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At least 127 records · Page 7

Characterizing Hazardous Gases from NMC811 Materials and Coin Cells with TGA and Tube-Furnace FTIR-MS Evolved-Gas-Analysis

Abuse testing is useful for informing the risks of different battery chemistries but has been limited to larger formats. This paper conducted thermal abuse tests at the smaller coin cell level to determine its relevance in specifying vent gas flammability and toxicity. A nitrogen purge carried the evolved gases into a parallel Fourier-transform infrared spectrometer (FTIR) and a mass spectrometer (MS) downstream of the tube furnace. The experimental system was validated by comparing evolved gas data for single components between the tube furnace system and a thermogravimetric analysis (TGA) instrument. Multiple samples were tested during validation, including CaCO3, electrolyte, delithiated NMC 811 cathode, and lithiated graphite anode. Temperature-resolved gas evolution of HF, CO2, CO, H2, and hydrocarbons from isolated components helped to characterize the emission sources. A previously unreported H2 generation mechanism was found. It was shown that the reduced NMC cathode acts as a catalyst to crack polypropylene-decomposed hydrocarbons into H2 at around 450 degrees C. It was also shown, while studying LiPF6 thermal decomposition, that using the tube furnace with a coin cell casing as the sample holder has some advantages for evolved-gas analysis of environmentally sensitive samples relative to testing in TGA instruments. After validation with single components, a fully charged NMC 811 coin cell was failed in the tube furnace. The measured evolved gases were found to be a combination of the species measured from the single component tests. H2 formation related to the reduced cathode was found to have greater abundance than H2 formed from the anode. Hydrogen fluoride emission factors and diethyl carbonate conversion emission factors assist in understanding the gaseous hazards for larger format cells.

25 ENERGY STORAGE↗

Wave Energy Converter Power Take-Off Modeling and Validation From Experimental Bench Tests

This article describes the implementation of a new numerical model of the power take-off system installed in the Monterey Bay Aquarium Research Institute wave energy converter, a device developed to provide power to various oceanic research missions. The simultaneous presence of hydraulic, pneumatic, and electrical subsystems in the power take-off system represents a significant challenge in forging an accurate model able to replicate the main dynamic characteristics of the system. The validation of the new numerical model is addressed by comparing simulations with the measurements obtained during a series of bench tests. Data from the bench tests show good agreement with the numerical model. The validated model provides deeper insights into the complex nonlinear dynamics of the power take-off system and will support further performance improvements in the future.

16 TIDAL AND WAVE POWER↗

Operation and Control of Electric Vehicle Charger with Enhanced Dynamic Performance Under Non-Ideal Grid Voltage Condition

This paper presents a three-phase electric vehicle charger connected to the grid, featuring multiple boost converters on the DC side, specifically designed to ensure smooth, oscillation-free power transfer during unsymmetrical voltage sags. Precise control mechanisms are implemented on the boost converter side to regulate both voltage and current on the electric vehicle side, thereby maintaining optimal charging conditions. The control architecture for both the grid-connected and boost converter components is based on the Lyapunov energy function, which is employed to achieve superior dynamic performance and stability. The system's robustness and reliability are demonstrated through its ability to maintain stable operation and efficient power transfer despite fluctuations in grid conditions. Furthermore, the implementation of Lyapunov-based control ensures rapid response and minimal energy loss, enhancing the overall efficiency of the system. To validate the effectiveness of this approach, a comprehensive model of the system was developed and tested using MATLAB/Simulink, with detailed computer simulations conducted across various significant case studies.

DC-DC boost converter↗

Adaptive Stiffness Power Take-Off System for a Hydraulic Hose-Pump Point Absorber Wave Energy Converter

Two crucial challenges faced in the design of ocean wave energy converters (WECs) are maintaining high capacity factors and remaining robust in everchanging, harsh ocean environments. This study introduces a novel mechanism for achieving reactive WEC control with a soft hydraulic power take-off, thereby addressing both challenges. The device of interest involves a hydraulic pump, constructed from a fluidic flexible matrix composite (F2MC), which is cyclically stretched by driving waves and pressurizes working fluid through a turbine-generator. This class of fiber-reinforced stretch hoses is established for ocean use as robust moorings and shock absorbers. The dynamic properties of the F2MC pump depend on internal pressure, which can be controlled by a continuously variable transmission between the turbine and generator, allowing the system to be adapted for better performance over a wide range of wave conditions. This work presents a dynamic model for operation and adaptive behavior of this power take-off system, experimentally validates components of the model, and performs dynamic simulations of the system that show increases in power production and capacity factor compared to non-adaptive operation for a variety of driving wave conditions. This work develops the basis for future large-scale experimental testing and controller design of this system.

Wave energy conversion, fluidic flexible matrix co↗

Defining Electrode-Level Metrics for Enabling Earth-Abundant, Mn-Rich Cathodes: A Technoeconomic Analysis of Experimental Materials

Manganese-rich oxides are attractive options as next-generation, earth-abundant cathodes and significant efforts are being directed toward commercial implementation. We report here an updated techno-economic analysis of the lithium- and manganese-rich (LMR) class of earth-abundant cathodes for electric vehicle applications. BatPaC modeling was used to define the cell-level metrics that must be met for these materials to be cost and energy competitive with the current commercial earth-abundant benchmark, LiFePO 4 , as well as anticipated variations such as LiMn 0.8 Fe 0.2 PO 4 . The model was used to evaluate a high-performance material from the literature and subsequently define R&D targets as the likely limits of practical performance for similar LMR systems. Experimental validation and BatPaC evaluation of an advanced, cobalt-free LMR cell system was also conducted. Results show that the advanced LMR cells come within ∼5% of the defined limits and exceed the energy of LiFe(Mn)PO 4 cells at a similar cost. Excellent cycle-life, low impedance, and low impedance rise were also achieved under the conditions tested and reveal that cobalt is not necessary to achieve high-performance LMR oxides. Although the analysis conducted herein reports on LMR cell systems, the methodology and target values defined for performance metrics easily extend to the evaluation of other systems under consideration as earth-abundant options.

Chen, Jiajun [Argonne National Laboratory (ANL), A↗

Semi-Annual Report for Horizontal Compact High Temperature Gas Reactor (HC-HTGR) Development during Performance Period April 2023 – September 2023

Horizontal Compact High Temperature Gas Reactor (HC-HTGR) is being designed by a multi-disciplinary team of nuclear, mechanical, and structural engineers under the support of a DOE-NE Advanced Reactor Demonstration Program’s Advanced Reactor Concepts-20 (ARC-20) award. The objective of this ARC-20 project is to deliver a conceptual design for the proposed HC-HTGR in 3 years and support its commercialization as a safe, low-cost HTGR. Argonne National Laboratory (Argonne) is responsible for the design and analysis of the reactor cavity cooling system (RCCS) as a safety system for passive decay heat removal of the reactor concept. Additionally, Argonne is providing analysis of the primary coolant system to ensure temperatures within the core remain below safety margins during steady-state and potential accident scenarios. This fourth semi-annual report summarized the progress made at Argonne on the two tasks during the second half of FY23. As a part of the RCCS design task, recent efforts have been made to complete a conceptual design of the RCCS for the HC-HTGR, including the design update of the water panel and system configuration favorable in point of view of fabrication and system operation. Design calculations were conducted under various heat load conditions to validate the system design. Transient simulations using RELAP5-3D were conducted to investigate system dynamics under transients of interest and to evaluate the system performance in the design condition. The results demonstrated the overall system feasibility that the RCCS design maintains structures temperatures lower than maximum allowable temperature with sufficient system inventory without any active heat sink. In the primary system thermal hydraulics task, the preliminary analysis was performed for a long term pressurized conduction cooldown (PCC) transient. This analysis used a combination of a fully resolved and coarse homogenized mesh to predict the temperature distribution for the steady-state initial condition and the PCC transient. The steady-state initial condition was determined using a fully resolved full core model with 3D solid to 1D fluid coupling. The fully resolved mesh was also used to model the first 20 seconds of the PCC. The temperature difference between fuel pins and the graphite matrix becomes minimal and the dominant heat transfer shifts to a larger scale radially towards the RCCS. After 20 seconds, a homogenized coarse mesh is used, greatly reducing the computational costs of the model. These results demonstrate that the core is designed to passively remove enough decay heat in a protected loss of primary coolant flow to prevent an unsafe rise of core temperatures.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Geothermal Heat Pump System Showcase: Short-Term Validation of Borehole Heat Exchanger Performance from Field Data to Numerical Modeling: Preprint

Since 2011, a geothermal heat pump (GHP) system has been operating to provide space heating and cooling for the Solar Radiation and Research Laboratory building at the National Laboratory of the Rockies (NLR) in Golden, Colorado. The system consists of 23 vertical boreholes, each extending to a depth of 300 ft (91 m), connected to 11 water-to-air heat pump units and four circulation pumps. Between fiscal years 2023 and 2025, additional power meters and temperature sensors were retrofitted to support detailed system performance assessment and model development. This study presents preliminary monitoring results and the development of an initial numerical model of the borehole heat exchanger field. The model incorporated site-specific geometry, ground thermal properties derived from thermal response tests, and ambient temperatures, and simulated system behavior over a representative operating day in September. Model predictions of outlet temperatures were compared against corresponding field measurements. Results showed that modeling initialized with a simplified linear subsurface temperature gradient presents systematic discrepancies in outlet temperature, whereas incorporating depth-resolved borehole temperature measurements for initialization yields substantially improved agreement with observations. The findings highlight the sensitivity of short-term predictive modeling to the representation of initial subsurface thermal conditions and underscore the value of high-resolution field measurements for model calibration and validation. These preliminary results inform ongoing efforts to extend the modeling framework to longer time horizons and to refine monitoring and modeling strategies that support the design guidance and operational optimization of GHP systems in research and commercial buildings.

15 GEOTHERMAL ENERGY↗

Summary for Z-Petawatt Laser Activities (CY2019)

The high-energy upgrade of the Z-Petawatt (ZPW) laser system involved a shot hiatus starting in October 2018 to allow the installation of full-aperture optics in the chain, including in the main amplifier section as well as in the branches associated with the ZPW compressor and co-injection (the narrowband nanosecond operating mode that is co-bored with Z-Beamlet). Laser shots resumed May 1 st , with most shots since being in the ns mode to reduce complexity (while conditioning optics and calibrating diagnostics) as well as to support experimental requests. To facilitate experimental needs while a final full-sized co-injection optic was prepared, a sub-apertured beam has been used for experimental applications and a full-apertured beam has been used to validate the system. In the latter case, the beam is directed to a large calorimeter placed before branching occurs to the ZPW compressor or co-injection. As of September 2019, full-aperture co-injection shots had ramped up to 960J in 2.3ns, with many cross-calibrations being used to map out a relative humidity dependency in the leaky diagnostic mirror. Several such cross-calibration shots have been done using a chirped pulse seed as well, verifying that the diagnostic calibrations are valid in both broadband and narrow-band modes. Summarizing, since May 1 st of 2019 when shots resumed, 93 full system shots were performed with the ZPW laser. This included 2 co-injection shots with ZBL into Z (in support of MagLIF), 26 Pecos gas cell shots (in support of MagLIF), 11 Conchas gas cell shots (in support of UXI applications development), 6 Jemez shots (in support of backlighter development), and 48 calorimeter shots (in support of validating the system performance). Of these 93 shots, 45 shots were in conjunction with ZBL.

43 PARTICLE ACCELERATORS↗

A comprehensive framework for validating simulation models of power system equipment using terminal measurements

Accurate simulation of power-plants is essential to the planning and operation of modern power grids. The current methods used to periodically check power-plant simulation models have many open questions about their limitations and accuracy. The research in this project explored using Monte-Carlo Experimentation (MCE) as a means for answering these important questions.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Field Validation of Electrochemical Water Filtration System on Open Loop Cooling Towers at Automotive Plants

Open loop cooling towers play a pivotal role in rejecting heat for chilled water systems serving industrial processes, heating, ventilation, and air conditioning loads. Exposure to outside conditions can present certain operating challenges to system performance including scaling, corrosion, and biological growth. These issues are mitigated through the use of effective cooling tower water filtration and treatment systems to reduce contaminants—along with other total suspended solids (TSS) and total dissolved solids (TDS)—in the system. The U.S. Department of Energy’s Industrial Efficiency and Decarbonization Office is interested in an electrochemical-based filtration system with the ability to remove TSS particulate down to 1 micron. The removal of finer particulates reduces the need for blowdown and, in turn, makeup water use and chemical treatment in the cooling tower. Additionally, the removal process can reduce fouling at the condensers, resulting in better heat exchange and energy savings. Two Industrial Technology Validation program projects validated the electrochemical water filtration system at the Toyota Motor Manufacturing, Mississippi plant in Blue Springs, Mississippi, and the Nissan Canton Vehicle Assembly Plant in Canton, Mississippi. Researchers found that installation of both systems resulted in water and chemical treatment savings with minimal impact on energy use.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A graph embedding‐based approach for automatic cyber‐physical power system risk assessment to prevent and mitigate threats at scale

Abstract Power systems are facing an increasing number of cyber incidents, potentially leading to damaging consequences to both physical and cyber aspects. However, the development of analytical methods for the study of large‐scale power infrastructures as cyber‐physical systems is still in its early stages. Drawing inspiration from machine‐learning techniques, the authors introduce a method inspired by the principles of graph embedding that is tailored for quantitative risk assessment and the exploration of possible mitigation strategies of large‐scale cyber‐physical power systems. The primary advantage of the graph embedding approach lies in its ability to generate numerous random walks on a graph, simulating potential access paths. Meanwhile, it enables capturing high‐dimensional structures in low‐dimensional spaces, facilitating advanced machine‐learning applications, and ensuring scalability and adaptability for comprehensive network analysis. By employing this graph embedding‐based approach, the authors present a structured and methodical framework for risk assessment in cyber‐physical systems. The proposed graph embedding‐based risk analysis framework aims to provide a more insightful perspective on cyber‐physical risk assessment and situation awareness for power systems. To validate and demonstrate its applicability, the method has been tested on two cyber‐physical power system models: the Western System Coordinating Council (WSCC) 9‐Bus System and the Illinois 200‐Bus System , thereby showing its advantages in enhancing the accuracy of risk analysis and comprehensiveness of situational awareness.

Sun, Shining↗

Oklo Sponsored Testing using PELICAN: System, Subchannel, and High-Fidelity Software Validation (Final CRADA Report)

Argonne National Laboratory (the Contractor), located in Lemont IL, and Oklo, Inc., (the Participant), headquartered in Santa Clara, CA, propose to enter into a Cooperative Research and Development Agreement (CRADA) to perform a gap analysis of thermal hydraulic data, perform prototypical fuel assembly pressure drop and cavitation model validation, generate the experimental data as well as the corresponding uncertainties for this matrix and, finally, develop the validation models with the Argonne system level code SAS4A/SASSYS-1, the Argonne subchannel analysis code DASSH, the Argonne high fidelity code Nek5000, and/or the Idaho National Laboratory code Pronghorn Subchannel. The work outlined below will significantly improve the experimental and validation database currently available for liquid metal fast reactors, thus making it a viable part of a comprehensive reactor design and licensing suite to be used by the participant.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Power-to-Gas Systems for Active Load Management at EV Charging Sites with High DER Penetration

Intermittent renewable systems and increasing electric vehicle (EV) penetrations increase load intermittency—and will require expensive distribution system infrastructure upgrades. Power-to-gas (P2G) systems are highly controllable loads that can be modulated to regulate the net load behind the meter. In this work, we present an active load management approach using P2G systems to regulate the net load for an EV charging station with high penetrations of renewable generation. The system also validates the feasibility of the proposed approach using a 750-kW electrolyzer operated with the distribution system in a real-time power-hardware-in-the-loop test. Finally, we evaluate the impact of the size of the P2G system on its ability to regulate the net load.

ADVANCED PROPULSION SYSTEMS,POWER TRANSMISSION AND↗

Residual Stress Measurements in Extreme Environments for Hazardous, Layered Specimens

In nuclear fuel plates of low-enriched U-10Mo (LEU) clad with aluminum by hot isostatic pressing (HIP), post-irradiation stresses arising during reactor shutdown are a major concern for safe reactor operations. Measurement of those residual stresses has not previously been possible because the high radioactivity of the plates requires handling only by remote manipulation in a hot cell. The incremental slitting method for measuring through-thickness stress profiles was modified, and a system for automated, remote operation was built and tested. Experimental modifications consisted of replacing electric-discharge machining (EDM) with a small end mill and strain-gauge measurements with cantilever displacement measurements. The inverse method used to calculate stresses was the pulse-regularization method modified to allow discontinuities across material interfaces. The new system was validated by comparing with conventional slitting on a depleted U-10Mo (DU) fuel plate. The new system was applied to two measurements each on six as-fabricated (pre-irradiation) LEU miniature fuel plates. Variations between the measurements at two locations in the same plate were strongly correlated with measured geometrical heterogeneity in the plate—a tilt in the fuel foil. Compressive stresses in the U-10Mo were shown to increase from 20 to 250 MPa as the ratio of aluminum thickness to U-10Mo thickness increased causing increased constraint during cooling. Faster cooling rates during processing also increased stress magnitudes. The measurements trends agreed with data in the literature from similar plates made with DU, which further validates the method. Because other methods are impractical in a hot cell, the modified slitting method is now poised for the first measurements of post-irradiation stresses.

36 MATERIALS SCIENCE↗

Experimental Validation of Models of a Hull-Based Tuned Mass Damper System for a Semisubmersible Floating Offshore Wind Turbine Platform

Floating offshore wind turbine designs can be further optimized if the controller and remaining systems are designed together, known as control co-design. To effectively perform control co-design, modeling tools predicting the influence of the control systems on the response of a system must be validated. This article presents an experimental validation that utilizes a scale model of a semisubmersible platform for an offshore wind turbine that is fitted with adjustable tuned mass dampers. These dampers can be tuned to attenuate either the hull-pitch resonance or the tower-bending resonance. The data from the experiment are used to validate state-of-the-art modeling tools. It is shown that the models capture the overall effects of the tuned mass dampers; however, some models overpredict the reduction in platform pitch motion when the dampers are tuned to the pitch resonance. The relative reduction in the tower-base bending moment is more consistently captured by the models when the dampers are tuned to the tower-bending resonance. However, there are significant differences in the absolute level of tower-base bending moment between the models and the experiment. Much of the differences observed are a consequence of the challenge with accurately predicting the baseline platform resonance motion and the tower-bending moment, which should be addressed in future modeling efforts.

17 WIND ENERGY↗

Scaling methodologies and similarity analysis for thermal hydraulics test facility development for water-cooled small modular reactor

Small modular reactors (SMRs) represent a promising option for providing clean and sustainable energy due to their potential for enhanced safety, reduced capital costs, and increased siting flexibility. However, new reactor systems require the development and operation of representative scaled-down test facilities to support the verification and validation of system computer codes and models. Here this study reviews the research on scaling methodologies and similarity principles pivotal in developing non-nuclear integral effects test and separate effects test facilities for water-cooled SMRs. The study focuses on a review of the scaling methods, similarity approaches, and possible challenges posed by the unique and compact design features of integral-pressurized water reactor-type SMRs, and their representative test facilities. This study also reviews previous research related to scaling and similarity methodologies and provides insights into design considerations for achieving prototypic conditions in test facilities. The findings and recommendations emphasize the broader impact of appropriate scaling and similarity principles to ensure meaningful and transferable results from non-nuclear test facilities to accelerate the safe and efficient deployment of next-generation water-cooled SMRs.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Energy performance analysis of smart wall system with switchable insulation and thermal storage capacity

The ever-increasing global energy demand and the issues caused by population growth and unsustainable energy resource usages have several environmental and economic impacts. The on-demand capability of dynamic wall systems with switchable insulation systems can contribute toward energy efficiency and reduced electric cost using "building-as-a-battery." In this paper, the performance of an exterior envelope system that employs a switchable insulation system is investigated. A COMSOL simulation was used to study the envelope performance under three switchable insulation locations in the wall system. The on and off switching cycle included insulating or conducting the exterior, interior, or both sides of the mass wall system. To validate the simulation work, an experimental test was conducted in climate chamber on a 4 × 8 in. wall system with identical wall components used in the COMSOL simulation. Results show a good agreement between the experiment and simulation results. The wall system with switchable insulation placed on the exterior side provided the highest interior inward heat flux when compared with the interior or split insulation. Also, an exterior switchable insulation system in addition to a thermal mass maintained a positive heat flow for more hours when the outdoor temperature was lower than the interior temperature.

Iffa, Emishaw↗