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At least 1,261 records · Page 70
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Thermodynamic Properties of Aqueous Carbonate Species and Solid Carbonate Phases of Selected Trace Elements pertinent to Drinking Water Standards of the U.S. Environmental Protection Agency

This report contains a series of tables summarizing the thermodynamic properties of aqueous carbonate complexes and solid carbonate phases of the following elements: arsenic (As), barium (Ba), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lead (Pb), manganese (Mn), mercury (Hg), nickel (Ni) thallium (Tl), uranium (U) and zinc (Zn). Most of these elements are potentially hazardous as defined by extant primary drinking water standards of the United States Environmental Protection Agency (EPA). The remainder are not considered hazardous, but are either listed by EPA under secondary standards, or because they can adversely affect drinking water quality. Additional tables are included giving the thermodynamic properties for carbonates of the alkali metal and alkali earth elements, sodium (Na), potassium (K), magnesium (Mg), calcium (Ca), and strontium (Sr), because of their value in developing correlative models to estimate the thermodynamic properties of carbonate minerals for which no such data currently exist. The purpose in creating the tables in this report is to provide future investigators with a convenient source for selecting and tracing the sources of thermodynamic data of the above listed elements for use in modeling their geochemical behavior in “underground sources of drinking water” (USDW). The incentive for doing so lies with a heightened concern over the potential consequences of the proposed capture and storage of carbon dioxide (CO2) generated by fossil fuel fired power plants in deep subsurface reservoirs. If CO2 were to leak from such reservoirs, it could migrate upward and contaminate USDWs with undesirable, but undetermined, consequences to water quality. The EPA, Office of Research and Development, through an Interagency Agreement with the U.S. Department of Energy at the Lawrence Berkeley National Laboratory, funded the preparation of this report.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Structure Biology of Membrane Bound Enzymes

The overall goal of the proposed research is to understand the membrane-associated active processes catalyzed by an alkane $\square$-hydroxylase (AlkB) from eubacterium Pseudomonase oleovorans. AlkB performs oxygenation of unactivated hydrocarbons found in crude oils. The enzymatic reaction involves energy-demanding steps in the membrane with the uses of structurally unknown metal active sites featuring a diiron [FeFe] center. At present, a critical barrier to understanding the membrane-associated reaction mechanism is the lack of structural information. The structural biology efforts have been challenged by technical difficulties commonly encountered in crystallization and structural determination of membrane proteins. The specific aims of the current budget cycle are to crystalize AlkB and initiate X-ray analysis to set the stage for structural determination. The long-term goals of our structural biology efforts are to provide an atomic description of AlkB structure, and to uncover the mechanisms of selective modification of hydrocarbons. The structural information will help elucidating how the unactivated C-H bonds of saturated hydrocarbons are oxidized to initiate biodegradation and biotransformation processes. The knowledge gained will be fundamental to biotechnological applications to biofuel transformation of non-edible oil feedstock. Renewable biodiesel is a promising energy carry that can be used to reduce fossil fuel dependency. The proposed research capitalizes on prior BES-supported efforts on over-expression and purification of AlkB to explore the inner workings of a bioenergy-relevant membrane-bound enzyme.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2016

Outlooks for Wind Power in the United States: Drivers and Trends under a 2016 Policy Environment

Over the past decade, wind power has become one of the fastest growing electricity generation sources in the United States. Despite this growth, the U.S. wind industry continues to experience year-to-year fluctuations across the manufacturing and supply chain as a result of dynamic market conditions and changing policy landscapes. Moreover, with advancing wind technologies, ever-changing fossil fuel prices, and evolving energy policies, the long-term future for wind power is highly uncertain. In this report, we present multiple outlooks for wind power in the United States, to explore the possibilities of future wind deployment. The future wind power outlooks presented rely on high-resolution wind resource data and advanced electric sector modeling capabilities to evaluate an array of potential scenarios of the U.S. electricity system. Scenario analysis is used to explore drivers, trends, and implications for wind power deployment over multiple periods through 2050. Specifically, we model 16 scenarios of wind deployment in the contiguous United States. These scenarios span a wide range of wind technology costs, natural gas prices, and future transmission expansion. We identify conditions with more consistent wind deployment after the production tax credit expires as well as drivers for more robust wind growth in the long run. Conversely, we highlight challenges to future wind deployment. We find that the degree to which wind technology costs decline can play an important role in future wind deployment, electric sector CO 2 emissions, and lowering allowance prices for the Clean Power Plan.

17 WIND ENERGY↗
DOE OSTI2016

A Prospective Analysis of the Costs, Benefits, and Impacts of U.S. Renewable Portfolio Standards

This report evaluates the future costs, benefits, and other impacts of renewable energy used to meet current state renewable portfolio standards (RPSs). It also examines a future scenario where RPSs are expanded. The analysis examines changes in electric system costs and retail electricity prices, which include all fixed and operating costs, including capital costs for all renewable, non-renewable, and supporting (e.g., transmission and storage) electric sector infrastructure; fossil fuel, uranium, and biomass fuel costs; and plant operations and maintenance expenditures. The analysis evaluates three specific benefits: air pollution, greenhouse gas emissions, and water use. It also analyzes two other impacts, renewable energy workforce and economic development, and natural gas price suppression. This analysis finds that the benefits or renewable energy used to meet RPS polices exceed the costs, even when considering the highest cost and lowest benefit outcomes.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2016

Assessment of potential greenhouse gas mitigation from changes to crop root mass and architecture

Reducing (and eventually reversing) the increase in greenhouse gases (GHGs) in the atmosphere due to human activities, and thus reducing the extent and severity of anthropogenic climate change, is one of the great challenges facing humanity. While most of the man-caused increase in GHGs has been due to fossil fuel use, land use (including agriculture) currently accounts for about 25% of total GHG emissions and thus there is a need to include emission reductions from the land use sector as part of an effective climate change mitigation strategy. In addition, analyses included in the recent IPCC 5th Climate Change Assessment report suggests that it may not be possible to achieve large enough emissions reductions in the energy, transport and industrial sectors alone to stabilize GHG concentrations at a level commensurate with a less than 2°C global average temperature increase, without the help of a substantial CO 2 sink (i.e., atmospheric CO 2 removal) from the land use sector. One of the potential carbon sinks that could contribute to this goal is increasing C storage in soil organic matter on managed lands. This report details a preliminary scoping analysis, to assess the potential agricultural area in the US – where appropriate soil, climate and land use conditions exist – to determine the land area on which ‘improved root phenotype’ crops could be deployed and to evaluate the potential long-term soil C storage, given a set of ‘bounding scenarios’ of increased crop root input and/or rooting depth for major crop species (e.g., row crops (corn, sorghum, soybeans), small grains (wheat, barley, oats), and hay and pasture perennial forages). The enhanced root phenotype scenarios assumed 25, 50 and 100% increase in total root C inputs, in combination with five levels of modifying crop root distributions (i.e., no change and four scenarios with increasing downward shift in root distributions). We also analyzed impacts of greater root production on the soil-crop nitrogen balance, from the standpoint of increased need for additional N inputs and consequences for increased N 2 O flux, as well as potential impacts if more and deeper roots contributed to reduced N leaching. In the enhanced root phenotype scenarios, the implicit assumption was that increases in overall plant production could be achieved (e.g., through increased CO 2 assimilation, greater growth efficiency) without reducing the harvested yield – that is, we did not include potential leakage and land substitution effects from potential decreased crop yield in the analysis.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Functional Gene Discovery and Characterization of Genes and Alleles Affecting Wood Biomass Yield and Quality in Populus

Adoption of biofuels as economically and environmentally viable alternative to fossil fuels would require development of specialized bioenergy varieties. A major goal in the breeding of such varieties is the improvement of lignocellulosic biomass yield and quality. These are complex traits and understanding the underpinning molecular mechanism can assist and accelerate their improvement. This is particularly important for tree bioenergy crops like poplars (species and hybrids from the genus Populus), for which breeding progress is extremely slow due to long generation cycles. A variety of approaches have been already undertaken to better understand the molecular bases of biomass yield and quality in poplar. An obvious void in these undertakings has been the application of mutagenesis. Mutagenesis has been instrumental in the discovery and characterization of many plant traits including such that affect biomass yield and quality. In this proposal we use activation tagging to discover genes that can significantly affect biomass associated traits directly in poplar, a premier bioenergy crop. We screened a population of 5,000 independent poplar activation tagging lines under greenhouse conditions for a battery of biomass yield traits. These same plants were then analyzed for changes in wood chemistry using pyMBMS. As a result of these screens we have identified nearly 800 mutants, which are significantly (P<0.05) different when compared to wild type. Of these majority (~700) are affected in one of ten different biomass yield traits and 100 in biomass quality traits (e.g., lignin, S/G ration and C6/C5 sugars). We successfully recovered the position of the tag in approximately 130 lines, showed activation in nearly half of them and performed recapitulation experiments with 20 genes prioritized by the significance of the phenotype. Recapitulation experiments are still ongoing for many of the genes but the results are encouraging. For example, we have shown successful recapitulation for a fascilin-like gene that when overexpressed increase many biomass-yield associated traits. Genes discovered through activation tagging showed polymorphisms in P. trichocarpa association mapping population linked to the traits modified by the activation tagging. This suggests that putative alleles that are associated with improvement of the trait o interest can be discovered and used in marker associated selection. This will significantly simplify and accelerate the breeding efforts.

09 BIOMASS FUELS↗
DOE OSTI2017

Tribal Energy Program for California Indian Tribes

A strategic plan is needed to catalyze clean energy in the more than 100 California Indian tribal communities with varying needs and energy resources. We propose to conduct a scoping study to identify tribal lands with clean energy potential, as well as communities with lack of grid-tied energy and communications access. The research focus would evaluate the energy mixture and alternatives available to these tribal communities, and evaluate greenhouse gas emissions associated with accessing fossil fuel used for heat and power. Understanding the baseline of energy consumption and emissions of communities is needed to evaluate improvements and advances from technology. Based on this study, we will develop a strategic plan that assesses solutions to address high energy fuel costs due to lack of electricity access and inform actions to improve economic opportunities for tribes. This could include technical support for tribes to access clean energy technologies and supporting collaboration for on-site demonstrations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2016

On the Path to SunShot - The Environmental and Public Health Benefits of Achieving High Penetrations of Solar Energy in the United States

Monetizing the environmental health benefits of solar could add ~3.5¢/kWh to the value of solar energy (see Wiser et al. 2016). The monetary impacts due to environmental degradation and public health impacts seem far removed from the apparent “sticker price” of electricity. Yet quantifying these impacts is essential to understanding the true costs and benefits of solar and conventional generating technologies. Compared with fossil fuel generators, PV and CSP produce far lower lifecycle levels of greenhouse gas (GHG) emissions and harmful pollutants including fine particular matter (PM2.5), sulfur dioxide (SO2), and nitrogen oxides (NOx). Achieving the SunShot-level solar deployment targets—14% of U.S. electricity demand met by solar in 2030 and 27% in 2050—could reduce cumulative power-sector GHG emissions by 10% between 2015 and 2050, resulting in savings of $238–$252 billion. This is equivalent to 2.0–2.2 cents per kilowatt-hour of solar installed (¢/kWh-solar). Similarly, realizing these levels of solar deployment could reduce cumulative power-sector emissions of PM2.5 by 8%, SO2 by 9%, and NOx by 11% between 2015 and 2050. This could produce $167 billion in savings from lower future health and environmental damages, or 1.4¢/kWh-solar—while also preventing 25,000–59,000 premature deaths. To put this in perspective, the estimated 3.5¢/kWh-solar in benefits due to SunShot-level solar deployment is approximately equal to the additional LCOE reduction needed to make unsubsidized utility-scale solar competitive with conventional generators today. In addition, water savings from achieving the SunShot goals, could result in the 2015–2050 cumulative savings of 4% of total power-sector withdrawals and 9% of total power-sector consumption—a particularly important consideration for arid states where substantial solar will be deployed. Improving public health and the environment is but one aspect of solar’s many costs and benefits. Clearly, however, the assignment of value

14 SOLAR ENERGY↗
DOE OSTI2016

The Vermont Bioenergy Initiative: Final Technical Report

The purpose of the Vermont Bioenergy Initiative (VBI) was to foster the development of sustainable, distributed, small-scale biodiesel and grass/mixed fiber industries in Vermont in order to produce bioenergy for local transportation, agricultural, and thermal applications, as a replacement for fossil fuel based energy. The VBI marked the first strategic effort to reduce Vermont’s dependency on petroleum through the development of homegrown alternatives.

09 BIOMASS FUELS↗
DOE OSTI2015

A Critical Review of the Impacts of Leaking CO 2 Gas and Brine on Groundwater Quality

Geological carbon sequestration (GCS) is a global carbon emission reduction strategy involving the capture of CO 2 emitted from fossil fuel burning power plants, as well as the subsequent injection of the captured CO 2 gas into deep saline aquifers or depleted oil and gas reservoirs. A critical question that arises from the proposed GCS is the potential impacts of CO 2 injection on the quality of drinking-water systems overlying CO 2 sequestration storage sites. Although storage reservoirs are evaluated and selected based on their ability to safely and securely store emplaced fluids, leakage of CO 2 from storage reservoirs is a primary risk factor and potential barrier to the widespread acceptance of geologic CO 2 sequestration (OR Harvey et al. 2013; Y-S Jun et al. 2013; DOE 2007). Therefore, a systematic understanding of how CO 2 leakage would affect the geochemistry of potable aquifers, and subsequently control or affect elemental and contaminant release via sequential and/or simultaneous abiotic and biotic processes and reactions is vital.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Algal-Based Renewable Energy for Nevada

To help in the overall evaluation of the potential for growing algal biomass in high productivity systems, we conducted a study that evaluated water from geothermal sources and cultivated mixed consortia from hot springs in Nevada, we evaluated their growth at moderately high varying temperatures and then evaluated potential manipulations that could possibly increase their biomass and oleaginous production. Studies were conducted at scales ranging from the laboratory benchtop to raceways in field settings. Mixed consortia were readily grown at all scales and growth could be maintained in Nevada year round. Moderate productivities were attained even during the shoulder seasons- where temperature control was maintained by hot water and seasonally cold temperatures when there was still plentiful solar radiation. The results enhance the prospects for economic feasibility of developing algal based industries in areas with geothermal energy or even other large alternative sources of heat that are not being used for other purposes. The public may benefit from such development as a means for economic development as well as development of industries for alternative energy and products that do not rely on fossil fuels.

09 BIOMASS FUELS↗
DOE OSTI2014

Final Scientific/Technical Report; Development of Concentrator Photovoltaic Systems for Solar Electricity; DE-FG36-08GO88002

This project will develop and validate a new technology for lowest cost production of utility-scale solar electric power, at a price competitive with fossil fuel generation. The second phase objective is to produce a working prototype of a new concentrating photovoltaic generator. The target output for the prototype is 15 kW. The prototypes will be built using new methods chosen with the potential to meet the cost objective of $1/watt installed, when replicated in high volume.

14 SOLAR ENERGY↗
DOE OSTI2017

Renewable Energy Zones for Balancing Siting Trade-offs in India

India’s targets of 175 GW of renewable energy capacity by 2022, and 40% generation capacity from non-fossil fuel sources by 2030 will require a rapid and dramatic increase in solar and wind capacity deployment and overcoming its associated economic, siting, and power system challenges. The objective of this study was to spatially identify the amount and quality of wind and utility-scale solar resource potential in India, and the possible siting-related constraints and opportunities for development of renewable resources. Using the Multi-criteria Analysis for Planning Renewable Energy (MapRE) methodological framework, we estimated several criteria valuable for the selection of sites for development for each identified potential "zone", such as the levelized cost of electricity, distance to nearest substation, capacity value (or the temporal matching of renewable energy generation to demand), and the type of land cover. We find that high quality resources are spatially heterogeneous across India, with most wind and solar resources concentrated in the southern and western states, and the northern state of Rajasthan. Assuming India's Central Electricity Regulatory Commission's norms, we find that the range of levelized costs of generation of wind and solar PV resources overlap, but concentrated solar power (CSP) resources can be approximately twice as expensive. Further, the levelized costs of generation vary much more across wind zones than those across solar zones because of greater heterogeneity in the quality of wind resources compared to that of solar resources. When considering transmission accessibility, we find that about half of all wind zones (47%) and two-thirds of all solar PV zones (66%) are more than 25 km from existing 220 kV and above substations, suggesting potential constraints in access to high voltage transmission infrastructure and opportunities for preemptive transmission planning to scale up RE development. Additionally and importantly, we find that about 84% of all wind zones are on agricultural land, which provide opportunities for multiple-uses of land but may also impose constraints on land availability. We find that only 29% of suitable solar PV sites and 15% of CSP sites are within 10 km of a surface water body suggesting water availability as a significant siting constraint for solar plants. Availability of groundwater resources was not analyzed as part of this study. Lastly, given the possible economic benefits of transmission extensions or upgrades that serve both wind and solar generators, we quantified the co-location opportunities between the two technologies and find that about a quarter (28%) of all solar PV zones overlap with wind zones. Using the planning tools made available as part of this study, these multiple siting constraints and opportunities can be systematically compared and weighted to prioritize development that achieves a particular technology target. Our results are limited by the uncertainties associated with the input datasets, in particular the geospatial wind and solar resource, transmission, and land use land cover datasets. As input datasets get updated and improved, the methodology and tools developed through this study can be easily adapted and applied to these new datasets to improve upon the results presented in this study. India is on a path to significantly decarbonize its electricity grid through wind and solar development. A stakeholder-driven, systematic, and integrated planning approach using data and tools such as those highlighted in this study is essential to not only meet the country's RE targets, but to meet them in a cost-effective, and socially and environmentally sustainable way.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2015

Technology Performance Report: Duke Energy Notrees Wind Storage Demonstration Project

Duke Energy Renewables owns and operates the Notrees Wind Farm in west Texas’s Ector and Winkler counties. The wind farm, which was commissioned in April 2009, has a total capacity of 152.6 MW generated by 55 Vestas V82 turbines, one Vestas 1-V90 experimental turbine, and 40 GE 1.5-MW turbines. The Vestas V82 turbines have a generating capacity of 1.65 MW each, the Vestas V90 turbine has a generating capacity of 1.86 MW, and the GE turbines have a generating capacity of 1.5 MW each. The objective of the Notrees Wind Storage Demonstration Project is to validate that energy storage increases the value and practical application of intermittent wind generation and is commercially viable at utility scale. The project incorporates both new and existing technologies and techniques to evaluate the performance and potential of wind energy storage. In addition, it could serve as a model for others to adopt and replicate. Wind power resources are expected to play a significant part in reducing greenhouse gas emissions from electric power generation by 2030. However, the large variability and intermittent nature of wind presents a barrier to integrating it within electric markets, particularly when competing against conventional generation that is more reliable. In addition, wind power production often peaks at night or other times when demand and electricity prices are lowest. Energy storage systems can overcome those barriers and enable wind to become a valuable asset and equal competitor to conventional fossil fuel generation.

17 WIND ENERGY↗
DOE OSTI2017

Robust metal-ceramic coaxial cable sensors for distributed temperature monitoring in fossil energy power systems

The project aims to develop a new type of low cost, robust metal-ceramic coaxial cable (MCCC) Fabry-Pérot interferometer (FPI) sensor and demonstrate the capability of cascading a series of FPI sensing points in a single MCCC for real-time distributed monitoring of temperature up to 1000°C. The technical accomplishments of this project include: (i) development of metal and ceramic materials for fabricating the MCCC suitable for use in high temperature (up to 1000oC) fossil fuel, (ii) design, construction and test of single point MCCC-FPI sensors for high temperature measurement at deviation within ±2.7%, (iv) demonstration of the MCCC-FPI sensors for real-time distributed temperature measurement with desired sensitivity, spatial resolution, stability, and response speed that are important to practical applications, and (v) development of a novel MCCC-FPI sensor platform for measuring high frequency dielectric constants for solids and liquids as function of temperature. Single point MCCC-FPI sensors are fabricated based on the FPI parameters, including the relationship between reflector width and reflectance as well as the inter-reflector distance for a FPI, estimated by model calculations. MCCC-FPI sensors have been made using insulators of packed ceramic powders, ceramic tubes, and air or inert gases; outer conductors of various metal tubes; inner conductors of wires of the same metal materials as the tubes used; and reflectors of dense ceramic discs, casted ceramic discs and air gaps. The insulator, conductor and reflector materials are investigated for their thermal, chemical, and structural stabilities under temperatures up to 1000°C in simulated coal-derived syngas. Based on the experimental findings, alumina tube and discs, and stainless steel tube and wire are selected for reflector, insulator and outer and inner conductors, respectively. Air or inert gases are found to be useful for reflectors (in the form of narrow groves) or insulators (in the form of empty chamber cavity between ceramic discs) in construction of MCCC-FPI sensors. Single point MCCC-FPI sensors have been fabricated using stainless steel as conductors, dense α-alumina tubes as dielectric insulators, and two air gaps in the insulator as reflectors. The MCCC-FPI sensor with air gap reflectors has been demonstrated for measuring temperature between 200 and 500°C using microwave as sensing signal in a frequency range of 2 – 8 GHz. The temperature measurement is achieved by monitoring the frequency shift (Δƒ) of a selected resonant peak of the microwave interferogram reflected from the pair of air gap reflectors. The MCCC-FPI sensor exhibited excellent linear temperature-dependence for Δƒ, good accuracy (deviation ±2.7%), and reasonable response speed (<180 s for stabilization). Thermal drifting of the sensing signal was also rather minimal for the MCCC-FPI sensors after operating for more than one week at around 500oC. MCCC-FPI sensors with each containing 2 or 3 pairs of reflectors (i.e. 2 or 3 FPIs in a single cable) have been fabricated and demonstrated for distributed temperature measurement between 250 and 550°C in a microwave frequency range of 3-6 GHz. The measurement is achieved by monitoring the frequency shift of a selected resonant peak of the reflected microwave interferogram, which is obtained by the join-time-domain signal processing method. The results demonstrate that the FPI sensing points in both the three-point and two-point MCCC sensors can measure distributed high temperature with good reproducibility and consistency in multiple runs of measurement tests. The sensor signal displays excellent linear dependence between temperature and the corresponding frequency shift. The 2-point and 3-point MCCC-FPI sensors also exhibit fast response to environmental temperature changes. A three-point MCCC-FPI sensor has been further examined for temperature measurement up to 1000°C for multiple heating-cooling cycles and the results prove that the sensor is suitable for distributed temperature measurement up to 1000°C. MCCC-FPI sensors with more than 4 FPIs point in a single line are made in two structures: the first uses alumina tube as insulation and air gaps as reflectors; and the second uses air chamber as insulation and complete circular alumina discs (2 mm-thick) as reflectors. MCCC-FPIs in neither of the two structures are able to exceed four FPIs in a cable because the reflections from the FPIs are too strong for the microwave to transmit through >4 FPIs over a long distance. Specially shaped alumina discs made by removing parts of the circular discs are found to decrease the microwave reflectance because of reduced reflection areas. However, the smallest reflectance (in terms of percentage of the incident signal) obtained in this work is as high as 7.5%, which is still too large to construct more than 10 FPIs in a single MCCC. Nevertheless, the feasibility of the proposed multipoint MCCC-FPI has been demonstrated using air insulation and 2 mm-thick low-ε r Teflon discs as reflectors on a 2 m-long cable containing 10 FPIs (with reflectance <5% on each FPI). These results indicate that the contrast of dielectric constant between the insulation and reflector has a more significant impact on the reflectance. Thus, future research efforts should also be directed to developing ceramic materials (dense or porous) with low dielectric constant values which, when used as insulation or reflector, can realize large numbers of FPIs in a single cable over a long distance. To assist the development of high temperature dielectric materials, a novel MCCC-FPI sensor platform is developed and successfully demonstrated for measuring high frequency dielectric constants for fluids, packed dielectric solids, and ceramic tube materials and determining ε r dependencies on temperature and chemical composition, etc..

36 MATERIALS SCIENCE↗
DOE OSTI2016

Hawaii Energy Sustainable Program

The objective of HESP was to support the development and deployment of distributed energy resource (DER) technologies to facilitate increased penetration of renewable energy resources and reduced use of fossil fuels in Hawaii’s power grids. All deliverables, publications and other public releases have been submitted to the DOE in accordance with the award and subsequent award modifications.

03 NATURAL GAS↗
DOE OSTI2017

Mesoscale Modeling of Kinetic Phase Behaviors in Mg-B-H (Subcontract Report)

Storage of hydrogen on board vehicles is one of the critical enabling technologies for creating hydrogenfueled transportation systems that can reduce oil dependency and mitigate the long-term effects of fossil fuels on climate change. Stakeholders in developing hydrogen infrastructure are currently focused on highpressure storage at 350 bar and 700 bar, in part because no viable solid-phase storage material has emerged. Nevertheless, solid-state materials, including high-density hydrides, remain of interest because of their unique potential to meet all DOE targets and deliver hydrogen at lower pressures and higher on-board densities. A successful solution would significantly reduce costs and ensure the economic viability of a U.S. hydrogen infrastructure. The Mg(BH 4 ) 2 -MgB 2 system represents a highly promising solution because of its reasonable reaction enthalpy, high intrinsic capacity, and demonstrated reversibility, yet suffers from poor reaction kinetics. This subcontract aims to deliver a phase-field model for the kinetics of the evolution of the relevant phases within the Mg-B-H system during hydrogenation and dehydrogenation. This model will be used within a broader theory, synthesis, and characterization framework to study the properties of geometry-selected nanoparticles of pristine and doped MgB 2 /Mg(BH 4 ) 2 with two aims: (1) understand the intrinsic limitations in (de)hydrogenation; (2) devise strategies for improving thermodynamics and kinetics through nanostructuring.

08 HYDROGEN↗
DOE OSTI2017

Large-Scale Power Production Potential on U.S. Department of Energy Lands

This report summarizes the potential for independent power producers to generate large-scale power on U.S. Department of Energy (DOE) lands and export that power into a larger power market, rather than serving on-site DOE loads. The report focuses primarily on the analysis of renewable energy (RE) technologies that are commercially viable at utility scale, including photovoltaics (PV), concentrating solar power (CSP), wind, biomass, landfill gas (LFG), waste to energy (WTE), and geothermal technologies. The report also summarizes the availability of fossil fuel, uranium, or thorium resources at 55 DOE sites.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗