Results for “GaS” — Page 70

DOE OSTI2022

Porewater Geochemical Assessment of Seismic Indications for Gas Hydrate Presence and Absence: Mahia Slope, East of New Zealand’s North Island

We compare sediment vertical methane flux off the Mahia Peninsula, on the Hikurangi Margin, east of New Zealand’s North Island, with a combination of geochemical, multichannel seismic and sub-bottom profiler data. Stable carbon isotope data provided an overview of methane contributions to shallow sediment carbon pools. Methane varied considerably in concentration and vertical flux across stations in close proximities. At two Mahia transects, methane profiles correlated well with integrated seismic and TOPAS data for predicting vertical methane migration rates from deep to shallow sediment. However, at our “control site”, where no seismic blanking or indications of vertical gas migration were observed, geochemical data were similar to the two Mahia transect lines. This apparent mismatch between seismic and geochemistry data suggests a potential to underestimate gas hydrate volumes based on standard seismic data interpretations. To accurately assess global gas hydrate deposits, multiple approaches for initial assessment, e.g., seismic data interpretation, heatflow profiling and controlled-source electromagnetics, should be compared to geochemical sediment and porewater profiles. A more thorough data matrix will provide better accuracy in gas hydrate volume for modeling climate change and potential available energy content.

03 NATURAL GAS↗

DOE OSTI2022

Monitoring Offshore CO 2 Sequestration Using Marine CSEM Methods; Constraints Inferred from Field- and Laboratory-Based Gas Hydrate Studies

Offshore geological sequestration of CO 2 offers a viable approach for reducing greenhouse gas emissions into the atmosphere. Strategies include injection of CO 2 into the deep-ocean or ocean-floor sediments, whereby depending on pressure–temperature conditions, CO 2 can be trapped physically, gravitationally, or converted to CO 2 hydrate. Energy-driven research continues to also advance CO 2 -for-CH 4 replacement strategies in the gas hydrate stability zone (GHSZ), producing methane for natural gas needs while sequestering CO 2 . In all cases, safe storage of CO 2 requires reliable monitoring of the targeted CO 2 injection sites and the integrity of the repository over time, including possible leakage. Electromagnetic technologies used for oil and gas exploration, sensitive to electrical conductivity, have long been considered an optimal monitoring method, as CO 2 , similar to hydrocarbons, typically exhibits lower conductivity than the surrounding medium. We apply 3D controlled-source electromagnetic (CSEM) forward modeling code to simulate an evolving CO 2 reservoir in deep-ocean sediments, demonstrating sufficient sensitivity and resolution of CSEM data to detect reservoir changes even before sophisticated inversion of data. Laboratory measurements place further constraints on evaluating certain systems within the GHSZ; notably, CO 2 hydrate is measurably weaker than methane hydrate, and >1 order of magnitude more conductive, properties that may affect site selection, stability, and modeling considerations.

58 GEOSCIENCES↗

DOE OSTI2022

LoTSS Jellyfish Galaxies. IV. Enhanced Star Formation on the Leading Half of Cluster Galaxies and Gas Compression in IC3949

With Mapping Nearby Galaxies at APO integral field spectroscopy, we present a resolved analysis of star formation for 29 jellyfish galaxies in nearby clusters, identified from radio continuum imaging taken by the Low Frequency Array. Simulations predict enhanced star formation on the "leading half" (LH) of galaxies undergoing ram pressure stripping, and in this work we report observational evidence for this elevated star formation. The dividing line (through the galaxy center) that maximizes this star formation enhancement is systematically tied to the observed direction of the ram-pressure-stripped tail, suggesting a physical connection between ram pressure and this star formation enhancement. We also present a case study on the distribution of molecular gas in one jellyfish galaxy from our sample, IC3949, using Atacama Large Millimeter/submillimeter Array CO J = 1 – 0, HCN J = 1 – 0, and HCO + J = 1 – 0 observations from the ALMA MaNGA Quenching and Star Formation Survey. The H2 depletion time (as traced by CO) in IC3949 ranges from ~1 Gyr in the outskirts of the molecular gas disk to ~11 Gyr near the galaxy center. IC3949 shows a clear region of enhanced star formation on the LH of the galaxy where the average depletion time is ~2.7 Gyr, in line with the median value for the galaxy on the whole. Dense gas tracers, HCN and HCO + , are only detected at the galaxy center and on the LH of IC3949. Our results favor a scenario in which ram pressure compresses the interstellar medium, promoting the formation of molecular gas that in turn fuels a localized increase of star formation.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1966

Development of high pressure gas systems

This paper presents a report on the latest advances and technology in the design, construction, testing, and operation of high pressure gas bimetallic pipe systems and high pressure gas tube fittings facilitating greater alinement and manufacturing tolerances, and the supercleaning of high pressure gas systems under field conditions. The following specific topics are discussed: - Analysis of noncorrosive steels versus bimetallic, high strength steels - Analysis of various protective finishes versus bimetallic piping - Testing of high pressure systems - Pipe liner adhesion properties under varying operating conditions - Modified flared tube fittings taking into account pressure ranges, materials, costs involved in manufacture, various methods employed to permit sealing of the fitting while meeting cleanliness requirements - Cleaning requirements appertaining to high pressure gas systems and a discussion of investigations on the effects of velocity and temperature as related to various cleaning chemicals. The presentation concludes with a discussion on the possible applications of materials and methods in commercial industry.

Fitting↗

NASA NTRS2016

Practical Techniques for Modeling Gas Turbine Engine Performance

The cost and risk associated with the design and operation of gas turbine engine systems has led to an increasing dependence on mathematical models. In this paper, the fundamentals of engine simulation will be reviewed, an example performance analysis will be performed, and relationships useful for engine control system development will be highlighted. The focus will be on thermodynamic modeling utilizing techniques common in industry, such as: the Brayton cycle, component performance maps, map scaling, and design point criteria generation. In general, these topics will be viewed from the standpoint of an example turbojet engine model; however, demonstrated concepts may be adapted to other gas turbine systems, such as gas generators, marine engines, or high bypass aircraft engines. The purpose of this paper is to provide an example of gas turbine model generation and system performance analysis for educational uses, such as curriculum creation or student reference.

aerothermodynamics↗

NASA NTRS2016

Practical Techniques for Modeling Gas Turbine Engine Performance

The cost and risk associated with the design and operation of gas turbine engine systems has led to an increasing dependence on mathematical models. In this paper, the fundamentals of engine simulation will be reviewed, an example performance analysis will be performed, and relationships useful for engine control system development will be highlighted. The focus will be on thermodynamic modeling utilizing techniques common in industry, such as: the Brayton cycle, component performance maps, map scaling, and design point criteria generation. In general, these topics will be viewed from the standpoint of an example turbojet engine model; however, demonstrated concepts may be adapted to other gas turbine systems, such as gas generators, marine engines, or high bypass aircraft engines. The purpose of this paper is to provide an example of gas turbine model generation and system performance analysis for educational uses, such as curriculum creation or student reference.

aerothermodynamics↗

NASA NTRS2016

Exocometary Gas in the HD 181327 Debris Ring

An increasing number of observations have shown that gaseous debris discs are not an exception. However, until now, we only knew of cases around A stars. Here we present the first detection of 12CO (2-1) disc emission around an F star, HD 181327, obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) observations at 1.3 mm. The continuum and CO emission are resolved into an axisymmetric disc with ring-like morphology. Using a Markov chain Monte Carlo method coupled with radiative transfer calculations, we study the dust and CO mass distribution. We find the dust is distributed in a ring with a radius of 86.0 +/- 0.4 au and a radial width of 23.2 +/- 1.0 au. At this frequency, the ring radius is smaller than in the optical, revealing grain size segregation expected due to radiation pressure. We also report on the detection of low-level continuum emission beyond the main ring out to approximately 200 au. We model the CO emission in the non-local thermodynamic equilibrium regime and we find that the CO is co-located with the dust, with a total CO gas mass ranging between 1.2 x 10(exp -6) solar mass and 2.9 x 10(exp -6) solar mass, depending on the gas kinetic temperature and collisional partners densities. The CO densities and location suggest a secondary origin, i.e. released from icy planetesimals in the ring. We derive a CO+CO2 cometary composition that is consistent with Solar system comets. Due to the low gas densities, it is unlikely that the gas is shaping the dust distribution.

exocometary gas↗

NASA NTRSDate not supplied

Considerations for the Extension of Gas Path Analysis to Electrified Aircraft Propulsion Systems

Aircraft operators rely on gas path analysis techniques for monitoring the performance and health of their gas turbine engine assets. This is accomplished by analyzing discernable shifts in measurement parameters acquired from the engine. This paper reviews the founding mathematical principles of gas path analysis, including conventional approaches applied for estimating engine performance deterioration. Considerations for extending the application of gas path analysis techniques to Electrified Aircraft Propulsion (EAP) systems is also discussed, and simulated results from their application to an EAP concept comprised of turbomachinery and electrical system hardware is provided. Results are provided comparing the parameter estimation accuracy offered by taking a whole-system approach towards the problem setup versus that offered by analyzing each subsystem individually. For the latter, the importance of having accurate direct or inferred measurements of external mechanical torque loads placed upon turbomachinery shafts is emphasized.

Electrified Aircraft Propulsion↗

NASA NTRS2021

Considerations for the Extension of Gas Path Analysis to Electrified Aircraft Propulsion Systems

Aircraft operators rely on gas path analysis techniques for monitoring the performance and health of their gas turbine engine assets. This is accomplished by analyzing discernable shifts in measurement parameters acquired from the engine. This paper reviews the founding mathematical principles of gas path analysis, including conventional approaches applied for estimating engine performance deterioration. Considerations for extending the application of gas path analysis techniques to Electrified Aircraft Propulsion (EAP) systems is also discussed, and simulated results from their application to an EAP concept comprised of turbomachinery and electrical system hardware is provided. Results are provided comparing the parameter estimation accuracy offered by taking a whole-system approach towards the problem setup versus that offered by analyzing each subsystem individually. For the latter, the importance of having accurate direct or inferred measurements of external mechanical torque loads placed upon turbomachinery shafts is emphasized.

Electrified Aircraft Propulsion↗

NASA NTRS2021

Considerations for the Extension of Gas Path Analysis to Electrified Aircraft Propulsion Systems

Aircraft operators rely on gas path analysis techniques for monitoring the performance and health of their gas turbine engine assets. This is accomplished by analyzing discernable shifts in measurement parameters acquired from the engine. This paper reviews the founding mathematical principles of gas path analysis, including conventional approaches applied for estimating engine performance deterioration. Considerations for extending the application of gas path analysis techniques to Electrified Aircraft Propulsion (EAP) systems is also discussed, and simulated results from their application to an EAP concept comprised of turbomachinery and electrical system hardware is provided. Results are provided comparing the parameter estimation accuracy offered by taking a whole-system approach towards the problem setup versus that offered by analyzing each subsystem individually. For the latter, the importance of having accurate direct or inferred measurements of external mechanical torque loads placed upon turbomachinery shafts is emphasized.

Electrified Aircraft Propulsion↗

NASA NTRSDate not supplied

Investigating Waste Preparation Methods for Trash-to-Gas Technologies

Trash-to-Gas technologies show promise in addressing the need for a proper waste management system onboard a long-duration space mission. However, there is a clear need to better understand how the initial waste preparation can affect the overall conversion efficiency. Factors such as the waste size, moisture content, and packing density can have significant impacts on the reactor performance. This paper will focus on the effects of various pre-processing steps on the overall solid-to-gas conversion on the state of the art Trash-to-Gas system developed at NASA Kennedy Space Center. These results will help inform future Trash-to-Gas technologies on what types of supporting subsystems will be necessary to operate effectively for exploration missions.

Trash to Gas↗

NASA NTRSDate not supplied

Investigating Waste Preparation Methods for Trash-to-Gas Technologies

Trash-to-Gas technologies show promise in addressing the need for a proper waste management system onboard a long-duration space mission. However, there is a clear need to better understand how the initial waste preparation can affect the overall conversion efficiency. Factors such as the waste size, moisture content, and packing density can have significant impacts on the reactor performance. This paper will focus on the effects of various pre-processing steps on the overall solid-to-gas conversion on the state of the art Trash-to-Gas system developed at NASA Kennedy Space Center. These results will help inform future Trash-to-Gas technologies on what types of supporting subsystems will be necessary to operate effectively for exploration missions.

Trash to Gas↗

NASA NTRS2023

Effect of the Electrostatic Field due to the Surface Monolayer Metal Atoms on the Dissociation of Homonuclear Diatomic Gases in Gas-Metal Surface Reactions

The present paper examines the role of an electrostatic field generated by the outermost monolayer of metal ions prior to gas adsorption in aiding the dissociation of homonuclear diatomic gas molecules. The interaction of five homonuclear diatomic gases, Cl 2 , F 2 , H 2 , N 2 and O 2 , with several pure metals are examined using Coulomb’s law to calculate the attractive and repulsive forces between the electrons or ions in the gas molecule and the free surface metallic electrons or ions assuming a Bohr model. These calculations demonstrate that the total energy of the electrostatic fields from the metals can exceed the molecular binding energies of Cl 2 , F 2 , and O 2 at some distance from the metallic surface thereby suggesting that these gases interact primarily with the metallic surface in their atomic states after molecular bond dissociation prior to reaction. In contrast, H 2 and N 2 gases do not dissociate prior to reaching the metal surface due to the fact that the effective charge of the gas ions is less than the total electron charge at the outermost electronic shell. The present results correlate linearly with the electrochemical series standard reduction potential as well as with the Pauling electronegativity for several metals.

Gas-metal reactions↗

NASA NTRS2023

Quantitative Gas Property Measurements By Filtered Rayleigh Scattering: A Review

Filtered Rayleigh scattering (FRS) is a laser-based diagnostic technique used to nonintrusively quantify various thermodynamic properties of a light-scattering gas. The backbone of FRS is the molecular filtering of Rayleigh scattered light. This concept was initially introduced by the atmospheric LIDAR community before being adopted within the aerospace research field in the early 1990s. Since then, FRS has matured into a versatile quantitative diagnostic tool and has found use in a variety of flow regimes ranging from sub- to supersonic speeds in both reacting and nonreacting environments. This adoption can be attributed to the wealth of information that can be obtained via FRS, including the gas density, pressure, temperature, velocity, species composition, or, in some cases, several of these properties at once. This article reviews the current state of FRS methodology in recovering such gas properties. As knowledge of the fundamentals of Rayleigh scattering and spectral light filtering is crucial to the design of an FRS experiment, we begin by briefly reviewing these areas. Subsequently, we conduct a survey of experimental design strategies, assumptions, and data reduction methods used to measure different gas properties using FRS. We conclude the review with a short discussion on quantification of experimental uncertainty and future trends in FRS.

filtered Rayleigh scattering↗

NASA NTRS2023

Automated Machine Learning to Evaluate the Information Content of Tropospheric Trace Gas Columns for Fine Particle Estimates Over India: A Modeling Testbed

India is largely devoid of high-quality and reliable on-the-ground measurements of fine particulate matter (PM 2.5 ). Ground-level PM 2.5 concentrations are estimated from publicly available satellite Aerosol Optical Depth (AOD) products combined with other information. Prior research has largely overlooked the possibility of gaining additional accuracy and insights into the sources of PM using satellite retrievals of tropospheric trace gas columns. We evaluate the information content of tropospheric trace gas columns for PM 2.5 estimates over India within a modeling testbed using an Automated Machine Learning (AutoML) approach, which selects from a menu of different machine learning tools based on the data set. We then quantify the relative information content of tropospheric trace gas columns, AOD, meteorological fields, and emissions for estimating PM 2.5 over four Indian sub-regions on daily and monthly time scales. Our findings suggest that, regardless of the specific machine learning model assumptions, incorporating trace gas modeled columns improves PM 2.5 estimates. We use the ranking scores produced from the AutoML algorithm and Spearman’s rank correlation to infer or link the possible relative importance of primary versus secondary sources of PM 2.5 as a first step toward estimating particle composition. Our comparison of AutoML-derived models to selected baseline machine learning models demonstrates that AutoML is at least as good as user-chosen models. The idealized pseudo-observations (chemical-transport model simulations) used in this work lay the groundwork for applying satellite retrievals of tropospheric trace gases to estimate fine particle concentrations in India and serve to illustrate the promise of AutoML applications in atmospheric and environmental research.

Machine learning↗

NASA NTRSDate not supplied

CFD Modeling of Tank Pressurization and Axial Jet Mixing Experiments with and without Non-Condensable Gas in the Ullage

A two-phase CFD model for tank pressurization and following jet mixing of a cryogenic storage tank is presented using VOF approach for representing the phase boundary and the associated interfacial heat, mass and momentum transfer between the liquid and vapor regions. The CFD model was validated against pressurization and liquid jet mixing data for a 110-inch diameter tank provided by Bullard1. Cases with like-gas and non-condensable gas pressurization are studied. The results of the cases with like-gas pressurization and following mixing are presented first, focusing on the effects of turbulence at the vapor-liquid interface on the tank pressure and phase change rates predictions. The second part of this paper is devoted to testing and validating the CFD model against non-condensable gas pressurization and following mixing. Tank pressures predicted in both cases are compared with each other and with the experimental data.

Computational Fluid Dynamics↗

NASA NTRSDate not supplied

CFD Modeling of Tank Pressurization and Axial Jet Mixing Experiments with and without Non-Condensable Gas in the Ullage

A two-phase CFD model for tank pressurization and following jet mixing of a cryogenic storage tank is presented using VOF approach for representing the phase boundary and the associated interfacial heat, mass and momentum transfer between the liquid and vapor regions. The CFD model was validated against pressurization and liquid jet mixing data for a 110-inch diameter tank provided by Bullard. Cases with like-gas and non-condensable gas pressurization are studied. The results of the cases with like-gas pressurization and following mixing are presented first, focusing on the effects of turbulence at the vapor-liquid interface on the tank pressure and phase change rates predictions. The second part of this paper is devoted to testing and validating the CFD model against non-condensable gas pressurization and following mixing. Tank pressures predicted in both cases are compared with each other and with the experimental data.

Computational Fluid Dynamics↗

NASA NTRS2024

Application of Long-Path Gas Cell Assisted Infrared Spectroscopy for Detection of Lunar Volatiles and Advanced Curation Efforts

The motivation behind analyzing gaseous samples from the Permanently Shadowed Regions (PSRs) on the lunar surface is built upon the volatiles observed during the LCROSS mission. Advanced curation techniques under cold conditions are essential to the critical scientific analysis of these returned samples. The detection of various volatiles in returned samples by gas-phase infrared (IR) spectroscopy is known to be a powerful tool to understand the resources present in planetary bodies and Astro-materials. The identification and quantification of volatile compounds in returned planetary samples and regolith simulants by advanced and custom-built analytical devices are areas of primary research interest in our group and the Planetary Exploration & Astromaterials Research Laboratory (PEARL) facility. In this context, we discuss recent advancements and experimental results for quick analysis of the major volatiles detected by the LCROSS (water, CO 2 , CH 3 OH, and NH 3 ) by a long-path gas cell/FTIR (Fourier Transform Infrared) spectrometer system. The applicability of this system is demonstrated by qualitative analysis of a series of volatiles measured individually. In addition, the linear dependence of absorption intensity on headspace sample volumes was checked by measuring gas-phase IR absorption spectra of increasing volumes of pure CO 2 gas aliquots. Finally, the instrument performance was evaluated by measuring the relative concentration of NH 3 (g) in methanol solution.

Curation↗