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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Nonlinear stability of solar type III radio bursts. I - Theory

A theory of the excitation of solar type III bursts is presented. Electrons initially unstable to the linear bump-in-tail instability are shown to rapidly amplify Langmuir waves to energy densities characteristic of strong turbulence. The three-dimensional equations which describe the strong coupling (wave-wave) interactions are derived. For parameters characteristic of the interplanetary medium the equations reduce to one-dimension. In that case the oscillating two-stream instability (OTSI) is the dominant nonlinear instability. OTSI is stabilized through the production of nonlinear ion density fluctuations that efficiently scatter Langmuir waves out of resonance with the electron beam. An analytical model of the electron distribution function is also developed which is used to estimate the total energy losses suffered by the electron beam as it propagates from the solar corona to 1 AU and beyond.

Smith, R. A.↗
DOE OSTI2018

AVANTech's Advanced Polymer Solidification for Radioactive and Mixed Waste Stabilization: Case Studies - 18571

This presentation describes recent developments in polymer technology, as well as summarizes several applications and the history of process improvements that simplify the process and improve the efficiency for stabilizing low and intermediate level radioactive and mixed radioactive/hazardous wastes. Polymer technology has been used successfully since the early 1990's to solidify and stabilize radioactive and mixed hazardous/radioactive waste at United States (US) Department of Energy (DOE), US Department of Defense (DOD), United Kingdom government sites, and at commercial nuclear power plants. It is an effective, efficient, and economical means of preparing waste for storage and disposal. Recently, polymer solidification has been combined with other waste pretreatment technologies, such as evaporator concentrate drying, to further enhance volume reduction and packaging efficiency. This presentation reviews applications of the technology and identifies waste streams where polymers have advantages over cement, vitrification, and other stabilization processes. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Role of mineral flotation technology in improving bitumen extraction from mined Athabasca oil sands—II. Flotation hydrodynamics of water‐based oil sand extraction

Abstract Bitumen flotation hydrodynamics in water‐based oil sand extraction is critically reviewed by comparing aeration of oil sand slurries with mineral flotation. The role of the two‐stage particle‐bubble attachment model in flotation is emphasized as a means to accelerate bitumen flotation recovery. It involves the generation of micro/nanobubbles and their frosting on hydrophobic bitumen droplets, followed by their attachment to a flotation‐size bubble via its coalescence with the nanobubbles frosted on the bitumen. Nanobubble generation by hydrodynamic cavitation demonstrates that the size of nanobubbles can be reduced, and the number of nanobubbles increased by fast liquid flow, intensified agitation, high dissolved gas content and surfactant concentration. The mechanism of pre‐existing gas nuclei in enhancing nanobubble generation by cavitation is utilized to produce a large volume of stabilized nanobubbles for practical flotation, by continuously recirculating the stream through a gas saturation tank or a cavitation tube. The aeration of oil sand slurries in hydrotransport pipelines is analyzed based on its similarity to dissolved air flotation. Bitumen extraction recovery increased significantly with the presence of nanobubbles in the system. The role of improved flotation hydrodynamics in bitumen recovery is briefly discussed in terms of the Suncor operation using flotation columns to process oil sand middling streams. Future research should be directed at understanding bitumen flotation kinetics, optimizing size ranges of nanobubbles for maximized flotation recovery, minimizing wearing of cavitation tubes in industrial operations, and intensifying the role of in‐situ nanobubble nucleation on hydrophobic particles/bitumen droplets in flotation, especially for bitumen extraction from underperforming oil sands.

Zhou, Joe Z.↗
DOE OSTI2025

Experimental Measurements of Soot and Soot Precursors of Sustainable Aviation Fuels

Sustainable Aviation Fuels (SAFs) are promising for decarbonizing the challenging-to-electrify aerospace sector and reducing yearly greenhouse gas emissions by thousands of tons. Developing predictive detailed chemical kinetic models for SAF (and traditional) fuel mixtures necessitates a robust experimental database to elucidate the intricate pyrolysis and oxidation chemistry of SAF fuel blend components. Two critical components of SAF surrogate mixtures are iso-dodecane isomers and trans-decalin. This report characterizes the structure of three slightly sooting, laminar, non-premixed, nitrogen-diluted Planar Mixing Layer Flames (PMLFs) fueled by either pure ethylene, ethylene doped with 1500ppm of either 2,2,4,6,6-pentamethyl-heptane or trans-decalin. The flames have the same stoichiometric mixture fraction and total mole fraction of fuels in the fuel stream (X F,F = X C2H4,F + X Dopant,F = 0.26), resulting in approximately the same maximum temperature (T max ≈ 1800 K) to highlight the effect of doping on soot and its gaseous precursors. The PMLF is unconfined and established between adjacent planar jets of the fuel and oxidizer streams surrounded by annular shielding nitrogen. The flow is stabilized by exhausting the hot buoyant flame products through a slot in a downstream plate onto which the cold flow impinges. Importantly, any horizontal cross-section of the PMLF has a self-similar thermochemical structure of a reactive boundary layer that grows at increasing Height Above the Burner (HAB). Therefore, the horizontal cross-sections of a PMLF can be modeled as a One-Dimensional Counterflow Flame (1D-CF) with very low strain rates which are unachievable in traditional CFs and yield a structure that is several millimeters thick. In brief, the PMLF is ideal for performing spatially resolved measurements with minimal effects of the sampling-induced perturbations, to develop and validate detailed chemical kinetic models on time scales of a few tens of milliseconds that are relevant in aviation applications. The horizontal profiles of C0-C18 gaseous species at HAB = 50 mm and soot volume fraction at 25 and 50 mm are measured using capillary sampling followed by GC-MS analyses and Laser Induced Emission Spectroscopy (LIES), respectively. Additionally, the Elastic Laser Light Scattering (E-LLS) coefficient is measured at HAB = 50 mm and 25 mm to determine the strain rates of the 1D-CFs equivalent to the characterized PMLF horizontal cross sections and the profile of the E-LLS equivalent diameter of soot. The comparison of the results in the base PMLF fueled only by ethylene with those in either doped PMLF in which 1500 ppm of ethylene are replaced with 2,2,4,6,6-pentamethyl-heptane or trans-decalin, reveals that the doping increases the mole fraction of several Polycyclic Aromatic Hydrocarbons (PAHs) at both HABs by a factor of approximately 2.5, and the soot volume fraction at both HABs by factors of ~1.5 for 2,2,4,6,6-pentamethyl-heptane and ~1.25 for trans-decalin doping, respectively. Conversely, doping causes a near doubling of the soot equivalent diameter only at HAB = 50 mm, without significant effects at 25 mm. The experimental results partially validate the tested state-of-the-art detailed chemical kinetic model and also point toward the further improvement of its predictive capabilities.

10 SYNTHETIC FUELS↗
NASA NTRS1990

Linear instability of the supersonic wake behind a flat plate aligned with a uniform stream

A theoretical and numerical study is presented of the growth of linear disturbances in the laminar compressible supersonic wake behind a flat plate aligned with a uniform stream. The approach adopted is that of classical linear stability theory and covers both two- and three-dimensional disturbances. The basic flow is described, and the linear stability problem is formulated that leads to the compressible Rayleigh equation. The stability of short-wave disturbances is then analyzed in the very near wake where the compressible analog of the Goldstein double structure provides an asymptotic description for the unperturbed flow. The behavior of long waves is then considered. The waves are not as long as the plate length but are long compared to the boundary-layer thickness. Numerical solutions of the Rayleigh equation are discussed. Numerical results are then presented for a range of streamwise stations, Mach numbers, and wave propagation angles.

Papageorgiou, D. T.↗
NASA NTRS1994

Large and small scale circulation signatures of the ERS-1 SAR over the Gulf Stream

Since September 1991, the ERS-1 SAR (Synthetic Aperture Radar) has collected approximately 170 frames of ocean imagery on 28 passes over the western Gulf Stream in support of ESA experiment US8-2c. SAR signatures of the north wall are seen on nearly all passes, with modulation depth varying from 3% to 35% for 100 m samples. Many small and mesoscale circulation features associated with the Stream are evident. The detailed form of the signature varies considerably, however. Narrow bright or dark linear features appear to follow streamlines, and on one occasion a strong dark line was associated with an in situ measurement of a sharp current shear. Similarly, larger spatial scale changes in backscatter over the Stream were associated with in situ measurements of atmospheric stability transitions. Physical explanations for the narrow features are not so obvious. However, the accumulation of surfactants along converging current boundaries or local short wave straining and breaking appear plausible. These preliminary results strongly suggest that a wide swath (approximately 500 km) SAR with at least 100 m resolution would be a useful adjunct to existing satellite AVHRR (Advanced Very High Resolution Radiometer) imagery.

Beal, R.↗
NASA NTRS1968

Inhomogeneous two-stream instability.

Two oppositely charged particle beams interaction instability in cold plasma, discussing stabilization by periodic electrostatic potential

Knorr, G.↗
NASA NTRS1991

Stability of compressible reacting mixing layer

Linear instability of compressible reacting mixing layers is analyzed with emphasis on the effects of heat release and compressibility. Laminar solutions of the compressible boundary-layer equations are used as the base flows. The parameters of this study are the adiabatic flame temperature, the Mach number of the upper stream, frequency, wavenumber, and the direction of propagation of the disturbance wave. Stability characteristics of the flow are presented. Three groups of unstable modes are found when the Mach number and/or heat release are large. Finally, it is shown that the unstable modes are two-dimensional for large heat release even in highly compressible flow.

Shin, D. S.↗
DOE OSTI2025

Effect of Fe on Co-Based SiO2Al2O3 Mixed Support Catalyst for Fischer–Tropsch Synthesis in 3D-Printed SS Microchannel Microreactor

This research explores the effect of a composite support of SiO2 and Al2O3 with Fe and Co incorporated as catalysts for Fischer–Tropsch synthesis (FTS) using a 3D-printed stainless steel (SS) microchannel microreactor. Two mesoporous catalysts, FeCo/SiO2Al2O3 and Co/SiO2Al2O3, were synthesized via a one-pot (OP) method and extensively characterized using N2 physisorption, XRD, SEM, TEM, H2-TPR, TGA-DSC, FTIR, and XPS. H2-TPR results revealed that the synthesis method significantly affected the reducibility of metal oxides, thereby influencing the formation of active FTS sites. SEM-EDS and TEM further revealed a well-defined hexagonal matrix with a porous surface morphology and uniform metal ion distribution. FTS reactions, carried out in the 200–350 °C temperature range at 20 bar with a H2/CO molar ratio of 2:1, exhibited the highest activity for FeCo/SiO2Al2O3, with up to 80% CO conversion. Long-term stability was evaluated by monitoring the catalyst performance for 30 h on stream at 320 °C under identical reaction conditions. The catalyst was initially active for the methanation reaction for up to 15 h, after which the selectivity for CH4 declined. Correspondingly, the C4+ selectivity increased after 15 h of time-on-stream, indicating a shift in the product distribution toward longer-chain hydrocarbons. This trend suggests that the catalyst undergoes gradual activation or restructuring under reaction conditions, which enhances chain growth over time. The increase in C4+ products may be attributed to the stabilization of the active sites and suppression of methane or light hydrocarbon formation.

Biochemistry & Molecular Biology↗
NASA NTRS2014

Designing Liquid Rocket Engine Injectors for Performance, Stability, and Cost

NASA is using computational fluid dynamics (CFD) simulations to lower the cost and increase the performance and stability of fuel injector designs for next-generation liquid rocket engines (LREs). The Loci-STREAM CFD code is used to simulate the complex combustion processes inside the LRE. These analyses enable efficient evaluation of the performance and stability characteristics of injector design concepts, while decreasing reliance on the costly test-fail-fix cycle of traditional design approaches. These injector simulations were recently employed as a key part of the design process for an Advanced Booster concept for NASA's heavy-lift Space Launch System (SLS).

Westra, Douglas G.↗
NASA NTRS1992

Computational study of transition front on a swept wing leading-edge model

The e(N) method is employed with Navier-Stokes calculations to study 3D supersonic boundary layers at the leading-edge region of swept wings with attention given to the conditions for linear stability. Mean-flow profiles are computed as solutions to the Navier-Stokes equations, and the e(N) method is used to identify the onset of the transition. Specific treatment is given to the identification of parameters which affect the transition such as free-stream Reynolds number, wall cooling, and boundary-layer suction levels. The boundary layer can be stabilized to below N=10 levels in all locations by utilizing distributed suction, and enhanced stabilization can also be achieved by employing wall cooling and reduced free-stream Reynolds numbers. This study presents key calculations for corresponding experimental investigations by shedding light on requirements for test conditions and measurement requirements.

Iyer, Venkit↗
NASA NTRS1991

Boundary layer stability and transition to turbulence; Proceedings of the Symposium, ASME and JSME Joint Fluids Engineering Conference, 1st, Portland, OR, June 23-27, 1991

The papers presented at the conference provide an overview of current research related to the mechanisms of the laminar-turbulent transition. The principal topics discussed include receptivity, bypass mechanisms, curvature, three-dimensionality, nonlinearities, breakdown, and control. Papers are included on linear and nonlinear receptivity to vortical free-stream disturbances; initiation of boundary-layer disturbances by nonlinear mode interactions; stability and transition to turbulence of thin liquid film flow along a rotating disk; and turbulent intermittency measurements for turbomachinery flows.

Reda, D. C.↗
DOE OSTI2024

Dynamic Behavior of Pt Multimetallic Alloys for Active and Stable Propane Dehydrogenation Catalysts

Improving the use of platinum in propane dehydrogenation catalysts is a crucial aspect to increasing the efficiency and sustainability of propylene production. A known and practiced strategy involves incorporating more abundant metals in supported platinum catalysts, increasing its activity and stability while decreasing the overall loading. Here, using colloidal techniques to control the size and composition of the active phase, we show that Pt/Cu alloy nanoparticles supported on alumina (Pt/Cu/Al 2 O 3 ) displayed elevated rates for propane dehydrogenation at low temperature compared to a monometallic Pt/Al 2 O 3 catalyst. We demonstrate that the enhanced catalytic activity is correlated with a higher surface Cu content and formation of a Pt-rich core and Cu-rich shell that isolates Pt sites and increases their intrinsic activity. However, rates declined on stream because of dynamic metal diffusion processes that led to a more uniform alloy structure. This transformation was only partially inhibited by adding excess hydrogen to the feed stream. Instead, cobalt was introduced to provide trimetallic Pt/Cu/Co catalysts with stabilized surface structure and stable activity and higher rates than the original Pt/Cu system. In conclusion, the structure–activity relationship insights in this work offer improved knowledge of propane dehydrogenation catalyst development featuring reduced Pt loadings and notable thermal stability for propylene production.

Alloys↗
DOE OSTI2022

Inorganometallic Catalyst Design Center (ICDC) EFRC Accomplishments

The ICDC focused largely on heterogeneous catalysis of oxidative chemical transformations, especially those that came to prominence as natural gas (wet shale gas) supplanted crude oil as the primary feedstock in North America for carbon-based manufacturing of commodity chemicals. Driven by fracking-enabled access to enormous stores of shale-trapped wet gas, the feedstock change from oil to gas enabled a shift away from high-temperature catalytic breakdown of large hydrocarbons to catalytic build-up of C4, C3, C2, and C1 into desired intermediates, but now at much more modest temperatures. In turn, the much lower thermal force accompanying these kinds of reactions facilitates catalyst stabilization and characterization, including operando characterization, while slowing on-stream catalyst evolution (i.e., preserving catalyst structure), accommodating catalyst complexity, and enabling creation of uniform arrays of heterogeneous catalysts with single-atom or near-single-atom precision—at least for model systems. Together these features have proven to be a boon to hypothesis-driven catalysis science and to experimentally testable computation-based design advances and mechanism explication. The ICDC has greatly facilitated the integration of catalyst synthesis, advanced characterization, performance assessment, and computational elucidation—with advances in each of these realms spurring achievements in catalysis science and complementary realms.

03 NATURAL GAS↗
NASA NTRS1987

Force, mass, and energy budgets of the Crary Ice Rise complex, Antarctica

The stress, mass, and energy-dissipation budgets of Crary Ice Rise are analyzed using field data collected during the 1983-1985 austral summers and in previous field programs. In addition, the net back pressure and ice-discharge rate along the grounding lines of ice streams are calculated to assess the effect of the ice rise on the surrounding flow. Comparison of the ice-rise budgets with the analysis of grounding-line data confirms the influence of the ice rise on ice-sheet stability, and suggests that Crary Ice Rise may have formed recently in response to an acceleration of one of the ice streams. It is concluded that feedback between ice-stream acceleration and ice-rise formation may control the future evolution of the above ice stream and promote long-term grounding-line stability in the face of strong natural fluctuations.

Macayeal, D. R.↗
NASA NTRS1996

The stability of compressible mixing layers in binary gases

We present the results of a study of the inviscid two-dimensional spatial stability of a parallel compressible mixing layer in a binary gas. The parameters of this study are the Mach number of the fast stream, the ratio of the velocity of the slow stream to that of the fast stream, the ratio of the temperatures, the composition of the gas in the slow stream and in the fast stream, and the frequency of the disturbance wave. The ratio of the molecular weight of the slow stream to that of the fast stream is found to be an important quantity and is used as an independent variable in presenting the stability characteristics of the flow. It is shown that differing molecular weights have a significant effect on the neutral-mode phase speeds, the phase speeds of the unstable modes, the maximum growth rates and the unstable frequency range of the disturbances. The molecular weight ratio is a reasonable predictor of the stability trends. We have further demonstrated that the normalized growth rate as a function of the convective Mach number is relatively insensitive (Approx. 25%) to changes in the composition of the mixing layer. Thus, the normalized growth rate is a key element when considering the stability of compressible mixing layers, since once the basic stability characteristics for a particular combination of gases is known at zero Mach number, the decrease in growth rates due to compressibility effects at the larger convective Mach numbers is somewhat predictable.

Kozusko, F.↗
NASA NTRS1991

Effect of heat release on the stability of compressible reacting mixing layer

Reacting free shear layers are of fundamental importance in many industrial systems including gas turbine combustors and rockets. Efficient propulsion systems are essential for air breathing supersonic ramjets in the high Mach number range. A limiting factor in these engines is the time for fuel and oxidizer to mix in the combustion chamber; for fast mixing, the flow must be vigorously turbulent which requires the laminar flow to be unstable. Understanding the stability characteristics of compressible reacting free shear layers is, therefore, very important and may allow one to control the flow. Low speed shear layers are highly unstable but, as chemical reaction and compressibility effects tend to stabilize them, it is important to investigate the stability of high speed reacting mixing layers. The latter consists of two fluid streams containing fuel and oxidizer respectively, and the conclusions are expected to apply, with quantitative modifications, to other shear flows, e.g., jets. Since low speed reacting cases have been studied earlier, we concentrate on the effects of Mach number and heat release. We are primarily interested in solving the stability problem over a large range of Mach number and heat release. In order to understand the effect of the heat release on the stability of this flow, one must first study the characteristics of the non-reacting flow. Inviscid theory is a reliable guide for understanding stability of compressible shear flows at moderate and large Reynolds numbers and is the basis for this work.

Shin, Dong-Shin↗