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At least 127 records · Page 7

Cryogenic Mixed Mode I – Mode II Fracture Toughness of Various Polymer Composite Materials

The present study investigates the mixed mode interlaminar fracture toughness of six polymer matrix composite materials at both room temperature and cryogenic liquid nitrogen temperature. The single leg bending test employed gives a mix of Mode I (opening) and Mode II (in-plane shearing) cracking. The tested thermoplastic-matrix composites were shown to have total mixed mode toughnesses 3.1–4.3 times higher than those of representative thermoset resin composites.

Carbon fiber↗

On the roles of welding residual stresses in determination of fracture toughness in austenitic stainless steel SUS 304 pipeline girth welds

Welding residual stresses especially the high tensile stresses are proved to have negative impacts on the fatigue and fracture behaviors of welded structures. In this study, a virtual fabrication of test specimens from welding process to specimen preparation was carried out by numerical simulation. An austenitic stainless steel multi-pass pipe welding was simulated by transient thermal–mechanical finite element analysis, the residual stresses were then mapped into the test specimen to evaluate fracture toughness. The findings in this study confirmed that, residual stress can be high in a sub-sized compact tensile specimen, which may accelerate or hinder the crack propagation during actual fatigue and fracture tests as reported in recent years. The influence of the cutting location and orientation of the specimen on fracture performance was investigated systematically to provide a fundamental understanding of welding residual stress and necessary insights into the specimen preparation procedure. Considering the limitation of measuring techniques and the complexity of the stress distribution, the developed numerical model can be a very useful tool to elucidate the stress evolution and quantify the effect of remaining welding stress on fracture toughness.

Fracture behavior↗

Tailoring Crosslinks through Time─A Paradigm for Tough Hydrogels

The multidisciplinary applications of hydrogels have motivated a thorough exploration of the relationship between their structural and mechanical properties, i.e., spatial structure–function relationships, with particular regard to strength and toughness. While this approach has driven fundamental advancements in the design of robust hydrogel structures, further complementary perspectives are needed to enable holistic, rational design schemes that integrate considerations such as fabrication and advanced functions like response and adaptation. To these ends, this review focuses on the dynamics of temporal-function relationships and their fundamental bases in order to highlight how the dynamic regulation of polymer interactions programs: 1) polymer assembly and material structure; 2) response to deformation and fracture behavior; 3) dynamic modulation of properties and structural remodeling/self-healing. Here, by exploring this intersection of hydrogel formation, function, and remodeling, this review seeks to shed light on the fundamental relationship between molecular structure, material assembly, and performance in order to connect the emerging area of bioinspired materials processing with tough hydrogel design, and further provides a lasting inspiration and impetus for future hydrogel development that enables valuable scientific and technological advancements.

36 MATERIALS SCIENCE↗

Tough and circular glass fiber composites via a tailored dynamic boronic ester interface

Glass fiber reinforced polymer (GFRP) composites are valued for their strength and cost-effectiveness. However, traditional GFRPs often face challenges for end-of-life recycling due to their non-depolymerizable thermoset matrices, and long-term performance due to inadequate interfacial adhesion, which can lead to fiber–matrix delamination. Here, in this work, we have designed dynamic fiber–matrix interfaces to allow tough and closed-loop recyclable GFRPs by utilizing a vitrimer, derived from upcycled polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene (SEBS) with boronic ester (S-Bpin) and amine-based diol crosslinker. The boronic ester groups in S-Bpin form dynamic covalent bonds with the naturally present hydroxyl groups on the unsized GF surface, which eliminates the need for fiber sizing and enables facile closed-loop recyclability of both the fibers and the vitrimer matrix. The resulting strong fiber–matrix interface, depicted by the Raman mapping, leads to a 552% increase in-plane shear toughness (6.2 ± 0.3 MJ m -3 ) and 27% ultimate tensile strength (361 ± 89.2 MPa) compared to those of the conventional epoxy-based matrix (0.95 ± 0.05 MJ m -3 and 264 ± 59.7 MPa, respectively). The network rearrangement through dynamic boronic ester exchange enables fast thermoformability and repairability of micro-cracks at elevated temperatures. Additionally, both the matrix and composite demonstrate strong adhesion to various surfaces including steel and glasses exhibiting ≥6 MPa lap shear strength, which expands their suitability for diverse industrial applications. The readily created dynamic interface between boronic ester functionalized vitrimer and neat GFs presents a promising strategy for developing closed-loop recyclable, multifunctional structural materials, offering a sustainable alternative to non-recyclable thermoset GFRPs and contributes to a circular economy in composite materials.

36 MATERIALS SCIENCE↗

The effect of microstructure and strength on the fracture toughness of an 18 ni, 300 grade maraging steel

Methods for increasing the strength of maraging steels are discussed. An investigation was conducted to systematically vary the strength of 18 weight percent nickel, 300 grade maraging steel, to isolate any attending microstructural changes, and to study the effects of these changes on the fracture toughness of the alloy. A study aimed at determining the aging behavior of the program alloy was carried out to provide data by which to estimate yield strength. The effects of various alloying materials on the strength of the maraging steel are examined. The mechanical properties of the 300 grade maraging steel were determined by tension tests, fatigue precracked Charpy impact tests, and plane strain fracture toughness tests.

Psioda, J. A.↗

Tough cryogenic alloys from the Fe-Mn and Fe-Mn-Cr systems

By adjusting composition, metastable gamma (austenite) and epsilon (hexagonal) martensite may be retained in Fe-Mn and Fe-Mn-Cr alloys and used to impact toughness through the TRIP mechanism. The resulting alloys have excellent toughness at cryogenic temperatures. The best alloys obtained to date are: Fe-20Mn, with sigma (sub y) = 79ksi and K sub IC = 275ksi square root of (in) at 77 K, and Fc-16Mn-8Cr, with sigma sub y = 85ksi and K sub IC = 72ksi square root of (in) at 77 K.

Schanfein, M. J.↗

An investigation of fracture toughness, fatigue-crack growth, sustained-load flaw growth, and impact properties of three pressure vessel steels

The elastic fracture toughness of the three steels is shown to not decrease significantly with decreasing temperature from room temperature to about 244 K (-20 F.). The elastic fracture toughness of the three steels increased with increasing specimen width and thickness. The fatigue-crack-growth data for all three steels fall into relatively narrow scatter bands on plots of rate against stress-intensity range. An equation is shown to predict the upper bounds of the scatter bands reasonably well. Charpy impact energies decreased with decreasing temperature in the nominal temperature range from room temperature to 244 K (-20 F). The nil-ductility temperatures of the steels are discussed.

Hudson, C. M.↗

Tough strong iron alloys for cryogenic service

Series of alloys with minor additions of reactive metals possesses outstanding strength and toughness at cryogenic temperatures. Effective metal additons include aluminum, niobium, titanium, and vanadium. Strengthening of series is achieved by thermomechanical processing and by precipitate strengthening while maintaining high level of toughness. Possible applications include liquefied natural-gas storage and transmission, structural members in superconducting machinery, and welding rod for other alloys such as nine nickel steels.

Stephens, J. R.↗

Heavy section fracture toughness screening specimen

Size requirements for a pin loaded double edge notch + crack tension specimen proposed for fracture toughness screening heavy section alloys were studied. Ranking of eight selected alloys based on the specimen's net strength was compared with that based on the valid plane strain fracture toughness separately determined. Performance of the specimen was judged on the basis of that comparison. The specimen's net strength was influenced by three critical specimen dimensions: distance between the crack plane and the loading hole, specimen width, and specimen thickness. Interaction between the stress fields of the crack and the loading holes reduced the net strength, but this effect disappeared as the separation reached a dimension equal to the specimen width. The effects of specimen width and thickness are interrelated and affect the net strength through their influence on the development of the crack tip plastic zone.

Shannon, J. L., Jr.↗

Weldability of high-toughness iron - 12 percent-nickel alloys with reactive metal additions of titanium, aluminum, or niobium

Three exceptionally high toughness Fe-12Ni alloys designed for cryogenic service were welded by using the gas tungsten arc welding process. Evaluation of their weldability included equivalent energy fracture toughness tests, transverse weld tensile tests at -196 and 25 C, and weld crack sensitivity tests. The Fe-12Ni-0.25Ti alloy proved extremely weldable for cryogenic applications, having weld and heat affected zone properties comparable to those of the wrought base alloy. The Fe-12Ni-0.5Al alloy had good weld properties only after the weld joint was heat treated. The Fe-12Ni-0.25Nb alloy was not considered weldable for cryogenic use because of its poor weld joint properties at -196 C and its susceptibility to hot cracking.

Delvetian, J. H.↗

Cryogenic Properties of a New Tough-Strong Iron Alloy

A program was undertaken to develop an iron-base alloy having a fracture toughness of 220 MPa. m superscript 1/2 with a corresponding yield stress of 1.4 GPa (200 ksi) at-196 C. An Fe-12Ni alloy was selected as the base alloy. Factors considered included reactive metal additions, effects of interstitial impurities, strengthening mechanisms, and weldability. The goals were met in an Fe-12Ni-0.5Al alloy strengthened by thermomechanical processing or by precipitate strengthening with 2 percent Cu. The alloy is weldable with the weld metal and heat affected zone in the postweld annealed condition having toughness equivalent to the base alloy.

Stephens, J. R.↗

Weldability of high toughness Fe-12% Ni alloys containing Ti, Al or Nb

Three exceptionally high-toughness Fe-12%Ni alloys designed for cryogenic service were welded using the GTA welding process. Evaluation of weldability included equivalent energy (KIed) fracture toughness tests, transverse-weld tensile tests at -196 and 25 C and weld crack sensitivity tests. The Fe-12%Ni-0.25%Ti alloy proved extremely weldable for cryogenic applications, having weld and HAZ properties comparable with those of the wrought base alloy. The Fe-12%Ni-0.5%Al had good weld properties only after the weld joint was heat treated. The Fe-12%Ni-0.25%Nb alloy was not considered weldable for cryogenic use because of its poor weld joint properties at -196 C and its susceptibility to hot cracking.

Devletian, J. H.↗

Heavy-section fracture toughness screening specimen

The reported study has the objective to fix the proportions and limits of application of a double-edge-notch specimen with one of the notches tipped with a fatigue crack (DENC). Details regarding the DENC specimen are discussed, taking into account specimen length, notch length, specimen width and thickness, and the loading pins. The influence of specimen width and thickness on the crack strenght and apparent plane-strain fracture toughness of the specimen has been determined for eight alloys. It is concluded that the DENC specimen shows promise for screening alloys with reference to their plane-strain fracture toughness in sections up to 1 in.

Shannon, J. L., Jr.↗

Correlations between ultrasonic and fracture toughness factors in metallic materials

A heuristic mathematical basis was proposed for the experimental correlations found between ultrasonic propagation factors and fracture toughness factors in metallic materials. A crack extension model was developed wherein spontaneous stress (elastic) waves produced during microcracking are instrumental in promoting the onset of unstable crack extension. Material microstructural factors involved in the process are measurable by ultrasonic probing. Experimental results indicate that ultrasonic attenuation and velocity measurements will produce significant correlations with fracture toughness properties and also yield strength.

Vary, A.↗

Effects of thermomechanical processing on strength and toughness of iron - 12-percent-nickel - reactive metal alloys at -196 C

Thermomechanical processing (TMP) was evaluated as a method of strengthening normally tough iron-12-nickel-reactive metal alloys at cryogenic temperatures. Five iron-12 nickel alloys with reactive metal additions of aluminum, niobium, titanium, vanadium, and aluminum plus niobium were investigated. Primary evaluation was based on the yield strength and fracture toughness of the thermomechanically processed alloys at -196 C.

Stephens, J. R.↗

Cryogenic properties of a new tough-strong iron alloy

A program was undertaken to develop an iron-base alloy having a fracture toughness of 220 MPa-sq root meters with a corresponding yield stress of 1.4 GPa (200 ksi) at -196 C. An Fe-12Ni alloy was selected as the base alloy. Factors considered include reactive metal additions, effects of interstitial impurities, strengthening mechanisms, and weldability. The goals of this program were met in an Fe-12Ni-0.5Al alloy strengthened by thermomechanical processing or by precipitate strengthening with 2 percent Cu. The alloy is weldable with the weld metal and heat affected zone in the post-weld annealed condition having toughness equivalent to the base alloy.

Stephens, J. R.↗