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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,261 records · Page 70
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NASA NTRS1991

Nitrogen abundances in carbon-rich stars that are progenitors to planetary nebulae

Published data for carbon stars losing more than 10 to the -6th solar mass/yr in the neighborhood of the sun are examined. The stars with higher terminal velocities have significantly higher fluxes of the J = 1-0 emission line of HCN relative to their infrared continuum emission at 60 microns. It is argued that this result is probably a reflection of a higher nitrogen abundance by perhaps a factor of 10 in these outflows. Such a high nitrogen abundance is consistent with the hypothesis that the high terminal velocity carbon stars have more massive main-sequence progenitors than average; these high terminal velocity carbon stars may, themselves, be the progenitors of type I planetary nebulae which display enhanced nitrogen abundances.

Jura, M.↗
NASA NTRS1991

Carbon suboxide in Comet Halley?

The extremely dark nucleus of Comet Halley suggests that its volatile ices contain a few percent of carbonaceous material in the form of graphitic or amorphous carbon. The very high abundance of light elements in the coma dust and the emission feature near 3.4 microns further suggest the presence of a significant organic component, although the identified carbon-containing materials' parent species cannot account for all of such a component. It is presently proposed that an additional contribution from carbon suboxide can account for these observational data, assuming a production rate about 0.03-0.04 times that of water.

Huntress, Wesley T., Jr.↗
NASA NTRS1991

Detectability of Martian carbonates from orbit using thermal neutrons

Numerical simulations of Martian neutron leakage flux spectra are made in order to explore the detectability of magnesium and calcium carbonate deposits using neutron spectroscopic techniques from orbit. The primary signature of such deposits is found to be an enhanced thermal amplitude. Although this enhancement is weakened by: (1) partial burial beneath an aeolian regolith blanket; (2) admixture with regolith on a microscopic (centimeter) or macroscopic (tens of centimeters) scale; and (3) reduction in the areal size of the deposit, near-surface stratigraphies of carbonates hypothesized by some authors as possible on Mars are still detectable by simple neutron sensors from orbit. However, the large variations in the magnitude of the thermal neutron enhancements caused by different carbonate deposit configurations found in this study require a combined gamma ray and neutron analysis for their unique specification.

Feldman, W. C.↗
NASA NTRS1992

LDEF impact craters formed by carbon-rich impactors: A preliminary report

Two impact craters found in Al from the Long Duration Exposure Facility (LDEF) experiment tray have residues concentrated in the bottoms, along the walls, and on top of overturned rims. Analyses indicate a 'chondritic' compositional signature (Si, S, Ca, Fe, Mg, and Ni) for the bulk residue. In one crater (number 74), round to irregular silicate grains are overlain by carbon. In addition, carbon also partially covers the crater walls, the top of the raised overturned rim, and extends outward from the crater. The second crater (number 31) also contains carbon with similar distribution in and about the crater, although the silicate residue appears to be glassy. Silver, I, K, and F (possibly some of the Ca, S, and Cl) appear to be contaminants as well as analyzed aromatic carbonaceous species associated with the raised rim and the area surrounding the crater. The origin of the impactors is assumed to be extraterrestrial. The existence of impactor residue in two craters implies impact velocities less than or equal to 6 km, based on experimental hypervelocity studies.

Bunch, T. E.↗
NASA NTRS1992

Results of the TTF-TCNQ and the calcium carbonate crystallization on the Long Duration Exposure Facility

Experiment A0139A on the Long Duration Exposure Facility (LDEF) carried four large containers into orbit five years with crystal growth solutions for lead sulfide, calcium carbonate, and TTF-TCNQ. Although temperature data was lost, the experimental program had been working since the valves in all containers had been opened. All four experiments produced crystals of varying quality. The calcium carbonate crystals had the best appearance. The TTF-TCNQ crystals were packed together near the valve openings of the container. When taken apart, the single crystals showed some unusual morphological properties. X ray investigations as well as conductivity measurements on long duration space grown TTF-TCNQ crystals will be presented. Comparisons will be made with our previous space solution growth experiments. The TTF-TCNQ crystals are no longer of the highest interest, so this activity has been terminated in favor of calcium carbonate and calcium phosphate crystallizations.

Nielsen, Kjeld Flemming↗
NASA NTRS1991

On the nature of the excess 100 micron flux associated with carbon stars

The emission from carbon stars with circumstellar dust shells of different structure, composition, opacity, and age was modeled with the purpose of determining the origin of the excess flux in the FIR and testing the detached shell hypotheses of Willems (1987) and Olofsson et al. (1990). Three possible sources for the excess flux were identified: (1) cool dust in a single extended shell; (2) emission from dust in the intervening interstellar medium; or (3) emission from a two-shell system in which the additional shell is a remnant from an earlier mass-loss episode. It was found that only the two-shell model with a remnant shell which is at least 1 pc thick could explain the 60- and 100-micron flux excesses seen in carbon stars with dust shells of a given opacity. Calculations of time scales for the production of the detached shells and of the carbon star lifetime were found to be consistent with the evolutionary scenario proposed by Willems.

Egan, Michael P.↗
NASA NTRS1991

Material processing with hydrogen and carbon monoxide on Mars

Several novel proposals are examined for propellant production from carbon dioxide and monoxide and hydrogen. Potential uses were also examined of CO as a fuel or as a reducing agent in metal oxide processing as obtained or further reduced to carbon. Hydrogen can be reacted with CO to produce a wide variety of hydrocarbons, alcohols, and other organic compounds. Methanol, produced by Fischer-Tropsch chemistry may be useful as a fuel; it is easy to store and handle because it is a liquid at Mars temperatures. The reduction of CO2 to hydrocarbons such as methane or acetylene can be accomplished with hydrocarbons. Carbon monoxide and hydrogen require cryogenic temperatures for storage as liquid. Noncryogenic storage of hydrogen may be accomplished using hydrocarbons, inorganic hydrides, or metal hydrides. Noncryogenic storage of CO may be accomplished in the form of iron carbonyl (FE(CO)5) or other metal carbonyls. Low hydrogen content fuels such as acetylene (C2H2) may be effective propellants with low requirements for earth derived resources. The impact on manned Mars missions of alternative propellant production and utilization is discussed.

Hepp, Aloysius F.↗
NASA NTRS1991

New candidates for carbon stars with silicate features

All stars in the General Catalog of Cool Galactic Carbon Stars with IRAS 12-micron fluxes greater than 10 Jy were searched for Low-Resolution-Spectrometer (LRS) spectra in the IRAS LRS data base. Out of the 532 spectra examined, 11 were found to show the 9.7-micron silicate emission feature. Four of these are identified for the first time. This group of carbon stars may represent transition objects between oxygen-rich and carbon-rich stars on the asymptotic giant branch.

Chan, S. J.↗
NASA NTRS1991

Equation of state of heated glassy carbon

New Hugoniot data are presented for glassy carbon preheated to 1550 K and shocked to 20 GPa. The high-temperature Hugoniot is very similar to the principal Hugoniot. This results argues against the diffusional mechanism for the shock-induced transformaton of amorphous carbon to diamond, although the present results are obviously limited to below 20 GPa. This study provides the first Higoniot data for carbon preheated to significantly high temperatures.

Sekine, Toshimori↗
NASA NTRS1992

A VLA 3.6 centimeter survey of N-type carbon stars

The results are presented of a VLA-continuum survey of 7 N-type carbon stars at 3.6 cm. Evidence exists for hot plasma around such stars; the IUE satellite detected emission lines of singly ionized metals in the optically brightest carbon stars, which in solar-type stars indicate the existence of a chromosphere. In the past, these emission lines were used to constrain the lower portion of the archetypical chromospheric model of N-type carbon stars, that of TX Psc. Five of the survey stars are semiregular (1 SRa and 4 SRb) variables and two are irregular (Lb) variables. Upper limits of about 0.07 mJy are set of the SRb and Lb variables and the lone SRa (V Hya) was detected with a flux of 0.22 mJy. The upper limits for the six stars that are not detected indicate that the temperature in their winds is less than 10,000 K. Various scenarios for the emission from V Hya are proposed, and it is suggested that the radio continuum is shock-related (either due to pulsation or the suspected bipolar jet) and not due to a supposed accretion disk around an unseen companion.

Luttermoser, Donald G.↗
NASA NTRS1992

Carbon and nitrogen abundances determined from transition layer lines

The possibility of determining relative carbon, nitrogen, and silicon abundances from the emission-line fluxes in the lower transition layers between stellar chromospheres and coronae is explored. Observations for main-sequence and luminosity class IV stars with presumably solar element abundances show that for the lower transition layers Em = BT sup -gamma. For a given carbon abundance the constants gamma and B in this relation can be determined from the C II and C IV emission-line fluxes. From the N V and S IV lines, the abundances of these elements relative to carbon can be determined from their surface emission-line fluxes. Ratios of N/C abundances determined in this way for some giants and supergiants agree within the limits of errors with those determined from molecular bands. For giants, an increase in the ratio of N/C at B-V of about 0.8 is found, as expected theoretically.

Boehm-Vitense, Erika↗
NASA NTRS1992

Candidates for extreme carbon stars

A group of candidates for extreme carbon stars has been identified based on their IRAS low-resolution spectra being similar to those of AFGL 3068 and IRC +10 deg 216, which are prototypes of highly evolved carbon stars with very high mass-loss rates. Ground-based photometry has been obtained for five of these sources in order to determine the peaks of their energy distributions. All five sources have color temperatures between 300 and 500 K, and have energy distributions very similar to AFGL 3068. The observed data are fitted with radiative transfer models with optical depths at 11.3 microns ranging from 1.4 to 8. These results suggest that these stars have among the most optically thick circumstellar envelopes of all carbon stars observed to date.

Volk, Kevin↗
NASA NTRS1992

Open hole and postimpact compressive fatigue of stitched and unstitched carbon-epoxy composites

The performance is studied of a stitched uniweave fabric composite and that of a toughened tape composite. The effects of stitching on compression fatigue life are addressed. Post impact compression fatigue and open hole fatigue tests were run on an AS4/3501-6 uniweave with stitching and a toughened IM7/8551-7 tape without stitching. Stitching was found to increase the thickness and consequently the weight of the composite material. The two materials were compared on an equal carbon content basis as well as on an equal weight basis. The excess thickness in the stitched uniweave composite was responsible for the lower fatigue life, on an equal carbon basis, compared to the toughened resin tape composite. Comparison of fatigue lives on an equal carbon content basis indicated that puncture or crimp type damage from stitching has very little effect on compression failure. Post impact fatigue test showed that although the damage area in the stitched uniweave composite was twice that of the toughened tape composite, the fatigue lives of the stitched composite were significantly longer than those of the toughened composite. Thus, it appears that the increase in thickness from stitching is much more of a penalty than crimped fibers or puncture type damage from stitching.

Portanova, Marc A.↗
NASA NTRS1992

Soil surface CO2 fluxes and the carbon budget of a grassland

Measurements of soil surface CO2 fluxes are reported for three sites within the First International Satellite Land Surface Climatology Project (ISLSCP) Field Experiment (FIFE) area, and simple empirical equations are fit to the data to provide predictions of soil fluxes from environmental observations. A prototype soil chamber, used to make the flux measurements, is described and tested by comparing CO2 flux measurements to a 40-L chamber, a 1-m/cu chamber, and eddy correlation. Results suggest that flux measurements with the prototype chamber are consistent with measurements by other methods to within about 20 percent. A simple empirical equation based on 10-cm soil temperature, 0- to 10-cm soil volumetric water content, and leaf area index predicts the soil surface CO2 flux with a rms error of 1.2 micro-mol sq m/s for all three sites. Further evidence supports using this equation to evaluate soil surface CO2 during the 1987 FIFE experiment. The soil surface CO2 fluxes when averaged over 24 hours are comparable to daily gross canopy photosynthetic rates. For 6 days of data the net daily accumulation of carbon is about 0.6 g CO2 sq m/d; this is only a few percent of the daily gross accumulation of carbon by photosynthesis. As the soil became drier in 1989, the net accumulation of carbon by the prairie increased, suggesting that the soil flux is more sensitive to temperature and drought than the photosynthetic fluxes.

Norman, J. M.↗
NASA NTRS1993

CO observations of candidates for carbon-rich asymptotic giant branch and post-asymptotic giant branch stars

Circumstellar CO emission has been detected in a number of featureless or weak SiC emission, low color temperature IRAS sources. The CO detections confirm the suggestion that these are either extreme carbon stars, carbon-rich proto-planetary nebulae (PPNs), or carbon-rich planetary nebulae (PNs). We find that the CO emission is relatively stronger for a given luminosity in post-AGB stars than AGB stars, suggesting a more efficient excitation mechanism is at work in the post-AGB phase. One probable post-AGB star was detected in HCN for the first time. The available HCN data suggest a rapid decline in HCN emission after the AGB. Molecular emission is shown to be a useful tracer of the evolution from asymptotic giant branch to the planetary nebula phase.

Volk, Kevin↗
NASA NTRS1991

Measurement of tropospheric carbon monoxide using gas filter radiometers

The measurement of tropospheric carbon monoxide with gas filter radiometers is examined on the basis of the MAPS experiment. The performance characteristics of an instrument that uses the MAPS detectors, broadband filters, and gas cells in a system similar to the GASCOFIL system described by Morrow and Nicholls (1985) is determined. The signal function for two carbon monoxide channels of the MAPS instrument as it was flown in 1981 is shown. The measurements of the lower pressure channel are weighted to a higher altitude. The signal function, when integrated over altitude and multiplied by the normalization constant, yields the value of the signal. Both signal functions approach zero at the top because the gas concentration approaches zero. The present data reduction technique assumes that there are no clouds in the field of view. If clouds are present, the inferred carbon monoxide mixing ratio is too high, and those points must be rejected from the data set.

Reichle, Henry G., Jr.↗
NASA NTRS1993

Infrared laser spectroscopy of jet-cooled carbon clusters - The bending dynamics of linear C9

We report improved measurements for the nu6 antisymmetric stretch fundamental and observation of the (nu6 + nu15) - nu15 and (nu6 + 2nu15) - 2nu15 hot bands of the linear C9 carbon cluster by direct absorption diode laser spectroscopy of a supersonic carbon cluster beam. Analysis of these bands characterizes C9 as a semirigid molecule with a bending potential similar to that of C5 and further evidences the alternation in degree of rigidity of linear carbon clusters with the g-u symmetry of the HOMO.

Van Orden, A.↗
NASA NTRS1993

Are crystalline C-(H-O-N) carbons the elusive meteoritic carbynes?

I present an internally consistent reinterpretation of carbyne diffraction data making a few plausible assumptions. The results support that carbynes could be crystalline, randomly interstratified (or mixed-layered) carbons with variable C/(C+H+O+N) ratios rather than thermodynamically stable carbon allotropes. The metastable carbynes are likely the result of incomplete, kinetically-inhibited, low-temperature pyrolysis of precursor material. A renewed interest in meteoritic carbynes should seek to combine light-element chemistry and crystallography of these elusive carbons.

Rietmeijer, Frans J. M.↗