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At least 1,261 records · Page 70

A Novel Rotating Flexure-Test Technique for Brittle Materials with Circular Geometries

The four-point bend test is one of the simplest and often the preferred flexural strength evaluation method for brittle materials. In this loading mode, fracture often initiates from a critical surface (or subsurface) flaw when subjected to a tensile stress state. However, if the critical flaw exists on the compression side of the test specimen, it may not activate to grow a crack and hence the resulting flexural strength will be higher than the true value. The goal of this study is to measure the true flexural strength of a solid or hollow cylindrical brittle specimen by ensuring that failure occurs at its weakest point by rotating along its longitudinal axis, thereby exposing and activating its critical surface flaw during a four-point bend test. A novel test fixture has been designed and fabricated, and the true flexural strengths of cylindrical brittle and quasi-brittle tubular specimens have been measured and compared to existing experimental data obtained through traditional four-point bend tests. In this work, experimental results showcase the orientation dependance on flexural strength for various materials. Additionally, similarities between experimental findings and those available in literature, including observations of fracture surfaces and relationships between surface roughness and material strength, are discussed.

36 MATERIALS SCIENCE↗

Plastic waste upcycling toward a circular economy

Large amounts of plastics are discarded worldwide each year, leading to a significant mass of waste in landfills and pollution to soil, air, and waterways. Upcycling is an efficient way to transform plastic waste into high-value products and can significantly lessen the environmental impact of plastic production/consumption. In this article, current advances and future directions in plastic waste upcycling technologies are discussed. In particular, this review focuses on the production of high-value materials from plastic waste conversion methods, including pyrolysis, gasification, photoreforming, and mechanical reprocessing. Plastic waste compositions, conversion products, reaction mechanisms, catalyst selection, conversion efficiencies, polymer design, and polymer modification are also explored. Furthermore, the main challenges facing the adoption and scale-up of these technologies are highlighted. Suggestions are given for focusing future research and development to increase the efficiency of upcycling practices.

30 DIRECT ENERGY CONVERSION↗

Paths to circularity for plastics in the United States

In 2019, the United States consumed over 57 million metric tons (MMT) of plastic with less than 7% recovered for reuse. This study provides an updated material flow analysis at national and regional scales for all durable and single-use plastics in the United States. From this material flow analysis, we develop a series of alternative future national plastic flow scenarios that envision a scale-up of recycling technologies, incorporating technical limitations and sorting infrastructure constraints. The results suggest that a maximum of 68% (24 MMT) of plastic waste could be diverted from landfills by scaling up existing commercial recycling technologies. Based on the current technological landscape, reaching near-zero waste is only possible if processes that are operating at pilot and laboratory scales can be effectively scaled and coupled with improved sorting infrastructure. Through these scenarios with increased recycling, the availability of postconsumer resin stocks could increase by 22–43 MMT.

36 MATERIALS SCIENCE↗