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At least 1,261 records · Page 70
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Ion pair extractant selective for LiCl and LiBr

Improved methods for achieving the selective extraction of lithium salts from lithium sources, including rocky ores, salt-lake brines, and end-of-life lithium-ion batteries, could help address projected increases in the demand for lithium. Here, we report an ion pair receptor (2) capable of extracting LiCl and LiBr into an organic receiving phase both from the solid state and from aqueous solutions. Ion pair receptor 2 consists of a calix[4]pyrrole framework, which acts as an anion binding site, linked to a phenanthroline cation binding motif via ether linkages. Receptor 2 binds MgBr 2 and CaCl 2 with high selectivity over the corresponding lithium salts in a nonpolar aprotic solvent. The preference for Mg 2+ and Ca 2+ salts is reversed in polar protic media, allowing receptor 2 to complex LiCl and LiBr with high selectivity and affinity in organic media containing methanol or water. The effectiveness of receptor 2 as an extractant for LiCl and LiBr under liquid–liquid extraction (LLE) conditions was found to be enhanced by the presence of other potentially competitive salts in the aqueous source phase.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2018

Investigations of Pole Erosion Mechanisms in the 12.5 kW HERMeS Hall Thruster Using Numerical Simulations and Ion Velocity Measurements

When the Hall Effect Rocket with Magnetic Shielding (HERMeS) was tested at the NASA GRC’s VF-5 the erosion rate on the pole covers was found to be at least a factor of two higher at 300 V and 20.8 A than at other operating conditions in the 400 V to 600 V range. Simulations using our hydrodynamics code Hall2De do not predict increased erosion rates at 300 V but accurately compute erosion rates similar to the measurements at the other operating conditions. We investigate the source of the discrepancy between measurements and simulations at 300 V using a combination of numerical simulations and experimental measurements of the ion velocity fields in the acceleration region of the thruster. By examining previous simulations that predicted the measured erosion rates for other thrusters and operating conditions, we determine that sputtering of the pole surfaces by high energy ions is the most likely mechanism behind the erosion rates at 300 V. High energy ions sputter the pole surfaces when the acceleration region of the thruster is downstream of the pole surface plane. When the latter occurs, the curvature of the plasma potential contours at the edges of the channel accelerates a small fraction of the high energy ions radially. We find that neither our Hall2De simulations nor the experimental measurements produce ions of sufficiently high energy and flux to the inner pole cover to explain the measured erosion there. Only at the outer edge of the cover is where we find the ions needed to yield simulation results that are comparable to the erosion measurements. We argue that one possible mechanism for the higher erosion is high energy ions that graze the channel corner of the pole and become trapped in a sheath that develops downstream. Within the sheath, we find that the electric field is large enough to turn the ions towards the surface of the pole. A simplified calculation shows that the erosion rates produced by sputtering of trapped ions are similar to the measurements. We also propose that the presence of local oscillations and high-energy cathode ions may be sources of the enhanced erosion We conclude this article by proposing a combination of analysis, simulation, and experimental measurements that can be used to address the validity of these hypotheses.

Mikellides, Ioannis G.↗
DOE OSTI2023

Extreme high vacuum for polarized electron sources

Nuclear physics experiments often require highly polarized electron beams to do precise measurements of the structure and size of nucleons and the nucleus, as well as for searches for physics beyond the standard model. Jefferson Lab?s electron source, with polarization near 90%, has been providing polarized electron beams for CEBAF for over two decades. Development is underway for polarized electron sources at MESA at Mainz and the Electron Ion Collider at Brookhaven National Lab, and there is potential for polarized electron beam in the future at facilities including the International Linear Collider, an electron upgrade at CERN, and the SuperKEKB collider in Japan. At Jefferson Lab there are even plans to make use of polarized electrons to make a polarized positron source for experimental nuclear physics. High polarization electron beams are generated using photoemission from strained superlattice GaAs based photocathodes, and photocathode lifetime is limited by the ionization of residual gas in the system, which is then accelerated into the photocathode. Extreme high vacuum (near 1x10-10 Pa) is required to operate the Jefferson Lab polarized electron source with an acceptable lifetime, and the upcoming projects will need various combinations of higher current, higher bunch charge and longer photocathode lifetimes. To meet the vacuum requirements for polarized electron sources, every component for a polarized electron source must be optimized, including chamber materials, pumps, bakeout procedure and the high voltage electrode geometry and processing. Each change in these components must be evaluated offline before being used in the accelerator, and effects on pressure are difficult to evaluate even using XHV-optimized hot filament ionization gauges. In fact, we do not get a final evaluation of system modifications until an electron source is built, installed and lifetime measurements are made over the course of months or years of operation. I will be discussing the evolution of vacuum in the Jefferson Lab polarized source system toward XHV pressures and discuss the characterization and limitations measured for commercially available XHV vacuum gauges. Finally, I?ll present the effect of system pressure on photocathode lifetime and highlight how XHV pressure standards can benefit the ongoing efforts to improve vacuum for the next generation of polarized electron sources.

Stutzman, Marcy↗
DOE OSTI2025

Liquid Metals for Advanced Batteries: Recent Progress and Future Perspective

ABSTRACT The shift toward sustainable energy has increased the demand for efficient energy storage systems to complement renewable sources like solar and wind. While lithium‐ion batteries dominate the market, challenges such as safety concerns and limited energy density drive the search for new solutions. Liquid metals (LMs) have emerged as promising materials for advanced batteries due to their unique properties, including low melting points, high electrical conductivity, tunable surface tension, and strong alloying tendency. Enabled by the unique properties of LMs, four key scientific functions of LMs in batteries are highlighted: active materials, self‐healing, interface stabilization, and conductivity enhancement. These applications can improve battery performance, safety, and lifespan. This review also discusses current challenges and future opportunities for using LMs in next‐generation energy storage systems. image

Zheng, Tianrui [Materials Science and Engineering ↗
DOE OSTI2022

Position-specific carbon isotope analysis of serine by gas chromatography/Orbitrap mass spectrometry, and an application to plant metabolism

Position-specific 13 C/ 12 C ratios within amino acids remain largely unexplored in environmental samples due to methodological limitations. We hypothesized that natural-abundance isotope patterns in serine may serve as a proxy for plant metabolic fluxes including photorespiration. Here we describe an Orbitrap method optimized for the position-specific carbon isotope analysis of serine to test our hypothesis and discuss the generalizability of this method to other amino acids. Position-specific carbon isotope ratios of serine were measured using a Thermo Scientific™ Q Exactive™ GC Orbitrap™. Amino acids were hydrolyzed from Arabidopsis biomass, purified from potential matrix interferences, and derivatized alongside standards. Derivatized serine (N,O-bis(trifluoroacetyl)methyl ester) was isolated using gas chromatography, trapped in a reservoir, and purged into the electron ionization source over tens of minutes, producing fragment ions containing different combinations of atoms from the serine-derivative molecule. The 13 C/ 12 C ratios of fragments with monoisotopic masses of 110.0217, 138.0166, and 165.0037 Da were monitored in the mass analyzer and used to calculate position-specific δ 13 C values relative to a working standard. This methodology constrains position-specific δ 13 C values for nanomole amounts of serine isolated from chemically complex mixtures. The δ 13 C values of fragment ions of serine were characterized with ≤1‰ precisions, leading to propagated standard errors of 0.7–5‰ for each carbon position. Position-specific δ 13 C values differed by up to ca 28 ± 5‰ between serine molecules hydrolyzed from plants grown under contrasting pCO 2 , selected to promote different fluxes through photosynthesis and photorespiration. The method was validated using pure serine standards characterized offline. Here this study presents the first Orbitrap-based measurements of natural-abundance, position-specific carbon isotope variation in an amino acid isolated from a biological matrix. We present a method for the precise characterization of isotope ratios in serine and propose applications probing metabolism in plants. We discuss the potential for extending these approaches to other amino acids, paving the way for novel applications.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Dataset of mechanically induced thermal runaway measurement and severity level on Li-ion batteries

The deployment of Li-ion batteries covers a wide range of energy storage applications, from mobile phones, e-bikes, electric vehicles (EV) and stationary energy storage systems. However, safety issue such as thermal runaway is always one of the most important concerns to prevent Li-ion batteries from further market penetration. A standardized single-side indentation test protocol was developed to mechanically induce an internal short-circuit. The cell voltage, compressive load, indenter stroke, and temperature at the indentation point are measured in time series. The test data of each cell, along with cell parameters such as dimensions, mass, chemistry, state of charge (SOC), capacity, are integrated together to calculate a thermal runaway severity score from 0 to100. Complete data collection process including the original measured record, test method, severity score calculation scheme is presented in this article. The thermal runaway severity analysis and the more than 100 tested Li-ion battery records provide a good data source for further comparison and ranking of thermal runaway risks.

25 ENERGY STORAGE↗
DOE OSTI2024

Lower hybrid drift instability in nonthermal plasmas

Lower hybrid drift instability (LHDI) is driven by the cross-field current and operates in the vicinity of the lower-hybrid frequency, between the ion- and electron-gyro frequencies, and with wavelengths between the electron and ion thermal gyro radii. The free energy source that drives this instability resides in the density gradient associated with an inhomogeneous plasma. The existing literature on LHDI assumes that the charged particle distribution function is given by a Maxwellian form, but the space plasma is pervasively observed to feature nonthermal characteristics. This paper extends the theory of LHDI to nonthermal plasmas. The generalized theory of LHDI is, thus, applicable to various space plasma environments characterized by nonthermal plasma velocity distribution functions.

Arya, Neetasha (ORCID:0009000236075605)↗
DOE OSTI2021

Exosphere Modeling of Proxima b: A Case Study of Photochemical Escape with a Venus-like Atmosphere

Exoplanets orbiting M dwarfs within habitable zones are exposed to stellar environments more extreme than that terrestrial planets experience in our solar system, which can significantly impact the atmospheres of the exoplanets and affect their habitability and sustainability. This study provides the first prediction of hot oxygen corona structure and the associated photochemical loss from a 1 bar CO 2 -dominated atmosphere of a Venus-like rocky exoplanet, where dissociative recombination of O 2 + ions is assumed to be the major source reaction for the escape of neutral O atoms and formation of the hot O corona (or exospheres) as on Mars and Venus. We employ a 3D Monte Carlo code to simulate the exosphere of Proxima Centauri b (PCb) based on the ionosphere simulated by a 3D magnetohydrodynamic model. Our simulation results show that variability of the stellar wind dynamic pressure over one orbital period of PCb does not affect the overall spatial structure of the hot O corona but contributes to the change in the global hot O escape rate that varies by an order of magnitude. The escape increases dramatically when the planet possesses its intrinsic magnetic fields as the ionosphere becomes more extended with the presence of a global magnetic field. Furthermore, the extended hot O corona may lead to a more extended H exosphere through collisions between thermal H and hot O, which exemplifies the importance of considering nonthermal populations in exospheres to interpret future observations.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1981

Upstream particles observed in the earth's foreshock region

The characteristics and interrelationships of upstream suprathermal particles and plasma waves observed in the earth's foreshock region are examined on the basis of data from eight instruments, including the University of Iowa Lepedeas, and plasma wave instruments, the Berkeley high time resolution particle detectors, and the UCLA magnetometer on ISEE 1 and 2. It is found that suprathermal ions in the foreshock region travel along the magnetic field away from the bow shock. It is also found that ions observed in the foreshock region display gyrophase organization produced by ion clusters with a spatial scale of less than 1 Rg, and that dispersed ion distributions are produced primarily by direct sources at or near the bow shock.

Eastman, T. E.↗
NASA NTRS1982

Plasma observations near Saturn - Initial results from Voyager 2

Results of plasma measurements made by Voyager 2 in the vicinity of Saturn are discussed and compared with those made by Pioneer 11 and Voyager 1 in a more limited range of latitudes. The initial bow shock crossing on the inbound trajectory closely agreed with the shock position inferred from the external ram pressure in the solar wind, although boundaries on the outbound pass were much further out than expected. Magnetospheric plasma observations reveal the presence of (1) shocked solar wind plasma in the magnetosheath between 30 and 22 Saturn radii; (2) a variable density region between 17 Saturn radii and the magnetopause; (3) an extended thick plasma sheet between 17 and 7 Saturn radii; and (4) an inner plasma torus probably originating from local sources. The ratio of heavy to light ions was observed to vary with distance to the equatorial plane in the dayside magnetosphere, with the heavy ions, probably O(+), more closely confined to the equatorial plane. The plasma data also account for the observed inner boundary of the neutral hydrogen torus discovered by Voyager 1.

Bridge, H. S.↗
NASA NTRS1982

The 2145 A dayglow and the high altitude nitric oxide density

It is argued that dissociative photoionization of N2 by solar ultraviolet radiation at wavelengths shorter than 329 A is a large source of atmospheric N(+)(5S 0 2) ions which radiate at 2143.6 A and 2139.7 A. Calculations of the daytime production of N(+)(5S 0 2) ions are carried out. The band pass of the instrument used to measure the intensity of the NO gamma band at 2150 A contains the N(+) emission wavelengths and we suggest that the NO densities at high altitudes may be affected.

Victor, G. A.↗
NASA NTRS1982

Experimental studies of the ion-induced binary nucleation

The aerosol nucleation phenomenon is studied in a binary mixture of H2O and H2SO4 vapors in a carrier stream of N2 gas in the presence of ions produced by a low energy beta source. Cluster spectra of the form (H2SO4)n.(H2O)m.H(+) are identified from the measurements of the cluster masses using a quadrupole mass spectrometer. Results show that the number of H2SO4 molecules in the clusters ranged from 0 to 6 whereas the number of H2O molecules ranged from 1 to 20 depending on the concentration of H2SO4 and H2O vapors in the reaction chamber. Among other conclusions, it is noted that a large number of clusters of the type investigated are formed in the presence of an ionization source even when the partial pressures of H2SO4 and H2O are very low. The cluster composition is found to be strongly dependent on the r.h. and r.a. values in the reaction cell. The cluster spectrum (n, m, l) contains a large number of low n- and low m-value clusters when the reaction cell pressure is high.

Singh, J. J.↗
NASA NTRS1984

Electrostatic ion (hydrogen) cyclotron and ion acoustic wave instabilities in regions of upward field-aligned current and upward ion beams

An investigation is made into the stability of electrostatic hydrogen ion cyclotron and ion acoustic waves in a model plasma where an ion beam, population 2, and oppositely directed drifting electrons pass through a stationary ion background, population 1. The excited wave properties are then compared with the characteristics of the unstable modes observed on the S3-3 satellite. Three temperature regimes are studied: (1) Te greater than Ti2 much greater than Ti1, (2) Ti2 greater than Te not less than Ti1, and (3) Te approximately equal to Ti1 greater than Ti2. It is found that the ion beam acts as a free energy source only in regime 1. This regime is also highly unstable to the electrons as a free energy source. Unstable modes in regimes 2 and 3 seem to best satisfy the electrostatic hydrogen cyclotron wave (EHC) properties at 1 earth radius. For these cases the electrons are the free energy source, the beam supplies damping.

Bergmann, R.↗
NASA NTRS1985

The polar ionosphere as a source of the storm time ring current

The transport of ions from the polar ionosphere to the inner magnetosphere during storm time conditions has been computed using a Monte Carlo diffusion code. The effect of the electrostatic turbulence assumed to be present during the substorm expansion phase was simulated by a process that accelerated the ions stochastically perpendicular to the magnetic field with a diffusion coefficient proportional to the rate of energization of the ions by the induced electric field. This diffusion process was continued as the ions were convected from the plasma sheet boundary layer to the double-spiral injection boundary. Inward of the injection boundary the ions were convected adiabatically. By using as input an O(+) flux of 2.8 x 10 to the 8th per sq cm per s (w greater than 10 eV) and an H(+) flux of 5.5 x 10 to the 8th per sq cm per s (w greater than .63 eV) the computed distribution functions of the ions in the ring current were found to be in good agreement, over a wide range in L (4-8), with measurements made with the ISEE 1 satellite during a storm. This O(+) flux and a large part of the H(+) flux appear to be consistent with the DE-1 and DE-2 satellite measurements of the polar ionospheric outflow during disturbed times.

Cladis, J. B.↗
NASA NTRS1986

Thermal structure of the Venus ionosphere - A two-dimensional model study

A simple, two-dimensional, spectral model of heat transport in the Venus ionosphere has been constructed. Numerical experiments with the model suggest that a nocturnal heat source about an order of magnitude smaller than the daytime source is required to simulate the observed ion and electron temperatures. The solar zenith angle dependence of the high-altitude ion temperature appears to be caused by expansion followed by compression of the plasma as it flows from the dayside to the nightside. Thermal-flux saturation appears to be significant on the nightside, but the formation of a standing shock wave does not seem to be required to explain the broad features of the observed, nocturnal ion temperature.

Whitten, R. C.↗