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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

A general circulation model study of the effects of faster rotation rate, enhanced CO2 concentration, and reduced solar forcing: Implications for the faint young sun paradox

Solar energy at the top of the atmosphere (solar constant), rotation rate, and carbon dioxide (CO2) may have varied significantly over Earth's history, especially during the earliest times. The sensitivity of a general circulation model to faster rotation, enhanced CO2 concentration, and reduced solar constant is presented. The control simulation of this study has a solar constant reduced by 10% the present amount, zero land fraction using a swamp ocean surface, CO2 concentrations of 330 ppmv, present-day rotation rate, and is integrated under mean diurnal and seasonal solar forcing. Four sensitivity test are performed under zero land fraction and reduced solar constant conditions by varying the earth's rotation rate atmospheric CO2 concentration and solar constant. The global mean sea surface temperatures (SSTs) compared to the control simulation: were 6.6 K to 12 K higher than the control's global mean temperature of 264.7 K. Sea ice is confined to higher latitudes in each experiment compared to the control, with ice-free areas equatorward of the subtropics. The warm SSTs are associated with a 20% reduction in clouds for the rotation rate experiments and higher CO2 concentrations in the other experiments. These results are in contrast to previous studies that have used energy balance and radiative convective models. Previous studies required a much larger atmospheric CO2 increase to prevent an ice-covered Earth. The results of the study, suggest that because of its possible feedback with clouds, the general circulation of the atmosphere should be taken into account in understanding the climate of early Earth. While higher CO2 concentrations are likely in view of the results, very large atmospheric CO2 concentrations may not be necessary to counterbalance the lower solar constant that existed early in Earth's history.

Jenkins, Gregory S.↗
NASA NTRS2015

Fe and O EELS Studies of Ion Irradiated Murchison CM2 Carbonaceous Chondrite Matrix

Introduction: The physical and chemical response of hydrated carbonaceous chondrite materials to space weathering processes is poorly understood. Improving this understanding is a key part of establishing how regoliths on primitive carbonaceous asteroids respond to space weathering processes, knowledge that supports future sample return missions (Hayabusa 2 and OSIRISREx) that are targeting objects of this type. We previously reported on He+ irradiation of Murchison matrix and showed that the irradiation resulted in amorphization of the matrix phyllosilicates, loss of OH, and surface vesiculation. Here, we report electron energy-loss spectroscopy (EELS) measurements of the irradiated material with emphasis on the Fe and O speciation. Sample and Methods: A polished thin section of the Murchison CM2 carbonaceous chondrite was irradiated with 4 kilovolts He(+) (normal incidence) to a total dose of 1 x 10(exp 18) He(+) per square centimeter. We extracted thin sections from both irradiated and unirradiated regions in matrix using focused ion beam (FIB) techniques with electron beam deposition for the protective carbon strap to minimize surface damage artifacts from the FIB milling. The FIB sections were analyzed using a JEOL 2500SE scanning and transmission electron microscope (STEM) equipped with a Gatan Tridiem imaging filter. EELS spectra were collected from 50 nanometer diameter regions with an energy resolution of 0.7 electronvolts FWHM at the zero loss. EELS spectra were collected at low electron doses to minimize possible artifacts from electron-beam irradiation damage. Results and Discussion: Fe L (sub 2,3) EELS spectra from matrix phyllosilicates in CM chondrites show mixed Fe(2+)/Fe(3+) oxidation states with Fe(3+)/Sigma Fe approximately 0.5. Fe L(sub 2,3) spectra from the irradiated/ amorphized matrix phyllosilicates show higher Fe(2+)/Fe(3+) ratios compared to spectra obtained from pristine material at depths beyond the implantation/amorphization layer. We also obtained O Ka spectra from phyllosilicates in both regions of the sample. The O Ka spectra show a pre-edge feature at approximately 530.5 electronvolts that is related to O 2p states hybridized with Fe 3d states. The intensity ratio of the O Ka pre-edge peak relative to the main part of the O Ka edge (that results from transitions of O 1s to 2p states) is lower in the irradiated layer compared to the pristine material and may reflect the loss of O (as OH) as was observed by IR spectroscopy. Conclusions: In addition to amorphization and OH loss, EELS spectra of He(+) irradiated matrix phyllosilicates in Murchison show that some of the Fe(3+) is reduced to Fe(2+). Spectral deconvolution is underway to extract quantitative ratios from the EELS spectra.

Keller, L. P.↗
NASA NTRS1973

Development of a laboratory prototype water quality monitoring system suitable for use in zero gravity

The development of a laboratory prototype water quality monitoring system for use in the evaluation of candidate water recovery systems and for study of techniques for measuring potability parameters is reported. Sensing techniques for monitoring of the most desirable parameters are reviewed in terms of their sensitivities and complexities, and their recommendations for sensing techniques are presented. Rationale for selection of those parameters to be monitored (pH, specific conductivity, Cr(+6), I2, total carbon, and bacteria) in a next generation water monitor is presented along with an estimate of flight system specifications. A master water monitor development schedule is included.

Misselhorn, J. E.↗
NASA NTRS2010

Depositing nanometer-sized particles of metals onto carbon allotropes

A process for depositing nanometer-sized metal particles onto a substrate in the absence of aqueous solvents, organic solvents, and reducing agents, and without any required pre-treatment of the substrate, includes preparing an admixture of a metal compound and a substrate by dry mixing a chosen amount of the metal compound with a chosen amount of the substrate; and supplying energy to the admixture in an amount sufficient to deposit zero valance metal particles onto the substrate. This process gives rise to a number of deposited metallic particle sizes which may be controlled. The compositions prepared by this process are used to produce polymer composites by combining them with readily available commodity and engineering plastics. The polymer composites are used as coatings, or they are used to fabricate articles, such as free-standing films, fibers, fabrics, foams, molded and laminated articles, tubes, adhesives, and fiber reinforced articles. These articles are well-suited for many applications requiring thermal conductivity, electrical conductivity, antibacterial activity, catalytic activity, and combinations thereof.

Watson, Kent A.↗
NASA NTRS1961

THERMAL DECOMPOSITION OF HYDRAZINE

The Thermal Stability of Hydrazine has been studied in the temperature and pressure intervals of 175" to 250"C. and 300 to 430 p.s.i., Respectively. Previous studies of the decomposition of hydrazine indicated that several factors affect its stability (2, 5, 7). the rate of decomposition is increased by the presence of certain surfaces (especially metals and salts). pH, oxygen, and carbon dioxide. Further explosive decomposition Is attributable to the uncontrolled heterogeneous, gas-phase decomposition. These factors were considered in selecting the following experimental conditions: highly purified hydrazine was prepared in a nitrogen atmosphere, and this product was decomposed over triply distilled mercury in outgassed borosilicate glass tubes at ullages that were initially zero. This study also included the effects of added quantities of ammonia on the rate of decomposition and an investigation of the products of the decomposition.

Harold W. Lucien↗
NASA NTRS1993

ASRM nozzle thermal analysis

This report describes results from the nozzle thermal analysis contract which has been performed to support NASA/Marshall Space Flight Center in the development of the Advanced Solid Rocket Motor (ASRM). The emphasis of this study has been directed to four potential problem areas of the nozzle. These areas are the submerged nozzle region containing the flex seal, the nozzle entrance region, the material interface region in the nozzle exit cone, and the aft region of the exit cone. This study was limited throughout by inadequate material response models, especially for the polyisoprene flex seal and the low density carbon phenolic used in the exit cone. Thermal response and particle erosion calculations were performed for each of the potential problem areas. Results from these studies showed excessive erosion (large negative safety margins) to occur in the flex seal and nozzle entrance regions. The exit cone was found to be marginally adequate (near zero safety margins) and the material interface region was found not to be a problem.

Strobel, Forrest↗
NASA NTRS1973

Correlation of heat transfer for the zero pressure gradient hypersonic laminar boundary layer for several gases

A theoretical study of heat transfer for zero pressure gradient hypersonic laminar boundary layers for various gases with particular application to the flows produced in an expansion tube facility was conducted. A correlation based on results obtained from solutions to the governing equations for five gases was formulated. Particular attention was directed toward the laminar boundary layer shock tube splitter plates in carbon dioxide flows generated by high speed shock waves. Computer analysis of the splitter plate boundary layer flow provided information that is useful in interpreting experimental data obtained in shock tube gas radiation studies.

Cook, W. J.↗
NASA NTRS1976

Sterols of a contemporary lacustrine sediment

Results are reported for detailed sterol analyses of several depths (corresponding to between zero and about 150 yr in age) in a contemporary lacustrine sediment from a freshwater lake of postglacial origin in England. Delta 5-, delta 22-, and delta 5,22-sterols are identified along with 5 alpha- and 5 beta-stanols as well as a C26 stanol with a C7 side chain. Solvent extraction yields carbon number distributions for the 5 alpha- and 5 beta-stanol sediment constituents that parallel the corresponding delta 5-sterol distributions. The amounts of 5 alpha-stanols are found to exceed those of 5 beta-stanols in the sediment, and variations in the ratio of 5 alpha- to 5 beta-stanol between sediment samples from similar depths are shown to suggest an inhomogeneity of the sediment. It is found that the sterol composition of sediment cores varies markedly with depth, reflecting both the effects of a sterol hydrogenation process and a changing input to the sediment. It is concluded that C29 sterols, of probable higher-plant origin, predominate at lower sediment depths while C27 sterols, possibly derived from autochthonous sources, are more abundant in the surface sediment.

Gaskell, S. J.↗
NASA NTRS1990

An atmospheric analysis of the carbon-rich white dwarf G35 - 26

The first detailed atmospheric analysis of the DQ white dwarf G35 - 26 is presented. The analysis is based on published spectra and on helium-rich, homogeneous, blanketed LTE models containing carbon, hydrogen, and small amounts of N, O, and Ca, and on the assumption that G35 - 26 is a single star. The observed spectra are fitted against the model spectra, and T(eff), log(g), and abundances of H, He, C are determined along with upper limits on N, O, and Ca. The mass and zero temperature Hamada-Salpeter (ZTHS) radius, distance, parallax, and tangential velocity are derived. The mass, 1.2-1.33 solar, is the highest yet observed for a single white dwarf if the star is on the ZTHS relation. O + Ne + Mg white dwarf in this mass range are predicted by theory and G35 - 26 may be the first such object discovered. Given an ZTHS radius, the distance is between 33 and 69 pc.

Thejll, Peter↗
NASA NTRS1996

The Size Distribution of Stardust Injected into the ISM

A multi-component method for the description of the evolution of the grain size distribution in consideration of a size dependent grain drift and growth rate is applied in order to model dust driven winds around cool C-stars. Grain drift introduces several modifications concerning dust growth: on one hand the residence time in the region of efficient growth is reduced, on the other hand the growth efficiency is higher due to an increased collisional rate. For carbon grains the surface density of radical sites is increased, but on the other hand there is a reduction of the sticking efficiency of the growth species for drift velocities larger than a few km/s. It is found that the consideration of drift results in a considerable distortion of the size distribution as compared to the case of zero drift velocity. Generally, there are less, but larger grains if drift is included.

Krueger, D.↗
NASA NTRS2006

Air/Oil Seals R and D at AlliedSignal

AlliedSignal aerospace company is committed to significantly improving the reliabilities of air/oil seals in their gas turbine engines. One motivation for this is that aircraft cabin air quality can be affected by the performance of mainshaft air/oil seals. In the recent past, coking related failure modes have been the focus of air/oil seal R&D at AlliedSignal. Many significant advances have been made to combat coke related failures, with some more work continuing in this area. This years R&D begins to address other commin failure modes. Among them, carbon seal "blistering" has been a chronic problem facing the sealing industry for many decades. AlliedSignal has launched an aggressive effort this year to solve this problem for our aerospace rated carbon seals in a short (one to two year) timeframe. Work also continues in developing more user-friendly tools and data for seal analysis & design. Innovations in seal cooling continue. Nominally non-contacting hydropad sealing concept is being developed for aerospace applications. Finally, proprietary work is in planning stages for development of a seal with the aggressive aim of zero oil leakage.

Ullah, M. Rifat↗
NASA NTRS2016

Computational and Experimental Study of Li-doped Ionic Liquids at Electrified Interfaces

We evaluate the influence of Li-salt doping on the dynamics, capacitance, and structure of three ionic liquid electrolytes, [pyr14][TFSI], [pyr13][FSI], and [EMIM][BF4], using molecular dynamics and polarizable force fields. In this respect, our focus is on the properties of the electric double layer (EDL) formed by the electrolytes at the electrode surface as a function of surface potential (Psi). The rates of EDL formation are found to be on the order of hundreds of picoseconds and only slightly influenced by the addition of Li-salt. The EDLs of three electrolytes are shown to have different energy storage capacities, which we relate to the EDL formation free energy. The differential capacitance obtained from our computations exhibits asymmetry about the potential of zero charge and is consistent with the camel-like profiles noted from mean field theories and experiments on metallic electrodes. The introduction of Li-salt reduces the noted asymmetry in the differential capacitance profile. Complementary experimental capacitance measurements have been made on our three electrolytes in their neat forms and with Li-salt. The measurements, performed on glassy carbon electrodes, produce U-like profiles, and Li-salt doping is shown to strongly affect capacitance at high magnitudes of Psi. Differences in the theoretical and experimental shapes and magnitudes of capacitance are rationalized in terms of the electrode surface and pseudocapacitive effects. In both neat and Li-doped liquids, the details of the computational capacitance profile are well described by Psi-induced changes in the density and molecular orientation of ions in the molecular layer closest to the electrode. Our results suggest that the addition of Li+ induces disorder in the EDL, which originates from the strong binding of anions to Li+. An in-depth analysis of the distribution of Li+ in the EDL reveals that it does not readily enter the molecular layer at the electrode surface, preferring instead to be localized farther away from the surface in the second molecular layer. This behavior is validated through an analysis of the free energy of Li+ solvation as a function of distance from the electrode. Free energy wells are found to coincide with localized concentrations of Li+, the depths of which increase with Psi and suggest a source of impedance for Li+ to reach the electrode.

Haskins, Justin B.↗
NASA NTRS1977

Spacecraft disinfectant/cleansing agent development

The sanitation agent container, which was selected in a trade off study, employs two chambers, a rigid outer container and an inner flexible bladder. The bladder contains the sanitation agent formulation and its release is controlled by a manually operated valve. The outer container holds a high pressure vapor. There is no void in the bladder which makes the package operation independent of orientation and therefore usable in zero gravity. Foam is developed by a low boiling point fluid or dissolved in the product. When the product is dispensed at atmospheric presure, the evolved gas or vapor whips up a goam in the valve. The sanitation agents were initially formulated with freons which produces an excellent foam. However freon is incompatible with the life support system and was replaced with carbon dioxide dissolved at high pressure. The CO2 system may limit high temperature exposure to prevent leakage or package distortion. The sanitation agents have been shown to be effective in cleaning soils from personnel and material.

Abbate, M.↗
NASA NTRS1984

An abrasion-ablation model description of galactic heavy-ion fragmentation

The fragmentation of high-energy galactic heavy ions by nuclear interactions with arbitrary target nuclei is described within the context of a simple abrasion-ablation fragmentation model. The abrasion part of the theory utilizes a quantum-mechanical formalism based upon an optical model potential approximation to the exact nucleus-nucleus multiple-scattering series. Nuclear charge distributions of the excited prefragments are calculated using either a hypergeometric distribution or a method based upon the zero-point oscillations of the giant dipole resonance. The excitation energy of the prefragment is estimated from the geometric clean-cut abrasion-ablation model. The decay probabilities for the various particle emission channels, in the ablation stage of the fragmentation, are obtained from the EVAP-4 Monte Carlo computer program. Elemental production cross sections for 1.88-GeV/nucleon iron colliding with carbon, silver, and lead targets are calculated and compared with experimental data and with the predictions from the semiempirical relations of Silberberg and Tsao.

Townsend, L. W.↗
NASA NTRS1999

Electro-mechanical Properties of Carbon Nanotubes: Effect of Small Tensile and Torsional Strains

We present a simple picture to calculate the bandgap ($E_g$) of carbon nanotubes (CNT) in the presence of uniform torsional and tensile strain ($\sigma$). We find that under tensile strain, $ absolute value of dE_g/d\sigma$ of zig-zag tubes is approximately equal to $3t_0$, where $t_0$ is the hopping parameter. Further, $ absolute value of dE_g/d\sigma$ decreases as the chirality changes to armchair, where it takes the value zero. The sign of $dE_g/d\sigma$ follows the $(N_x-N_y) *mod 3$(equal to - 1, 0 and +1) rule. In contrast to the above, we show that under torsional strain, $absolute value of dE_g/d\sigma$ of armchair tubes is approximately equal to $3t_0$ and continually decreases as the chirality changes to zig-zag, where is takes a small value. The sign of $dE_g/d\sigma$ again follows the $(N_x-N_y)*mod 3$ rule. Finally, we predict a change in the sign of $dE_g/d\sigma$ as function of strain, corresponding to a change in the value of $q$ that corresponds to the bandgap minimum.

Anantram, M. P.↗
NASA NTRS1986

Optical model calculations of heavy-ion target fragmentation

The fragmentation of target nuclei by relativistic protons and heavy ions is described within the context of a simple abrasion-ablation-final-state interaction model. Abrasion is described by a quantum mechanical formalism utilizing an optical model potential approximation. Nuclear charge distributions of the excited prefragments are calculated by both a hypergeometric distribution and a method based upon the zero-point oscillations of the giant dipole resonance. Excitation energies are estimated from the excess surface energy resulting from the abrasion process and the additional energy deposited by frictional spectator interactions of the abraded nucleons. The ablation probabilities are obtained from the EVA-3 computer program. Isotope production cross sections for the spallation of copper targets by relativistic protons and for the fragmenting of carbon targets by relativistic carbon, neon, and iron projectiles are calculated and compared with available experimental data.

Townsend, L. W.↗
NASA NTRS1980

Effect of tangential traction and roughness on crack initiation/propagation during rolling contact

Rolling fatigue tests of 0.45 percent carbon steel rollers were carried out using a four roller type rolling contact fatigue tester. Tangential traction and surface roughness of the harder mating rollers were varied and their effect was studied. The results indicate that the fatigue life decreases when fraction is applied in the same direction as that of rolling. When the direction of fraction is reversed, the life increases over that obtained with zero traction. The roughness of harder mating roller also has a marked influence on life. The smoother the mating roller, the longer the life. Microscopic observation of specimens revealed that the initiation of cracks during the early stages of life is more strongly influenced by the surface roughness, while the propagation of these cracks in the latter stages is affected mainly by the tangential traction.

Soda, N.↗
NASA NTRS2016

Modeling of Gaseous Oxygen Liquefaction Inside Mars Ascent Vehicle Propellant Tank

The In-Situ production of propellants for Mars missions has been considered to utilize the Carbon dioxide (CO2) in Mars atmosphere to produce Oxygen using a high temperature solid oxide electrolyzer. The oxygen then needs to be cooled, liquefied, and stored to be available for propulsion and other end users. The storage period could be up to two years either in the actual Mars ascent propulsion tanks or in a separate tank. Recent investigations have demonstrated the feasibility of both achieving zero-boil-off and controlling the pressure of oxygen within a tank using high efficiency cryocoolers. A representative configuration of tube on tank liquefaction using cryocooler is shown in Fig. 1.

Cryogenic fluids↗