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At least 127 records · Page 7

Specific heats and thermodynamic critical fields in Zn-doped YBa2Cu3O(7-x) according to an induced-pairing model

Electronic specific heats and thermodynamic critical fields are calculated in a mean-field version of an induced-pairing model for superconductivity, and compared with results of Loram et al. (1990) on YBa2(Cu(1-y)Zn(y))3O(7-x). This model involves induction of pairing of holes in a wideband by strongly bound electronlike pairs. It is assumed that the planar hole concentration for no Zn addition is close to, but slightly higher than, that for the maximum Tc, and that it increases by 0.015 per planar Cu ion for each increase of y by 0.01. Parameters of the model are taken to be the same as in a previous publication in which energy gaps were discussed, except that an effective hybridization parameter is adjusted for each Zn concentration to give agreement with the observed Tc. Results are presented for y = 0.0, 0.01, and 0.03. The agreement with experiment is good for thermodynamic critical fields, and is fair for specific heats. For specimens with larger y, with relatively low T(c)s, it is argued that the model should be supplemented to include effects of a BCS-type interaction amongst the wideband carriers.

Eagles, D. M.↗

Performance of large inert-gas thrusters

The performance of large inert-gas thrusters is predicted based on present knowledge of ion optics performance and discharge chamber operation. Calculated performance data are given for argon and xenon propellants. The effect of varying propellant utilization and thruster diameter is discussed and the optimum choice of beam diameter for very large systems is indicated for low, intermediate, and high specific impulses. Optimum discharge chamber depths are also specified. Although detailed design considerations may modify the predictions, the general trends indicated should still be useful for directing future technology efforts and evaluating mission studies involving large thrusters.

Kaufman, H. R.↗

Alteration of an annealed and irradiated lunar fines sample by adsorbed water

Apollo 12 lunar fines sample 12070,403 was annealed at 1000 C and subsequently irradiated with a beam of 130 MeV Fe(9+) ions. Adsorptions of nitrogen and water were measured before and after the irradiation. Prior to the irradiation, the fines were nonporous and water had no effect on the physical characteristics of the lunar fines. In contrast, after the irradiation, the interaction with water caused an increase in the specific surface area and created a pore system. These results are definitive evidence that the interaction of water with damage tracks is the prime factor involved in the alteration of lunar fines by adsorbed water.

Holmes, H. F.↗

A Multi-Sims Investigation of Water Content and D/H Ratios in Roberts Massif 04262 with Insight to Sources of Hydrogen in Maskelynite

We want to define the H2O content ([H2O]) and hydrogen (H) isotope composition of meteoritic material from Mars [1-3] with motivation to understand Mars’ volatile history, constrain geochemical signatures of interior water reservoirs (i.e. the Martian mantle) and explore effects of planetary (e.g. planet formation, magma ocean degassing) and local (e.g. volcanic degassing, impact melting and degassing) processes on H incorporated in minerals. Secondary ion mass spectrometry (SIMS) allows multiple avenues to address these questions. However, application to (1) precious astromaterials and (2) low level H measurements, pose specific challenges that are further complicated when combined. We present preliminary data of a multi-approach (SIMS vs. NanoSIMS) study of H in Roberts Massif 04262 (RBT 04262), an enriched lherzolitic shergottite with nonpoikilitic (NP) and poikilitic (P) lithologies [4]. We analyze olivine, pyrox-ene, and melt inclusions to compare indigenous mantle water, with impact-generated maskelynite to investigate H signatures due to shock.

Dudley, J. M.↗

Dose- and Ion-Dependent Effects in the Oxidative Stress Response to Space-Like Radiation Exposure in the Skeletal System

Exposure to space radiation may pose a risk to skeletal health during subsequent aging. Irradiation acutely stimulates bone remodeling in mice, although the long-term influence of space radiation on bone-forming potential (osteoblastogenesis) and possible adaptive mechanisms are not well understood. We hypothesized exposure to ionizing radiation impairs osteoblastogenesis in an ion-type specific manner, with low doses capable of modulating expression of redox-related genes. 16-week old, male, C57BL6/J mice were exposed to low linear-energy-transfer (LET) protons (150 mega electron volts per nucleon) or high-LET (sup 56) Fe ions (600 mega electron volts per nucleon) using either low (5 or 10 centigrays) or high (50 or 200 centigrays) doses at NASAs Space Radiation Lab at Brookhaven National Lab (NSRL/BNL). Tissues were harvested 5 weeks or 1 year after irradiation and bones were analyzed by microcomputed tomography for cancellous microarchitecture and cortical geometry. Marrow-derived, adherent cells were grown under osteoblastogenic culture conditions. Cell lysates were analyzed for select groups by RT-PCR (Reverse Transcription-Polymerase Chain Reaction) during the proliferative phase or the mineralizing phase, and differentiation was analyzed by imaging mineralized nodules (percentage surface area). Representative genes were selected for expression analyses, including cell proliferation (PCNA, Cdk2, p21, p53), differentiation (Runx2, Alpl, Bglap), oxidative metabolism (Catalase, GPX, MnSOD, CuZnSOD, iNos, Foxo1), DNA-damage repair (Gadd45), or apoptosis (Caspase 3). As expected, a high dose (200 centigrays), but not low doses, of either (sup 56) Fe or protons caused a loss of cancellous bone volume per total volume. Marrow cells produced mineralized nodules ex vivo regardless of radiation type or dose; (sup 56) Fe (200 centigrays) inhibited median nodule area by more than 90 percent at 5 weeks and 1 year post-irradiation, compared to controls. At 5 weeks post exposure, irradiation with protons or (sup 56) Fe caused few changes in gene expression levels during osteoblastogenesis, although a high dose of (sup 56) Fe (200 centigrays) increased levels of Catalase and Gadd45. In addition, supplementing cell culture media with SOD protected marrow-derived osteoprogenitors from the damaging effects of exposure to low-LET ((sup 137) Cs gamma) if irradiated in vitro, but had limited protective effects on high-LET (sup 56) Fe-exposed cells. In sum, exposure of mice to either protons or (sup 56) Fe at a relatively high dose (200 cGy) caused persistent bone loss, whereas only high-LET (sup 56) Fe increased expression of redox-related genes and inhibited osteoblastogenesis, albeit to a limited extent. We conclude that high-LET irradiation impaired osteoblastogenesis and regulated steady-state gene expression of select redox-related genes during osteoblastogenesis, which may contribute to persistent bone loss.

ionizing radiation↗

One Million Newton-Second Duration Test of a 600 Watt Hall Effect Thruster Fueled By Xenon

A Hall Effect Thruster fueled by xenon was duration tested for7,198 hours at NASA’s Glenn Research Center.The thruster generated 1 million Newton-seconds of total impulse before the test was terminated voluntarily. Thrust, flow rate, and many other parameters were tracked continuously. Over 98.5% of the test was conducted at a single operating point, where the discharge power was 600 W, mean thrust was 39 mN and mean specific impulse was 1500 s. The shape of the discharge channel was measured via laser profilometery. The shape changed considerably over the course of the test, due to ion sputtering. However, the standard deviation of the thrust and specific impulse measurements at the nominal operating point was less than 1%. Evolution of the plasma plume was measured with a Faraday probe mounted upon a rotating arm. Plume divergence decreased over the course of the test

Electric Propulsion↗

Incoherent scatter radar observations of irregular structure in mid-latitude sporadic E layers

The basic experiments used phase-coded pulses to record electron density profiles with a resolution of 600 m in range and 300 m in horizontal extent, while scanning in azimuth. Data from incoherent scatter radar were compared with simultaneous ionosonde observations. Observations of sporadic E layers by incoherent scatter radar were discussed in terms of the effects of the neutral wind system acting on metallic ions. Several features were noted in the data, which support the wind shear mechanism of layer formation. The sporadic E layers often contained a pronounced small-scale structure, especially at times when partially transparent echoes were observed by the ionosonde. Under specific conditions, the ions in a meteor trail can be converged by a shear in the neutral wind into a relatively small irregularity at the center of a sporadic E layer.

Miller, K. L.↗

Radiation enhanced dissociation of hydrogen in nuclear rockets

The effect of radiation-induced dissociation of hydrogen gas in nuclear rockets is studied. The dissociation degree is obtained by solving rate equations, which include the fast-ion induced dissociation and ionization of atomic and molecular hydrogens. Analytical formulas are used to estimate a change in the viscosity and the specific impulse. It was found that the fast-ion induced dissociation plays an important role in enhancing the specific impulse for nuclear rocket concepts using hydrogen gas at low pressures (less than 0.1 MPa) and low temperatures (less than 3000 K). It is also shown that the specific impulse is enhanced by mixing helium-3, lithium-6, boron-10, or uranium-235 with hydrogen.

Watanabe, Yoichi↗

Sub-Micrometer Scale Minor Element Mapping in Interplanetary Dust Particles: A Test for Stratospheric Contamination

Combined X-ray microprobe (XRM), energy dispersive x-ray fluorescence using a Transmission Electron Microscope (TEM), and electron microprobe measurements have determined that the average bulk chemical composition of the interplanetary dust particles (IDPs) collected from the Earth s stratosphere is enriched relative to the CI meteorite composition by a factor of 2 to 4 for carbon and for the moderately volatile elements Na, K, P, Mn, Cu, Zn, Ga, Ge, and Se, and enriched to approximately 30 times CI for Br. However, Jessberger et al., who have reported similar bulk enrichments using Proton Induced X-ray Emission (PIXE), attribute the enrichments to contamination by meteor-derived atmospheric aerosols during the several weeks these IDPs reside in the Earth s atmosphere prior to collection. Using scanning Auger spectroscopy, a very sensitive surface analysis technique, Mackinnon and Mogk have observed S contamination on the surface of IDPs, presumably due to the accretion of sulfate aerosols during stratospheric residence. But the S-rich layer they detected was so thin (approximately 100 angstroms thick) that the total amount of S on the surface was too small to significantly perturb the bulk S-content of a chondritic IDP. Stephan et al. provide support for the contamination hypothesis by reporting the enrichment of Br on the edges of the IDPs using Time-of-Flight Secondary-Ion Mass-Spectrometry (TOFSIMS), but TOF-SIMS is notorious for producing false edge-effects, particularly on irregularly-shaped samples like IDPs. Sutton et al. mapped the spatial distribution of Fe, Ni, Zn, Br, and Sr, at the approximately 2 m scale, in four IDPs using element-specific x-ray fluorescence (XRF) computed microtomography. They found the moderately volatile elements Zn and Br, although spatially inhomogeneous, were not concentrated on the surface of any of the IDPs they examined, suggesting that the Zn and the Br enrichments in the IDPs are not due to contamination during stratospheric residence.

Flynn, G. J.↗

Characterization of hollow cathode, ring cusp discharge chambers

An experimental study into the effects of changes in such physical design parameters as hollow cathode position, anode position and ring cusp magnetic field configuration and strength on discharge chamber performance, is described. The results are presented in terms of comparative plasma ion energy cost, extracted ion fraction and ion beam profile data. Such comparisons are used to demonstrate specific means by which changes in these design parameters induce changes in performance, i.e., through changes in the loss rates of primary electrons to the anode, of ions to discharge chamber walls or of ions to cathode and anode surfaces. Results show: (1) the rate of primary electron loss to the anode decreases as the anode is moved downstream of the ring cusp toward the screen grid, (2) the loss rate of ions to hollow cathode surfaces are excessive if the cathode is located upstream of a point of peak magnetic flux density on the discharge chamber centerline, and (3) the fraction of the ions produced that are lost to discharge chamber walls and ring magnet surfaces is reduced by positioning the magnet rings so the plasma density is uniform over the grid surface and so there are no steep magnetic flux density gradients near the walls through which ions can be lost by Bohm diffusion. The uniformity of the plasma density at the grids can also be improved by moving the point of primary electron injection into the discharge chamber off of the chamber centerline. Other results show the discharge chamber losses decrease when a filament cathode is substituted for a hollow cathode to the extent of the hollow cathode operating power. When plasma ion energy cost is determined in such a way that the cost of operating the hollow cathode is subtracted out, the performance using either electron source is similar.

Vaughn, Jason A.↗

Modeling the effects of fast shocks on solar winds ions

Observations show that, when alpha particles and other minor ions in the solar wind plasma encounter fast shocks, they are heated more than protons and their bulk motion is decelerated less than protons. These effects have been studied using a three-fluid model, and the model predictions have been compared with observations. The comparison indicates that, for supercritical fast shocks, the three-fluid model can explain cross-shock minor ion heating which is significantly greater than that of protons. When the ratio of specific heats for minor ions, gamma (alpha), equals 2, both the lesser cross-shock deceleration and the greater heating of minor ions than of protons can be predicted by the model; thus, the minor ion heating through the shock transition region is consistent with the involvement of two degrees of freedom. Because the analysis is formulated in the de Heffmann-Teller frame of reference, the method is not valid for perpendicular shocks or when the angle is large. These results agree with the few extant observations and might be confirmed by further observations at the earth's bow shock.

Zhao, Xuepu↗

Long-term effects of acute irradiation and isolation on crew age-matched mice

The future of space missions beyond low-Earth orbit presents exciting opportunities but may come with formidable health challenges. Astronauts face a unique combination of space stressors capable of exerting effects on the central nervous system (CNS) with possible sex-dependent differences. The interaction of these combined spaceflight stressors may induce oxidative stress, thereby altering brain integrity and behavioral performance. Understanding these changes is critical for safeguarding astronaut health and enabling successful exploration. By understanding the physiological responses to the combined effects of ionizing radiation (IR) and social isolation in the brain through immunohistochemistry (IHC), proteomics and cytokine expression analyses, we aim to identify CNS pathways ripe for countermeasure development to mitigate adverse brain changes with future deep space exploration. Here, we study the combined effects of simulated 5-ion galactic cosmic radiation (GCRsim) at acute dosage (5, 15, and 50 cGy) and social isolation on crew age-matched male and female mice at 124 days post-irradiation. We conducted analyses of hippocampal cytokine biomarkers and proteomic profiling on hippocampal lysates. Our findings reveal sex-specific regulation of hippocampal cytokines and proteomic profiles. Ongoing immunohistochemistry findings on the hippocampus will provide qualitative information regarding key protein expression and cellular changes such as microglial activation, blood brain barrier integrity, and neuroinflammation. With future plans for long-duration space missions, such as Mars exploration, understanding CNS changes over extended periods in mice can provide insights into potential long-term health impacts on astronauts. This project will provide us with valuable insights into sex-differences in neurobiological processes and disease mechanisms impacting men and women in space.

space radiation↗

Valence State Partitioning of V between Pyroxene and Melt for Martian Melt Compositions Y 980459 and QUE 94201: The Effect of Pyroxene Composition and Crystal Structure

A spiked (with REE, V, Sc) martian basalt Y980459 composition was used to synthesize olivine, spinel, and pyroxene at 1200 C at 5 oxygen fugacities: IW-1, IW, IW+1, IW+2, and QFM. The high spike levels for REE were used for two specific reasons. First, we wanted to be able to analyze REE by both electron microprobe and ion probe. Second, we wanted the most important "Others" components, (i.e., those outside the pyroxene quadrilateral such as Al, Cr3+, Fe3+, REE3+, V3+, V4+, etc.) to be REE3+Mg (Si,Al)2O6. At the doped levels we used, the most important "Others" component is REE3+ in the M2 site coupled with Al in the tetrahedral site. The goal of this paper is to explain the significant increase in the value of D(sub V)(sup pyroxene/melt) with increased Wo content of the pyroxene. We compare augite (Wo approx. 33), pigeonite (Wo approx. 13) and orthopyroxene (Wo approx 3.8). We also show olivine for comparison. The crystal chemical factors which account for this remarkable increase of DV with Wo are twofold. First, with Ca in the M2 site (as in diopside, CaMgSi2O6) the site is large and 8-coordinated while Mg in the M2 site (as in enstatite, Mg2Si2O6) the site is smaller and 6- coordinated. Second, tetrahedral Al in the pyroxene chains provides charge balance and makes the M2 site larger and more compliant for the introduction of REE.

Papike, J. J.↗

Holographic fabrication of gratings in metal substrates

A program for investigating the grain enlargement resulting from the laser recrystallization of a thin gallium arsenide film on a patterned substrate, a technique known as graphoepitaxy was evaluated. More specifically, the effects of recrystallizing an uncapped gallium arsenide film using a continuous wave neodymium YAG laser operating at 1.06 microns were studied. In an effort to minimize arsenic loss from the film, the specimens were held in an arsine atmosphere during recrystallization. Two methods for fabricating patterned substrates were developed, one using reactive ion etching of a molybdenum film on both sapphire and silicon substates and another by preferential wet etching of a silicon substrate onto which a film of molybdenum was subsequently deposited.

Fletcher, R. M.↗

Method of reducing the green density of a slip cast article

The method disclosed in this specification is one of reducing the green density of an article cast in a slip casting operation. The article is cast from a casting slip containing silicon metal particles, yttrium containing particles, and a small amount of a fluoride salt which is effective to suppress flocculation of the silicon metal particles by y.sup.+3 ions derived from the yttrium containing particles. The method is characterized by the following step. A small amount of compound which produces a cation which will partly flocculate the particles of silicon metal is added to the casting slip. The small amount of this compound is added so that when the casting slip is slip cast into a casting mold, the partly flocculated particles of silicon will interrupt an otherwise orderly packing of the particles of silicon and particles of yttrium. In this manner, the green density of the slip cast article is reduced and the article may be more easily nitrided.

Mangels, John A.↗

Process Control for Precipitation Prevention in Space Water Recovery Systems

The ability to recover and purify water through physiochemical processes is crucial for realizing long‐term human space missions, including both planetary habitation and space travel. Because of their robust nature, rotary distillation systems have been actively pursued by NASA as one of the technologies for water recovery from wastewater primarily comprised of human urine. A specific area of interest is the prevention of the formation of solids that could clog fluid lines and damage rotating equipment. To mitigate the formation of solids, operational constraints are in place that limits such that the concentration of key precipitating ions in the wastewater brine are below the theoretical threshold. This control in effected by limiting the amount of water recovered such that the risk of reaching the precipitation threshold is within acceptable limits. The water recovery limit is based on an empirically derived worst case wastewater composition. During the batch process, water recovery is estimated by monitoring the throughput of the system. NASA Johnson Space Center is working on means of enhancing the process controls to increase water recovery. Options include more precise prediction of the precipitation threshold. To this end, JSC is developing a means of more accurately measuring the constituent of the brine and/or wastewater. Another means would be to more accurately monitor the throughput of the system. In spring of 2015, testing will be performed to test strategies for optimizing water recovery without increasing the risk of solids formation in the brine.

Sargusingh, Miriam↗

Entropy and charge in molecular evolution--the case of phosphate

Biopoesis, the creation of life, implies molecular evolution from simple components, randomly distributed and in a dilute state, to form highly organized, concentrated systems capable of metabolism, replication and mutation. This chain of events must involve environmental processes that can locally lower entropy in several steps; by specific selection from an indiscriminate mixture, by concentration from dilute solution, and in the case of the mineral-induced processes, by particular effectiveness in ordering and selective reaction, directed toward formation of functional biomolecules. Numerous circumstances provide support for the notion that negatively charged molecules were functionally required and geochemically available for biopoesis. Sulfite ion may have been important in bisulfite complex formation with simple aldehydes, facilitating the initial concentration by sorption of aldehydes in positively charged surface active minerals. Borate ion may have played a similar, albeit less investigated role in forming charged sugar complexes. Among anionic species, oligophosphate ions and charged phosphate esters are likely to have been of even more wide ranging importance, reflected in the continued need for phosphate in a proposed RNA world, and extending its central role to evolved biochemistry. Phosphorylation is shown to result in selective concentration by surface sorption of compounds, otherwise too dilute to support condensation reactions. It provides protection against rapid hydrolysis of sugars and, by selective concentration, induces the oligomerization of aldehydes. As a manifestation of life arisen, phosphate already appears in an organic context in the oldest preserved sedimentary record.

NASA Discipline Exobiology↗

The effect of track structure on the induction of chromosomal aberrations in murine cells

PURPOSE: To measure chromosome aberrations in C3H 10T1/2 mouse fibroblasts using FISH painting at the first mitosis following exposure to 30 keV/microm hydrogen or neon ions. MATERIALS AND METHODS: Cells in plateau-phase were irradiated with 0.86 MeV protons at the TTT-3 Tandem accelerator in Naples (Italy), or with 400 MeV/n Ne ions at the HIMAC accelerator in Chiba (Japan). Colcemid-blocked cells were harvested at the first mitosis following exposure, and chromosome spreads were hybridized in situ with a fluorescein-labelled composite mouse DNA probe specific for chromosomes 2 and 8. RESULTS: Protons were more efficient than neon ions at the same LET in the induction of chromosome interchanges and breaks. Yields of complex exchanges were similar for both particles at the same dose, but protons produced mostly insertions, while with Ne exposure non-reciprocal exchanges were the most frequent complex-type exchange. CONCLUSIONS: Charged particles with the same LET produce different yields of chromosome aberrations, and some observed differences can be explained based on the available track-structure models.

NASA Center JSC↗