Volume (SSV), the signal environment in the volume surrounding the Earth that enables real-time PNT measurements from GNSS systems at altitudes of 3000 km and above. To support the current missions and planned future missions within the SSV, initiatives are being conducted in the United States and internationally to ensure that GNSS signals are available, robust, and yield precise navigation performance. These initiatives include the Interagency Forum for Operational Requirements (IFOR) effort in the United States, to support GPS SSV signal robustness through future design changes, and the United Nations-sponsored International Committee on GNSS (ICG), to coordinate SSV development across all international GNSS constellations and regional augmentations. The results of these efforts have already proven fruitful, enabling new missions through radically improved navigation and timing performance, ensuring quick recovery from trajectory maneuvers, improving space vehicle autonomy and making GNSS signals more resilient from potential disruptions. Missions in the SSV are operational now and have demonstrated outstanding PNT performance characteristics; much better than what was envisioned less than a decade ago. The recent launch of the first in a series of US weather satellites will employ the use of GNSS in the SSV to substantially improve weather prediction and public-safety situational awareness of fast moving events, including hurricanes, flash floods, severe storms, tornados and wildfires. Thus, the benefits of the GNSS expansion and use into the SSV are tremendous, resulting in orders of magnitude return in investment to national governments and extraordinary societal benefits, including lives saved and critical infrastructure and property protected. However, this outstanding success is tempered by dual challenges: that for GPS, the current SSV specifications do not adequately protect SSV future use; and that for GNSS, the capabilities that are currently available are not protected in the future by specifications.

Bauer, Frank H.↗

NASA NTRS2017

Developing a Robust, Interoperable GNSS Space Service Volume (SSV) for the Global Space User Community

Bauer, Frank H.↗

NASA NTRS2026

Influence of Processing Parameters on the Mechanical Properties of 3D Printed Borosilicate Particulate Reinforced Polymer Composites

Emerging composite materials are expanding the potential of additive manufacturing and enabling applications previously restricted by traditional manufacturing methods. The multi-phase nature of these composite materials combined with the complex in-ternal geometry of additively manufactured parts have enabled unique behavior, and potentially new applications. Additionally, these materials can be pyrolyzed to create dense metal, ceramic, and glass parts with geometries typically not achievable by tra-ditional processes. Additive manufacturing of borosilicate glass-based systems can open new applications in nuclear engineering, astronomy, and bone regrowth therapy. To elucidate the process-parameter relationship of borosilicate-polylactic acid (PLA) composites, mechanical testing was conducted and compared with a pure polylactic acid polymer baseline. Test specimens were fabricated by fused-filament fabrication with minimal post-processing. Yield strength, ultimate strength, and elastic modulus were calculated from stress-strain curves. Optical and scanning electron microscopy were conducted to observe the specimen microstructure before and after testing. The highest compressive yield strength for the composite was 28.22 MPa, and the highest compressive yield strength for PLA was 49.30 MPa. Print orientation was found to benefit the composite material but have a detrimental effect on the pure matrix material. An elastic modulus of 2.66 GPa was recorded for the borosilicate-PLA composite at 100% infill, 1 shell wall, and layer lines parallel to compression axis. Microscopy revealed that lower modulus composite specimens had the particulates re-distributed within the matrix. Tensile testing was done according to a polymer testing standard, which caused difficulties obtaining consistent fracture within the gauge length.

mechanical testing↗

NASA NTRS1994

The Fraternal Twins of Quartet O4(+)

Eleven stationary geometries of quartet O4(+) have been studied by ab initio methods. The geometries were optimized at the Complete Active Space Self-Consistent Field (CASSCF) level of theory and the energies were calculated by the multiconfigurational second order pertubation method (CASPT2), using Double-Zeta Plus polarization (DZP), Triple-Zeta Plus Double Polarization (TZ2P), average Atomic Natural Orbital (ANO) (5s4p2d) and average ANO (6s5p3d2f) basis sets. The rectangular and trans-planar structures are found to be the most stable, with an energy barrier to conversion between the two at the threshold of dissociation. Both have a delocalized hole and are stable relative to separated 02 and 02(+)by 11.0 and 11.5 kcal/mol for the rectangular and the 2 trans-planar structure, respectively, compared with the experimentally deduced energy in the range of 9.2 to 10.8 kcal/mol. The adiabatic ionization potentials of 04 and 02 are computed to be 11.67 and 12.21 eV, while experimental values are 11.66 and 12.07 eV, respectively. The vibrational frequencies have been computed for all degrees of freedom at the CASSCF level of theory. Symmetry breaking is found to be a particular problem in the computation of the antisymmetric stretch frequency for the delocalized structures at the CASSCF level of theory. Attempts to rectify these problems using the restricted active space self-consistent field (RASSCF) method leads to additional difficulties, but further analysis yields insight into the symmetry breaking and problems with earlier calculations. Finally, a nonorthogonal configuration interaction (CI) calculation based on the interaction of localized CASSCF wave functions using the Complete Active Space State Interation (CASSI) method leads to a balanced treatment of the antisymmetric stretch which is free from symmetry breaking. The study explains the four most prominent absorption frequencies observed in the partially unassigned IR spectrum of O4(+) isolated in solid neon as the antisymmetric OO stretch, and the combination band of the symmetric and antisymmetric 00 stretch of both the rectangular and trans-planar structures.

Lindh, Roland↗