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At least 1,261 records · Page 70

Early-stage dynamics of chloride ion–pumping rhodopsin revealed by a femtosecond X-ray laser

Chloride ion–pumping rhodopsin (ClR) in some marine bacteria utilizes light energy to actively transport Cl – into cells. How the ClR initiates the transport is elusive. Here, we show the dynamics of ion transport observed with time-resolved serial femtosecond (fs) crystallography using the Linac Coherent Light Source. X-ray pulses captured structural changes in ClR upon flash illumination with a 550 nm fs-pumping laser. High-resolution structures for five time points (dark to 100 ps after flashing) reveal complex and coordinated dynamics comprising retinal isomerization, water molecule rearrangement, and conformational changes of various residues. Combining data from time-resolved spectroscopy experiments and molecular dynamics simulations, this study reveals that the chloride ion close to the Schiff base undergoes a dissociation–diffusion process upon light-triggered retinal isomerization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Jitter-correction for IR/UV-XUV pump-probe experiments at the FLASH free-electron laser

In pump-probe experiments employing a free-electron laser (FEL) in combination with a synchronized optical femtosecond laser, the arrival-time jitter between the FEL pulse and the optical laser pulse often severely limits the temporal resolution that can be achieved. Here, we present a pump-probe experiment on the UV-induced dissociation of 2,6-difluoroiodobenzene C 6 H 3 F 2 I) molecules performed at the FLASH FEL that takes advantage of recent upgrades of the FLASH timing and synchronization system to obtain high-quality data that are not limited by the FEL arrival-time jitter. Here, we discuss in detail the necessary data analysis steps and describe the origin of the time-dependent effects in the yields and kinetic energies of the fragment ions that we observe in the experiment.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

The role of edge resonant magnetic perturbations in edge-localized-mode suppression and density pump-out in low-collisionality DIII-D plasmas

Two-fluid nonlinear MHD simulations using the TM1 code demonstrate that the formation of magnetic islands at the top and bottom of the H-mode pedestal, together with the strong screening of resonant fields in the gradient region of the pedestal, can account for ELM suppression and density pump-out by n = 2 resonant magnetic perturbations (RMPs) in low-collisionality DIII-D ITER similar shape (ISS) plasmas. Using experimentally relevant transport coefficients, neoclassical resistivity, electron collisionality, and RMP amplitudes, nonlinear MHD simulations reproduce the observed level of density reduction (density pump-out) in DIII-D due to the formation of narrow magnetic islands in the resistive foot of pedestal. For large amplitude RMPs ( B r / B t > 1 × 10 -4 ) simulations predict resonant field penetration and resulting in pressure reduction at the top of the pedestal, consistent with experimental observations at the onset of ELM suppression. The predicted reduction in the height and width of the pedestal by magnetic island enhanced collisional transport provides a quantitative mechanism for the stabilization of the peeling-ballooning mode (PBM). Importantly, these simulations predict strong screening of resonant fields in the steep gradient region of the pedestal due to strong E × B rotation and diamagnetic flows. Yet, if the plasma resistivity is made artificially larger (~ 10X) than neoclassical, the simulations predict magnetic stochasticity throughout the plasma edge and the collapse of the pedestal due to the reduction in the penetration threshold with increasing resistivity. A scaling relation for resonant field penetration at the pedestal top, using several hundred nonlinear simulations, reproduces the density and E × B rotation dependence of the ELM suppression threshold observed in DIII-D. Simulations using ITER model equilibria indicate that the penetration threshold at the top of the ITER pedestal will be lower than in DIII-D due to the anticipated lower perpendicular flow velocities in ITER, resulting in the weaker screening of resonant fields.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Superconductivity-enhanced spin pumping: Role of Andreev resonances

Here we describe a simple hybrid superconductor–ferromagnetic-insulator structure manifesting spin-resolved Andreev bound states in which dynamic magnetization is employed to probe spin related physics. We show that, at low bias and below T c , the transfer of spin angular momentum pumped by an externally driven ferromagnetic insulator is greatly affected by the formation of spin-resolved Andreev bound states. Our results indicate that these bound states capture the essential physics of condensate-facilitated spin flow. For finite thicknesses of the superconducting layer, comparable to the coherence length, resonant Andreev bound states render highly transmitting subgap spin transport channels. We point out that the resonant enhancement of the subgap transport channels establishes a prototype Fabry-Pérot resonator for spin pumping.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Intervalley energy of GaN conduction band measured by femtosecond pump-probe spectroscopy

Time-resolved transmission and reflection measurements were performed for bulk GaN at room temperature to evaluate the energy of the first conduction band satellite valley. From this, the measurements showed clear threshold-like spectra for transmission decay and reflection rise times. The thresholds were associated with the onset of the intervalley electron scattering. Transmission measurements with pump and probe pulses in the near infrared produced an intervalley energy of 0.97 ± 0.02 eV. Ultraviolet pump and infrared probe reflection provided a similar value. Comparison of the threshold energies obtained in these experiments allowed estimating the hole effective mass in the upper valence band to be 1.4m 0 .Modeling of the reflection transients with rate equations has allowed estimating electron–LO (longitudinal optical) phonon scattering rates and the satellite valley effective mass.

36 MATERIALS SCIENCE↗

Surface studies and measurement of pumping characteristic of NEG coating (Ti-V-Zr)

NEGs (non evaporable getters) when coated as thin film on the inner wall of vacuum pipes or chamber play vital role in the evacuation of a sealed off system after heating it to activation temperature. It creates the uniformity of pressure between two long pipes where pumping is not possible at each and every part. Ternary coating of materials Ti, Zr and V has prepared on SS304L by DC-magnetron sputtering technique. These coatings was claimed to be very good in H{sub 2} adsorption which lead to achieve very low pressures of the order of 10{sup -12}-10{sup -13} mbar, low SEY(Secondary Electron Yield) and Low photo desorption yield compared to bare SS surface. We have shown the morphology of surfaces of these coatings which play the principal role in adsorption of (H{sub 2},CO,CO{sub 2}, H{sub 2}O etc.) have been extensively studied by SEM/EDX technique. SEM showed the micron size thick film. Film thickness of micron level is useful for NEG to work for no. of atmospheric exposed cycles. Reduction of superficial surface oxide after heating it to different temperatures was main concern and studied by X-ray Photoelectron spectroscopic technique. It has also reported the pumping characteristic of the NEG coating. (author)

43 PARTICLE ACCELERATORS↗

A Pumped Thermal Energy Storage Cycle with Capacity for Concentrated Solar Power Integration

Pumped thermal energy storage (PTES) is a grid-scale energy management technology that stores electricity in the form of thermal energy. A number of PTES systems have been proposed using different thermodynamic cycles, including a variant based on a regenerated Brayton cycle that stores the thermal energy in liquid storage media (such as molten salts) via heat exchangers. This has several advantages, including the possibility to consider hybrid 'solar-PTES' systems employing technology developed by the concentrated solar power (CSP) industry. Such a hybrid system could charge the same hot stores using either solar energy or off-peak electricity (e.g, from nearby wind farms), increasing the capacity factor of the plant while employing the same heat engine during discharge. In this paper, two different configurations of solar-PTES systems are proposed and studied numerically: (i) a configuration in which an existing CSP plant is retrofitted with a Brayton heat pump, and (ii) a configuration in which a new hybrid plant uses the Brayton cycle both for charge and discharge. In both cases, the need to absorb and reject heat at conditions close to ambient temperature requires the Brayton cycle to incorporate intercooled stages at the cold side of the cycle. On the other hand, the intercooling process increases the minimum temperature of the cold stores, meaning that widely available and nonflammable antifreeze solutions (such as water-ethylene glycol) may be used as the cold storage medium.

14 SOLAR ENERGY↗

A Configuration Based Pumped Storage Hydro Model in the MISO Day-Ahead Market

Pumped storage hydro units (PSHU) can provide flexibility to power systems. This becomes particularly valuable in recent years with the increasing shares of intermittent renewable resources. However, due to emphasis on thermal generation in the current market practices, the flexibility from PSHUs have not been fully explored and utilized. This paper proposes a configuration based pumped storage hydro (PSH) model for the day-ahead market, in order to enhance the use of PSH resources in the system. A strategic design of incorporating and fully optimizing PSHUs in the day-ahead market is presented. Here, we show the compactness of the proposed model. Numerical studies are presented in an illustrative test system and the Midcontinent Independent System Operator (MISO) system.

13 HYDRO ENERGY↗

Sustainable Energy Solutions for Thermal Load in Buildings—Role of Heat Pumps, Solar Thermal, and Hydrogen-Based Cogeneration Systems

Economic and population growth is leading to increased energy demand across all sectors—buildings, transportation, and industry. Adoption of new energy consumers such as electric vehicles could further increase this growth. Sensible utilization of clean renewable energy resources is necessary to sustain this growth. Thermal needs in a building pose a significant challenge to the energy infrastructure. Potential technological solutions to address growing energy demand while simultaneously lowering the carbon footprint and enhancing the grid flexibility are presented in this study. Performance assessment of heat pumps, solar thermal collectors, nonfossil fuel-based cogeneration systems, and their hybrid configurations is reported in this study. The impact of design configuration, coefficient of performance (COP), electric grid’s primary energy efficiency on the key attributes of total carbon footprint, life cycle costs, operational energy savings, and site-specific primary energy efficiency are analyzed and discussed in detail. In conclusion, heat pumps and hydrogen-fueled solid oxide fuel cells (SOFCs) are highly effective building energy resources compared to traditional approaches; however, the carbon intensity of electrical energy and hydrogen production are keys to the overall environmental benefit.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Coupled Heat Power Operation of Smart Buildings via Modular Pumped Hydro Storage

In the United States, building sector is responsible for around 40% of total energy consumption and contributes about 40% of carbon emissions since 2012. Within the past several years, various optimization models and control strategies have been studied to improve buildings’ energy efficiency and reduce operational expenses under the constraints of satisfying occupants’ comfort requirements. However, the majority of these studies consider building electricity demand and thermal load being satisfied by unidirectional electricity flow from the power grid or on-site renewable energy generation to electrical and thermal home appliances. Opportunities for leveraging low-grade heat for electricity have largely been overlooked due to impracticality at small scale. In 2016, a modular pumped hydro storage technology was invented in Oak Ridge National Laboratory, named Ground Level Integrated Diverse Energy Storage (GLIDES). In GLIDES, employing high-efficiency hydraulic machinery instead of gas compressor/turbine, liquid is pumped to compress gas inside high-pressure vessel creating head on ground level. This unique design eliminates the geographical limitation associated with the existing state-of-the-art energy storage technologies. It is easy to be scaled for building level, community level, and grid level applications. By using this novel hydro-pneumatic storage technology, opportunities for leveraging low-grade heat in building can be economical. In this research, the potential of utilizing low-grade thermal energy to augment electricity generation of GLIDES is investigated. Since GLIDES relies on gas expansion in the discharge process and the gas temperature drops during this non-isothermal process, available thermal energy, e.g., from thermal storage, combined cooling, heat and power system (CCHP), can be utilized by GLIDES to counter the cooling effect of the expansion process and elevate the gas temperature and pressure and boost the roundtrip efficiency. Here, several groups of comparison experiments have been conducted, and the experimental results show that a maximum 12.9% cost saving could be achieved with unlimited heat source for GLIDES, and a moderate 3.8% cost improvement can be expected when operated coordinately with CCHP and thermal energy storage in a smart building.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Features of the Magnetic Resonance of an Alkali Metal upon Biharmonic Pumping

The dynamics of spin projections of the electron shell of an alkali metal on the coordinate axis is considered in the electron paramagnetic resonance scheme with continuous pumping by biharmonic circularly polarized laser radiation. The working region is a cell with alkali vapor metal vapors and a buffer gas at a high concentration at temperature 60°C. It was found that the use of biharmonic pumping causes not only the expected electron-spin precession, but also pulsations of the electron-spin projection on the axis along which the magnetic field is directed. The frequency of these pulsations depends on the nuclear angular momentum of alkali metal atoms. In the case of the transverse electron magnetic resonance, this effect is absent.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Nonresonance Phase Conjugation of Light at the Surface of GaN Films Upon High-Power Optical Pumping

The possibility of the nonresonance phase conjugation of light in an excited semiconductor medium is shown theoretically and experimentally. In epitaxial GaN films pumped with a nitrogen laser at room temperature, the induced phase conjugation of light in the visible and infrared spectral regions is detected for the first time. The dependences of the phase-conjugation signal intensity on the photon energy and laser-pumping intensity are studied. An interpretation of the effect as a result of the absorption and refraction of light at laser-induced free charge carriers in the semiconductor medium is proposed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The Nature of the Effect of Precession-Frequency Mismatch between {sup 129}Xe and {sup 131}Xe Nuclei under Spin-Exchange Pumping by Alkali-Metal Atoms

The effect of precession-frequency mismatch between {sup 129}Xe and {sup 131}Xe xenon-isotope nuclei, which arises under spin-exchange pumping by optically oriented alkali-metal (Cs) atoms and affects the characteristics of measuring and navigation devices based on balanced Schemes with spin-exchange pumping of xenon isotopes, has been investigated. An attempt to explain this effect has been made, and methods for its minimization and elimination have been proposed and experimentally verified.

74 ATOMIC AND MOLECULAR PHYSICS↗

Using Multichannel Laser Complexes for Incoherent Pumping of X-ray Compton Free-Electron Lasers

It is used that there is great potential in the use of multichannel laser complexes for incoherent pumping of X-ray Compton free-electron lasers based on stimulated wave backscattering on high-current moderately relativistic electron beam. The relative width of the pump spectrum must be comparable with that of the energy spectrum of the electron beam, which ensures involvement of a significant fraction of particles into the scattering process and, hence, high efficiency of their kinetic energy conversion into X-ray radiation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Development of a tritium monitor combined with an electrochemical tritium pump using a proton conducting oxide

The detection of low level tritium is one of the key issues for tritium management in tritium handling facilities. Such a detection can be performed by tritium monitors based on proton conducting oxide technique. We tested a tritium monitoring system composed of a commercial proportional counter combined with an electrochemical hydrogen pump equipped with CaZr{sub 0.9}In{sub 0.1}O{sub 3-α} as proton conducting oxide. The hydrogen pump operated at 973 K under electrolysis conditions using tritiated water vapor (HTO). The proton conducting oxide extracts tritium molecules (HT) from HTO and tritium concentration is measured by the proportional counter. The advantage of the proposed tritium monitoring system is that it is able to convert HTO into molecular hydrogen.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

GHPsRUS: Geothermal Heat Pump Employment and Installation Price Data

The GHPsRUS Project's full name is "Measuring the Costs and Benefits of Nationwide Geothermal Heat Pump Deployment." The dataset contains employment and installation price data collected by four economic surveys: (1)GHPsRUS Project Manufacturer & OEM Survey, (2) GHPsRUS Project Geothermal Loop Survey, (3) GHPsRUS Project Mechanical Equipment Installation Survey, and (4) GHPsRUS Geothermal Heat Pump Industry Survey

15 GEOTHERMAL ENERGY↗

Brady Geothermal Field Well Pumping Data During Deployment

Contains pumping data associated with the wells used in the 2016 Spring Campaign led partially by UW - Madison, LBNL, and LLNL scientists. The well coordinates and the depths to the pressure sensors used in the pumping wells can be found at the link "Coordinates and Sensor Depths" below.

15 GEOTHERMAL ENERGY↗

Finite Volume Based Computer Program for Ground Source Heat Pump System

This report is a compilation of the work that has been done on the grant DE-EE0002805 entitled "Finite Volume Based Computer Program for Ground Source Heat Pump Systems." The goal of this project was to develop a detailed computer simulation tool for GSHP (ground source heat pump) heating and cooling systems. Two such tools were developed as part of this DOE (Department of Energy) grant; the first is a two-dimensional computer program called GEO2D and the second is a three-dimensional computer program called GEO3D. Both of these simulation tools provide an extensive array of results to the user. A unique aspect of both these simulation tools is the complete temperature profile information calculated and presented. Complete temperature profiles throughout the ground, casing, tube wall, and fluid are provided as a function of time.

15 GEOTHERMAL ENERGY↗