Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “enhanced stability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,261 records · Page 70

The Effects of Substrate Material and Thermal Processing Atmosphere on the Strength of PS304: A High Temperature Solid Lubricant Coating

PS304, a plasma spray deposited solid lubricant coating developed for high temperature sliding contacts was deposited on nine different substrate metals, heat treated at 650C in either air or argon and subsequently tested for strength using a commercially available pull-off adhesion test. Some samples were examined metallographically to help elucidate and explain the results. As deposited coatings exhibit pull-off strengths typically between 16 and 20 MPa with failure occuring (cohesively) within the coating. Heat treatment in argon at 650 C results in a slight increase in coating (cohesive) strength of about 30 percent to 21 to 27 MPa. Heat treatment in air at 650 C results in a dramatic increase in strength to over 30 MPa, exceeding the strength of the epoxy used in the pull test. Cross section metallographic analyses show that no microstructural coating changes occur following the argon heat treatments, however, exposure to air at 650C gives rise to the formation of a second chromium-rich phase precipitate within the PS304 NiCr constituent which provides a strengthening effect and a slight (approximately 5 percent) coating thickness increase. Subsequent heat treatments do not result in any further coating changes. Based upon these studies, PS304 is a suitable coating for use on a wide variety of high temperature substrates and must be heat treated following deposition to enhance strength and ensure dimensional stability.

DellaCorte, Christopher↗

Protection of Conductive and Non-conductive Advanced Polymer-based Paints from Highly Aggressive Oxidative Environments

Research has been continued to further improve the space durability of conductive and non-conductive polymer-based paints and of conductive thermal control paints for space applications. Efforts have been made to enhance the space durability and stability of functional Characteristics in ground-based space environment imitating conditions, using specially developed surface modification treatment. The results of surface modification of new conductive paints, including the ground-based testing in aggressive oxidative environments, such as atomic oxygen/UV and oxygen plasma, and performance evaluation are presented. Functional properties and performance characteristics, such as thermal optical properties (differential solar absorptance and thermal emittance representing the thermal optical performance of thermal control paints) and surface resistivity characteristics of pristine, surface modified, and tested materials were verified. Extensive surface analysis studies have been performed using complementary surface analyses including SEM/EDS and XPS. Test results revealed that the successfully treated materials exhibit reduced mass loss and no surface morphology change, thus indicating good protection from the severe oxidative environment. It was demonstrated that the developed surface modification treatment could be applied successfully to charge dissipative and conductive paints.

Gudimenko, Y.↗

Advanced Microgravity Acceleration Measurement Systems (AMAMS) Being Developed

The Advanced Microgravity Acceleration Measurement Systems (AMAMS) project is part of NASA s Instrument Technology Development program to develop advanced sensor systems. The primary focus of the AMAMS project is to develop microelectromechanical systems (MEMS) for acceleration sensor systems to replace existing electromechanical sensor systems presently used to assess relative gravity levels aboard spacecraft. These systems are used to characterize both vehicle and payload responses to low-gravity vibroacoustic environments. The collection of microgravity acceleration data is useful to the microgravity life sciences, microgravity physical sciences, and structural dynamics communities. The inherent advantages of semiconductor-based systems are reduced size, mass, and power consumption, with enhanced long-term calibration stability.

Sicker, Ronald J.↗

Development of inflatable antenna structures

Self-rigidizable spring-tape-reinforced (STR) booms were used to develop structural systems for large-aperture space inflatable radar antennas. The lightweight planar frames built with STR booms can be compactly stowed for launch, deployed by inflation pressure in space, and used to tension the RF membrane apertures of the antennas. Engineering models of a Ka-band reflectarray antenna and a L-band synthetic-aperture radar antenna were developed and have successfully demonstrated stowage and deployment, as well as RF performance. A design improvement was also being implemented to enhance long-term configuration stability and widen the application range of the STR booms.

inflatable antenna structures deployment↗

The Response of the North American Monsoon to Increased Greenhouse Gas Forcing

[1] We analyze the response of the North American Monsoon (NAM) to increased greenhouse gas (GHG) forcing (emissions scenario RCP 8.5) using new simulations available through the Coupled Model Intercomparison Project version 5 (CMIP5). Changes in total monsoon season rainfall with GHG warming are small and insignificant. The models do, however, show significant declines in early monsoon season precipitation (June-July) and increases in late monsoon season (September-October) precipitation, indicating a shift in seasonality toward delayed onset and withdrawal of the monsoon. Early in the monsoon season, tropospheric warming increases vertical stability, reinforced by reductions in available surface moisture, inhibiting precipitation and delaying the onset of the monsoon. By the end of the monsoon season, moisture convergence is sufficient to overcome the warming induced stability increases, and precipitation is enhanced. Even with no change in total NAM rainfall, shifts in the seasonal distribution of precipitation within the NAM region are still likely to have significant societal and ecological consequences, reinforcing the need to not only understand the magnitude, but also the timing, of future precipitation changes.

rain↗

Magnetospheric State of Sawtooth Events

Magnetospheric sawtooth events, first identified in the early 1990s, are named for their characteristic appearance of multiple quasiperiodic intervals of slow decrease followed by sharp increase of proton differential energy fluxes in the geosynchronous region. The successive proton flux oscillations have been interpreted as recurrences of stretching and dipolarization of the nightside geomagnetic field. Due to their often extended intervals with 210 cycles, sawteeth occurrences are sometimes referred to as a magnetospheric mode. While studies of sawtooth events over the past two decades have yielded a wealth of information about such events, the magnetospheric state conditions for the occurrence of sawtooth events and how sawtooth oscillations may depend on the magnetospheric state conditions remain unclear. In this study, we investigate the characteristic magnetospheric state conditions (specified by Psw interplanetary magnetic field (IMF) Btot, IMF Bz Vsw, AE, Kp and Dst, all time shifted with respect to one another) associated with the intervals before, during, and after sawteeth occurrences. Applying a previously developed statistical technique, we have determined the most probable magnetospheric states propitious for the development and occurrence of sawtooth events, respectively. The statistically determined sawtooth magnetospheric state has also been validated by using out-of-sample events, confirming the notion that sawtooth intervals might represent a particular global state of the magnetosphere. We propose that the sawtooth state of the magnetosphere may be a state of marginal stability in which a slight enhancement in the loading rate of an otherwise continuous loading process can send the magnetosphere into the marginally unstable regime, causing it to shed limited amount of energy quickly and return to the marginally stable regime with the loading process continuing. Sawtooth oscillations result as the magnetosphere switches between the marginally stable (loading) and unstable (unloading) phases.

Fung, Shing F.↗

Assessment of Aerosol Optical Property and Radiative Effect for the Layer Decoupling Cases over the Northern South China Sea During the 7-SEAS Dongsha Experiment

The aerosol radiative effect can be modulated by the vertical distribution and optical properties of aerosols, particularly when aerosol layers are decoupled. Direct aerosol radiative effects over the northern South China Sea (SCS) were assessed by incorporating an observed data set of aerosol optical properties obtained from the Seven South East Asian Studies (7-SEAS)/Dongsha Experiment into a radiative transfer model. Aerosol optical properties for a two-layer structure of aerosol transport were estimated. In the radiative transfer calculations, aerosol variability (i.e., diversity of source region, aerosol type, and vertical distribution) for the complex aerosol environment was also carefully quantified. The column-integrated aerosol optical depth (AOD) at 500nm was 0.1-0.3 for near-surface aerosols and increased 1-5 times in presence of upper layer biomass-burning aerosols. A case study showed the strong aerosol absorption (single-scattering albedo (omega) approx. = 0.92 at 440nm wavelength) exhibited by the upper layer when associated with predominantly biomass-burning aerosols, and the omega (approx. = 0.95) of near-surface aerosols was greater than that of the upper layer aerosols because of the presence of mixed type aerosols. The presence of upper level aerosol transport could enhance the radiative efficiency at the surface (i.e., cooling) and lower atmosphere (i.e., heating) by up to -13.7 and +9.6W/sq m2 per AOD, respectively. Such enhancement could potentially modify atmospheric stability, can influence atmospheric circulation, as well as the hydrological cycle over the tropical and low-latitude marginal northern SCS.

biomass burning↗

Frozen Freedom: Unleashing Grocery Store Demand Flexibility: Preprint

Grocery stores consumed approximately 3% of total electricity used by commercial buildings in the U.S. in 2018 (EIA 2018), representing a unique end-use load profile characterized by the critical use of refrigerated display cases. Exploring demand response (DR) scenarios in grocery stores presents an opportunity to enhance the efficiency and sustainability of surrounding communities. In addition, recent studies demonstrate that implementing control algorithms considering demand flexibility strategies can lead to load and peak reductions in standalone refrigerated display cases. Because small business grocery stores operate on thin margins, the energy bill cost savings DR might provide could make a positive difference toward continued operations. Still, uncertainty remains about the extent of demand flexibility potential controls could provide when coupling refrigeration with whole building operation. To enhance economic viability and grid stability, it is essential to quantify the load flexibility capability of grocery stores. Advanced controls can optimize energy consumption by responding to load shedding, shifting, and DR events, as well as daily Time-of-Use (TOU) rates without compromising food safety. Using both quantitative data and interviews with community-based organizations, we developed a full-size store model and two small store models with controlled refrigerated cases, HVAC, and lighting systems based on actual grocery store properties. Through simulations, we have assessed load flexibility strategies with varied DR events. The results highlight potential for energy and peak reduction with advanced or basic controls. However, interviews and data indicate that more support is needed to make DR strategies consistently accessible to small grocery stores.

demand flexibility↗

Designing carbon wetting layers with inorganic salts as additives for enhanced adhesion and molten sodium wettability in electrochemical application

ß” alumina solid-state electrolyte (BASE) is considered one of the most promising materials for sodium batteries due to its high ionic conductivity and exceptional stability with molten sodium. However, at lower operating temperatures, the poor physical contact at the liquid-solid interface between molten sodium and BASE results in high interfacial resistance. In this study, we explore the optimization of carbon wetting layers with various salt additives to enhance adhesion and improve molten sodium wettability. Using a spray-coating method, carbon layers incorporating sodium hexametaphosphate (Na6(PO3)6, SHMP) as an additive demonstrate superior adhesion, mechanical stability, and enhanced wettability with molten sodium. Scanning Electron Microscopy (SEM) analysis reveals that SHMP preserves the porous carbon network required for efficient sodium transport while minimizing structural defects such as cracks and voids. Electrochemical testing using Na symmetric cells confirms that SHMP-modified layers significantly reduce interfacial resistance and overpotential, outperforming No salts counterparts. These findings highlight that the strategic incorporation of suitable additives, such as SHMP, in the design of microscale carbon layers could significantly enhance the performance of molten sodium batteries at lower operating temperatures.

Han, Henry H.↗

Valuation of Anode Materials for High-Performance Lithium Batteries: From Graphite to Lithium Metal and Beyond

Lithium-ion batteries have revolutionized energy storage, yet advanced technologies such as electric vehicles and eVTOLs demand even higher performance and safety. Anodes, the negative electrodes, are crucial in enhancing batteries’ safety, lifespan, and fast-charging capabilities. This review paper comprehensively evaluates the progression of anode materials from traditional graphite to advanced anodes like lithium metal. Graphite anodes, with a capacity of 372 mAh g −1 , enabled the first commercial lithium-ion batteries, but future applications require higher energy densities and fast-charging capabilities. Emerging anode materials, including alloying, and conversion types, as well as lithium metal, offer significantly higher capacities, with lithium metal offering a theoretical capacity of 3 860 mAh g −1 . However, these advanced anodes face challenges such as volume expansion, high surface reactivity, sluggish Li+ kinetics, and unstable lithium deposition morphologies. Here, this review critically examines the electrochemical performance, interfacial properties, mechanical attributes, and stability issues of various anode materials. It further discusses solid electrolyte interphase (SEI) formation, strategies for enhancing interface stability, and the requirements of anodes for solid-state batteries. Additionally, the review explores potential solutions for limitations with each anode type, highlights innovative anode-free architectures, and evaluates the current and future trends of battery anode industries. Ultimately, this paper aims to guide the development of high-performance anode materials, paving the way for the next generation of efficient, reliable lithium batteries.

Alloying anodes↗

Single crystal purification reduces trace impurities in halide perovskite precursors, alters perovskite thin film performance, and improves phase stability

Impurities present in commercially available halide perovskite precursors are known to affect photovoltaic performance. Here, we employ bulk single crystal growth of FAPbI 3 using solvent orthogonality induced crystallization (SONIC) to remove a broad set of extrinsic impurities from commercially available halide perovskite precursors, as verified by detailed chemical analysis. Following SONIC purification, FAPbI 3 films made from PbI 2 of originally low purity (99%) and high purity (99.99%) show improved phase purity and stability under light and heat relative to films made from raw precursors or precursors purified via retrograde powder crystallization (RPC) in 2-methoxyethanol, a method commonly utilized in recent reports of the highest-efficiency perovskite solar cells. In conclusion, single-crystal purification of precursors improves film stability under operational stressors, and the large enhancements in material purity provide a cleaner slate for improved isolation of compositional and additive effects on perovskite phase stability.

14 SOLAR ENERGY↗

Distortion Tolerant Control Flight Demonstration Shown to Be Successful

Future aircraft turbine engines, both commercial and military, will have to be able to successfully accommodate expected increased levels of steady-state and dynamic engine-face distortion. Advanced tactical aircraft are likely to use thrust vectoring for enhanced aircraft maneuverability. As a result, the engines will see more extreme distortion levels than currently encountered with present-day aircraft. Also, the mixed-compression inlets needed for the High-Speed Civil Transport (HSCT) will likely encounter disturbances similar to those seen by tactical aircraft, in addition to planar pulse, inlet buzz, and high distortion levels at low flight speed and off-design operation. The current approach of incorporating sufficient component design stall margin to tolerate these expected levels of distortion would result in significant performance penalties. The objectives of NASA's High Stability Engine Control (HISTEC) program, which has reached a highly successful conclusion, were to design, develop, and flight demonstrate an advanced, high-stability, integrated engine control system that uses measurement-based real-time estimates of distortion to enhance engine stability. The resulting distortion tolerant control adjusts the stall margin requirement online in real time. This reduces the design stall margin requirement, with a corresponding increase in performance and decrease in fuel burn.

Litt, Jonathan S.↗

Seasonal stabilization effects slowed the greening of the Northern Hemisphere over the last two decades

Rising atmospheric CO₂ and warming spring temperatures increase vegetation growth and the terrestrial carbon sink. However, drought, heat stress, phenology, and resource limitations may stabilize or limit theses projected increases. We investigate the balance between these amplifying and stabilizing ecological factors by asking whether enhanced early-season growth leads to continued late-season growth. Using the Moderate Resolution Imaging Spectroradiometer (MODIS) leaf area index (LAI) dataset, we identify three seasonal growth patterns based on early- and peak-season positive LAI anomalies: (1) amplification, where late-season LAI anomalies exceed earlier ones; (2) weak stabilization, where late-season anomalies remain similar or slightly lower; and (3) strong stabilization, where late-season anomalies become negative. Weak and strong stabilization events dominate across 67% and 26% of Northern Hemisphere ecosystems above 30°N, respectively. The absence of any trend in amplifying or stabilizing events suggests stabilizing factors seasonally offset CO₂ and temperature-induced spring greening. Terrestrial biosphere models underestimate strong stabilization and overestimate amplification events. This inconsistency arises from the models’ underestimation late-season LAI sensitivity to precipitation in water-limited regions; overlook negative legacy effects of early enhanced LAI on late-season soil moisture via evapotranspiration losses in energy-limited regions. Our findings suggest water/heat stress and resource limitations limit greening and the land carbon sink.

Zhang, Wen↗

Cyclic olefin copolymer-based reinforced anion exchange membranes for water electrolyzers

Anion exchange membranes (AEMs) have emerged as a promising technology for water electrolysis in hydrogen production since they offer significant cost reduction in choices of electrocatalysts and bipolar plates. However, AEMs satisfying multiple requirements of high ionic conductivity, good chemical stability, robust mechanical properties, scalable synthesis, and low manufacturing costs are rare. Herein, we introduce quaternary ammonium functionalized cyclic olefin copolymers (COCs) as a new class of chemically stable and low-cost AEM materials. To further enhance the mechanical robustness, we prepared reinforced composite AEMs by impregnating the ionically functionalized COC into a mechanically robust matrix. The resulting reinforced composite membrane exhibits a high hydroxide conductivity of 127 mS cm −1 and excellent mechanical strength. In water electrolyzers, the MEA demonstrated outstanding performance, achieving a current density of 2.24 A cm −2 at 1.8 V, attributable to high conductivity, enhanced mechanical properties, and good alkaline stability of the composite membrane. These results indicate that the COC-based AEMs demonstrate good potential for application in AEM electrolyzers.

08 HYDROGEN↗

Distortion Tolerant Control Demonstrated in Flight

Future aircraft turbine engines, both commercial and military, will have to be able to successfully accommodate expected increased levels of steady-state and dynamic engine-face distortion. Advanced tactical aircraft are likely to use thrust vectoring for enhanced aircraft maneuverability. As a result, the engines will see more extreme aircraft angle-of-attack alpha and sideslip beta levels than currently encountered with present-day aircraft. Also, the mixed-compression inlets needed for the High Speed Civil Transport (HSCT) will likely encounter disturbances similar to those seen by tactical aircraft, in addition to planar pulse, inlet buzz, and high distortion levels at low flight speed and off-design operation. The current approach of incorporating sufficient component design stall margin to tolerate these expected levels of distortion would result in significant performance penalties. The objective of NASA's High Stability Engine Control (HISTEC) program is to design, develop, and flight demonstrate an advanced, high-stability, integrated engine control system that uses measurement-based real-time estimates of distortion to enhance engine stability. The resulting distortion tolerant control adjusts the stall margin requirement online in real-time. This reduces the design stall margin requirement, with a corresponding increase in performance and decrease in fuel burn.

DeLaat, John C.↗

Effects of Longwave Cloud Radiative Forcing Anomalies on the Atmospheric Response to Equatorial Pacific Sea Surface Temperature Anomalies

The latest version of the National Center for Atmospheric Research community climate model (CCM2) has been used to investigate cloud radiative forcing (CRF) anomalies associated with equatorial Pacific sea surface temperature (SST) anomalies and the effects of the longwave CRF (LWCRF) anomalies on the atmospheric response to the SST anomalies. The SST anomalies cause large CRF anomalies, both longwave and shortwave, as well as latent heat anomalies at low latitudes on a global scale. The relative magnitude of the simulated longwave and shortwave CRF anomalies is consistent with the result of the Earth Radiation Budget Experiment (ERBE), implying that cloud height and cloud radiative properties such as emissivity and reflectivity are well simulated by the model. The LWCRF anomaly strongly enhances the precipitation anomaly in the whole tropical belt. The positive (negative) LWCRF anomaly warms (cools) the troposphere and destabilizes (stabilizes) the upper troposphere. The LWCRF anomaly enhances the Southern Oscillation and the related Walker circulation anomaly. The effects of the LWCRF anomaly are essential to the northern hemispheric extratropical circulation anomaly, the Pacific/North American pattern.

Chen, M.↗

Nitric Oxide Enhances Charge-Coupled Device

Simple treatment increases and stabilizes quantum efficiency of charge-coupled-device photodetector illuminated on back surface at wavelengths less than 4,500 Angstrom. Must be biased in strong accumulation mode. Physical principle of enhancement explained more fully in "Metal Film Increases CCD Output" (NPO-16815). Useful for imaging at wavelengths from ultraviolet to blue; for example, in astronomical observations.

Hecht, Michael H.↗

Growth of Carbon Nanotubes Using Mixed-Metal Catalysts That Include Heavy Refractory Metals as Catalyst Stabilizers

Here, we report new findings from studies of a novel technique to augment the growth of CNTs. In this method, the catalytic metals used for CNT growth are combined with high-melting-point heavy refractory metals, which serve to stabilize the metal catalyst nanoparticles, from which the CNTs nucleate and grow. Our study investigates the combination of an iron catalyst with tungsten and osmium refractory stabilizers. We find that both tungsten and osmium enhance the lifetime of the iron catalyst particles by a factor of approximately two. Tungsten stabilizer resulted in production of CNTs longer by a factor of 1.25 compared to those produced using a pure iron catalyst, while the osmium stabilizer did not significantly affect the ultimate length of the CNTs due to the decreased CNT growth rate with a combined Fe/Os catalyst. These results suggest a possible new route toward producing CNTs with lengths sufficient for materials applications.

Park, Wonjung [Univ. of Tampa, FL (United States)]↗