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Results for “generative diffusion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,261 records · Page 70
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Harnessing surface-bound enzymatic reactions to organize microcapsules in solution

By developing new computational models, we examine how enzymatic reactions on an underlying surface can be harnessed to direct the motion and organization of reagent-laden microcapsules in a fluid-filled microchannel. In the presence of appropriate reagents, surface-bound enzymes can act as pumps, which drive large-scale fluid flows. When the reagents diffuse through the capsules’ porous shells, they can react with enzymatic sites on the bottom surface. The ensuing reaction generates fluid density variations, which result in fluid flows. These flows carry the suspended microcapsules and drive them to aggregate into “colonies” on and near the enzyme-covered sites. This aggregation continues until the reagent has been depleted and the convection stops. Here, we show that the shape of the assembled colonies can be tailored by patterning the distribution of enzymes on the surface. This fundamental physicochemical mechanism could have played a role in the self-organization of early biological cells (protocells) and can be used to regulate the autonomous motion and targeted delivery of microcarriers in microfluidic devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Transport Processes in a Li-ion Cell during an Internal Short-Circuit

Internal short-circuit in a lithium-ion cell causes an abrupt increase in cell temperature and triggers subsequent thermal runaway. In this work, we present a detailed electrochemical-thermal model to investigate the physical behavior during an internal short-circuit. Simulations at wide range of heat transfer coefficients and short-circuit resistances are conducted to illustrate electrochemical and thermal behavior under a wide range of conditions. The Joule heating at the shorted region promotes electrochemical reactions nearby, causing in-plane non-uniformity of electrolyte and active material transport. Furthermore, it is found that diffusion in solid active materials plays a significant role at very high shorting currents (~20 C), as electrochemical reactions rate are being controlled progressively more by availability of Li + at the interface, due to limitations in diffusion through the active material with increasing discharge rates. This diffusion limitation causes a drop in available energy, and subsequently a decrease in cell equilibrium potential and the heat generation rate at the location of the short. On the other hand, rapid depletion of lithium concentration in the electrolyte and accumulation on the electrode surface results in highly non-uniform transport properties resulting in higher heat generation rates. Hence, the heating regime shifts from "local heating" to "global heating". Based on the findings, important design parameters for battery safety are discussed.

25 ENERGY STORAGE↗
DOE OSTI2024

The quantitative genetics of gene expression in Mimulus guttatus

Gene expression can be influenced by genetic variants that are closely linked to the expressed gene (cis eQTLs) and variants in other parts of the genome (trans eQTLs). We created a multiparental mapping population by sampling genotypes from a single natural population of Mimulus guttatus and scored gene expression in the leaves of 1,588 plants. We find that nearly every measured gene exhibits cis regulatory variation (91% have FDR < 0.05). cis eQTLs are usually allelic series with three or more functionally distinct alleles. The cis locus explains about two thirds of the standing genetic variance (on average) but varies among genes and tends to be greatest when there is high indel variation in the upstream regulatory region and high nucleotide diversity in the coding sequence. Despite mapping over 10,000 trans eQTL / affected gene pairs, most of the genetic variance generated by trans acting loci remains unexplained. This implies a large reservoir of trans acting genes with subtle or diffuse effects. Mapped trans eQTLs show lower allelic diversity but much higher genetic dominance than cis eQTLs. Several analyses also indicate that trans eQTLs make a substantial contribution to the genetic correlations in expression among different genes. They may thus be essential determinants of “gene expression modules,” which has important implications for the evolution of gene expression and how it is studied by geneticists.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2015

Many Molecular Properties from One Kernel in Chemical Space

We introduce property-independent kernels for machine learning modeling of arbitrarily many molecular properties. The kernels encode molecular structures for training sets of varying size, as well as similarity measures sufficiently diffuse in chemical space to sample over all training molecules. Corresponding molecular reference properties provided, they enable the instantaneous generation of ML models which can systematically be improved through the addition of more data. This idea is exemplified for single kernel based modeling of internal energy, enthalpy, free energy, heat capacity, polarizability, electronic spread, zero-point vibrational energy, energies of frontier orbitals, HOMOLUMO gap, and the highest fundamental vibrational wavenumber. Models of these properties are trained and tested using 112 kilo organic molecules of similar size. Resulting models are discussed as well as the kernels’ use for generating and using other property models.

Ramakrishnan, Raghunathan↗
DOE OSTI2021

Rapid Alloy Surface Engineering through Closed-Vessel Reagent Pyrolysis

For rapid surface engineering of Cr-containing alloys by low-temperature nitrocarburization, we introduce a process based on pyrolysis of solid reagents, e.g., urea, performed in an evacuated closed vessel. Upon heating to temperatures high enough for rapid diffusion of interstitial solute, but low enough to avoid second-phase precipitation, the reagent is pyrolyzed to a gas atmosphere containing molecules that (i) activate the alloy surface by stripping away the passivating Cr 2 O 3 -rich surface film (diffusion barrier) and (ii) rapidly infuse carbon and nitrogen into the alloy. We demonstrate quantitatively that this method can generate a subsurface zone with concentrated carbon and nitrogen comparable to what can be accomplished by established (e.g., gas-phase- or plasma-based) methods, but with significantly reduced processing time. As another important difference to established gas-phase processing, the interaction of gas molecules with the alloy surface can have auto-catalytic effects by altering the gas composition in a way that accelerates solute infusion by providing a high activity of HNCO. The new method lends itself to rapid experimentation with a minimum of laboratory equipment.

36 MATERIALS SCIENCE↗
DOE OSTI2016

High-energy neutrino emission from white dwarf mergers

The merger of two white dwarfs is expected to result in a central fast-rotating core surrounded by a debris disk, in which magnetorotational instabilities give rise to a hot magnetized corona and a magnetized outflow. The dissipation of magnetic energy via reconnection could lead to the acceleration of cosmic-rays (CRs) in the expanding material, which would result in high energy neutrinos. We discuss the possibility of using these neutrino signals as probes of the outflow dynamics, magnetic energy dissipation rate, and CR acceleration efficiency. Importantly, the accompanying high-energy gamma-rays are absorbed within these sources because of the large optical depth, so these neutrino sources can be regarded as hidden cosmic-ray accelerators that are consistent with the non-detection of gamma-rays with Fermi-LAT. While the CR generation rate is highly uncertain, if it reaches ∼10{sup 45} erg Mpc{sup −3} yr{sup −1}, the diffuse neutrino flux could contribute a substantial fraction of the IceCube observations. We also evaluate the prospect of observing individual merger events, which provides a means for testing such sources in the future.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1977

Use of experimental separation limits in the theoretical design of V/STOL inlets

Experimental data from several model inlets are used to generate two parameters which are related to the limit of operation for inlet flow separation. One parameter, called the diffusion ratio, is the ratio of the peak velocity on the inlet surface to the velocity at the diffuser exit and is related to the boundary-layer separation at low throat Mach numbers. The other parameter, the peak Mach number on the inlet surface, is related to the separation at high throat Mach numbers. These parameters are easily calculated from potential flow solutions and thus can be used as a design tool in screening proposed inlet geometries. An illustrative example of an application to an inlet design study for a tilt nacelle VTOL airplane is presented. The value of contraction ratio required to meet the operating requirements yet allow the inlet to remain free of separation as indicated by the two separation parameters is shown.

Boles, M. A.↗
NASA NTRS1977

Use of experimental separation limits in the theoretical design of V/STOL inlets

Experimental data from several model inlets have been used to generate two parameters which are related to the limit of operation for inlet flow separation. One parameter, called the diffusion ratio, is the ratio of the peak velocity on the inlet surface to the velocity at the diffuser exit and is related to the boundary-layer separation at low throat Mach numbers. The other parameter, the peak Mach number on the inlet surface, is related to the separation at high throat Mach numbers. These parameters are easily calculated from potential flow solutions and thus can be used as a design tool in screening proposed inlet geometries. Any of the geometric design variables can be analyzed by this technique; but, this paper is restricted to the consideration of the internal lip contraction ratio. An illustrative example of an application to an inlet design study for a tilt nacelle VTOL airplane is presented. The study will show what value of contraction ratio is required to meet the operating requirements yet allow the inlet to remain free of separation as indicated by the two separation parameters.

Boles, M. A.↗
NASA NTRS1977

Characterization of silicon-gate CMOS/SOS integrated circuits processed with ion implantation

Progress in developing the application of ion implantation techniques to silicon gate CMOS/SOS processing is described. All of the conventional doping techniques such as in situ doping of the epi-film and diffusion by means of doped oxides are replaced by ion implantation. Various devices and process parameters are characterized to generate an optimum process by the use of an existing SOS test array. As a result, excellent circuit performance is achieved. A general description of the all ion implantation process is presented.

Woo, D. S.↗
NASA NTRS1987

On the wave excitation in the turbulent meteor trace

The solution to the problem of excitation of longitudinal and transverse electromagnetic waves in randomly inhomogeneous media is reduced to the derivation of a complex effective dielectric constant (EDC) tensor which nonlocally connects together the average macroscopic electromagnetic fields in continuous media, it is implied that the field values which are rapidly fluctuating on a microscopic scale in space and time become smoothed out in a specified way due to the inhomogeneous mixing of diffusion. Proceedings from the derived general expression for the EDC tensor new modes of longitudinal and transverse electromagnetic wave generation due to fluctuation in the parameters of the medium was predicted. In this connection, it is of interest to investigate the peculiarities of electromagnetic longitudinal and transverse wave propagation in such randomly inhomogeneous media where, apart from the charged particle concentration change, the random spatial and temporal changes of natural frequency of closely located oscillators take place.

Jandieri, G. V.↗
NASA NTRS1989

Global Reference Atmosphere Model (GRAM)

GRAM series of four-dimensional atmospheric model validated by years of data. GRAM program, still available. More current are Gram 86, which includes atmospheric data from 1986 and runs on DEC VAX, and GRAM 88, which runs on IBM 3084. Program generates altitude profiles of atmospheric parameters along any simulated trajectory through atmosphere, and also useful for global circulation and diffusion studies.

Woodrum, A. W.↗
NASA NTRS1991

Picked-up protons near Mars - Phobos observations

The measurements carried out by the plasma spectrometer, Aspera, on board the Phobos-2 spacecraft show that protons, originating in the extended hydrogen corona of Mars, were observed at altitudes not greater than 7500 km. The cyclotron instability of these pickup ions appears to generate Alfven waves observed by the Magma magnetometer. Analysis of the plasma data shows that weak pitch-angle diffusion of a ring-distribution of pickup protons occurs. The altitude profiles of pickup proton fluxes and number densities of the parent hydrogen atoms are derived.

Barabash, S.↗
NASA NTRS1992

Formed platelets for low cost regeneratively cooled rocket combustion chambers

Formed platelet technology can be used to fabricate LO2/LH2-fueled rocket propulsion chambers with higher heat capacity, higher cycle life, and lower pressure drops, in conjunction with lower costs due to the application of high volume production methods. The formed-platelet combustor liner is an assembly of identical platelets, each of which is composed of diffusion-bonded, photoetched laminae with coolant flow passages; the platelets are also joined by diffusion bonding to form the combustor's circumference. Attention is given to the fabrication of a platelet combustion chamber generating 40 Klbf of thrust.

Burkhardt, W. M.↗
NASA NTRS1992

Mapping the sky with the COBE differential microwave radiometers

The Differential Microwave Radiometers (DMR) instrument on COBE is designed to determine the anisotropy of the Cosmic Microwave Background by providing all-sky maps of the diffuse sky brightness at microwave frequencies. The principal intent of this lecture is to show how these maps are generated from differential measurements.

Janssen, M. A.↗
NASA NTRS2013

Direct Simulation of Extinction in a Slab of Spherical Particles

The exact multiple sphere superposition method is used to calculate the coherent and incoherent contributions to the ensemble-averaged electric field amplitude and Poynting vector in systems of randomly positioned nonabsorbing spherical particles. The target systems consist of cylindrical volumes, with radius several times larger than length, containing spheres with positional configurations generated by a Monte Carlo sampling method. Spatially dependent values for coherent electric field amplitude, coherent energy flux, and diffuse energy flux, are calculated by averaging of exact local field and flux values over multiple configurations and over spatially independent directions for fixed target geometry, sphere properties, and sphere volume fraction. Our results reveal exponential attenuation of the coherent field and the coherent energy flux inside the particulate layer and thereby further corroborate the general methodology of the microphysical radiative transfer theory. An effective medium model based on plane wave transmission and reflection by a plane layer is used to model the dependence of the coherent electric field on particle packing density. The effective attenuation coefficient of the random medium, computed from the direct simulations, is found to agree closely with effective medium theories and with measurements. In addition, the simulation results reveal the presence of a counter-propagating component to the coherent field, which arises due to the internal reflection of the main coherent field component by the target boundary. The characteristics of the diffuse flux are compared to, and found to be consistent with, a model based on the diffusion approximation of the radiative transfer theory.

spheres↗
DOE OSTI2011

Recent results from milagro and prospects for HAWC

The High Altitude Water Cherenkov (HAWC) observatory is a new experiment for observing 50 GeV to 100 TeV photons from high energy gamma ray sources. The experiment is under construction at Sierra Negra, Mexico and will be comprised of 300 large water tanks instrumenting an area of 150 x 150 meters. HAWC is the next generation of the Milagro experiment which measured multi-TeV emission from the Galactic plane resolving sources and measuring diffuse emission. HAWC will feature approximately 15 times the sensitivity of the Milagro experiment and will be used to measure and constrain particle acceleration in the Galaxy.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2015

Fully-Coupled Metallic Fuel Performance Simulations using BISON

This document is a set of slides intended to accompany a talk at a meeting. The first topic taken up is zirconium redistribution. The rod edge Zr increase is evidently due to the Soret term and temperature gradient. Then metallic fission gas release modeling is considered. Based on a GRSIS/FEAST model, the approach of generating fission gas in the fuel matrix is described. A sensitivity study on parameters is presented, including sodium bond & diffusion coefficient sensitivity along with dt sensitivity. Finally, results of some coupled simulations are shown, with ideas about future work.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2022

Understanding Low Level Jets in the US Atlantic Offshore

Low level jets (LLJs) in the atmosphere exhibit a local windspeed maximum in the boundary layer, with positive shear beneath the jet and negative shear above the jet. Wind turbines tend to experience increased loads with varying wake recovery characteristics in the presence of an LLJ, therefore understanding the mechanism and impact of LLJs is crucial to wind energy development. The US Mid-Atlantic offshore region is a huge potential wind energy resource, yet LLJs in this area are poorly understood. In particular, the coastal offshore environment does not exhibit the same diurnal cycle that leads to strong LLJs in the well-characterized Great Plains region. In this study, we use the Weather Research and Forecasting model (WRF) plus lidar buoy data to identify case studies for LLJ events in 2020 in the New York Bight. A reduced order model is presented to explain the onset of these events based on the competing effects of baroclinicity and eddy diffusivity. Finally, using the macro-scale WRF, we drive a micro-scale large eddy simulation (LES) to generate a more detailed characterization of the Marine Boundary Layer during an LLJ. Gaining a better understanding of LLJs and their impacts on offshore wind in the mid-Atlantic is crucial for a transition toward renewable energy.

atmospheric boundary layer↗