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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,261 records · Page 70
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Computational attributes of the integral form of the equation of transfer

Difficulties can arise in radiative and neutron transport calculations when a highly anisotropic scattering phase function is present. In the presence of anisotropy, currently used numerical solutions are based on the integro-differential form of the linearized Boltzmann transport equation. This paper, departs from classical thought and presents an alternative numerical approach based on application of the integral form of the transport equation. Use of the integral formalism facilitates the following steps: a reduction in dimensionality of the system prior to discretization, the use of symbolic manipulation to augment the computational procedure, and the direct determination of key physical quantities which are derivable through the various Legendre moments of the intensity. The approach is developed in the context of radiative heat transfer in a plane-parallel geometry, and results are presented and compared with existing benchmark solutions. Encouraging results are presented to illustrate the potential of the integral formalism for computation. The integral formalism appears to possess several computational attributes which are well-suited to radiative and neutron transport calculations.

Frankel, J. I.↗
NASA NTRS1990

Interpretation of satellite-measured bidirectional reflectance from Cirrus cloudy atmospheres

The interpretation of the observed bidirectional reflectance from cirrus cloudy atmospheres is presented. A theoretical model was developed for the computation of the transfer of solar radiation in an anisotropic medium with particular applications to oriented ice crystals in cirrus clouds. In this model, the adding principle for radiative transfer was used with modifications to account for the anisotropy of scattering particles and the associated scattering phase matrix. The single-scattering properties, including the phase function, single-scattering albedo, and extinction cross sections, were used for randomly and horizontally oriented hexagonal ice crystals in radiative transfer computations. The radiative transfer model developed for the cirrus clouds was modified to account for the scattering contributions from the atmosphere and the surface. In order to test the relevance and significance of the ice crystal model for the interpretation of observed bidirectional reflectance from satellites, visible radiances collected on the half hour by the GOES series were selected. The data are calibrated and corrected with the proper filter functions, then navigated to match selected landmark data. A number of clear and cloudy cases during the cirrus IFO of the Fire experiment were chosen for theoretical analyses. The cloud particle shape and size distributions that were taken during satellite overpasses are used in radiative transfer calculations. The sensitivities of the shape, orientation, and size distribution of ice crystals on the reflected intensities at the top of the atmosphere are investigated. Finally, the relative importance of these cloud microphysical properties in the interpretation of satellite bidirectional reflectance are assessed and presented.

Takano, Y.↗
NASA NTRSDate not supplied

RF Differential Phase Noise Measurements of the LISA TRL-6 Laser

RF differential phase noise (RF modulation sideband phase noise): phase jitter between the optical sideband generated from phase modulation and the optical carrier. Clock noise information of each space craft (s/c) is imprinted on the RF modulation sidebands and transferred between s/c through beating of the sidebands. Therefore, it is necessary to manage the RF modulation phase noise as light propagates from the phase modulator to the power amplifier delivery fiber.

Phase noise↗
NASA NTRS1984

Microwave radiances from precipitating clouds containing aspherical ice, combined phase, and liquid hydrometeors

A numerical algorithm based on Eddington's second approximation to the equation of radiative transfer has been developed in order to compute the radiances with horizontal and vertical polarization that emerge from precipitating clouds. This algorithm yields a rapid solution to problems pertaining to clouds with vertically inhomogeneous structure. Precipitating clouds containing liquid, mixtures of phases, and ice hydrometeors are modelled. It is shown that the lower-frequency radiances are sensitive to liquid precipitation at low altitudes while the higher-frequency radiances are more sensitive to the ice hydrometeors at the cloud tops. The extinction coefficients of aspherical hydrometeors are presented as a function of rainfall rates. The fact that vertically polarized radiances are warmer than horizontally polarized ones at high rainfall rates, with the difference diminishing at lower frequencies, is due to aspherical ice hydrometeors in the upper regions of precipitating clouds.

Wu, R.↗
NASA NTRS1980

Performance analysis and simulation of the SPS reference phase control system

The solar power satellite (SPS) concept envisions several hundred thousand synchronized microwave power amplifiers operating in parallel to produce an aggregate power output of 5-10 GW. This power is to be transferred to earth with the aid of a microwave/millimeter-wave beaming system operating in a synchronous orbit. The reference phase control system is considered along with aspects of pilot signal parameter selection. A power transponder analysis is conducted and an SPS performance evaluation is performed. Attention is given to system jitters and imperfections, the definition of power transfer efficiency, and the effects of system imperfections on SPS efficiency. It is found that the power transfer efficiency is relatively insensitive to the amplitude jitters. However, the effects of location jitters can produce a severe degradation of efficiency.

Chie, C. M.↗
NASA NTRS2010

Phase and Pupil Amplitude Recovery for JWST Space-Optics Control

This slide presentation reviews the phase and pupil amplitude recovery for the James Webb Space Telescope (JWST) Near Infrared Camera (NIRCam). It includes views of the Integrated Science Instrument Module (ISIM), the NIRCam, examples of Phase Retrieval Data, Ghost Irradiance, Pupil Amplitude Estimation, Amplitude Retrieval, Initial Plate Scale Estimation using the Modulation Transfer Function (MTF), Pupil Amplitude Estimation vs lambda, Pupil Amplitude Estimation vs. number of Images, Pupil Amplitude Estimation vs Rotation (clocking), and Typical Phase Retrieval Results Also included is information about the phase retrieval approach, Non-Linear Optimization (NLO) Optimized Diversity Functions, and Least Square Error vs. Starting Pupil Amplitude.

Dean, B. H.↗
DOE OSTI2020

Computational thermomechanics for crystalline rock. Part II: Chemo-damage-plasticity and healing in strongly anisotropic polycrystals

We present a thermal–mechanical–chemical-phase field model that captures the multi-physical coupling effects of precipitation creeping, crystal plasticity, anisotropic fracture, and crack healing in polycrystalline rock at various temperature and strain-rate regimes. This model is solved via a fast Fourier transfer solver with an operator-split algorithm to update displacement, temperature and phase field, and chemical concentration incrementally. In nuclear waste disposal in salt formation, brine inside the crystal salt may migrate along the grain boundary and cracks due to the gradient of interfacial energy and pressure. This migration has a significant implication on the permeability evolution, creep deformation, and crack healing within rock salt but is difficult to incorporate implicitly via effective medium theories compared with computational homogenization. As such, we introduce a thermodynamic framework and a corresponding computational implementation that explicitly captures the brine diffusion along the grain boundary and crack at the grain scale. Meanwhile, the anisotropic fracture and healing are captured via a high-order phase field that represents the regularized crack region in which a newly derived non-monotonic driving force is used to capture the fracture and healing due to the solution–precipitation. Numerical examples are presented to demonstrate the capacity of the thermodynamic framework to capture the multiphysics material behaviors of rock salt.

42 ENGINEERING↗
NASA NTRSDate not supplied

Design of a Thrust Vector Servoelastic Filter for SLS Block 2 Booster Thrust Vector Control System

This paper presents a method to improve the thrust vector servoelastic (TVSE) response of a launch vehicle. TVSE is the coupling between the Thrust Vector Control (TVC) system nozzle dynamics and the vehicle flexible modes. A poorly phased TVC response, i.e. in phase with the structural velocity, can lead to instability of the flexible modes due to the energy injection from the thrust. For large boosters with heavy nozzles, TVSE is more likely to cause instability. This instability is part of the plant dynamics and may not be readily detected by the flight control system. In this paper, TVSE is treated as a disturbance rejection problem with the inertial force of the flexible motion viewed as an external disturbance to the TVC actuator control system. By effectively rejecting this disturbance, the engine can be decoupled from the flexible dynamics thus improving TVSE stability. The actuator disturbance transfer function is modified by inserting a filter into the servo-loop control system. The filter aims to reduce the magnitude and introduce phase lead of the disturbance transfer function over the TVSE sensitive frequency range while maintaining adequate stability margins of the actuator control system. A prefilter is also designed to improve command tracking performance. The filter and prefilter resulting from this method are usually of low order and can be included to an existing actuator controller if the controller is programmable. This method was demonstrated for a hydraulic Simplex actuator model. Its applications to the Space Launch System (SLS) Block 1 and Block 2 TVC actuator are also described. The Block 2 actuator controller was modified based on the results of this method. The tradeoff between TVSE stability and the servo-loop stability can be balanced by adjusting the amount of phase lead introduced by the TVSE filter. This method provides a useful way to solve the TVSE instability issue without costly and time-consuming hardware solutions. This method is based on the basic control principles of loop shaping and disturbance rejection and has been proven to be effective under proper circumstances.

Thrust vector control↗
NASA NTRS2023

Heat Transfer and Interfacial Flow Physics of Microgravity Flow Boiling in Single-Side-Heated Rectangular Channel with Subcooled Inlet Conditions – Experiments Onboard the International Space Station

This study is the culmination of a long-term collaborative effort between researchers from the Purdue University Boiling and Two-Phase Flow Laboratory (PU-BTPFL) and the NASA Glenn Research Center to investigate gravitational effects on flow boiling and flow condensation. The science and design concepts for this large-scale effort were initiated in 2011 and included several studies detailing various aspects of two-phase fluid physics in both Earth gravity and microgravity, culminating in construction of the large-scale experimental facility named “Flow Boiling and Condensation Experiment (FBCE)”. The experiment was launched to the International Space Station (ISS) in August 2021. Following the successful installation of FBCE, equipped with the Flow Boiling Module (FBM), onboard the ISS and completion of several safety checks, flow boiling experiments were performed for five months from February 2022 until July 2022. This resulted in a large flow boiling database covering broad ranges of operating parameters and heating configurations spanning several research objectives. This study investigates microgravity flow boiling of n-perfluorohexane with subcooled inlet in a single-side-heated rectangular channel of dimensions 114.6-mm heated length, 2.5-mm heated width, and 5.0-mm height. Key operating parameters investigated are mass velocity (199.90 – 3200.13 kg/m 2 s), inlet subcooling (0.10 – 45.76°C), and inlet pressure (113.30 – 164.29 kPa). Images and image sequences acquired via high-speed-video are presented to elucidate the interfacial flow physics. To analyze and explain the effects of various parameters in microgravity, heat transfer results are presented as flow boiling curves, streamwise profiles of wall temperature and heat transfer coefficient, and parametric trends of local and averaged heat transfer coefficient. Mass velocity and inlet subcooling significantly influenced most of the aforementioned aspects of flow boiling, whereas effects of inlet pressure were comparatively insignificant. Although the data and observed flow physics might be different, the parametric effects and trends in microgravity are similar to vertical upflow in Earth gravity. Some cases, especially low mass velocities, high heat fluxes, and large degrees of inlet subcooling, experienced temporally anomalous flow behaviors caused by two-phase flow instabilities manifesting as flow reversals and resulted in deviations in overall trends. Severe thermodynamic non-equilibrium is observed throughout the channel. Overall, FBCE’s ISS experiments were successful for subcooled inlet with single-sided heating of rectangular channel, and the collected data well established the various effects on flow boiling physics in highly controlled long-term microgravity conditions.

flow boiling↗
NASA NTRS1987

Space station experiment definition: Long term cryogenic fluid storage

A preliminary design of an experiment to demonstrate and evaluate long-term cryogenic fluid storage and transfer technologies has been performed. This Long-Term Cryogenic Fluid Storage (LTCFS) experiment is a Technology Development Mission (TDM) experiment proposed by the NASA Lewis Research Center to be deployed on the Initial Operational Capability (IOC) space station. Technologies required by future orbital cryogenic systems such as Orbital Transfer Vehicles (OTV's) were defined, and critical technologies requiring demonstration were chosen to be included in the experiment. A three-phase test program was defined to test the following types of technologies: (1) Passive Thermal Technologies; (2) Fluid Transfer Technologies; and (3) Active Refrigeration Technologies. The development status of advanced technologies required for the LTCFS experiment is summarized, including current, past and future programs.

Riemer, David H.↗
NASA NTRS2016

Zero Boil-Off Tank (ZBOT) Experiment

The Zero-Boil-Off Tank (ZBOT) experiment has been developed as a small scale ISS experiment aimed at delineating important fluid flow, heat and mass transport, and phase change phenomena that affect cryogenic storage tank pressurization and pressure control in microgravity. The experiments use a simulant transparent low boiling point fluid (PnP) in a sealed transparent Dewar to study and quantify: (a) fluid flow and thermal stratification during pressurization; (b) mixing, thermal destratification, depressurization, and jet-ullage penetration during pressure control by jet mixing. The experiment will provide valuable microgravity empirical two-phase data associated with the above-mentioned physical phenomena through highly accurate local wall and fluid temperature and pressure measurements, full-field phase-distribution and flow visualization. Moreover, the experiments are performed under tightly controlled and definable heat transfer boundary conditions to provide reliable high-fidelity data and precise input as required for validation verification of state-of-the-art two-phase CFD models developed as part of this research and by other groups in the international scientific and cryogenic fluid management communities.

ISS↗
NASA NTRS1976

Effective thermal property improves phase change paint data

The phase-change coating technique presents itself as a valuable tool in determining the heat transfer rate over the surface of small complex wind tunnel models. A numerical technique is described which shows that an effective thermophysical property - the square root of the product of thermal conductivity, density, and specific heat - may significantly improve the accuracy of the phase-change coating technique with allowance for model inhomogeneity and temperature dependency in a transient environment. Results of the measured steady-state variation of the effective thermophysical property with temperature and the effect of surface heating rate on the effective thermophysical property are plotted for a representative homogeneous model material and for an extreme nonhomogeneous model material. The use of an effective thermophysical property to reduce phase-change paint data is recommended. The analysis also confirms that the apparatus described by Corwin and Kramer (1975) can be used to measure directly this effective thermophysical property for use in wind tunnel model heat-transfer measurements.

Drummond, J. P.↗
DOE OSTI2020

Screened Range-Separated Hybrid Functional with Polarizable Continuum Model Overcomes Challenges in Describing Triplet Excitations in the Condensed Phase Using TDDFT

Long range-corrected (LRC) or range-separated hybrid (RSH) functionals where the long-range (LR) limit of electronic interactions is set to the exact exchange have been shown to correct the tendency of traditional density functional theory (DFT) to underestimate the frontier orbital gap. Consequently, the use of such functionals in calculating electronic excited states using linear response based time-dependent DFT (TDDFT) has been successful in correcting the tendency for underestimating the energies of charge transfer states by DFT-based calculations. More recently formulations of functionals that attenuate the LR limit to address condensed-phase effects to polarize the electronic density have been reported. In particular screened RSH (SRSH) combined with polarizable continuum model (PCM) was benchmarked successfully in reproducing the fundamental gap and charge transfer state energies of molecular systems in the condensed phase. Here we use SRSH-PCM to address triplet excited states, and show its success in obtaining correspondence of the low-lying triplet states to the singlet–triplet gap in a similar way that the fundamental orbital gap corresponds to electron removal and addition energies. Importantly, the accuracy of the SRSH-PCM in calculating triplet excitations stands on the polarization consistent framework in addressing the scalar dielectric constant and without affecting the optimal tuning by triplet energies. Finally, the prospect of even further improving the SRSH-PCM accuracy in calculating triplet states can be achieved by optimal tuning on the basis of the spin multiplicity gap.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Interaction of Methane with Calcium Ferrite in the Chemical Looping Partial Oxidation Application: Experimental and DFT Study

In this study, experimental studies using mass spectroscopy, thermogravimetric analysis, in situ X-ray diffraction (XRD), and theoretical density functional theory calculations were carried out to investigate the mechanism of methane partial oxidation over a CaFe 2 O 4 oxygen carrier. The XRD analysis revealed the formation of the calcium ferrite phases during methane reduction occurred in the sequence CaFe 2 O 4 →CaFe 3 O 5 + Ca 2 Fe 2 O 5 →FeO + Fe + CaO→Fe + CaO. Each of these phases was modeled using periodic density functional theory to study the activity of these phases for the reactivity with CH 4 , CO, and H 2 along with the adsorbed surface species to help elucidate the effect that phase changes during reduction have on the chemical looping products CO and H 2 . Mass spectroscopic analysis revealed the formation of H 2 O and CO 2 occurred prior to the formation of CO and H 2 , and these products may be due to the removal of lattice oxygen bound in the discrete primary phase, which contributes to a small portion (~16%) of the total transferable oxygen in the solid. The density functional theory (DFT) results suggest that the gaseous CO and H 2 are not thermodynamically favorable to react with the Ca 2 Fe 2 O 5 where the release of CO and H 2 led to an increase in selectivity for these products. The DFT results suggest that some of the adsorbed atomic hydrogen combined to form adsorbed H 2 and then gaseous H 2 on the CaFe 2 O 4 surface, while the carbon deposition and some adsorbed atomic hydrogen react to form the CaFe 3 O 5 and Ca 2 Fe 2 O 5 phases simultaneously. DFT simulations suggest that both the gaseous H 2 and adsorbed atomic H are less thermodynamically favorable to drive the deep reduction of Ca 2 Fe 2 O 5 to CaO and Fe0. The deep reduction of the calcium ferrite therefore favors the generation of syngas products (CO and H 2 ) through mechanisms of methane dehydrogenation and selective oxidation of carbon to CO. The significant difference in mechanisms for partial oxidation of methane to syngas with the CaFe 2 O 4 carrier can be correlated to the differences in the oxide phases present during the reduction process, concentration of oxygen species, and bonding in the lattice structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Limit cycle oscillations in the zonal-flow-catalyzed interactions of ion-temperature-gradient turbulence

Limit-cycle oscillations are studied for ion temperature gradient turbulence, which, in the absence of large diamagnetic (mean) shear flows, saturates through energy transfer from unstable modes to large-scale stable modes via zonal-flow intermediary modes. Oscillations of zonal flow and turbulence levels are strongly constrained by the reactive, largely non-dissipative character of the zonal flows. Since existing predator–prey models for observed oscillations in experiments do not include energy transfer through zonal flows to stable modes, low-order fluid models with this physics are constructed and investigated. A simple three-wave truncation produces low-amplitude zonal flows that slowly oscillate around a zero mean, with turbulence oscillations between coupled wavenumbers that exceed linear frequencies by orders of magnitude. This inconsistency with experimental observations is caused by the weak non-linear drive of zonal flows in three-wave systems and the lack of multiple-wavenumber turbulent interactions. A more comprehensive model that preserves multiple wavenumber interactions within the context of conservative zonal-flow-mediated energy transfer to stable modes accurately reflects observed dynamics when the phase between stable and unstable modes is occasionally randomized.

Li, P. -Y. (ORCID:0000000295254171)↗
DOE OSTI2024

Scanning electrochemical probe microscopy investigation of two-dimensional materials

Research interests in two-dimensional (2D) materials have seen exponential growth owing to their unique and fascinating properties. The highly exposed lattice planes coupled with tunable electronic states of 2D materials have created manifold opportunities in the design of new platforms for energy conversion and sensing applications. Still, challenges in understanding the electrochemical (EC) characteristics of these materials arise from the complexity of both intrinsic and extrinsic heterogeneities that can obscure structure–activity correlations. Scanning EC probe microscopic investigations offer unique benefits in disclosing local EC reactivities at the nanoscale level that are otherwise inaccessible with macroscale methods. This review summarizes recent progress in applying techniques of scanning EC microscopy (SECM) and scanning EC cell microscopy (SECCM) to obtain distinctive insights into the fundamentals of 2D electrodes. We showcase the capabilities of EC microscopies in addressing the roles of defects, thickness, environments, strain, phase, stacking, and many other aspects in the heterogeneous electron transfer, ion transport, electrocatalysis, and photoelectrochemistry of representative 2D materials and their derivatives. Perspectives for the advantages, challenges, and future opportunities of scanning EC probe microscopy investigation of 2D structures are discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Pairing correlations in the cuprates: A numerical study of the three-band Hubbard model

We study the three-band Hubbard model for the copper oxide plane of the high-temperature superconducting cuprates using determinant quantum Monte Carlo and the dynamical cluster approximation (DCA) and provide a comprehensive view of the pairing correlations in this model using these methods. Specifically, we compute the pair-field susceptibility and study its dependence on temperature, doping, interaction strength, and charge-transfer energy. Using the DCA, we also solve the Bethe-Salpeter equation for the two-particle Green's function in the particle-particle channel to determine the transition temperature to the superconducting phase on smaller clusters. Our calculations reproduce many aspects of the cuprate phase diagram and indicate that there is an “optimal” value of the charge-transfer energy for the model where T c is largest. Finally, these results have implications for our understanding of superconductivity in both the cuprates and other doped charge-transfer insulators.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗