DOE OSTI2016
At high burn up nuclear fuel undergoes a significant restructuring, and in particular near the pellet edge, where large 10 μm UO{sub 2} grains of the fresh fuel fragment to yield a material with grain size of 100-300 nm and porosity up to 20%. This so-called 'High Burn up Structure (HBS)' has been investigated in the past to elucidate its morphology, grain size, crystal structure, thermal conductivity, hardness, etc.. Handling of spent fuel, however, is difficult due to its high radioactivity and the concomitant shielding needed to manipulate even the smallest samples. The establishment of a route to prepare a surrogate material closely mimicking the HBS morphology is an essential step, if all the details of this fascinating material are to be understood. Furthermore, preparation of dense bulk nanocrystalline UO{sub 2} as a function of grain size and porosity enables the effect of these crucial parameters to be distinguished, ultimately to provide a full insight into properties of HBS and their detailed assessment. We have successfully produced high density UO{sub 2} disks (φ = 4 mm, h= 1 mm) with grain sizes tunable in the 40 to 1000 nm range, from 10 nm UO{sub 2} powders generated by oxalate precipitation of UO{sub 2} from U(IV) solutions. Consolidation has been achieved using a specially constructed spark plasma sintering (SPS) unit housed in a radiological glovebox, which is equipped with a special die system incorporating SiC inserts to achieve pressures of 500 MPa. The latter innovation has reduced processing times and temperatures, which in turn limits grain growth, but still enabling fully dense compacts to be produced. These results now open the path to determine the potential effect of grain size on mechanical properties, thermal conductivity, irradiation damage (and its recovery), and gas (fission and helium) behaviour therein. Furthermore, using suitable pore formers, samples with controlled porosity to fully emulate the HBS in irradiated fuel can be prepared. (authors)
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗