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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Buried and Visible Impact Basin Distribution on Mars: Comparison with Magnetization, Gravity and Crustal Thickness Models

The large population of buried impact basins found in MOLA elevation data on Mars provides compelling evidence for a pre-Noachian crust below the oldest visible Early Noachian surface units, and lowland crust below the younger plains that is Early Noachian in age, older than much of the visible highlands, but not as old as the buried pre-Noachian highlands. The large (D greater than 200 km) buried basins are suggested by Quasi-Circular Depressions (QCDs) that are not apparent in image data, and include features up to 3000 lun diameter in both the lowlands (Utopia) and highlands (a newly found "Ares Basin"). There are about a dozen QCDs larger than 1000 km diameter. We have placed these large features in a relative age sequence based on superimposed smaller QCD. Only the youngest and most obvious of these (Hellas, Argyre, Isidis) lack magnetic anomalies within their main rings. These all have an N(200) cumulative crater density of less than 2.5. Somewhat older lowland-making basins (Utopia, Chryse, Acidalia) with an N(200) age of approximately 3.0, have weak magnetic anomalies, and the oldest, most subdued basins (including Ares) with N(200) greater than 3.5 have many strong magnetic anomalies within their main ring. These older basins likely formed before the main magnetic field died. We have compared our inventory of large QCDs with the distribution of gravity anomalies and with a crustal thickness model which shows many roughly circular areas of thinner crust completely or partly surrounded by narrow regions of thicker crust. These have the structure expected for impact basins, and many of them do correspond to the visible or buried QCDs we previously identified. But there are cases where the crustal thickness feature is offset from the QCD found in topography alone, and there are also several, sometimes large examples of such features which do not coincide with QCDs previously identified. For example, we find several likely buried basins revealed in the crustal thickness data in the Arcadia and Amazonis regions which we did not previously identify, including several features in the 600-1200 km diameter range.

Frey, Herbert↗
NASA NTRS2004

Multi-Wavelength Observations of Asteroid 2100 Ra-Shalom: Visible, Infrared, and Thermal Spectroscopy Results

The August 2003 apparition of asteroid 2100 Ra-Shalom brought together a collaboration of observers with the goal of obtaining rotationally resolved multiwavelength spectra at each of 5 facilities: infrared spectra at the NASA Infrared Telescope Facility (Clark and Shepard), radar images at Arecibo (Shepard and Clark), thermal infrared spectra at Palomar (Lim, McConnochie and Bell), visible spectra at McDonald Observatory (Vilas, Lederer and Jarvis), and visible lightcurves at Ondrojev Observatory (Pravec). The radar data was to be used to develop a high spatial resolution physical model to be used in conjunction with spectral data to investigate compositional and textural properties on the near surface of Ra Shalom as a function of rotation phase. This was the first coordinated multi-wavelength investigation of any Aten asteroid. There are many reasons to study near-Earth asteroid (NEA) 2100 Ra-Shalom: 1) It has a controversial classification (is it a C- or K-type object)? 2) There would be interesting dynamical ramifications if Ra-Shalom is a K-type because most K-types come from the Eos family and there are no known dynamical pathways from Eos to the Aten population. 3) The best available spectra obtained previously may indicate a heterogeneous surface (most asteroids appear to be fairly homogeneous). 4) Ra-Shalom thermal observations obtained previously indicated a lack of regolith, minimizing the worry of space weathering effects in the spectra. 5) Radar observations obtained previously hinted at interesting surface structures. 6) Ra-Shalom is one of the largest Aten objects. And 7) Ra-Shalom is on a short list of proposed NEAs for spacecraft encounters and possible sample returns. Preliminary results from the visible, infrared, and thermal spectroscopy measurements will be presented here.

Clark, Beth Ellen↗
NASA NTRS2005

Relative Ages of the Highlands, Lowlands, and Transition Zone Along a Portion of the Mars Crustal Dichotomy from Densities of Visible and Buried Impact Craters

Understanding the fundamental age relationships of the different parts of the Mars Crustal Dichotomy is essential to fully understanding the events that shaped the early history and formation of the surface of Mars. A dominant question is what are the true relative ages of the Northern Lowlands and the Southern Highlands? Using MOLA data from the Mars Global Surveyor and Viking visual images, a dataset of both buried and visible crater diameters was created over a nine million sq km study area of a section of the dichotomy boundary stretching from Arabia Terra to Utopia Planitia. Cumulative frequency plots on a log-log scale were used to determine the relative ages for the Highlands, the Lowlands, and the Transition Zone, separately for the visible, the buried and the combined total (visible+ buried) populations. We find the overall Highland crater population in this area is slightly older than the Lowlands, consistent with previous global studies, but the Lowlands and Transition Zone are also very old and formed at roughly the same time. It appears that the formation of the Lowlands in this region formed contemporaneously with a large-scale resurfacing event in the Highlands, perhaps caused by the process responsible for the Lowland formation.

DeSoto, G. E.↗
NASA NTRS2010

Visible Nulling Coronagraphy Testbed Development for Exoplanet Detection

Three of the recently completed NASA Astrophysics Strategic Mission Concept (ASMC) studies addressed the feasibility of using a Visible Nulling Coronagraph (VNC) as the prime instrument for exoplanet science. The VNC approach is one of the few approaches that works with filled, segmented and sparse or diluted aperture telescope systems and thus spans the space of potential ASMC exoplanet missions. NASA/Goddard Space Flight Center (GSFC) has a well-established effort to develop VNC technologies and has developed an incremental sequence of VNC testbeds to advance the this approach and the technologies associated with it. Herein we report on the continued development of the vacuum Visible Nulling Coronagraph testbed (VNT). The VNT is an ultra-stable vibration isolated testbed that operates under high bandwidth closed-loop control within a vacuum chamber. It will be used to achieve an incremental sequence of three visible light nulling milestones of sequentially higher contrasts of 10(exp 8) , 10(exp 9) and 10(exp 10) at an inner working angle of 2*lambda/D and ultimately culminate in spectrally broadband (>20%) high contrast imaging. Each of the milestones, one per year, is traceable to one or more of the ASMC studies. The VNT uses a modified Mach-Zehnder nulling interferometer, modified with a modified "W" configuration to accommodate a hex-packed MEMS based deformable mirror, a coherent fiber bundle and achromatic phase shifters. Discussed will be the optical configuration laboratory results, critical technologies and the null sensing and control approach.

Lyon, Richard G.↗
NASA NTRS2013

Flight Deck Technologies to Enable NextGen Low Visibility Surface Operations

Many key capabilities are being identified to enable Next Generation Air Transportation System (NextGen), including the concept of Equivalent Visual Operations (EVO) . replicating the capacity and safety of today.s visual flight rules (VFR) in all-weather conditions. NASA is striving to develop the technologies and knowledge to enable EVO and to extend EVO towards a Better-Than-Visual operational concept. This operational concept envisions an .equivalent visual. paradigm where an electronic means provides sufficient visual references of the external world and other required flight references on flight deck displays that enable Visual Flight Rules (VFR)-like operational tempos while maintaining and improving safety of VFR while using VFR-like procedures in all-weather conditions. The Langley Research Center (LaRC) has recently completed preliminary research on flight deck technologies for low visibility surface operations. The work assessed the potential of enhanced vision and airport moving map displays to achieve equivalent levels of safety and performance to existing low visibility operational requirements. The work has the potential to better enable NextGen by perhaps providing an operational credit for conducting safe low visibility surface operations by use of the flight deck technologies.

Prinzel, Lawrence (Lance) J., III↗
NASA NTRS2014

Using Vision System Technologies to Enable Operational Improvements for Low Visibility Approach and Landing Operations

Flight deck-based vision systems, such as Synthetic and Enhanced Vision System (SEVS) technologies, have the potential to provide additional margins of safety for aircrew performance and enable the implementation of operational improvements for low visibility surface, arrival, and departure operations in the terminal environment with equivalent efficiency to visual operations. To achieve this potential, research is required for effective technology development and implementation based upon human factors design and regulatory guidance. This research supports the introduction and use of Synthetic Vision Systems and Enhanced Flight Vision Systems (SVS/EFVS) as advanced cockpit vision technologies in Next Generation Air Transportation System (NextGen) operations. Twelve air transport-rated crews participated in a motion-base simulation experiment to evaluate the use of SVS/EFVS in NextGen low visibility approach and landing operations. Three monochromatic, collimated head-up display (HUD) concepts (conventional HUD, SVS HUD, and EFVS HUD) and two color head-down primary flight display (PFD) concepts (conventional PFD, SVS PFD) were evaluated in a simulated NextGen Chicago O'Hare terminal environment. Additionally, the instrument approach type (no offset, 3 degree offset, 15 degree offset) was experimentally varied to test the efficacy of the HUD concepts for offset approach operations. The data showed that touchdown landing performance were excellent regardless of SEVS concept or type of offset instrument approach being flown. Subjective assessments of mental workload and situation awareness indicated that making offset approaches in low visibility conditions with an EFVS HUD or SVS HUD may be feasible.

Kramer, Lynda J.↗
NASA NTRS2015

Visible-Light-Responsive Catalyst Development for Volatile Organic Carbon Remediation Project

Photocatalysis is a process in which light energy is used to 'activate' oxidation/reduction reactions. Unmodified titanium dioxide (TiO2), a common photocatalyst, requires high-energy UV light for activation due to its large band gap (3.2 eV). Modification of TiO2 can reduce this band gap, leading to visible-light-responsive (VLR) photocatalysts. These catalysts can utilize solar and/or visible wavelength LED lamps as an activation source, replacing mercury-containing UV lamps, to create a "greener," more energy-efficient means for air and water revitalization. Recently, KSC developed several VLR catalysts that, on preliminary evaluation, possessed high catalytic activity within the visible spectrum; these samples out-performed existing commercial VLR catalysts.

Technology Portfolio System↗
NASA NTRS2015

Using Vision System Technologies for Offset Approaches in Low Visibility Operations

Flight deck-based vision systems, such as Synthetic Vision Systems (SVS) and Enhanced Flight Vision Systems (EFVS), have the potential to provide additional margins of safety for aircrew performance and enable the implementation of operational improvements for low visibility surface, arrival, and departure operations in the terminal environment with equivalent efficiency to visual operations. Twelve air transport-rated crews participated in a motion-base simulation experiment to evaluate the use of SVS/EFVS in Next Generation Air Transportation System low visibility approach and landing operations at Chicago O'Hare airport. Three monochromatic, collimated head-up display (HUD) concepts (conventional HUD, SVS HUD, and EFVS HUD) and three instrument approach types (straight-in, 3-degree offset, 15-degree offset) were experimentally varied to test the efficacy of the SVS/EFVS HUD concepts for offset approach operations. The findings suggest making offset approaches in low visibility conditions with an EFVS HUD or SVS HUD appear feasible. Regardless of offset approach angle or HUD concept being flown, all approaches had comparable ILS tracking during the instrument segment and were within the lateral confines of the runway with acceptable sink rates during the visual segment of the approach. Keywords: Enhanced Flight Vision Systems; Synthetic Vision Systems; Head-up Display; NextGen

Kramer, Lynda J.↗
NASA NTRS2016

Visible-Light-Responsive Photocatalysis: Ag-Doped TiO2 Catalyst Development and Reactor Design Testing

In recent years, the alteration of titanium dioxide to become visible-light-responsive (VLR) has been a major focus in the field of photocatalysis. Currently, bare titanium dioxide requires ultraviolet light for activation due to its band gap energy of 3.2 eV. Hg-vapor fluorescent light sources are used in photocatalytic oxidation (PCO) reactors to provide adequate levels of ultraviolet light for catalyst activation; these mercury-containing lamps, however, hinder the use of this PCO technology in a spaceflight environment due to concerns over crew Hg exposure. VLR-TiO2 would allow for use of ambient visible solar radiation or highly efficient visible wavelength LEDs, both of which would make PCO approaches more efficient, flexible, economical, and safe. Over the past three years, Kennedy Space Center has developed a VLR Ag-doped TiO2 catalyst with a band gap of 2.72 eV and promising photocatalytic activity. Catalyst immobilization techniques, including incorporation of the catalyst into a sorbent material, were examined. Extensive modeling of a reactor test bed mimicking air duct work with throughput similar to that seen on the International Space Station was completed to determine optimal reactor design. A bench-scale reactor with the novel catalyst and high-efficiency blue LEDs was challenged with several common volatile organic compounds (VOCs) found in ISS cabin air to evaluate the system's ability to perform high-throughput trace contaminant removal. The ultimate goal for this testing was to determine if the unit would be useful in pre-heat exchanger operations to lessen condensed VOCs in recovered water thus lowering the burden of VOC removal for water purification systems.

Photocatalysis↗
NASA NTRS2018

Enhancements to the Open Access Spectral Band Adjustment Factor Online Calculation Tool for Visible Channels

With close to 40 years of satellite observations, from which, cloud, land-use, and aerosol parameters can be measured, inter-consistent calibrations are needed to normalize retrievals across satellite records. Various visible-sensor inter-calibration techniques have been developed that utilize radiometrically stable Earth targets, e.g., deep convective clouds and desert/polar ice pseudo-invariant calibration sites. Other equally effective, direct techniques for intercalibration between satellite imagers are simultaneous nadir overpass comparisons and ray-matched radiance pairs. Combining independent calibration results from such varied techniques yields robust calibration coefficients, and is a form of self-validation. One potential source of significant error when cross-calibrating satellite sensors, however, are the often small but substantial spectral discrepancies between comparable bands, which must be accounted for. As such, visible calibration methods rely on a Spectral Band Adjustment Factor (SBAF) to account for the spectral-response function- induced radiance differences between analogous imagers. The SBAF is unique to each calibration method as it is a function of the Earth-reflected spectra. In recent years, NASA Langley pioneered the use of SCIAMACHY-, GOME-2-, and Hyperion-retrieved Earth spectra to compute SBAFs. By carefully selecting hyperspectral footprints that best represent the conditions inherent to an inter-calibration technique, the uncertainty in the SBAF is greatly reduced. NASA Langley initially provided the Global Space-based Inter-calibration System processing and research centers with online SBAF tools, with which users select conditions to best match their calibration criteria. This article highlights expanded SBAF tool capabilities for visible wavelengths, with emphasis on the use of the spectral range filtering for the purpose of separating scene conditions for the channel that the SBAF is needed based on the reflectance values of other bands. In other words, spectral filtering will enable better scene-type selection for bands where scene determination is difficult without information from other channels, which should prove valuable to users in the calibration community.

Scarino, Benjamin↗
NASA NTRS2020

Radiative Transfer Models for Deriving Geostationary Broadband Shortwave Radiances Directly from Visible Channels for the Ceres SYN1DEG Product

The Clouds and the Earth's Radiant Energy System(CERES)project was designed to observe the Earth’s radiation budget at the 1° regional and global scale. The CERES instruments on the Terra (10:30 AM local equator crossing time) and Aqua (1:30 PM) satellite may not accurately capture the 24-hour mean flux over regions with systematic diurnal cycles. The Terra-only and Aqua-only derived regional monthly mean SW flux can differ by 25 Wm-2 over maritime stratus and land afternoon convective regions. The CERES project utilizes hourly Geostationary imager (GEO) derived broadband fluxes to more accurately estimate the regional diurnal flux in between CERES measurements. We propose an approach that converts the GEO visible radiance to broadband radiance using RTM radiances that are specific to the individual GEO visible channel spectral response functions. The RTM is first validated using the very spectrally narrow MODIS visible channel and CERES broadband radiances.

geostationary derived broadband radiances↗
NASA NTRSDate not supplied

Evaluation of Spectral Band Adjustment Factors for Cross-Calibration of Visible Imagers

The CERES EBAF dataset provides TOA SW and LW fluxes for long-term monitoring of the Earth’s energy balance and to validate climate models. The EBAF products, based on the Terra and Aqua CERES instrument observed radiances, rely on coincident measurements from the onboard MODIS imagers to determine cloud properties that are used in the angular distribution model scene selection required to convert the CERES observed radiances into flux values. Once the Terra and Aqua orbits start drifting outside of their 15-minute window, the CERES project will rely solely on the NOAA-20 CERES observations. A seamless transition of fluxes and clouds can only occur if the analogous MODIS and VIIRS channels are properly inter-calibrated. The visible band (0.65 µm) in MODIS (band 1) and VIIRS (M5 or I1) is critical for retrieving the cloud mask and optical depth. The spectral response functions (SRF) of these bands differ noticeably and will require scene dependent spectral band adjustment factors (SBAF) for proper radiometric scaling between them. Fortunately, the VIIRS I1 and M5 bands are calibrated using the same solar diffuser as a reference, which implies that band reflectance differences must be due to the spectral disparity. The coincident I1 and M5 TOA reflectance measurements provide the optimal opportunity to validate SBAFs over many surface and cloud conditions. The CERES project maintains SCIAMACHY, GOME-2, Hyperion, and radiative transfer model-based scene-stratified hyper-spectral reflectance measurements that can be convolved with sensor pair SRFs to compute the corresponding SBAF. This study will evaluate the SCIAMACHY, GOME-2, Hyperion, and RTM based SBAFs over tropical ocean targets used in SNO inter-calibration of MODIS and VIIRS, including clear-sky ocean, deep convective clouds (DCC), and liquid cloud targets in terms of their applicability to absolute intercomparison of visible imagers. The large SCIAMACHY and GOME-2 footprints and the lack of Hyperion cloudy scenes will impact the resulting SBAFs and necessitates the need for future CLARREO hyper-spectral reflectances to decrease SBAF uncertainties Preliminary results indicate that the SCIAMACHY and GOME-2 based SBAFs for the VIIRS I1 and M5 band pairs may differ by 1.5% for some ATO scene types. Because most of the modern GEOs visible band SRFs encompass the VIIRS I1 band SRF, these evaluations are critical to ensure that the MODIS, VIIRS, and GEO clouds and fluxes are consistent. SBAFs for Libya-4, Dome-C and other Earth invariant target will also be evaluated.

D. R. Doelling↗
NASA NTRS2022

Sources, Transport and Visibility Impact of Ambient Submicrometer Particle Size Distributions in an Urban Area of Central Taiwan

This study applied positive matrix factorization (PMF) to identify the sources of size-resolved submicrometer (10–1000 nm) particles and quantify their contributions to impaired visibility based on the particle number size distributions (PNSDs), aerosol light extinction (b p ), air pollutants (PM 10 , PM 2.5 , SO 2 , O 3 , and NO), and meteorological parameters (temperature, relative humidity, wind speed, wind direction, and ultraviolet index) measured hourly over an urban basin in central Taiwan between 2017 and 2021. The transport of source-specific PNSDs was evaluated with wind and back trajectory analyses. The PMF revealed six sources to the total particle number (TPN), surface (TPS), volume (TPV), and b p . Factor 1 (F1), the key contributor to TPN (35.0 %), represented nucleation (<25 nm) particles associated with fresh traffic emission and secondary new particle formation, which were transported from the west-southwest by stronger winds (>2.2 m s -1 ). F2 represented the large Aitken (50–100 nm) particles transported regionally via northerly winds, whereas F3 represented large accumulation (300–1000 nm) particles, which showed elevated concentrations under stagnant conditions (<1.1 m s −1 ). F4 represented small Aitken (25–50 nm) particles arising from the growth and transport of the nucleation particles (F1) via west-southwesterly winds. F5 represented large Aitken particles originating from combustion-related SO 2 sources and carried by west-northwesterly winds. F6 represented small accumulation (100–300 nm) particles emitted both by local sources and by the remote SO 2 sources found for F5. Overall, large accumulation particles (F3) played the greatest role in determining the TPV (66.4 %) and TPS (34.8 %), and their contribution to bp increased markedly from 17.3 % to 40.7 % as visibility decreased, indicating that TPV and TPS are better metrics than TPN for estimating b p . Furthermore, slow-moving air masses—and therefore stagnant conditions—facilitate the build-up of accumulation mode particles (F3 + F6), resulting in the poorest visibility.

source apportionment↗
NASA NTRSDate not supplied

Visible and Infrared Imaging of Various Flow Regimes in the Flow Boiling and Condensation Experiment Transfer Line

The Flow Boiling and Condensation Experiment (FBCE) Transfer Line (TL) test module is being developed to study fluid physics of cryogenic transfer lines in microgravity. The TL module will reside in the FBCE facility located within the Fluids Integration Rack (FIR) aboard the International Space Station (ISS). TL will use the same normal perfluoro hexane (nPFH) used in the previous FBCE test sections. To simulate cryogenic line transfer in the visualization section, a sapphire tube coated with indium tin oxide (ITO) is heated via Joule heated while a bypass line is used to flow liquid nPFH at the desired inlet conditions. Once the visualization line reaches steady-state temperature and pressure conditions, flow is diverted through the heated line and chilldown begins. All flow regimes observed within a cryogenic TL are created and studied using visible imaging with diffuse backlighting to image inverted annular flow, transition, and nucleate boiling. A visible laser light sheet provided by FIR will provide a means to observe and track droplets in the dispersed flow regime. IR imaging of the visualization tube outer surface with the emissivity of the ITO coating provides the surface chilldown temperature profile. Preliminary imaging system development includes some of the components used in the Flow Boiling Module (FBM) and some new components that are easily integrated into the PC-based system but will require some refinement to operate properly on the FIR PCIe/104 imaging system. Optical design and packaging within the limited volume of the module enclosure is also presented. This paper presents FBCE-TL visible and infrared laboratory-based imaging studies and anticipated visualization capabilities of the TL module under preliminary breadboard development and under the utilization constraints within the FBCE/FIR host facility.

transfer line↗
NASA NTRS2023

In-Flight Validation of the Metis Visible-Light Polarimeter Coronagraph on Board Solar Orbiter

Context. The Metis coronagraph is one of the remote sensing instruments of the ESA-NASA Solar Orbiter mission. The goal for the instrument is to enable the study of the solar atmosphere and solar wind by simultaneously acquiring images of the solar corona at two different wavelengths: visible light (VL), within a band ranging from 580 nm to 640 nm, and ultraviolet light, in the HI Lyα 121.6 ± 10 nm. The visible-light channel of the coronagraph includes a polarimeter with electro-optically modulating liquid crystal variable retarders to measure the linearly polarized brightness of the K-corona and derive the electron density. Aims. In this paper, we present the first in-flight validation results of the Metis polarimetric channel together with a comparison to the on-ground calibrations. This paper seeks to validate the first use of an electro-optical device, the liquid crystal-based polarimeter, in deep space and within a hard radiation environment. Methods. We used the orientation of the K-corona’s linear polarization vector during the roll maneuvers of the Space Orbiter spacecraft for the in-flight calibration. Results. The Metis coronagraph on board the Solar Orbiter shows good agreement with the on-ground measurements. The in-flight validation confirms the expected performance of the visible-light channel polarimeter. Furthermore, a comparison between the first polarized brightness value obtained by Metis and the polarized brightness values obtained by the space-based coronagraph LASCO and the ground-based coronagraph K-Cor shows the consistency of the Metis calibrated results.

Sun: corona↗
NASA NTRS2021

Calibration of the DSCOVR EPIC Visible and NIR Channels using Multiple LEO Radiometers

The first five years of operation of the Deep Space Climate Observatory (DSCOVR) Earth Polychromatic Imaging Camera (EPIC) at the Lagrange one point have produced results that uniquely complement the data from currently operating low orbit Earth-observing instruments. In this paper we describe an updated unified approach to EPIC calibration. In this approach, calibration coefficients and their trends were obtained by comparing EPIC observations to the measurements from polar orbiting radiometers. In this study L1B reflectances from Moderate Resolution Imaging Spectroradiometer (MODIS) onboard the Aqua and Terra satellites, Multi-angle Imaging Spectroradiometer (MISR) onboard Terra and Visible Infrared Imaging Radiometer (VIIRS) onboard the Suomi National Polar-orbiting Partnership (Suomi NPP) spacecraft were used to infer calibration coefficients for four EPIC visible and near-infrared channels: 443 nm, 551 nm, 680 nm, and 780 nm. EPIC Version three measurements made between June 2015 and August 2020 were used for comparison. The calibration procedure identifies the most homogeneous low Earth orbit radiometer scenes matching scattering angles that are temporarily and spatially collocated with EPIC observations. These scenes are used to determine reflectance to count (R/C) ratios in spectrally analogous channels. Seasonal average R/C ratios were analyzed to obtain EPIC calibration gains and trends. The trends for the full dataset period are not statistically significant except in the 443 nm channel. No significant changes in calibration were found after the instrument’s exit from safe hold in March 2020. The R/C ratios were also used to determine the differences in EPIC gains resulting from separate calibrations: against MODIS Aqua or Terra, as well as against forward or aftward MISR cameras. Statistical tests indicate that the differences between the two datasets are not significant except in the 780 nm channels where Aqua-derived coefficients may be around 2% lower compared to Terra. The dependence of EPIC calibration gains on the instrument scattering angle and on DSCOVR-Earth distance were investigated. Lastly, model Low Earth Orbit (LEO) reflectances calculated to match the EPIC viewing geometry were employed to study how EPIC calibration coefficients depend on EPIC-LEO viewing geometry differences. The effect of LEO and EPIC angular mismatch on calibration was shown to be small.

deep space climate observatory/earth polychromatic↗
DOE OSTI2020

Visible-Light-Activated Photocatalytic Films toward Self-Cleaning Membranes

Membranes are among the most promising means of delivering increased supplies of fit-for-purpose water, but membrane fouling remains a critical issue restricting their widespread application. Coupling photocatalysis with membrane separation has been proposed as a potentially effective approach to reduce membrane fouling. However, commonly used materials in photocatalysis limit use of low-cost sources such as sunlight due to their large band gaps. There are few examples of in situ photocatalytic self-cleaning of membranes, with removal from the filtration system and ex situ illumination being more common. In this study, a visible-light-activated photocatalytic film prepared by nitrogen doping into the lattice of TiO 2 was deposited on commercial ceramic membranes via atomic layer deposition (ALD). The synergy between membrane separation and redox reactions between organic pollutants and reactive oxygen species (ROS) produced by the visible-light-activated layer offers a possibility for stable and sustainable membrane operation under in situ solar irradiation.

36 MATERIALS SCIENCE↗
DOE OSTI2021

In situ preparation of visible-light-driven carbon quantum dots/NaBiO 3 hybrid materials for the photoreduction of Cr(VI)

Here, different carbon quantum dots (CQDs)/NaBiO 3 hybrid materials were synthesized as photocatalysts to effectively utilize visible light for the photocatalytic degradation of contaminants effectively. These hybrid materials exhibit an enhanced photocatalytic reduction of hexavalent chromium (Cr(VI)) in the aqueous medium. Zero-dimensional nanoparticles of CQDs were embedded within the two-dimensional NaBiO 3 nanosheets by the hydrothermal process. Compared with that of the pure NaBiO 3 nanosheets, the photocatalytic performance of the hybrid catalysts was significantly high and 6 wt.% CQDs/NaBiO 3 catalyst exhibited better photocatalytic performance. We performed the first-principles density functional theory calculations to study the interfacial properties of pure NaBiO 3 nanosheets and hybrid photocatalysts, and confirmed the CQDs played an important role in the CQDs/NaBiO 3 composites. The experimental results indicated that the enhanced reduction of Cr(VI) was probably due to the high loading of CQDs (electron acceptor) on NaBiO 3 , which made NaBiO 3 nanomaterials to respond in visible light and significantly improved their electron-hole separation efficiency.

54 ENVIRONMENTAL SCIENCES↗