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At least 127 records · Page 7

Robust H infinity control design for the space station with structured parameter uncertainty

A robust H-infinity control design methodology and its application to a Space Station attitude and momentum control problem are presented. This new approach incorporates nonlinear multi-parameter variations in the state-space formulation of H-infinity control theory. An application of this robust H-infinity control synthesis technique to the Space Station control problem yields a remarkable result in stability robustness with respect to the moments-of-inertia variation of about 73% in one of the structured uncertainty directions. The performance and stability of this new robust H-infinity controller for the Space Station are compared to those of other controllers designed using a standard linear-quadratic-regulator synthesis technique.

Byun, Kuk-Whan↗

Turbine Engine Stability/Instability With Rub Forces Axisymmetric Rotor-Support Stiffness

The stability/instability condition of a turbine rotor with axisymmetric supports is determined in the presence of gyroscopic loads and rub-induced destabilizing forces. A modal representation of the turbine engine is used, with one mode in each of the vertical and horizontal planes. The use of non-spinning rotor modes permits an explicit treatment of gyroscopic effects. The two linearized modal equations of motion of a rotor with axisymmetric supports are reduced to a single equation in a complex variable. The resulting eigenvalues yield explicit expressions at the stability boundary, for the whirl frequency as well as the required damping for stability in the presence of the available rub-induced destabilization. Conversely, the allowable destabilization in the presence of the available damping is also given.

Gallardo, Vicente↗

Turbomachinery Application of Lagrangian Dynamics to the Motion of Continuous Discrete Rotors

The stability/instability condition of a turbine rotor with axisymmetric supports is determined in the presence of gyroscopic loads and rub-induced destabilizing forces. A modal representation of the turbine engine is used, with one mode in each of the vertical and horizontal planes. The use of non-spinning rotor modes permits an explicit treatment of gyroscopic effects. The two linearized modal equations of motion of a rotor with axisymmetric supports are reduced to a single equation in a complex variable. The resulting eigenvalues yield explicit expressions at the stability boundary, for the whirl frequency as well as the required damping in the presence of the available rub-induced destabilization. Conversely, the allowable destabilization in the presence of the available damping is also given.

Source record↗

Perfluoroalkylene-Ether Triazine Elastomers

New process yields product that resists heat and action of oxygen and water. Ring closing step, which gives elastomer its stability, imidoylamidine dinitrile reacts with perfluoroether acide, yielding prepolymer. Prepolymer then treated with ammonia and cured by heating to form polymer. Elastomers are highly resistant to heat, oxidation, and hydrolysis.

Rosser, R. W.↗

Adaptive quadrilateral and triangular finite-element scheme for compressible flows

The development of an adaptive mesh refinement procedure for analyzing high-speed compressible flows using the finite-element method is described. This new adaptation procedure, which uses both quadrilateral and triangular elements, was implemented with two explicit finite-element algorithms - the two-step Taylor-Galerkin and the multistep Galerkin-Runge-Kutta schemes. A von Neumann stability analysis and a rotating 'cosine hill'problem demonstrate the instability of the Taylor-Galerkin scheme when coupled with the adaptation procedure. For the same adaptive refinement scheme, the Galerkin-Runge-Kutta procedure yields stable solutions within its explicit stability limit. The utility of this new adaptation procedure for the prediction of compressible flow features is illustrated for inviscid problems involving strong shock interactions at hypersonic speeds.

Ramakrishnan, R.↗

Synthesis and stability of Br2, ICl and IBr intercalated pitch-based graphite fibers

The intercalation of halogens in pitch-based fiber is studied as well as the stability of the resultant intercalation compounds. It is found that IBr intercalates P-100 to yield a high-sigma GIC with attractive stability properties. During ICl intercalation, the presence of O2 interferes with the reaction and necessitates a higher threshold pressure for intercalation.

Wessbecher, Dorothy E.↗

Polarization-stabilized 1.15- and 3.39-micron He-Ne lasers

Two methods for polarization stabilization of an internal-mirror 3.39-micron He-Ne laser are reported. The first relies on a concurrently lasing 1.15-micron transition by fixing the relative amplitude of two orthogonally polarized longitudinal modes that are split by a Rochon prism and detected with separate Si photodiodes. In the second method, two spatially separated orthogonally polarized adjacent 3.39-micron modes are optically balanced, differentially chopped, and recombined on a single InSb photodiode for phase-sensitive detection. The dual-wavelength scheme has been tested by beating against a methane-stabilized 3.39-micron He-Ne laser, which yields maximum excursions of less than 0.5 MHz over several hours and comparable reproducibility. The polarization-stabilized He-Ne laser has been used as a reference for a tunable color-center laser molecular-beam optothermal spectrometer and provides a precision of better than 2 MHz.

Junttila, M.-L.↗

Photo-Reactive Amine-Based Direct Air Capture and Conversion of CO2

This study presents a novel photochemical approach to direct air capture (DAC) and CO2 conversion, utilizing a ruthenium-modified mesoporous TiO2 composite infused with linear polyethyleneimine (L-PEI) and enhanced by light absorbing and earth abundant titanium nitride (TiN). This light-activated system operates at ambient pressure and addresses long-standing challenges in conventional amine-based thermal reactive carbon capture (RCC), including amine degradation and CO2 slip. Our findings demonstrate that L-PEI effectively stabilizes CO2 adsorption and facilitates high-yield methanation over 50 cycles with a non-flammable forming gas mixture (approximately 5% H2). Comparatively, composites incorporating small-molecule amines exhibited poor stability under illumination, while highly mobilie branched PEI (B-PEI) formulations suffered from significant catalyst deactivation. A technoeconomic analysis suggests that methane synthesis via this platform could be achieved at costs below $5/kg under current electrocatalytic hydrogen pricing. These findings highlight the potential of this approach to enhance energy security by enabling decentralized, scalable fuel production from atmospheric CO2.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Stability correction functions for the mean wind speed and temperature in the unstable surface layer

In accordance with a theoretical analysis by Kader and Yaglom, interpolation expressions are proposed for the Monin-Obukhov functions for the wind speed and temperature profiles under unstable conditions in the surface layer of the atmospheric boundary layer. The values of the parameters are adjusted to agree with earlier work under weak instability, as reviewed by Hogstrom. The resulting formulations are valid for considerably larger values of their argument than those that were hitherto available. Their advantage is that they yield concise and closed-form stability correction functions which can be readily applied in profile analysis and model calculations.

Brutsaert, Wilfried↗

Evaluation of constraint stabilization procedures for multibody dynamical systems

Comparative numerical studies of four constraint treatment techniques for the simulation of general multibody dynamic systems are presented, and results are presented for the example of a classical crank mechanism and for a simplified version of the seven-link manipulator deployment problem. The staggered stabilization technique (Park, 1986) is found to yield improved accuracy and robustness over Baumgarte's (1972) technique, the singular decomposition technique (Walton and Steeves, 1969), and the penalty technique (Lotstedt, 1979). Furthermore, the staggered stabilization technique offers software modularity, and the only data each solution module needs to exchange with the other is a set of vectors plus a common module to generate the gradient matrix of the constraints, B.

Park, K. C.↗

Thermocapillary convection instability in microgravity crystal growth

Energy and linear stability theories are applied to study the stability properties of thermocapillary convection in a half zone model of the float zone crystal growth process. The analyses yield results which provide sufficient conditions for both stability and instability, respectively, and therefore, lower and upper bounds for the Marangoni numbers at which oscillatory thermocapillary convection will appear. The results of the analyses are compared with available experimental and numerical data.

Neitzel, G. P.↗

On the consistency of Reynolds stress turbulence closures with hydrodynamic stability theory

The consistency of second-order closure models with results from hydrodynamic stability theory is analyzed for the simplified case of homogeneous turbulence. In a recent study, Speziale, Gatski, and MacGiolla Mhuiris showed that second-order closures are capable of yielding results that are consistent with hydrodynamic stability theory for the case of homogeneous shear flow in a rotating frame. It is demonstrated in this paper that this success is due to the fact that the stability boundaries for rotating homogeneous shear flow are not dependent on the details of the spatial structure of the disturbances. For those instances where they are -- such as in the case of elliptical flows where the instability mechanism is more subtle -- the results are not so favorable. The origins and extent of this modeling problem are examined in detail along with a possible resolution based on rapid distortion theory (RDT) and its implications for turbulence modeling.

Speziale, Charles G.↗

Engineered IL-18 variants with half-life extension and improved stability for cancer immunotherapy

Background The pro-inflammatory cytokine, interleukin-18 (IL-18), plays an instrumental role in bolstering anti-tumor immunity. However, the therapeutic application of IL-18 has been limited due to its susceptibility to neutralization by IL-18 binding protein (IL-18BP), short in vivo half-life, and unfavorable physicochemical properties. Methods In order to overcome the poor drug-like properties of IL-18, we installed an artificial disulfide bond, removed the native, unpaired cysteines, and fused the stabilized cytokine to an IgG Fc domain. The stability, potency, pharmacokinetic and pharmacodynamic properties as well as efficacy of disulfide-stabilized IL-18 Fc-fusion (dsIL-18-Fc) were assessed via in vitro and in vivo studies. Results The stability and mammalian host cell production yields of dsIL-18-Fc were improved, compared to the wild-type (WT) cytokine, while maintaining its biological potency and interactions with IL-18 receptor α (IL-18Rα) and IL-18BP. Recombinant fusion of the cytokine to an IgG Fc domain provided extended half-life. Notably, despite maintaining sensitivity to IL-18BP, dsIL-18-Fc was effective at activating both T and natural killer (NK) cells, and elicited a strong anti-tumor response, either as a single agent, or in conjunction with anti-programmed cell death-ligand 1 (anti-PD-L1) therapy. Conclusions We engineered IL-18 for reinforced stability, extended half-life, and improved manufacturability. The therapeutic benefit of dsIL-18-Fc, coupled with a more favorable manufacturability profile and enhanced drug-like properties, underscores the potential utility of this engineered cytokine in cancer immunotherapy.

Immunology↗

Achieving ultrahigh modulus of resilience and enhanced thermal stability in ZnO x /SU-8 interpenetrating network polymer nanocomposite nanopillars

The modulus of resilience, a mechanical property that quantifies the maximum strain energy density a material can store during elastic deformation, is a crucial parameter for materials used in flexible displays, micro/nano-electro-mechanical system (M/NEMS) actuators, and ultra-sensitive pressure sensors. In this study, ZnO x /SU-8 nanocomposite nanopillars with a diameter of 300 nm, fully infiltrated with a uniformly distributed, interpenetrating amorphous ZnO x filler network, were synthesized via vapor-phase infiltration (VPI). In-situ uniaxial nano-compression tests revealed that the modulus of resilience of ZnO x /SU-8 reaches ∼ 12 MJ/m 3 , which is an ultrahigh value among all engineering materials with comparable strength. In addition, the synthesis fidelity, inorganic infiltration depth, and mechanical performance were all significantly improved compared to VPI-synthesized AlO x nanocomposites. Thermal stability, another key requirement for M/NEMS device materials operating under extreme environments, was also notably enhanced. Furthermore, partial crystallization of the amorphous ZnO x fillers during annealing contributed to an additional increase in modulus of resilience, reaching up to ∼ 13.9 MJ/m 3 . This work presents an effective fabrication strategy for producing nanostructured organic–inorganic hybrid nanocomposites with ultrahigh modulus of resilience and superior thermal stability, paving the way for their integration into next-generation flexible displays and high-performance M/NEMS devices working under harsh environments.

36 MATERIALS SCIENCE↗

MHD modeling of magnetotail instability for anisotropic pressure

Results of three-dimensional MHD simulations of magnetotail dynamics with anisotropic pressure are presented. The pressure tensor is assumed to be gyrotropic, satisfying a modified double adiabatic approximation including Ohmic heating. It is found that these constraints tend to stabilize the tail with respect to the resistive tearing instability. Including an increasing level of additional isotropization results in a gradual transition to the fast instability found in an isotropic model, which is discussed for comparison. Possible isotropization mechanisms yielding magnetotail instability are discussed also. The stabilizing anisotropies are found primarily in the plasma sheet boundary region. This fact indicates a possibly important role of isotropization mechanisms operating in this region in destabilizing the magnetotail and initiating a tearing instability without the necessity of changes in fluctuation levels in the neutral sheet.

Hesse, Michael↗

Solvent effects on triplet yields in BODIPY-based photosensitizers

Here, we employ molecular dynamics simulations and quantum rate theories to elucidate the complex condensed-phase dynamics underpinning triplet-state formation in organic photosensitizers. Using models informed by first-principles calculations complete with a molecular representation of solvents of different polarities, we elucidate the interplay of the internal and environmental interactions underlying triplet yield. We find that triplet yields depend sensitively on the dielectric stabilization of the charge transfer intermediate that facilitates a transition into the triplet manifold. Our results illustrate the importance of molecularly detailed models in understanding the excited-state internal charge-transfer dynamics of photochemically relevant organic molecules.

Coello Escalante, Leonardo [University of Californ↗

Cooling Matters: Benchmarking Large Language Models and Vision-Language Models on Liquid-Cooled Versus Air-Cooled H100 GPU Systems

The unprecedented growth in artificial intelligence (AI) workloads, recently dominated by large language models (LLMs) and vision-language models (VLMs), has intensified power and cooling demands in data centers. This study benchmarks LLMs and VLMs on two HGX nodes, each with 8× NVIDIA H100 graphics processing units (GPUs), using liquid and air cooling. Leveraging GPU Burn, Weights & Biases, and IPMItool, we collect detailed thermal, power, and computation data. Results show that the liquid-cooled systems maintain GPU temperatures between 41-50$^\circ$C, while the air-cooled counterparts fluctuate between 54-72$^\circ$C under load. This thermal stability of liquid-cooled systems yields 17% higher performance (54 TFLOPs/ GPU vs. 46 TFLOPs/GPU), performance-per-watt, reduced energy overhead, and greater system efficiency than the air-cooled counterparts. These findings underscore the energy and sustainability benefits of liquid cooling, offering a compelling path forward for hyperscale data centers seeking to optimize AI infrastructure. https://github.com/iscaas/Cooling-Matters.

Latif, Imran↗