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At least 127 records · Page 7

PRP: The Proven Solution for Cleaning Up Oil Spills

The basic technology behind PRP is thousands of microcapsules, tiny balls of beeswax with hollow centers. Water cannot penetrate the microcapsule s cell, but oil is absorbed right into the beeswax spheres as they float on the water s surface. This way, the contaminants, chemical compounds that originally come from crude oil such as fuels, motor oils, or petroleum hydrocarbons, are caught before they settle. PRP works well as a loose powder for cleaning up contaminants in lakes and other ecologically fragile areas. The powder can be spread over a contaminated body of water or soil, and it will absorb contaminants, contain them in isolation, and dispose of them safely. In water, it is important that PRP floats and keeps the oil on the surface, because, even if oil exposure is not immediately lethal, it can cause long-term harm if allowed to settle. Bottom-dwelling fish exposed to compounds released after oil spills may develop liver disease, in addition to reproductive and growth problems. This use of PRP is especially effective for environmental cleanup in sensitive areas like coral reefs and mangroves.

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The hydrogen economy can reduce costs of climate change mitigation by up to 22%

In response to the urgent need to mitigate climate change via net-zero targets, many nations are renewing their interest in clean hydrogen as a net-zero energy carrier. Although clean hydrogen can be directly used in various sectors for deep decarbonization, the relatively low energy density and high production costs have raised doubts as to whether clean hydrogen development is worthwhile. Here, we improve on the GCAM model by including a more comprehensive and detailed representation of clean hydrogen production, distribution, and demand in all sectors of the global economy and simulate 25 scenarios to explore the cost-effectiveness of integrating clean hydrogen into the global energy system. We show that, due to costly technical obstacles, clean hydrogen can only provide 3%–9% of the 2050 global final energy use. Nevertheless, clean hydrogen deployment can reduce overall energy decarbonization costs by 15%–22%, mainly via powering “hard-to-electrify” sectors that would otherwise face high decarbonization expenditures. Our work provides practical references for cost-effective clean hydrogen planning.

08 HYDROGEN↗

Oxygen Systems Cleaners for Aerospace Applications

New environmental regulations have forced extensive evaluations of many different cleaning agents for use in oxygen systems. This is no simple process because pure oxygen is a very strong oxidizer, and when placed in contact with a foreign substance, the combination may be explosive. This foreign substance can easily be a cleaning agent residue left over in the oxygen system after cleaning. This paper focuses on the factors that must be considered when selecting a cleaning agent for oxygen systems, as well as the approval processes which are currently being utilized by NASA for oxygen compatibility of materials. This paper will provide a working description of how to begin selecting a cleaning agent for oxygen systems. The paper will present the following: Background information on the necessity of a stringent selection process for oxygen system cleaners; Specifications and regulations concerning cleaning for oxygen service; Changing oxygen cleaning specifications given current environmental concerns; Testing for cleanliness in oxygen systems, Cleaning agents that have been tested for oxygen systems, including an extensive list of some of the newer 'environmentally friendly' cleaning agents; and Test results and conclusions from the testing. The paper will also provide instructions on the proper procedures for obtaining NASA approval on a candidate oxygen systems cleaning agent.

Davis, Samuel E.↗

Curation and Analysis of Samples from Comet Wild-2 Returned by NASA's Stardust Mission

The NASA Stardust mission returned the first direct samples of a cometary coma from comet 81P/Wild‐2 in 2006. Intact capture of samples encountered at 6 km/s was enabled by the use of aerogel, an ultralow dense silica polymer. Approximately 1000 particles were captured, with micron and submicron materials distributed along ~mm scale length tracks. This sample collection method and the fine scale of the samples posed new challenges to the curation and cosmochemistry communities. Sample curation involved extensive, detailed photo‐documentation and delicate micro‐surgery to remove particles without loss from the aerogel tracks. This work had to be performed in highly clean facility to minimize the potential of contamination. JSC Curation provided samples ranging from entire tracks to micrometer‐sized particles to external investigators. From the analysis perspective, distinguishing cometary materials from aerogel and identifying the potential alteration from the capture process were essential. Here, transmission electron microscopy (TEM) proved to be the key technique that would make this possible. Based on TEM work by ourselves and others, a variety of surprising findings were reported, such as the observation of high temperature phases resembling those found in meteorites, rarely intact presolar grains and scarce organic grains and submicrometer silicates. An important lesson from this experience is that curation and analysis teams must work closely together to understand the requirements and challenges of each task. The Stardust Mission also has laid important foundation to future sample returns including OSIRIS‐REx and Hayabusa II and future cometary nucleus sample return missions.

Nakamura-Messenger, Keiko↗

Integration of Clean Energy into Oil Field Operations

Integrating clean energy into oil and gas operations could reduce emissions and maximize higher-value use of produced hydrocarbons. In this published study, analysts from the Joint Institute for Strategic Energy Analysis (JISEA) and the National Renewable Energy Laboratory (NREL) evaluated clean power technologies for an oil field in the Delaware Basin using NREL’s Renewable Energy Integration and Optimization, or REopt, tool. The analysts evaluated different configurations of distributed energy resources based on the technologies available and the load they could satisfy, available land, and hypothetical carbon pricing. The analysis is part of a collaborative program with industry to understand site-specific energy consumption and prices in the oil and gas supply chain and determine under what conditions clean energy options are economically attractive. This work was sponsored by a consortium including ConocoPhillips, Baker Hughes, Extraction Oil & Gas, Kinder Morgan, and the Interstate Natural Gas Association of America Foundation.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Demonstrating Advanced Nuclear Energy Solutions for Net Zero

Background/Objectives. The aggressive goals being set by nation states, communities, and private industry for decarbonization of grid electricity, industrial heat sources, and transportation around the world are imperative to mitigating the devastating effects that we are seeing from climate change. Although many of these goals focus on accomplishments by 2035 or 2050, the decisions that we make today won’t just impact the landscape of energy systems for the next 20 or 30 years—they will shape the world’s environment for centuries to come. That means that we can’t just focus on technologies that will get us to 2050, but technologies that will withstand our energy demands over that long-ranging future. Success will require us to utilize all of the clean energy resources that we have available to meet demands for electricity, heat, and steam, and we will need energy carriers such as hydrogen that do not emit additional greenhouse gases at the point of use. Nuclear energy, ranging from technologies in service today to advanced, higher temperature and modular systems that will be in service this decade, will provide a robust complement to renewable energy resources that operate variably. Researchers across the U.S. Department of Energy laboratory complex are working to advance multiple aspects of these clean energy solutions, with many focusing on integrated energy system solutions that leverage all available clean energy assets to meet wide-ranging energy demands. Approach/Activities. Nuclear energy is a proven, zero-emission option during operation that can provide consistent, dispatchable power to meet electricity demands while also providing high-quality heat that can meet energy demands beyond the electricity sector. Energy system design should seek to maximize these assets. As a dispatchable energy source with a small land utilization footprint, nuclear energy can be collocated with renewable resources, and the smaller systems that will be deployed this decade (ranging from a few megawatts to hundreds of megawatts) can be installed right where that energy is needed. Integrated nuclear and renewable systems will enhance power grid reliability and resilience, and they will help stabilize the grid through their increasingly flexible operation. Licensing, installation, and broad adoption of these advanced nuclear energy systems are expected to progress significantly in the 2020s, but this may be longer than desired by some stakeholders wishing to implement impactful clean energy decisions today. However, one must recall that nuclear energy systems will operate for 80 or more years, as is being demonstrated by current fleet nuclear systems. The nuclear community is extremely thorough in reviewing these systems with regard to safety and security; these efforts ensure that the deployed systems will continue to provide reliable, resilient energy over that operational lifetime. That investment of time up front will ensure that we can support energy demands over the centuries to come. While advanced nuclear technologies move through this process, communities and private industry may choose to install renewable generation systems that can later be coupled to the complementary nuclear systems as they become available—thus moving closer to the net zero goals in the near term. Choosing technologies and deployment configurations that allow small modular nuclear powerhouses to be added to these “energy parks” as they become available will ensure that advanced technologies can be readily adopted to support growing demands for clean energy. Results/Lessons Learned. The primary focus of integrated energy systems (IES) research is to assess the technical and economic potential of novel multi-input, multioutput solutions that are expected to enhance energy system flexibility, reliability, and resilience as we pursue a clean energy transition. Various energy applications and product streams beyond electricity are being evaluated, ranging from generation of potable water to production of hydrogen, fertilizers, synthetic fuels, and various chemicals. In early FY23 Idaho National Laboratory (INL) will commission thermal energy generation systems that emulate nuclear fission energy input using electric heating and will allow for integrated system testing with thermal energy storage, hydrogen production via high temperature electrolysis (HTE), and power systems hardware to demonstrate operation of a clean energy park within a microgrid or larger grid infrastructure, supporting up to 450 kW of heat input via electric heating and demonstrating operation of HTE systems at the multi-hundred kW scale. This presentation will highlight the wide array of RD&D being conducted at INL and partner laboratories to develop and deploy nuclear and renewable-based IES that will be key to achieving our net zero goals, including both computational and experimental demonstrations. By working with key collaborators in industry, analytical st

08 HYDROGEN↗

Monolayer organic thin films as particle-contamination–resistant coatings

Abstract Three organic monolayers coatings were developed and tested for their effectiveness to increase cleaning efficiency of attached microscale particles by air flows. The experiments were performed using silica substrates coated with these organic thin films and subsequently exposed to stainless-steel and silica microparticles as a model of contamination. Laser-induced–damage tests confirmed that the coatings do not affect the laser-induced–damage threshold values. The particle exposure results suggest that although the accumulation of particles is not significantly affected under the experimental conditions used in this work, the coated substrates exhibit significantly improved cleaning efficiency with a gas flow. A size-distribution analysis was conducted to study the adsorption and cleaning efficiency of particles of different sizes. It was observed that larger size (> 5-μm) particles can be removed from coated substrates with almost 100% efficiency. It was also determined that the coatings improve the cleaning efficiency of the smaller particles (≤ 5 μm) by 17% to 30% for the stainless steel metal and 19% to 38% for the silica particles.

36 MATERIALS SCIENCE↗

Clean Energy Integration in Natural Gas Compressor Station Operations

Integrating renewable energy into oil and gas operations could reduce emissions and maximize higher-value use of produced hydrocarbons. In this study, analysts from the Joint Institute for Strategic Energy Analysis (JISEA) and the National Renewable Energy Laboratory (NREL) evaluated clean power technologies for a natural gas compressor station in Texas, using NREL’s REopt tool. Different configurations of distributed energy resources were evaluated based on the technologies available and the load they can satisfy, available land, and hypothetical carbon pricing. The analysis is part of a collaborative program with industry to understand site-specific energy consumption and prices in the oil and gas supply chain and determine under what conditions clean energy options are economically attractive. This work was sponsored by a consortium including Kinder Morgan, Interstate Natural Gas Association of America Foundation, Extraction Oil & Gas, Baker Hughes, and ConocoPhillips.

03 NATURAL GAS↗

Inventory of Clean Energy Education and Workforce Development Programs in Allegheny County, PA

Building on other analysis work completed through the Communities LEAP pilot, this document is intended to provide an overview of: 1) what clean energy and related education and workforce development (EWD) resources already exist in and around the Hill District, 2) gaps in EWD resources, and 3) opportunities to expand clean energy education, training, and job opportunities for Hill District residents.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Catastrophic Impact of Silicon on Silicon: Unraveling the Genesis Impact Using Sample 61881

The Genesis mission collected solar wind and brought it back to Earth in order to provide precise knowledge of solar isotopic and elemental compositions. The ions in the solar wind were stopped in the collectors at depths on the order of 10 to a few hundred nanometers. This shallow implantation layer is critical for scientific analysis of the composition of the solar wind and must be preserved throughout sample handling, cleaning, processing, distribution, preparation and analysis. The current work is motivated by the need to understand the interaction of the Genesis payload with contamination during the crash in the Utah desert. Silicon contamination has been found to be notoriously difficult to remove from silicon samples despite multiple cleanings with multiple techniques. However, the question has been posed, "Does the silicon really need to be removed for large area analyses?." If the recalcitrant silicon contamination is all pure silicon from fractured collectors, only a very tiny fraction of that bulk material will contain solar wind, which could skew the analyses. This could be complicated if the silicon trapped other materials and/or gases as it impacted the surface.

Kuhlman, K. R.↗

New Mobility Technology Assessment - Benefits, Risks, and Safety

The age of vehicle automation is upon us. The fundamental perception and control technology is maturing as we speak (and write) with robo-taxis proliferating in select US cities. The news cycle is no longer filled with technological skepticism, but rather societal commentary on our collective response and use of the technology. This maturing of the technology is also accompanied by a renaissance in new types of urban movement technology to more effectively link people with goods, services, and employment, particularly in dense development areas where vehicle congestion (even automated vehicles) prevents high quality mobility. The National Renewable Energy Laboratory, through the DOE Clean Energy to Communities (C2C) program has worked with two jurisdictions to assess the benefits, risks, and safety concerns for a new product offering based on suspended cable technology which is fully automated and proposes an aerial network of self-propelled gondolas. The recognized need, independent of the technology, is to fairly assess the benefits of the proposed transportation system, assess its technical maturity, as well as risks and safety concerns. Using this new technology as an example, a technology represented by Swyft Cities, NREL developed a succession of mini-studies that characterized the technical maturity level, assessed the proposed benefits for Greenville, SC, examined the risks involved in moving forward with an emerging mobility technology, and determined the governing safety protocols and standards that are applicable to the space. These mini-case studies, though centered on Swyft Cities aerial automated gondola technology, are highly transferable to any type of new mobility technology and lays out a repeatable process for assessing new technology within an city or community context.

33 ADVANCED PROPULSION SYSTEMS↗

A Fair and Equitable Clean Energy Transition in Alachua County

Alachua County, Florida is committed to transitioning to renewable energy in order to address the climate crisis and secure energy justice for low-income and underserved communities. Alachua County's community-led Project EMPOWER (Energy Modernization for People, Opportunity, Work, Equity, and Renewables) is focused on making the clean energy transition fair and equitable for everyone, and is partnering with the U.S. Department of Energy's Communities LEAP (Local Energy Action Program) Pilot.

Alachua County↗

Panel Session 120: Roundtable: Waste Management - Energy Facilities Contractor Operating Group (EFCOG WM)

This Roundtable focused on the WM EFCOG working group as they met to discuss a variety of issues of importance to US DOE waste management operations. The purpose of the WM EFCOG is to seek out and promote the best management and operating practices, cost effective technologies and disposal options for all waste streams generated at US DOE facilities whether destined for US DOE or commercial facilities. Each site representative provided a radioactive waste management lessons learned briefing. Panelists with presentations: Savannah River Site (SRS) Solid Waste Program Update (Kerri Crawford); Idaho Clean-up Project Status (Frederick Hughes); West Valley Demonstration Project Update - EFCOG Waste Management Working Group (John Rendall); Key Project Challenges and Successes (Kalli Shupe); EFCOG WMWG Challenging Waste Subgroup Update (Tammy Monday); CH TRU Difficult Waste Stream Processing Challenges (Daniel Pancake); Argonne Building 350 Clean-up Success Using Effective Work Control (Daniel Dilday); Problematic Waste Streams on the Oak Ridge Reservation (John Wrapp)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Dispersion strengthened nickel-yttria sheet alloy produced from comminuted powders

An investigation was conducted to determine whether a nickel matrix with yttria as a dispersoid could be produced by a comminution and blending (wet attrition-NASCAB) approach. Concentration of yttria, powder cleaning temperature, screening (sieving) of the powders, and amount of thermomechanical working were major variables. Tensile strength and stress-rupture life at 1093 C were determined. A product containing 4v/o Y2O3, cleaned at 315 or 371 C with screening exhibited 1093 C tensile strength equivalent to NASCAB Ni-4ThO2 and to commercially produced thoriated nickel sheet.

Sikora, P. F.↗

Management of Alkali and Alkaline Earth Fission Products in Used Pyroprocessing Salt

Pyroprocessing of spent nuclear fuel (SNF) involves dissolving metallic fuel into a molten salt electrolyte (typically eutectic LiCl-KCl) and then preferentially depositing actinides onto inert cathodes. Subsequent operations include drawdown of residual actinides and lanthanides from the electrolyte prior to re-using the salt. The recovered actinides are recycled and the recovered lanthanides are disposed as waste. Alkali and alkaline earth metal fission products in the fuel, such as Cs, Sr and Ba, dissolve into the salt during electrorefining. The concentrations of these elements buildup over time in the molten salt electrolyte, which may change the freezing point. The radioactive decay of 137 Cs and 90 Sr (half life 30 and 29 years) generates significant heat and produces strong ionizing radiation fields (β and γ). The increasing heat load and radioactivity as these elements build up in the molten salt requires frequent replacement and disposal of the electrolyte salt. Alternatively, the salt can be treated to remove these and other elements and then recycled to the electrorefiner. An effective strategy to manage these alkali and alkaline earth metal fission products in the molten salt electrolyte would increase the efficiency of pyroprocessing and decrease the volume of salt waste requiring disposal. Alkali and alkaline earth metal fission products are extremely stable in molten salt as chlorides--even more stable than the LiCl-KCl eutectic base salt--making them challenging to remove. They are not removed during drawdown operations to recover residual actinides and lanthanides and a separate operation is required to sufficiently purify the salt for reuse. This work is focused on selecting a method for separating Cs, Sr and Ba from the salt recovered from the lanthanide drawdown operation prior to recycling the cleaned salt back to the electrorefiner. Not addressed in this work is the management of the waste stream produced by the separation. This report summarizes the issues to be addressed when developing removal strategies for cesium, strontium, and barium and reviews existing methods to identify suitable methods and any technological gaps in their application.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Precision Cleaning of Oxygen Systems and Components

Currently, NASA uses Dichloropentafluoropropane (HCFC-225), a Class II ozone depleting substance (ODs), to clean contaminated oxygen systems. Starting in 20 15, the Montreal Protocols and Clean Air Act prohibit the production and importation of all hydrochlorofluorocarbons (HCFC), except for limited use in refrigeration applications. Thus, a new non-ozone depleting solvent needs to be developed for use in cleaning. Optimally, such a solvent should also be environmentally benign or green to avoid needing to replace the new solvent with yet another solvent in the future due to other environmental concerns. Work for the first year consisted of two parts. The first part was developing a method of testing the cleaning efficiency of potential solvents. Stainless steel coupons were contaminated with a known weight of various contaminants and contaminant combinations and then immersed in solvent for ten minutes. The coupons were then removed and dried in an oven until all solvent had evaporated. Once dry, the coupons were weighed and the mass of the non-volatile residue (NVR) left on the coupon was determined. The cleaning efficiency of the solvents is reported as percent cleaning, with 100% cleaning being zero NVR left on the test coupon. The second half of the first goal was to use the develop method to perform baseline testing on current solvents. The second part of the work was to begin exploring alternative cleaning solvents. A variety of hydrofluorocarbons (HFCs) were tested. Preliminary testing was also performed with ionic liquids and aqueous surfactant solutions. Once potential solvents were identified, an analysis of the performance and environmental characteristics of each was to be conducted. Four contaminants were specified for use in testing. These are Mil-Spec-H-5606 (5606), a hydraulic fluid, Mil-H-83282B (83282), another hydraulic fluid, diethylhexyl sebacate (Sebacate), and WD-40. The structures of these contaminants are all similar, with long aliphatic hydrocarbon chains of lengths between fifteen and fifty. Contaminants were tested both individually and in combination. All combinations were done with equal weights of the constituent contaminants.

McLaughlin, Russell↗

Clean Water for Remote Locations

Marshall Space Flight Center engineers are working on creating the Regenerative Environmental Control and Life Support System, a complex system of devices intended to sustain the astronauts living on the ISS and, in the future, sustain those who are blasting off to the Moon or Mars. The devices make use of the available resources, by turning wastewater from respiration, sweat, and urine into drinkable water. One of the devices that Marshall has been working on is the Water Recovery System (WRS). Marshall has teamed with long-time NASA contractor, Hamilton Sundstrand Space Systems International, Inc., of Windsor Locks, Connecticut. Hamilton Sundstrand, the original designer of the life support devices for the space suits, developed the Water Processor Assembly (WPA). It, along with the Urine Processor Assembly (UPA) developed by Marshall, combines to make up the total system, which is about the size of two refrigerators, and will support up to a six-member crew. The system is currently undergoing final testing and verification. "The Water Processor Assembly can produce up to about 28 gallons of potable recycled water each day," said Bob Bagdigian, Marshall Regenerative Environmental Control and Life Support System project manager. After the new systems are installed, annual delivered water to the ISS should decrease by approximately 15,960 pounds, or about 1,600 gallons.

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