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1,256 records · Page 70

Mars Sample Return Landed with Red Dragon

A Mars Sample Return (MSR) mission is the highest priority science mission for the next decade as recommended by the recent Decadal Survey of Planetary Science. However, an affordable program to carry this out has not been defined. This paper describes a study that examined use of emerging commercial capabilities to land the sample return elements, with the goal of reducing mission cost. A team at NASA Ames examined the feasibility of the following scenario for MSR: A Falcon Heavy launcher injects a SpaceX Dragon crew capsule and trunk onto a Trans Mars Injection trajectory. The capsule is modified to carry all the hardware needed to return samples collected on Mars including a Mars Ascent Vehicle (MAV), an Earth Return Vehicle (ERV) and Sample Collection and Storage hardware. The Dragon descends to land on the surface of Mars using SuperSonic Retro Propulsion (SSRP) as described by Braun and Manning [IEEEAC paper 0076, 2005]. Samples are acquired and deliverd to the MAV by a prelanded asset, possibly the proposed 2020 rover. After samples are obtained and stored in the ERV, the MAV launches the sample-containing ERV from the surface of Mars. We examined cases where the ERV is delivered to either low Mars orbit (LMO), C3 = 0 (Mars escape), or an intermediate energy state. The ERV then provides the rest of the energy (delta V) required to perform trans-Earth injection (TEI), cruise, and insertion into a Moon-trailing Earth Orbit (MTEO). A later mission, possibly a crewed Dragon launched by a Falcon Heavy (not part of the current study) retrieves the sample container, packages the sample, and performs a controlled Earth re-entry to prevent Mars materials from accidentally contaminating Earth. The key analysis methods used in the study employed a set of parametric mass estimating relationships (MERs) and standard aerospace analysis software codes modified for the MAV class of launch vehicle to determine the range of performance parameters that produced converged spacecraft designs capable of meeting mission requirements. Subsystems modeled in this study included structures, power system, propulsion system, nose fairing, thermal insulation, actuation devices, and GN&C. Best practice application of loads and design margins for all resources were used. Both storable and cryogenic propellant systems were examined. The landed mass and lander capsule size provide boundary conditions for the MAV design and packaging. We estimated the maximum mass the Dragon capsule is capable of landing. This and the volume capability to store the MAV was deduced from publically available data from SpaceX as well as our own engineering and aerodynamic estimates. Minimum gross-liftoff mass (GLOM) for the MAV were obtained for configurations that used pump-fed storable bi-propellant rocket engines for both the MAV and the ERV stage. The GLOM required fits within our internal estimate of the mass that Dragon can land at low elevation/optimal seasons on Mars. Based on the analysis, we show that a single Mars launch sample return mission is feasible using current commercial capabilities to deliver the return spacecraft assets.

Mars Ascent Vehicle (MAV)↗

Injection of oxygen vacancies in the bulk lattice of layered cathodes

Surfaces, interfaces, and grain boundaries are, classically, known to be sinks at which defects generated within bulk lattice will preferentially migrate to and get annihilated, therefore rejuvenating a crystalline lattice to restore the intended functionalities.1, 2, 3 Here we report an inverse case by which the defects generated at the particle surface are continuously pumped into the bulk lattice and consequentially compromising the intended functionalities. We discovered that during the operation of a rechargeable battery, oxygen vacancies generated at cathode particle surfaces migrate toward inside of a perfect lattice in lithium-rich layered cathodes, featuring electrochemical driven surface vacancy creation, injection and condensation phenomenon and revealing an unrecognized surface process induced bulk lattice degradation featured with void formation and lattice reorganization. This process is associated with a high-cutoff voltage at which the anionic redox is activated. Coupling with calculations, we substantiate that triggering of anionic redox leads to sharply lowering of both formation energy of oxygen vacancy and migration barrier of oxidized oxide ions, therefore enabling migration of oxygen vacancy via oxidized oxide ion and leading to the injection of oxygen vacancy generated at the particle surface into the bulk lattice. This work unveils unpredicted behavior of oxidized oxide ion, leading to essential insight for designing of high capacity cathode for better batteries through coupled cationic and anionic redox dynamics in layered cathodes. In a broad term, this work provides insight on the intimate coupling between interfacial process and bulk lattice behavior for governing electrode functionality.

Yan, Pengfei↗

Bulk-like and Interfacial Water Dynamics in Nafion Fuel Cell Membranes Investigated with Ultrafast Nonlinear IR Spectroscopy

The water confined in the hydrophilic domains of Nafion fuel cell membranes is central to its primary function of ion transport. Water dynamics are intimately linked to proton transfer and are sensitive to the structural features and length scales of confinement. Here, ultrafast polarization-selective pump-probe and two-dimensional infrared vibrational echo (2D IR) experiments were performed on fully hydrated Nafion membranes with sodium counterions to explicate the water dynamics. Like aerosol-OT reverse micelles (AOT RMs), the water dynamics in Nafion are attributed to bulk-like core water in the central region of the hydrophilic domains and much slower interfacial water. Population and orientational dynamics of water in Nafion are slowed by polymer confinement. Comparison of the observed dynamics to those of AOT RMs helps identify local interactions between water and sulfonate anions at the interface and among water molecules in the core. This comparison also demonstrates that the well-known spherical cluster morphology of Nafion is not appropriate. Spectral diffusion of the interfacial water, which arises from structural dynamics, was obtained from the 2D IR experiments taking the core water to have dynamics similar to bulk water. Like the orientational dynamics, spectral diffusion was found to be much slower at the interface compared to bulk water. Together, the dynamics indicate slow reorganization of weakly hydrogen-bonded water molecules at the interface of Nafion. We report these results provide insights into proton transport mechanisms in fuel cell membranes, and more generally, water dynamics near the interface of confining systems.

25 ENERGY STORAGE↗

Enabling off-highway diesel engine downsizing and performance improvement using electrically assisted turbocharging

Internal combustion engine (ICE) downsizing through various turbocharging configurations is generally known by the powertrain design community as an effective means to reduce frictional losses, increase waste heat recovery, and improve fuel efficiency while increasing engine power density. However, often is the case that turbocharging strategies, including variable geometry turbochargers, and regulated two-stage turbochargers, incur the performance tradeoff between transient response and fuel economy (pumping losses) at high engine speeds. For off-highway vehicles having particularly transient and high-powered duty cycles, efforts to improve this tradeoff and increase operational flexibility have turned to evaluating various electrified air system architectures. In this study, a 4.5 L diesel-ICE configured with an electrically driven compressor (eBooster ® ) is placed in series with a conventional turbocharger and integrated into a 48 V mild-hybrid powertrain architecture. The objective of this powertrain configuration is to enable engine downsizing by 34%, replacing the current 6.8 L ICE platform with the hybridized 4.5 L ICE concept. The commercial 1-D simulation software GT-SUITE is used for powertrain system development and system optimization. Development and validation of the GT-SUITE model and air system controls is concurrently supported through experimental data collection. The simulation model development includes using machine learning methods for optimizing exhaust gas dilution, injection timing, and eBooster ® power to improve steady-state and transient brake-specific fuel consumption while minimizing criteria pollutant emissions. It was found that total specific fluid consumption over the standardized non-road transient engine duty cycle could be reduced by 18% over the current 6.8 L engine by using an optimized eBoosted 4.5 L engine. The hybridized 4.5 L engine concept concurrently showed sufficient transient response capability and nearly an order of magnitude reduction in duty cycle total soot production.

25 ENERGY STORAGE↗

Pulse Jet Mixing Tests With Noncohesive Solids (Revised)

This report summarizes results from pulse jet mixing (PJM) tests with noncohesive solids in Newtonian liquid. The tests were conducted during FY 2007 and 2008 to support the design of mixing systems for the Hanford Waste Treatment and Immobilization Plant (WTP). Tests were conducted at three geometric scales using noncohesive simulants, and the test data were used to develop models predicting two measures of mixing performance for full-scale WTP vessels. The models predict the cloud height (the height to which solids will be lifted by the PJM action) and the critical suspension velocity (the minimum velocity needed to ensure all solids are suspended off the floor, though not fully mixed). From the cloud height, the concentration of solids at the pump inlet can be estimated. The predicted critical suspension velocity for lifting all solids is not precisely the same as the mixing requirement for 'disturbing' a sufficient volume of solids, but the values will be similar and closely related. These predictive models were successfully benchmarked against larger scale tests and compared well with results from computational fluid dynamics simulations. The application of the models to assess mixing in WTP vessels is illustrated in examples for 13 distinct designs and selected operational conditions. The values selected for these examples are not final; thus, the estimates of performance should not be interpreted as final conclusions of design adequacy or inadequacy. However, this work does reveal that several vessels may require adjustments to design, operating features, or waste feed properties to ensure confidence in operation. The models described in this report will prove to be valuable engineering tools to evaluate options as designs are finalized for the WTP. Revision 1 refines data sets used for model development and summarizes models developed since the completion of Revision 0.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Integrated Modeling and Monitoring Technologies for Environmental Resiliency in Nuclear Energy

Environmental concerns pose the biggest challenge for the development of the nuclear energy industry, often preventing or limiting the construction of new plants and radioactive waste disposal facilities. There are currently numerous sites in the world at which surface and groundwater are contaminated by nuclear weapon production and testing, as well as due to nuclear power plant accidents. Many of those sites remain unused or inhabited primarily due to public concern. Improving scientific and technical capabilities to develop environmental resiliency is critical not only to address existing contamination, but also to build public confidence and support for nuclear energy. One of the obstacles in remediation is to tackle a large volume of contaminated soil and groundwater with relatively low concentrations. Although many contaminant removal technologies have developed (e.g., pump-and-treat systems), they are often expensive and not cost-effective for low-concentration radionuclide contamination. Although soil removal is often the most effective, it produces a large amount of waste that has to be stored securely for a long period of time or treated at the special treatment facilities. Transporting a large amount of waste may also produce greenhouse gases and disrupt local communities. Recently, the concept of 'sustainable remediation' has been proposed to improve a remediation system as a whole, including the consideration of cost effectiveness, reduction of greenhouse emission, waste production and energy usage. Rather than just focusing on removing contaminants, the sustainable remediation highlights the use of passive remediation technologies to immobilize radionuclides along with the application of monitored natural attenuation and longer institutional control. However, such passive technologies and monitored natural attenuation require the increased burden of proof to ensure that those immobilized contaminants would not compromise the long-term public health. Although contaminant transport modeling and risk assessments are always performed, they sometimes fail due to the lack of understanding the contaminant transport proposes at the time of the risk assessment or due to some unexpected processes. Monitoring technologies are critical to ensure the long-term stability of such remediated sites, and also to address the public concerns. Recent advances in in situ sensor technologies and spatially-extensive mapping technologies (such as unmanned aerial vehicles, airborne mapping, geophysics) have improved monitoring of contamination over space and time. In addition to new sensing devices, data management and data analytics technologies have been expanded to manage and process large spatial and temporal datasets. Such technologies can be used to reduce monitoring cost significantly, and to facilitate long-term monitoring. In this study, we demonstrate our data analytics technologies for two nuclear-related contaminated sites: (1) air dose rate monitoring in Fukushima prefecture, and (2) groundwater monitoring at the Savannah River Site F-Area. We are developing the spatial and temporal data integration methodologies to integrate various spatially extensive data and time-series data for improving long-term monitoring. Such monitoring technologies and experiences at the existing contaminated sites can be transferred to build a better monitoring system for nuclear facilities, such as nuclear power plants or nuclear waste storages.

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Direct Air Capture of CO 2 and Delivery to Photobioreactors for Algal Biofuel Production (Final Report)

A mobile DAC system was designed and constructed to pair with photobioreactors growing algae for biofuel production. The DAC system was designed as a versatile research system, rather than a compact production unit. The system was constructed and mounted on a mobile skid to facilitate transportation to the algae production site. Within the DAC system, CO 2 was captured using amine-loaded monoliths that allow for high CO 2 uptake with low pressure drop. The CO 2 is collected using a Global Thermostat patented temperature/vacuum swing adsorption (TVSA) process. Amine sorbents and process conditions were optimized to produce 10 to >20 g CO 2 .h-1. The stability of the amine sorbents was also studied, with sorbent modifications made to improve stability to degradation by oxidation. An Algenol-developed Spirulina strain (Arthrospira platensis AB2293) was selected as the production cyanobacterial strain. AB2293 cultured was inoculum for outdoor production following PBR installation by Algenol. The PBR system was composed of three independent PBRs, with each PBR composed of four hanging bags internally recirculated by a liquid turnover pump. The PBRs were operated outdoors in Atlanta, GA, and integrated with the DAC system. Algae were grown with similar productivity using DAC-CO 2 as algae grown using pure CO 2 obtained commercially (Airgas). Throughout the experimental duration, no discoloration was observed, and cellular morphology was consistent between the two experimental treatments. An LCA including lifecycle greenhouse gas emissions, full life cycle inventory of the Algenol system and the DAC system and integrated DAC+PBR system was developed. Lifecycle greenhouse gas emissions were calculated for capture of carbon dioxide using input from Global Thermostat and the National Renewable Energy Laboratory. Three scenarios for energy provision were evaluated: a natural gas combined heat and power system sized to meet the electricity requirement, a natural gas combined heat and power system sized to meet the process heat requirements, and a system without on-site power that procures the electricity from the grid. In all three cases, as expected, the major contributor to the emissions is the energy consumption associated with the desorption step of the DAC process. The LCA quantified the reduced potential energy and greenhouse gas emissions of heat and mass integration of DAC and Algenol compared to unintegrated DAC and Algenol systems. A life cycle assessment of the role of sorbent productivity and lifetime was also developed. The development of more robust, oxidation resistant DAC sorbents may enable small reductions in energy requirements and in lifecycle greenhouse gas emissions and other environmental impacts. NREL performed techno-economic analysis (TEA) to identify the integration scenario most likely to achieve a 15% cost reduction target versus the baseline. Heat and mass integration of DAC and the PBR is critical to minimizing the MFSP. The baseline case utilizes no heat and mass integration, and the DAC system provides 100% of the CO 2 required by the photobioreactors (20 tonnes/hr), operating for 12 hours/day capturing 40 tonnes CO 2 /operating hour. The minimum fuel selling price (MFSP) of ethanol calculated from the baseline case was $10.68/gal ethanol. This corresponds with a targeted MFSP of $9.07/gal ethanol (or 15% reduction). This target was achieved by integration Option 2a with the greatest cost reduction of 17.8% (or $8.78/gal) and integration Option 2b with a cost reduction of 16.4% (or $8.93/gal). Reductions in MFSP are attributed to two primary process considerations: (a) CO 2 storage at night reduces the capital expenses associated with DAC (i.e., increasing on-stream time); and (b) distributed DAC scenarios (DAC-PBR integration Options 2a and 2b) make use of boiler and DAC CHP flue gas CO 2 (free). Direct air capture on-stream time was one of the largest contributors to MFSP reduction.

09 BIOMASS FUELS↗

Measuring Thermal Conductivity and Moisture Absorption of Cryo-Insulation Materials

NASA is seeking to develop thermal insulation material systems suitable for withstanding both extremely high temperatures encountered during atmospheric re-entry heating and aero- braking maneuvers, as well as extremely low temperatures existing in liquid fuel storage tanks. Currently, materials used for the high temperature insulation or Thermal Protection System (TPS) are different from the low temperature, or cryogenic insulation. Dual purpose materials are necessary to the development of reusable launch vehicles (RLV). The present Space Shuttle (or Space Transportation System, STS) employs TPS materials on the orbiter and cryo-insulation materials on the large fuel tank slung under the orbiter. The expensive fuel tank is jettisoned just before orbit is achieved and it burns up while re-entering over the Indian Ocean. A truly completely reusable launch vehicle must store aR cryogenic fuel internally. The fuel tanks will be located close to the outer surface. In fact the outer skin of the craft will probably also serve as the fuel tank enclosure, as in jet airliners. During a normal launch the combined TPS/cryo-insulation system will serve only as a low temperature insulator, since aerodynamic heating is relatively minimal during ascent to orbit. During re-entry, the combined TPS/cryo-insulation system will serve only as a high temperature insulator, since all the cryogenic fuel will have been expended in orbit. However, in the event of an.aborted launch or a forced/emergency early re-entry, the tanks will still contain fuel, and the TPS/cryo-insulation will have to serve as both low and high temperature insulation. Also, on long duration missions, such as to Mars, very effective cryo-insulation materials are needed to reduce bod off of liquid propellants, thereby reducing necessary tankage volume, weight, and cost. The conventional approach to obtaining both low and high temperature insulation, such as is employed for the X-33 and X-34 spacecraft, is to use separate TPS and cryo-insulation materials, which are connected by means of adhesives or stand-offs (spacers). Three concepts are being considered: (1) the TPS is bonded directly to the cryo-insulation which, in turn, is bonded to the exterior of the tank, (2) stand-offs are used to make a gap between the TPS and the cryo-insulation, which is bonded externally to the tank, (3) TPS is applied directly or with stand-offs to the exterior so the tank, and cryo-insulation is applied directly to the interior of the tank. Many potential problems are inherent in these approaches. For example, mismatch between coefficients of thermal expansion of the TPS and cryo-insulation, as well as aerodynamic loads, could lead to failure of the bond. Internal cryo-insulation must be prevent from entering the sump of the fuel turbo-pump. The mechanical integrity of the stand-off structure (if used) must withstand multiple missions. During ground hold (i.e., prior to launch) moisture condensation must be minimized in the gap between the cryo-insulation and the TPS. The longer term solution requires the development of a single material to act as cryo- insulation during ground hold and as TPS during re-entry. Such a material minimizes complexity and weight while improving reliability and reducing cost.

Lambert, Michael A.↗

Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils. Final Report

This University of Massachusetts, Amherst project, "Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils" started on 1st February 2009 and finished on August 31st 2011. The project consisted following tasks: Task 1.0: Char Removal by Membrane Separation Technology The presence of char particles in the bio-oil causes problems in storage and end-use. Currently there is no well-established technology to remove char particles less than 10 micron in size. This study focused on the application of a liquid-phase microfiltration process to remove char particles from bio-oil down to slightly sub-micron levels. Tubular ceramic membranes of nominal pore sizes 0.5 and 0.8m were employed to carry out the microfiltration, which was conducted in the cross-flow mode at temperatures ranging from 38 to 45 C and at three different trans-membrane pressures varying from 1 to 3 bars. The results demonstrated the removal of the major quantity of char particles with a significant reduction in overall ash content of the bio-oil. The results clearly showed that the cake formation mechanism of fouling is predominant in this process. Task 2.0 Acid Removal by Membrane Separation Technology The feasibility of removing small organic acids from the aqueous fraction of fast pyrolysis bio-oils using nanofiltration (NF) and reverse osmosis (RO) membranes was studied. Experiments were carried out with a single solute solutions of acetic acid and glucose, binary solute solutions containing both acetic acid and glucose, and a model aqueous fraction of bio-oil (AFBO). Retention factors above 90% for glucose and below 0% for acetic acid were observed at feed pressures near 40 bar for single and binary solutions, so that their separation in the model AFBO was expected to be feasible. However, all of the membranes were irreversibly damaged when experiments were conducted with the model AFBO due to the presence of guaiacol in the feed solution. Experiments with model AFBO excluding guaiacol were also conducted. NF membranes showed retention factors of glucose greater than 80% and of acetic acid less than 15% when operated at transmembrane pressures near 60 bar. Task 3.0 Acid Removal by Catalytic Processing It was found that the TAN reduction in bio-oil was very difficult using low temperature hydrogenation in flow and batch reactors. Acetic acid is very resilient to hydrogenation and we could only achieve about 16% conversion for acetic acid. Although it was observed that acetic acid was not responsible for instability of aqueous fraction of bio-oil during ageing studies (described in task 5). The bimetallic catalyst PtRe/ceria-zirconia was found to be best catalyst because its ability to convert the acid functionality with low conversion to gas phase carbon. Hydrogenation of the whole bio-oil was carried out at 125°C, 1450 psi over Ru/C catalyst in a flow reactor. Again, negligible acetic acid conversion was obtained in low temperature hydrogenation. Hydrogenation experiments with whole bio-oil were difficult to perform because of difficulty to pumping the high viscosity oil and reactor clogging. Task 4.0 Acid Removal using Ion Exchange Resins DOWEX M43 resin was used to carry out the neutralization of bio-oil using a packed bed column. The pH of the bio-oil increased from 2.43 to 3.7. The GC analysis of the samples showed that acetic acid was removed from the bio-oil during the neutralization and recovered in the methanol washing. But it was concluded that process would not be economical at large scale as it is extremely difficult to regenerate the resin once the bio-oil is passed over it. Task 5.0 Characterization of Upgraded Bio-oils We investigated the viscosity, microstructure, and chemical composition of bio-oils prepared by a fast pyrolysis approach, upon aging these fuels at 90ºC for periods of several days. Our results suggest that the viscosity increase is not correlated with the acids or char present in the bio-oils. The viscosity increase is due to formation of high molecular weight polymeric species over time. Our work also suggests that hydrogenation of the samples is beneficial in eliminating the viscosity increase. Task 6.0 Commercialization Assessment Renewable Oil International LLC (ROI) was responsible for Task 6.0, Commercialization Assessment. As part of this effort ROI focused on methods to reduce char carryover in the vapor stream from the fast pyrolysis reactor and residence time of the vapor in the reactor. Changes were made in the bio-oil recovery methodology and a reactor sweep gas used to reduce vapor residence time. Cyclones were placed in the vapor stream to reduce char particulate carryover. Microfiltration of the bio-oil was also researched to remove char particulate from the bio-oil. The capital cost for these improvements would be less than 2% of the total plant capital cost.

09 BIOMASS FUELS↗

DEMONSTRATION OF MIXING AND TRANSFERRING SETTLING COHESIVE SLURRY SIMULANTS IN THE AY-102 TANK

In support of Hanford's waste certification and delivery of tank waste to the Waste Treatment and Immobilization Plant (WTP), Savannah River National Laboratory (SRNL) was tasked by the Washington River Protection Solutions (WRPS) to evaluate the effectiveness of mixing and transferring tank waste in a Double Shell Tank (DST) to the WTP Receipt Tank. The work discussed in this report (Phase III) address the impacts cohesive simulants have on mixing and batch transfer performance. The objective of the demonstrations performed in Phase III was to determine the impact that cohesive particle interactions in the simulants have on tank mixing using 1/22{sup nd} scale mixing system and batch transfer of seed particles. This testing is intended to provide supporting evidence to the assumption that Hanford Small Scale Mixing Demonstration (SSMD) testing in water is conservative. The batch transfers were made by pumping the simulants from the Mixing Demonstration Tank (MDT) to six Receipt Tanks (RTs), and the consistency in the amount of seed particles in each batch was compared. Tests were conducted with non-Newtonian cohesive simulants with Bingham yield stress ranging from 0.3 Pa to 7 Pa. Kaolin clay and 100 {mu}m stainless steel seed particles were used for all the non-Newtonian simulants. To specifically determine the role of the yield stress on mixing and batch transfer, tests were conducted with a Newtonian mixture of glycerol and water with at viscosity of 6.2 cP that was selected to match the Bingham consistency (high shear rate viscosity) of the higher yield stress kaolin slurries. The water/glycerol mixtures used the same 100 {mu}m stainless steel seed particles. For the transfer demonstrations in Phase III, the mixer jet pumps were operated either at 10.0 gpm (28 ft/s nozzle velocity, U{sub o}D=0.63 ft{sup 2}/s) or 8.0 gpm (22.4 ft/s nozzle velocity, U{sub o}D=0.504 ft{sup 2}/s). All batch transfers from the MDT to the RTs were made at 0.58 gpm (MDT suction velocity 3.95 ft/s). The demonstrations that used simulants that ranged from 1.6 Pa to 7 Pa yield stress had the most successful batch transfer of solids to the RTs in terms of the total quantity of seed particles transferred. Testing suggest that when mixing water/seed particles and transferring, water provides the least desired batch transfer of solids based on the total quantity transferred. For the water tests, large dead zones of solids formed in the MDT and fewer solids get transferred to the RTs. For simulants with a yield stress of 0.3 Pa and below, the batch transfer behavior in terms of total transfer of seed particles was slightly higher than water test results. The testing did show somewhat more batch-to-batch variation in the transfer of seed particles with the slurries in comparison to water. A comparison of batch transfers with the kaolin slurries that had Bingham consistencies (viscosities) that wernearly the same as the Newtonian glycerol/water mixtures showed that the kaolin slurries with Bingham yield stresses of 1.6 and 7 Pa gave better batch transfer of seed particles based on the total quantities transferred. Overall, the batch transfer testing results show that testing with water is conservative, since using a simulant with a yield stress and/or elevated viscosity always resulted in a better total transfer of solids.

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The SURE House (Solar Decathlon 2015)

Coastal towns and cities across the Northeastern US, with their high population density, aged utility infrastructure, and unique geography, are increasingly vulnerable to climate change related storm events. In October 2012 superstorm Sandy highlighted the fragility of our current coastal building types and made clear the need for a new model of design and construction which works to understand and mitigate these weaknesses. Dramatic changes in public policy, championed by both The Federal Emergency Management Agency (FEMA) and the National Flood Insurance Program (NFIP) are driving the rebuilding of these shore communities, often resulting in costly renovations, un-sustainable neighborhood configurations and in direct conflict with concurrent government policies such as The American with Disabilities Act (ADA). The SURE HOUSE demonstrates a series of new design solutions to these conflicting public policies and environmental imperatives. At Stevens Institute of Technology, the 2015 Solar Decathlon started with the challenge: Can we design a home for coastal New Jersey that dramatically reduces its energy use while protecting itself from the realities of a changing, more extreme climate? The SURE HOUSE merges the iconic 20th century shore home with 21st century building science. Utilizing innovative renewable energy technologies, a ‘Passive House’ level building envelope, and rugged glass-fiber-composite materials to flood-proof the home, the SURE HOUSE is a high-performance, net-zero-energy home, armored against extreme weather, designed for the contemporary lifestyle of the Jersey Shore and other vulnerable coastal communities. SUSTAINABLE At Stevens, we recognize that energy use in the home and workplace is directly connected to the growing problem of climate change. Reducing our energy consumption by designing higher performing, compact homes that are both functional, comfortable and desirable is the first critical step towards a modern, sustainable architecture for New Jersey and beyond. This is what informed the architectural design of the house. Configured about a compact form, thickly insulated and air-sealed walls eliminate thermal bridging and minimize energy losses while advanced glazing brings in free solar heat during the winter months. As a result of these passive design strategies, the SURE HOUSE has a greatly reduced carbon footprint requiring 91% less energy than a typical New Jersey home. Photovoltaic (PV) arrays on both the rooftop and operable shutters easily provide energy in excess of the home’s modest demands. The Stevens team considers a truly sustainable home in the era of climate change, one that prioritizes low energy use, and integrates right-sized renewable generation to supply the home’s needs. Low consumption, low production. RESILIENT In October of 2012, Hurricane Sandy wreaked havoc along the east coast of the US. In New Jersey alone there was an estimated 29.4 billion dollars in damages, 346,000 homes affected, and almost two and a half million people left without power, in some cases for over 10 days. Recovery from this storm and associated flooding is ongoing to this day, as many New Jersey homeowners grapple with the large costs of rebuilding and struggle to adapt to complicated new home building regulations. Damage from this storm to Hoboken, the home of the Stevens Institute of Technology’s campus, and to the New Jersey shore was extensive and many students on the SURE HOUSE team were directly affected by this historic event. The Stevens design team recognizes that in a world of more frequent and stronger storms, the ability to absorb and adapt to change is more important than ever. Successfully weathering the next storm and its aftermath is one of the primary goals in the design of the SURE HOUSE prototype. The SURE HOUSE introduces unique ‘dry flood-proofing’ methods to residential construction. Innovative wall and floor flood-proofing, utilizing durable composite sheathing materials adapted from the boating industry, were developed by the student team to render the SURE House’s building envelope flood proof up to the FEMA AE 6/7 Zone (+ 6/7 feet of water above sea-level). Designed and fabricated utilizing glass-fiber composite materials, the custom storm shutter system serves to protect the large glazed openings of the home from both air-borne debris impact and water infiltration during a storm event while also providing deterrence from the vandalism that often occurs in the aftermath of a calamitous event. During extended power outages, a ‘resilient’ solar array is capable of supplying critical amounts of energy and hot water to the home, without the use of battery storage or grid infrastructure. PV Description AC GRID-TIED PV SYSTEM The SURE HOUSE solar system consists of two distinct arrays, the grid-tied rooftop array which produces AC Powerand the shutter-mounted array which converts DC power generated by the modules directly into usable heat for the domestic hot water (DHW). The roof-mounted AC grid-tied array is comprised of three strings, two 11 module strings connected to an SMA SB 5000TL-US-223 inverter and a single 10 module string equipped and an SMA SB 3000TL-US-22 central inverter. All modules for the rooftop AC array are LG MonoX 2804 watt solar panels, chosen for their durability and efficiency. Inverter sizing and string size are optimized to the electrical characteristics of the chosen PV modules and the desired energy production, see Appendix 5B. The SURE HOUSE is projected to produce 12,353 kWh per year to meet 6,157 kWh per year of estimated consumption. Solar modules for the two AC grid-tied sub arrays are mounted on the main roof surface of the SURE HOUSE with a 10 degree tilt angle using a partially-ballasted polyethylene roof mounting system made by Renusol, which is particularly suited to the corrosive salt air of a coastal environment. This method was chosen for its installation simplicity and to limit detrimental roof penetrations. The 10 degree tilt optimizes the energy generated per roof area at a lower price, see Appendix 5A, and ensures that there is minimal wind uplift. DC SOLAR ELECTRIC DOMESTIC HOT WATER The SURE HOUSE’s approach to sustainable and resilient domestic hot water (DHW) consists of a unique, custom engineered DC solar electric hot water system. Employing the use of Advanced Energy’s DC electric PV heater (DCPVH)5 to heat domestic water well beyond the draw temperature, the SURE HOUSE is able to obtain a remarkably high solar fraction of 75% or more. The custom modified 80 gallon Vaughn DHW tank acts as a large solar ‘battery’ that stores heat energy in the form of hot water at almost 150 degrees, harvesting energy when the sun is out for use later in the day or overnight. The system, which uses electricity rather than heated fluid, is distinct from traditional ‘solar thermal’ systems by eliminating the dangers and associated maintenance issues of fluid based systems. By forgoing the use of external fluid loops, overheated solar collectors and pipes are not an issue for the SURE HOUSE system which never needs any yearly or seasonal flushing. In weather conditions where the integrated DCPVH unit cannot produce enough hot water via solar energy alone, the Vaughn hot water tank comes factory made with an AC powered 2.6 COP heat pump and a AC heating coil that serve as back-up heating elements. The DCPVH is powered by a DC array consisting of 10 custom-made Solbian by PVilion 180 watt, monocrystalline, flexible solar modules6. The Solbian modules are directly mounted to the top half of the operable storm shutters on the south façade of the SURE HOUSE. The SURE HOUSE team worked closely with PVillion, a PV system designer specializing in flexible architectural photovoltaics, to design an adhesive system that works with the glass-fiber storm shutter surface in a reliable manner over an extended period. Because this system operates in DC-only mode and never connects to the municipal power grid, the system can continue to create hot water safely and effectively even during grid disruption events. This hot water, and the energy stored within it, could be used for a range of activities including washing and cooking to more elaborate hydronic heating systems as desired. See Appendix 6 for system engineering, sizing and modeling.

14 SOLAR ENERGY↗

SRS Strategy for Tank 3 Salt Dissolution - Performance and Lessons Learned - 20441

The Savannah River Site (SRS) Tank Farms have 51 underground waste tanks used to store and process liquid nuclear waste materials. There are 4 different tank types, ranging in capacity from 2,840,000 to 4,920,000 L (750,000 to 1,300,000 Gal). Twenty-four of the tanks are older style and do not meet full secondary containment standards. The older style tanks are the initial focus of waste removal efforts for tank closure at SRS. Eight of these twenty-four tanks have completed waste removal and are filled with grout. Prior to salt dissolution, Tank 3 was a dry salt tank that contained 5.06 m (199.3 in) of salt and sludge waste. Additional salt waste was present on cooling coils above the salt layer up to approximately 5.59 m (220 in). Three mixing eductors were installed in Tank 3 to aid in dissolving salt waste in three tank riser access ports. A transfer pump was installed, and the transfer pump suction was located 25.4 cm (10 in) from the tank bottom. Well water was added to the tank through a downcomer until the dry bulk salt was covered with liquid. During the initial fill of Tank 3, approximately 242,000 L (64,000 Gal) of rain water were added from periodic F-Tank Farm (FTF) Catch Tank additions and approximately 17,000 L (4,500 Gal) of well water were added. Following liquid additions to cover the dry bulk salt, well water was added through the three mixing eductors in batches during each stage. Additionally, during the salt dissolution campaigns, the FTF Catch Tank was utilized to add rain water through a downcomer in the center tank riser access port as needed for volume relief in the FTF Catch Tank. Following liquid additions, the water was recirculated (internal to the tank) using the transfer pump, and a sample was pulled to confirm the target specific gravity (SpG) of the dissolved salt solution was achieved. The dissolved salt solution was then transferred to the receipt tank (Tank 7), and the mixing eductors were lowered as close to the new bulk salt layer as possible, to support subsequent dissolution campaigns. While the mixing jets were able to dissolve salt successfully in Tank 3, they did not do so in a completely uniform manner. Throughout dissolution, mounds were discovered under Riser 1, Riser 2, and the Center Riser. The mixing jets dissolved the salt around the edges of the tank well but were not as effective toward the center of the tank. FTF Catch Tank additions through the center tank riser access port downcomer were required to impact the mound under the center tank riser. FTF Catch Tank additions were sporadic as they were dependent on rainfall in the area. Additionally, all mixing jets were rarely able to be lowered to the same elevation, indicating some mounding in the bulk salt layer. Indexing of the mixing jets was also utilized to impact the salt mounds. Overall, Tank 3 salt dissolution was successful as approximately 1,476,000 L (390,000 Gal) of dissolved salt solution was transferred to Tank 7 over six stages. Slightly less than 852,000 L (225,000 Gal) of water were added to Tank 3. The original material balance prediction estimated that the bulk salt level in Tank 3 would be 3.88 m (152.8 in) after six salt dissolution stages. After six stages the actual bulk salt level was 3.38 m (133 in). This paper will discuss the salt removal strategy, each salt dissolution stage, and lessons learned for future salt dissolution. (authors)

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TCCR Operational Summary and Optimization for Tank 9 Processing - 20314

Savannah River Remediation (SRR) manages and operates the liquid waste facilities at Savannah River Site (SRS) for the Department of Energy (DOE). Stored liquid waste is a complex mixture of insoluble solids (sludge) and soluble salts in an alkaline solution. SRR has deployed the Tank Closure Cesium Removal (TCCR) system, a tank-side ion exchange process, to remove radioactive cesium from salt waste and enable onsite disposal of the resulting decontaminated salt solution as low-level waste at the Saltstone facilities. The TCCR system consists of two prefilters, four ion exchange (IX) columns, one resin trap, and a ventilation system. The IX process uses a form of inorganic crystalline silicotitanate (CST), which has a high affinity for cesium and other alkali metals, strontium, and actinides. This process is currently deployed utilizing salt feed from Tank 10, with future plans to dissolve solid salt in Tank 9 and transfer the salt solution to Tank 10 for processing through TCCR. The feed for TCCR must be created from salt-cake in Tank 10 through a dissolution process. Once enough salt has been dissolved, a qualification process is entered. This process characterizes the feed and ensures the cesium loading on the columns will not cause boiling of waste within the columns during or after processing. Once the batch has been qualified, salt waste is fed to the TCCR system through a transfer pump in the center of the tank. The waste is filtered through a set of two shielded, dead-end prefilters that prevent solids buildup in the columns. The filtered salt solution then travels to the shielded IX columns, which can be operated individually or in series, where the cesium is sorbed on the CST media. The decontaminated salt solution (DSS) then travels through a resin trap and out of the module to Tank 11. TCCR has successfully processed approximately 795,000 L of Tank 10H radioactive salt waste over two batches to date. There has not yet been a system induced shutdown. The prefilters performed as expected with only minor degradation in recovery of differential pressure after a backflush sequence. The time between backflushes decreased as each batch reached the end of processing. The hydraulics in the IXCs mostly performed as expected at all flow rates, except for one IXC that will be further investigated during Batch 3 processing. The TCCR system has shown some opportunities for more efficient processing during the length of the demonstration so far. For future processing of material from Tank 9H through Tank 10H and the TCCR unit, TCCR 1A will implement changes to the prefilters and the IXCs. The prefilters will have an increased surface area and a new filter media in an effort to increase time between filter swaps and improve backwashing cleaning capability. The IXCs will have a reduced diameter to allow for increased heat transfer out of the column and increased loading of Cs-137. Additionally, a new form of CST with an increased kinetic performance is being investigated for use during TCCR 1A operation. (authors)

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TESTING OF ENHANCED CHEMICAL CLEANING OF SRS ACTUAL WASTE TANK 5F AND TANK 12H SLUDGES

Forty three of the High Level Waste (HLW) tanks at the Savannah River Site (SRS) have internal structures that hinder removal of the last approximately five thousand gallons of waste sludge solely by mechanical means. Chemical cleaning can be utilized to dissolve the sludge heel with oxalic acid (OA) and pump the material to a separate waste tank in preparation for final disposition. This dissolved sludge material is pH adjusted downstream of the dissolution process, precipitating the sludge components along with sodium oxalate solids. The large quantities of sodium oxalate and other metal oxalates formed impact downstream processes by requiring additional washing during sludge batch preparation and increase the amount of material that must be processed in the tank farm evaporator systems and the Saltstone Processing Facility. Enhanced Chemical Cleaning (ECC) was identified as a potential method for greatly reducing the impact of oxalate additions to the SRS Tank Farms without adding additional components to the waste that would extend processing or increase waste form volumes. In support of Savannah River Site (SRS) tank closure efforts, the Savannah River National Laboratory (SRNL) conducted Real Waste Testing (RWT) to evaluate an alternative to the baseline 8 wt. % OA chemical cleaning technology for tank sludge heel removal. The baseline OA technology results in the addition of significant volumes of oxalate salts to the SRS tank farm and there is insufficient space to accommodate the neutralized streams resulting from the treatment of the multiple remaining waste tanks requiring closure. ECC is a promising alternative to bulk OA cleaning, which utilizes a more dilute OA (nominally 2 wt. % at a pH of around 2) and an oxalate destruction technology. The technology is being adapted by AREVA from their decontamination technology for Nuclear Power Plant secondary side scale removal. This report contains results from the SRNL small scale testing of the ECC process using SRS sludge tank sample material. A Task Technical and Quality Assurance Plan (TTQAP) details the experimental plan as outlined by the Technical Task Request (TTR). The TTR identifies that the data produced by this testing and results included in this report will support the technical baseline with portions having a safety class functional classification. The primary goals for SRNL RWT are as follows: (1) to confirm ECC performance with real tank sludge samples, (2) to determine the impact of ECC on fate of actinides and the other sludge metals, and (3) to determine changes, if any, in solids flow and settling behavior.

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