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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,261 records · Page 70
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

1,2-Dichlorohexafluoro-Cyclobutane (1,2-c-C4F6Cl2, R-316c) a Potent Ozone Depleting Substance and Greenhouse Gas: Atmospheric Loss Processes, Lifetimes, and Ozone Depletion and Global Warming Potentials for the (E) and (Z) stereoisomers

The atmospheric processing of (E)- and (Z)-1,2-dichlorohexafluorocyclobutane (1,2-c-C4F6Cl2, R-316c) was examined in this work as the ozone depleting (ODP) and global warming (GWP) potentials of this proposed replacement compound are presently unknown. The predominant atmospheric loss processes and infrared absorption spectra of the R-316c isomers were measured to provide a basis to evaluate their atmospheric lifetimes and, thus, ODPs and GWPs. UV absorption spectra were measured between 184.95 to 230 nm at temperatures between 214 and 296 K and a parametrization for use in atmospheric modeling is presented. The Cl atom quantum yield in the 193 nm photolysis of R- 316c was measured to be 1.90 +/- 0.27. Hexafluorocyclobutene (c-C4F6) was determined to be a photolysis co-product with molar yields of 0.7 and 1.0 (+/-10%) for (E)- and (Z)-R-316c, respectively. The 296 K total rate coefficient for the O(1D) + R-316c reaction, i.e., O(1D) loss, was measured to be (1.56 +/- 0.11) × 10(exp −10)cu cm/ molecule/s and the reactive rate coefficient, i.e., R-316c loss, was measured to be (1.36 +/- 0.20) × 10(exp −10)cu cm/molecule/s corresponding to a approx. 88% reactive yield. Rate coefficient upper-limits for the OH and O3 reaction with R-316c were determined to be <2.3 × 10(exp −17) and <2.0 × 10(exp −22)cu cm/molecule/s, respectively, at 296 K. The quoted uncertainty limits are 2(sigma) and include estimated systematic errors. Local and global annually averaged lifetimes for the (E)- and (Z)-R-316c isomers were calculated using a 2-D atmospheric model to be 74.6 +/- 3 and 114.1 +/-10 years, respectively, where the estimated uncertainties are due solely to the uncertainty in the UV absorption spectra. Stratospheric photolysis is the predominant atmospheric loss process for both isomers with the O(1D) reaction making a minor, approx. 2% for the (E) isomer and 7% for the (Z) isomer, contribution to the total atmospheric loss. Ozone depletion potentials for (E)- and (Z)-R-316c were calculated using the 2-D model to be 0.46 and 0.54, respectively. Infrared absorption spectra for (E)- and (Z)-R-316c were measured at 296 K and used to estimate their radiative efficiencies (REs) and GWPs; 100-year time-horizon GWPs of 4160 and 5400 were obtained for (E)- and (Z)-R-316c, respectively. Both isomers of R-316c are shown in this work to be long-lived ozone depleting substances and potent greenhouse gases.

UV cross section↗
DOE OSTI2025

On the Dependence of Simulated Convection on Domain Size in CRMs

Abstract We present a heuristic model to explain the suppression of deep convection in convection‐resolving models (CRMs) with a small number of grid columns, such as those used in super‐parameterized or multi‐scale modeling framework (MMF) general circulation models (GCM) of the atmosphere. Domains with few grid columns require greater instability to sustain convection because they force a large convective fraction, driving strong compensating subsidence warming. Updraft dilution, which is stronger for reduced horizontal grid spacing, enhances this effect. Thus, suppression of deep convection in CRMs with few grid columns can be reduced by increasing grid spacing. Radiative‐convective equilibrium simulations using standalone CRM simulations with the System for Atmospheric Modeling (SAM) and using GCM‐coupled CRM simulations with the Energy Exascale Earth System Model (E3SM)‐MMF confirm the heuristic model results.

CRM↗
DOE OSTI2020

Moderate-resolution K-band Spectroscopy of Substellar Companion κ Andromedae b

We present moderate-resolution (R ∼ 4000) K-band spectra of the “super-Jupiter,” κ Andromedae b. The data were taken with the OSIRIS integral field spectrograph at Keck Observatory. The spectra reveal resolved molecular lines from H{sub 2}O and CO, and are compared to a custom PHOENIX atmosphere model grid appropriate for young planetary-mass objects. We fit the data using a Markov chain Monte Carlo forward-modeling method. Using a combination of our moderate-resolution spectrum and low-resolution, broadband data from the literature, we derive an effective temperature of T {sub eff} = 1950–2150 K, a surface gravity of logg=3.5--4.5, and a metallicity of [M/H] = −0.2–0.0. These values are consistent with previous estimates from atmospheric modeling and the currently favored young age of the system (<50 Myr). We derive a C/O ratio of 0.70{sub −0.24}{sup +0.09} for the source, broadly consistent with the solar C/O ratio. This, coupled with the slightly subsolar metallicity, implies a composition consistent with that of the host star, and is suggestive of formation by a rapid process. The subsolar metallicity of κ Andromedae b is also consistent with predictions of formation via gravitational instability. Further constraints on formation of the companion will require measurement of the C/O ratio of κ Andromedae A. We also measure the radial velocity of κ Andromedae b for the first time, with a value of −1.4 ± 0.9 km s{sup −1} relative to the host star. We find that the derived radial velocity is consistent with the estimated high eccentricity of κ Andromedae b.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1977

Remote estimation of surface temperature in pollution measurement experiments

The procedure described was developed for inferring the effective brightness temperature (EBT) of the underlying surface (at a given altitude) from the computed value of the radiance corresponding to a known surface temperature. A standard temperature correction to EBT (termed 'base correction') is first determined by using a 'base model atmosphere' for computing the upwelling radiance. Additional temperature corrections are then determined by considering several variations of the different surface and atmospheric parameters from their 'base model' values. Empirical relations are derived between the deviations of various surface and atmospheric parameters (from their base model values) and the additional corrections required for the EBT as a result of these variations. Use of such relations for large-scale data reduction, instead of radiative transfer calculations, is expected to result in drastic cost decrease.

Gupta, S. K.↗
NASA NTRS1981

The detection of companion stars to the Cepheid variables ETA Aquilae and T Monocerotis

Ultraviolet spectra of the classical Cepheid variables eta Aq1 and T Mon at several phases in their periods were obtained with IUE. For eta Aq1 significant ultraviolet emission is detected at wavelengths less than 1600 A, where little flux is expected from classical Cepheids. Furthermore, the emission at wavelengths less than about 1600 A does not vary with phase. Comparison with model atmosphere flux distributions shows that the nonvariable emission is consistent with the flux expected from a main sequence companion star with an effective temperature of about 9500 K (AO V - A1 V). For T Mon a nonvarying component to the ultraviolet emission is observed for wavelengths less than 2600 A. Comparison with model atmosphere flux distributions suggests that the companion has an effective temperature of around 10,000 K (AO) and is near the main sequence.

Mariska, J. T.↗
NASA NTRS2014

A Two-Habit Ice Cloud Optical Property Parameterization for GCM Application

We present a novel ice cloud optical property parameterization based on a two-habit ice cloud model that has been proved to be optimal for remote sensing applications. The two-habit ice model is developed with state-of-the-art numerical methods for light scattering property calculations involving individual columns and column aggregates with the habit fractions constrained by in-situ measurements from various field campaigns. Band-averaged bulk ice cloud optical properties including the single-scattering albedo, the mass extinction/absorption coefficients, and the asymmetry factor are parameterized as functions of the effective particle diameter for the spectral bands involved in the broadband radiative transfer models. Compared with other parameterization schemes, the two-habit scheme generally has lower asymmetry factor values (around 0.75 at the visible wavelengths). The two-habit parameterization scheme was widely tested with the broadband radiative transfer models (i.e. Rapid Radiative Transfer Model, GCM version) and global circulation models (GCMs, i.e. Community Atmosphere Model, version 5). Global ice cloud radiative effects at the top of the atmosphere are also analyzed from the GCM simulation using the two-habit parameterization scheme in comparison with CERES satellite observations.

Yi, Bingqi↗
DOE OSTI2022

Thermodynamically consistent versions of approximations used in modelling moist air

Abstract Some existing approaches to modelling the thermodynamics of moist air make approximations that break thermodynamic consistency , such that the resulting thermodynamics does not obey the first and second laws or has other inconsistencies. Recently, an approach to avoid such inconsistency has been suggested: the use of thermodynamic potentials in terms of their natural variables , from which all thermodynamic quantities and relationships (equations of state) are derived. In this article, we develop this approach for unapproximated moist‐air thermodynamics and two widely used approximations: the constant‐ approximation and the dry heat capacities approximation. The (consistent) constant‐ approximation is particularly attractive because it leads to, with the appropriate choice of thermodynamic variable, adiabatic dynamics that depend only on total mass and are independent of the breakdown between water forms. Additionally, a wide variety of material from different sources in the literature on thermodynamics in atmospheric modelling is brought together. It is hoped that this article provides a comprehensive reference for the use of thermodynamic potentials in atmospheric modelling, especially for the three systems considered here.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1981

IUE observations of eight OB stars in NGC 2244 - Ultraviolet continua and extinction

Low-resolution IUE ultraviolet continuum observations of O and B stars in the young open cluster NGC 2244 are presented. When only relative energy distributions are considered, thereby eliminating any dependence on reddening corrections or absolute energy calibrations, it is found that the ultraviolet energy distributions of the O stars have significantly cooler ultraviolet color temperatures than the cluster early B stars. The effect is not considered a property of the B stars because their observed continua can be well represented by model atmospheres and ultraviolet extinction characteristic of the local interstellar medium. The effect is thus thought to originate with the O star continua and can be due to either interstellar effects (the cluster O stars suffer additional extinction which has an anomalous wavelength dependence) or stellar effects (the physics incorporated into current O star model atmospheres is inadequate). It is noted that current data do not allow a definitive distinction to be made between these two alternatives, and the possible origins and consequences of each are considered.

Massa, D.↗
NASA NTRS1977

The upper Jovian atmosphere aerosol content determined from a satellite eclipse observation

An eclipse of Ganymede observed in 30 colors with a multichannel spectrometer and the 5-m Hale telescope is analyzed to determine the aerosol content of the upper Jovian atmosphere. Contemporary radiative-equilibrium atmospheric models are used, and less restrictive a priori assumptions about the aerosol distribution are made than in previous studies. Preliminary processing of the raw data to correct for telescope aperture change and to remove scattered light is described, eclipse light-curve theory is reviewed, and light-curve features are examined. The primary 'cloudy' atmospheric model employed is outlined along with the computational method, and results are presented on aerosol profiles, the upper limit of the aerosol region, the aerosol structure, the sensitivity of the aerosol profiles to various parameters, and the stratospheric aerosol distribution. The aerosol profiles are found to indicate a very dilute stratospheric haze overlying a tenuous tropopause cloud or cloud top.

Smith, D. W.↗
NASA NTRS2006

Aerocapture Technologies

Aeroassist technology development is a vital part of the NASA In-Space Propulsion Technology (ISPT) Program. One of the main focus areas of ISPT is aeroassist technologies through the Aerocapture Technology (AT) Activity. Within the ISPT, the current aeroassist technology development focus is aerocapture. Aerocapture relies on the exchange of momentum with an atmosphere to achieve thrust, in this case a decelerating thrust leading to orbit capture. Without aerocapture, a substantial propulsion system would be needed on the spacecraft to perform the same reduction of velocity. This could cause reductions in the science payload delivered to the destination, increases in the size of the launch vehicle (to carry the additional fuel required for planetary capture) or could simply make the mission impossible due to additional propulsion requirements. The AT is advancing each technology needed for the successful implementation of aerocapture in future missions. The technology development focuses on both rigid aeroshell systems as well as the development of inflatable aerocapture systems, advanced aeroshell performance sensors, lightweight structure and higher temperature adhesives. Inflatable systems such as tethered trailing ballutes ('balloon parachutes'), clamped ballutes, and inflatable aeroshells are also under development. Aerocapture-specific computational tools required to support future aerocapture missions are also an integral part of the ATP. Tools include: engineering reference atmosphere models, guidance and navigation, aerothermodynamic modeling, radiation modeling and flight simulation. Systems analysis plays a key role in the AT development process. The NASA in-house aerocapture systems analysis team has been taken with multiple systems definition and concept studies to complement the technology development tasks. The team derives science requirements, develops guidance and navigation algorithms, as well as engineering reference atmosphere models and aeroheating specifications. The study team also creates designs for the overall mission spacecraft. Presentation slides are provided to further describe the aerocapture project.

Keys, Andrew S.↗
NASA NTRS1998

Recovery of 29 Second Oscillations in Hubble Space Telescope Eclipse Observations of the Cataclysmic Variable UX Ursae Majoris

Low-amplitude (approximately 0.5%) 29 s oscillations have been detected in Hubble Space Telescope Faint Object Spectrograph eclipse observations of the nova-like cataclysmic variable UX UMa. These are the same dwarf nova-type oscillations that were originally discovered in this system in 1972. The 29 s oscillations are seen in one pair of eclipse sequences obtained with the FOS/PRISM in 1994 November but not in a similar pair obtained with the FOS/GI60L grating in August of the same year. The oscillations in the PRISM data are sinusoidal to within the small observational errors and undergo an approximately - 360' phase shift during eclipses (i.e., one cycle is lost). The amplitudes are highest at pre-eclipse orbital phases and exhibit a rather gradual eclipse whose shape is roughly similar to, although perhaps slightly narrower than, LTX UMa's overall light curve in the PRISM bandpass (2000-8000 A). Spectra of the oscillations have been constructed from pre-, mid, and post-eclipse data segments of the November observations. The spectra obtained from the out-of-eclipse segments are extremely blue, and only lower limits can be placed on the temperature of the source that dominates the modulated flux at these orbital phases. Lower limits derived from blackbody (stellar atmosphere) model fits to these data are >or equal to 95,000 K (> or equal to 85,000 K); the corresponding upper limits on the projected area of this source are all less than 2% of the white dwarf (WD) surface area. By contrast, oscillation spectra derived from mid- eclipse data segments are much redder. Fits to these spectra yield temperature estimates in the range 20,000 K approximately greater T and T approximately less than 30,000 K for both blackbody and stellar atmosphere models and corresponding projected areas of a few percent of the WD surface area. These estimates are subject to revision if the modulated emission is optically thin. We suggest that the ultimate source of the oscillations is a hot, compact region near disk center, but that a significant fraction of the observed, modulated flux is due to reprocessing of the light emitted by this source in the accretion disk atmosphere. The compact source is occulted at orbital phases near mid-eclipse, leaving only part of the more extended reprocessing region(s) to produce the weak oscillations that persist even at conjunction. The highly sinusoidal oscillation pulse shape does not permit the identification of the compact comonent in this model with emission produced by a rotating disturbance in the inner disk or in a classical, equatorial boundary layer. Instead, this component could arise in a bright spot on the surface of the WD, possibly associated with a magnetic pole. However, a standard intermediate polar model can also be ruled out since UX UMa's oscillation period has been seen to change on timescales much shorter than the minimum timescale required to spin up the WD by accretion torques. A model invoking magnetically controlled accretion onto differentially rotating WD surface layers may be viable, but needs more theoretical work.

Knigge, Christian↗
DOE OSTI2017

Diagnosing Cloud Biases in the GFDL AM3 Model With Atmospheric Classification

In this paper, we define a set of 21 atmospheric states, or recurring weather patterns, for a region surrounding the Atmospheric Radiation Measurement Program's Southern Great Plains site using an iterative clustering technique. The states are defined using dynamic and thermodynamic variables from reanalysis, tested for statistical significance with cloud radar data from the Southern Great Plains site, and are determined every 6 h for 14 years, creating a time series of atmospheric state. The states represent the various stages of the progression of synoptic systems through the region (e.g., warm fronts, warm sectors, cold fronts, cold northerly advection, and high-pressure anticyclones) with a subset of states representing summertime conditions with varying degrees of convective activity. We use the states to classify output from the NOAA/Geophysical Fluid Dynamics Laboratory AM3 model to test the model's simulation of the frequency of occurrence of the states and of the cloud occurrence during each state. The model roughly simulates the frequency of occurrence of the states but exhibits systematic cloud occurrence biases. Comparison of observed and model-simulated International Satellite Cloud Climatology Project histograms of cloud top pressure and optical thickness shows that the model lacks high thin cloud under all conditions, but biases in thick cloud are state-dependent. Frontal conditions in the model do not produce enough thick cloud, while fair-weather conditions produce too much. Finally, we find that increasing the horizontal resolution of the model improves the representation of thick clouds under all conditions but has little effect on high thin clouds. However, increasing resolution also changes the distribution of states, causing an increase in total cloud occurrence bias.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Fragmentation in Collisions of Snow with Graupel/Hail: New Formulation from Field Observations

Abstract Secondary ice production (SIP) has been attributed to the generation of most ice particles observed in precipitating clouds with cloud tops warmer than −36°C, from various aircraft- and ground-based field observations across the globe. One of the known SIP mechanisms is fragmentation during collisions among ice particles. It has been studied with our theoretical formulation, which has been applied in microphysical schemes of atmospheric models in a few studies. These have predicted an extensive impact on cloud glaciation and radiative properties. However, there has been a lack of experimental field studies, especially involving naturally falling snowflakes, to better understand this particular mechanism of SIP. This study reports the first field measurements with modern technology for fragmentation during collisions between naturally falling snowflakes and graupel/hail particles. This was observed with an innovatively designed portable chamber that was deployed outdoors in northern Sweden. Applying the observations from this field-based study, we optimized the existing formulation for predicting numbers of fragments from collisions of snow with graupel/hail. The observations show the average numbers of fragments per collision for dendritic (3–12 mm) and nondendritic (1–3 mm) snow were about 12 and 1, respectively. This represents a boost of predicted fragment numbers relative to our original formulation published in 2017. The updated formulation for breakup in ice–ice collisions can be implemented in the microphysical schemes of atmospheric models.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2018

The Use of Gridded Fossil Fuel CO2 Emissions (FFCO2) Inventory for Climate Mitigation Applications: Errors, Uncertainties, and Current and Future Challenges

Emission Inventory (EI) is a fundamental tool to monitor global compliance of greenhouse gases (GHGs) emissions reduction actions. Inventory guidelines provide a best practice to help EI compilers to make comparable national emission estimates, in spite of the differences in data availability across countries and regions. There are a variety of sources of errors and uncertainties, however, that originate beyond what the inventory guidelines define. For example, spatially-explicit EIs, which are a key product for atmospheric modeling applications, are often developed for research purposes, and there are no specific guidelines to disaggregate emission estimates from country scale. On top of that, EIs are fundamentally prone to systematic biases due to the simple calculation methodology and thus an objective evaluation (e.g. atmospheric top-down estimates) is needed to assure the accuracy of the estimates. ODIAC is a global high-resolution (1x1 km) fossil fuel carbon dioxide (CO2) gridded EI that is now often used in atmospheric CO2 modeling. ODIAC is based on disaggregation of national emission estimates made by CDIAC, which is the well accepted standard in the community. The ODIAC emission data product is updated on an annual basis using best available statistical data. Subnational spatial emission patterns are estimated using power plant profiles and satellite-observations of nighttime lights. In addition to the conventional CDIAC gridded data product, ODIAC carries international bunker emissions (shipping and aviation), which allows flux inversion modelers to accurately impose the global total fossil fuel emissions and their horizontal and vertical distribution. We have extensively evaluated ODIAC emissions using fine-grained EIs as well as a high-resolution atmospheric model simulation across different scales (national, subnational/regional, and urban policy relevant) with a focus on the uncertainties associated with the emission disaggregation. We have examined the use of NASA's Black Marble Suomi-NPP/VIIRS nightlight data.

Oda, Tomohiro↗
DOE OSTI2019

Background Conditions Influence the Estimated Cloud Radiative Effects of Anthropogenic Aerosol Emissions From Different Source Regions

Abstract Using the Community Earth System Model, with the Community Atmosphere Model version 5.3, we investigate the cloud radiative effects of anthropogenic aerosols emitted from different source regions and global shipping. We also analyze aerosol burdens, cloud condensation nuclei concentration, liquid water path, and ice water path. Due to transboundary transport and sublinearity in the response of clouds to aerosols, the cloud radiative effects of emissions from a given source region are influenced by emissions from other source regions. For example, the shortwave cloud radiative effect of shipping is −0.39 ± 0.03 W/m 2 when other anthropogenic emissions sources are present (the “present‐day background” assumption) compared with −0.60 ± 0.03 W/m 2 when other anthropogenic emissions sources are absent (the “natural background” assumption). In general, the cloud radiative effects are weaker if present‐day background conditions are assumed compared with if natural background conditions are assumed. Assumptions about background conditions should be carefully considered when investigating the climate impacts of aerosol emissions from a given source region.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1980

Orbit accuracy assessment for Seasat

Laser range measurements are used to determine the orbit of Seasat during the period from July 28, 1978, to Aug. 14, 1978, and the influence of the gravity field, atmospheric drag, and solar radiation pressure on the orbit accuracy is investigated. It is noted that for the orbits of three-day duration, little distinction can be made between the influence of different atmospheric models. It is found that the special Seasat gravity field PGS-S3 is most consistent with the data for three-day orbits, but an unmodeled systematic effect in radiation pressure is noted. For orbits of 18-day duration, little distinction can be made between the results derived from the PGS gravity fields. It is also found that the geomagnetic field is an influential factor in the atmospheric modeling during this time period. Seasat altimeter measurements are used to determine the accuracy of the altimeter measurement time tag and to evaluate the orbital accuracy.

Schutz, B. E.↗
NASA NTRS2005

The impact of ozone field horizontal inhomogeneities on nadir-viewing orbital backscatter UV measurements

Radiative transfer calculations for nadir-viewing satellites normally assume the atmosphere to be horizontally homogeneous. Yet it has been shown recently that horizontal gradients can lead to significant errors in satellite infrared and microwave soundings. We extend the methodology to backscatter ultra-violet observations of ozone, and present a first estimate of the effect s magnitude. The Solar Backscatter Ultra-Violet/2 (SBUV/2) instrument, a pure nadir sounder, serves as our test bed. Our results indicate that in a vast majority of cases the abovementioned errors can be neglected. However, occurrence of higher errors, particularly at wavelengths longer than 300 nm, coincides with some of the most interesting atmospheric phenomena like tropopause folds and the South polar ozone hole. This leads to a seasonal variation of the magnitude of the effect. Due to the mostly zonal geometry of the ozone distribution, there is also the possibility that biases may be introduced, which is particularly critical if the data are to be assimilated or used to determine trends. The results presented are tested for robustness using different model atmospheres. The influence of horizontal inhomogeneities will be even more pronounced for cross-track sounders and limb viewers, and easier to detect once higher resolution atmospheric models are available. This will be investigated in future studies.

Mueller, Martin D.↗