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At least 127 records · Page 7

Implementation of active sites to capture pitting of oxidizing carbon materials in DSMC.

In this work we demonstrate a newly developed capability to capture pitting of carbon fibers in DSMC simulations, specifically using the Stochastic PArallel Rarefied-gas Time-accurate Analyzer (SPARTA) code [1]. State-of-the-art reactive surface models in DSMC compute collision dependent carbon consumption rates (usually through desorption of CO) based on a set of surface reactions that has been derived from molecular beam experiments [2]. The reactivity on each carbon surface element is constant in those models, such that the carbon surface recedes uniformly as a result of ablation. However, it is well known that in reality the carbon surface has locally different reaction rates due to the presence of defects at the atomic scale [3]. These defective sites have a much higher reactivity than the average sites (2-3 orders of magnitude) and are first to react during ablation leading to its removal. This causes all the neighboring atoms to be defective and increase their reactivity, thus leading to the localized carbon removal around these ”active” sites (as shown in Fig. 1). In this manner, these highly reactive defective sites serve as nucleation sites for the formation and growth of etch pits with potentially detrimental effects on the structural integrity. Recently a detailed surface chemistry framework was developed in SPARTA, capable of incorporating various reaction mechanisms such as adsorption, desorption, Eley-Rideal (ER) and Langmuir-Hinshelwood (LH) mechanisms [4]. Within this framework, we have implemented the capability of a single surface having multiple site sets with different reactivities. Using this feature, we can simulate the presence of active sites on carbon surfaces, whose reactivity is much greater than an average site as a result of defects. We have implemented the active site fraction as a property of surface elements within SPARTA, which is directly proportional to the local reactivity of each surface element. By introducing an initial distribution of the active site fraction across the carbon surface, and propagating it in a manner that mimics the evolution of real reacting carbon surfaces, we are able to capture the formation and growth of etch pits as a result of surface consumption reactions such as oxidation.

DSMC↗

Implementation of Active Sites in DSMC to Capture Pitting of Oxidizing Carbon Materials

In this work we demonstrate a newly developed capability to capture pitting of carbon fibers in DSMC simulations, specifically using the Stochastic PArallel Rarefied-gas Time-accurate Analyzer (SPARTA) code. State-of-the-art reactive surface models in DSMC compute collision dependent carbon consumption rates (usually through desorption of CO) based on a set of surface reactions that has been derived from molecular beam experiments. The reactivity on each carbon surface element is constant in those models, such that the carbon surface recedes uniformly as a result of ablation. However, it is well known that in reality the carbon surface has locally different reaction rates due to the presence of defects at the atomic scale. These defective sites have a much higher reactivity than the average sites (2-3 orders of magnitude) and are first to react during ablation leading to its removal. This causes all the neighboring atoms to be defective and increase their reactivity, thus leading to the localized carbon removal around these ”active” sites. In this manner, these highly reactive defective sites serve as nucleation sites for the formation and growth of etch pits with potentially detrimental effects on the structural integrity. Recently a detailed surface chemistry framework was developed in SPARTA, capable of incorporating various reaction mechanisms such as adsorption, desorption, Eley-Rideal (ER) and Langmuir-Hinshelwood (LH) mechanisms. Within this framework, we have implemented the capability of a single surface having multiple site sets with different reactivities. Using this feature, we can simulate the presence of active sites on carbon surfaces, whose reactivity is much greater than an average site as a result of defects. We have implemented the active site fraction as a property of surface elements within SPARTA, which is directly proportional to the local reactivity of each surface element. By introducing an initial distribution of the active site fraction across the carbon surface, and propagating it in a manner that mimics the evolution of real reacting carbon surfaces, we are able to capture the formation and growth of etch pits as a result of surface consumption reactions such as oxidation.

DSMC↗

Dashboard for Marine Energy Site Assessment and Monitoring

The marine energy (ME) industry presently relies upon fragmented site assessment solutions that require high resource expenditure for deployment at each site and do not leverage the wealth of readily available tools and information. A wave energy resource assessment dashboard, currently in development, will substantially improve siting, permitting, operations, and maintenance of ME projects by providing an integrated solution that is a one-stop-shop for a developer’s needs. The Site Energy Assessment and MOnitoring Dashboard (SEAMOD) will be of commercial interest to anyone seeking to deploy an ME project and is easily expandable to include tidal and wind energy site assessments. The integrated dashboard is being developed using state-of-the-art database and cloud computing methods and data-assimilative modeling tools that can be coupled with low-cost, rapidly deployable wave buoys and environmental sensing hardware. The combined software and hardware dashboard will reduce wave energy site characterization and wave climate monitoring costs by more than 60 percent and provide assessments that meet international industry standards. To realize a thriving global ME industry, the physical environment at a potential deployment site must be understood, not only for resource characterization, but also for optimization of device and power conversion performance. SEAMOD directly addresses these needs with a commercially marketable product. SEAMOD is a low-cost solution that provides comprehensive ME resource assessments, baseline environmental monitoring, and offshore characterizations required for successful ME development. The key technical objectives for Phase I were a series of software development goals, which when implemented with monitoring solutions, produced an initial proof-of-concept low-cost wave energy resources dashboard. In Phase II, the development of the prototype SEAMOD continued. The basic framework employed was the development of a revised dashboard and monitoring tool customized for ME applications by focusing on IEC site assessment and method requirements. Development was focused on the integration of full hindcast metocean products to provide hindcast resource characterization and environmental information. The final integrated dashboard provides a low-cost solution that delivers comprehensive, scalable, industry-standard energy resource assessments and offshore characterizations required for successful ME development. The integrated dashboard offers visibility of the most recent site modeling, measurements, and historical data. The application and integration of consensus-based standards for wave energy resource assessment, as determined by the International Electrotechnical Commission (IEC), are crucial for the impact and value of SEAMOD. SEAMOD includes monthly, seasonal, and yearly statistics, as well as the total 30-year record, offering temporal resolution of the IEC parameters to aid potential developers in determining the available wave energy resources in their area of interest.

16 TIDAL AND WAVE POWER↗

Hyperspectral leaf reflectance of grasses varies with evolutionary lineage more than with site

Abstract To predict ecological responses at broad environmental scales, grass species are commonly grouped into two broad functional types based on photosynthetic pathway. However, closely related species may have distinctive anatomical and physiological attributes that influence ecological responses, beyond those related to photosynthetic pathway alone. Hyperspectral leaf reflectance can provide an integrated measure of covarying leaf traits that may result from phylogenetic trait conservatism and/or environmental conditions. Understanding whether spectra‐trait relationships are lineage specific or reflect environmental variation across sites is necessary for using hyperspectral reflectance to predict plant responses to environmental changes across spatial scales. We measured hyperspectral leaf reflectance (400–2400 nm) and 12 structural, biochemical, and physiological leaf traits from five grass‐dominated sites spanning the Great Plains of North America. We assessed if variation in leaf reflectance spectra among grass species is explained more by evolutionary lineage (as captured by tribes or subfamilies), photosynthetic pathway (C 3 or C 4 ), or site differences. We then determined whether leaf spectra can be used to predict leaf traits within and across lineages. Our results using redundancy analysis ordination (RDA) show that grass tribe identity explained more variation in leaf spectra (adjusted R 2 = 0.12) than photosynthetic pathway, which explained little variation in leaf spectra (adjusted R 2 = 0.00). Furthermore, leaf reflectance from the same tribe across multiple sites was more similar than leaf reflectance from the same site across tribes (adjusted R 2 = 0.12 and 0.08, respectively). Across all sites and species, trait predictions based on spectra ranged considerably in predictive accuracies ( R 2 = 0.65 to <0.01), but R 2 was >0.80 for certain lineages and sites. The relationship between Vc max , a measure of photosynthetic capacity, and spectra was particularly promising. Chloridoideae, a lineage more common at drier sites, appears to have distinct spectra‐trait relationships compared with other lineages. Overall, our results show that evolutionary relatedness explains more variation in grass leaf spectra than photosynthetic pathway or site, but consideration of lineage‐ and site‐specific trait relationships is needed to interpret spectral variation across large environmental gradients.

Pau, Stephanie [Department of Geography University↗

Author Correction: US oil and gas system emissions from nearly one million aerial site measurements

Correction to: Naturehttps://doi.org/10.1038/s41586-024-07117-5 Published online 13 March 2024 In the version of the article initially published, several errors were present and have been corrected in the HTML and PDF versions of the article and Supplementary Information. The main results, conclusions, and our interpretations of the data remain unchanged. See the new Supplementary Information Section S15 for a more detailed description of the errors corrected and the resulting effects on the analysis. Data processing and methods corrections Overflight count correction: We previously used pre-computed source coverage data for some Carbon Mapper campaigns that was computed differently than was required for our analysis. We have re-computed Carbon Mapper source coverage based on flightline polygons and source coordinates. Transition point computation, well sites: The updated version now correctly compares the cumulative emissions distribution of simulated well site emissions with that of aerially detected sources (rather than plumes) when computing the transition point. Transition point computation, midstream: Additionally, the transition point calculation has been corrected to exclude aerially detected midstream emissions below the transition point, which was previously leading to double counting of these emissions. This error was not present for upstream (well site) emissions. Calculation errors Unit error: We corrected a specific unit conversion error affecting well site emissions in the Kairos Fort Worth dataset. Across all datasets, we also correct the conversion factor for converting from standard volume to mass for midstream emissions. Sorting error: We correct code that was applying incorrect sorting when computing correction factors to account for partial detection at well sites. Small typographical corrections were made in Fig. 1b and SI Section S4.1. Data processing and methods corrections Overflight count correction: We previously used pre-computed source coverage data for some Carbon Mapper campaigns that was computed differently than was required for our analysis. We have re-computed Carbon Mapper source coverage based on flightline polygons and source coordinates. Transition point computation, well sites: The updated version now correctly compares the cumulative emissions distribution of simulated well site emissions with that of aerially detected sources (rather than plumes) when computing the transition point. Transition point computation, midstream: Additionally, the transition point calculation has been corrected to exclude aerially detected midstream emissions below the transition point, which was previously leading to double counting of these emissions. This error was not present for upstream (well site) emissions. Calculation errors Unit error: We corrected a specific unit conversion error affecting well site emissions in the Kairos Fort Worth dataset. Across all datasets, we also correct the conversion factor for converting from standard volume to mass for midstream emissions. Sorting error: We correct code that was applying incorrect sorting when computing correction factors to account for partial detection at well sites. Small typographical corrections were made in Fig. 1b and SI Section S4.1. The following practices may help researchers conducting similar analyses avoid making similar errors: 1, Clear, accessible documentation explaining the interpretation of all columns in data input tables and all internal variables within the model, 2, Simple cross-check calculations computed before and after unit conversions.

Sherwin, Evan D↗

AmeriFlux FLUXNET-1F US-SD1 Shatto Ditch Paired Cropland - Site 1 (Corn/Soy; No Cover Crops)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-SD1 Shatto Ditch Paired Cropland - Site 1 (Corn/Soy; No Cover Crops). This is the FLUXNET version of the carbon flux data for the site US-SD1 Shatto Ditch Paired Cropland - Site 1 (Corn/Soy; No Cover Crops) produced by applying the standard ONEFlux (1F) software. Site Description - US-SD1, located on mostly flat terrain with some gentle hills, is an actively managed farmland operated by working farmers following a conventional no-till corn–soybean rotation in the U.S. Midwest. US-SD1 is one of two paired working farm sites which are relatively close by; both are managed using similar conventional practices with the key difference being that the paired site (US-SD2) incorporates cover crops into its rotation, along with minor differentiating terrain and soil type, where US-SD2 is located on a gently sloped site with more sandy soils. This paired design enables direct site-to-site comparisons to assess the impacts of cover cropping on carbon, water, and energy fluxes.

Key, Kesondra [Indiana University - Bloomington]↗

Lunar shear velocity structure at Apollo sites 12, 14, and 15

Spectral amplitude ratios of horizontal-to-vertical motion produced on seismograms of meteoroid impacts at the Apollo 12, 14, and 15 sites, the Apollo 14 and 15 lunar-module impacts, and the Apollo 15 S4B impact show consistent differences among the recording sites. On the assumption that the motion represents predominantly fundamental-mode Reyleigh waves and that the compressional-wave velocity structure is similar to that derived in other investigations involving the Apollo seismic experiments, estimates are made of the shear-wave velocity structure under the three sites. Near-surface velocities are about 35 m/s at the three sites. The results for site 14 indicate an increase to about 100 m/s near the 8-m depth and to 200 m/s at the 38-m depth. Results for sites 12 and 15 show a smoother gradient and generally a greater velocity at a given depth than that indicated at site 14, reaching velocities of about 400 m/s near the 120-m depth. If the assumed P velocity structures are correct and if changes in S velocity coincide with changes in P velocity, then the ratio of these velocities decreases from 2.9 to 2.0 in the upper 19 meters at site 12, in the upper 38 meters at site 14, and in the upper 21 meters at site 15.

Mark, N.↗

Selection of the Mars Pathfinder Landing Site

The Mars Pathfinder spacecraft will land on a depositional fan near the mouth of the catastrophic outflow channel, Ares Vallis (19.5 deg N, 32.8 deg W). This site offers the prospect of analyzing a variety of rock types from the ancient cratered highlands, intermediate-age ridged plains, and reworked channel deposits. Analyses of these rocks by Pathfinder instruments will enable first-order scientific questions to be addressed, such as differentiation of the crust, the development of weathering products, and the nature of the early environment, as well as their subsequent evolution on Mars. Constraints imposed by: (1) spacecraft and rover designs (which are robust), (2) entry, descent, and landing, (3) scientific potential at various sites, and (4) safety were important considerations in site selection. Engineering constraints require a 70 km by 200 km smooth, flat (low slopes) area located between 10 deg and 20 deg N that is below 0 km elevation, with average radar reflectivity, little dust, and moderate rock abundance. Three regions on Mars are between 10 deg and 20 deg N and below 0 km elevation: Chryse, Amazonis, and Isidis-Elysitun. Science considerations favor sites at the mouths of outflow channels (grab bag sites offer an assay of rock types on Mars), highland sites (early crustal differentiation and climate), and sites covered with dark (unoxidized) material. Sites are considered safe if they are clearly below 0 km elevation, appear acceptably free of hazards in high-resolution (less than 50 m/pixel) Viking orbiter images and have acceptable reflectivity and roughness at radar wavelengths, thermal inertia, rock abundance, red to violet ratio, and albedo. Recent 3.5-cm wavelength radar observations were used to verify elevation, reflectivity, and roughness within the landing ellipses. Three sites meet all of these criteria: Ares Vallis, Tritonis Lacus, and Isidis. Although Isidis appears to be safer than Tritonis and Ares, the greater scientific potential at Ares Vallis resulted in its selection. Comparisons of the Grand Coulee (channel) and the depositional Ephrata Fan of the Channeled Scabland in eastern Washington, with Ar-es Vallis and its depositional fan also suggest the Ares Vallis landing site is safe and scientifically interesting.

Golombek, M. P.↗

Preliminary Assessment of Mars Exploration Rover Landing Site Predictions

Selection of the Mars Exploration Rover (MER) landing sites took place over a three year period in which engineering constraints were identified, 155 possible sites were downselected to the final two, surface environments and safety considerations were developed, and the potential science return at the sites was considered. Landing sites in Gusev crater and Meridiani Planum were selected because they appeared acceptably safe for MER landing and roving and had strong morphologic and mineralogical indicators of liquid water in their past and thus appeared capable of addressing the science objectives of the MER missions, which are to determine the aqueous, climatic, and geologic history of sites on Mars where conditions may have been favorable to the preservation of evidence of possible pre-biotic or biotic processes. Engineering constraints important to the selection included: latitude (10 N-15 S) for maximum solar power; elevation (<-1.3 km) for sufficient atmosphere to slow the lander; low horizontal winds, shear and turbulence in the last few kilometers to minimize horizontal velocity; low 10-m scale slopes to reduce airbag spinup and bounce; moderate rock abundance to reduce abrasion or stroke-out of the airbags; and a radar-reflective, load-bearing and trafficable surface safe for landing and roving that is not dominated by fine-grained dust. In selecting the MER landing sites these engineering constraints were addressed via comprehensive evaluation of surface and atmospheric characteristics from existing remote sensing data and models as well as targeted orbital information acquired from Mars Global Surveyor and Mars Odyssey. This evaluation resulted in a number of predictions of the surface characteristics of the sites, which are tested in this abstract. Relating remote sensing signatures to surface characteristics at landing sites allows these sites to be used as ground truth for the orbital data, is essential for selecting and validating landing sites for future missions, and is required for correctly interpreting the surfaces and materials globally present on Mars.

Golombek, M.↗

Determination of Site Occupancy in the M–Pd–Zn (M = Cu, Ag, and Au) γ-Brass Phase by CALculation of PHAse Diagrams Modeling and Rietveld Refinement

The Pd–Zn γ-brass phase provides exciting opportunities for synthesizing site-isolated catalysts with precisely controlled Pd active site ensembles. Introducing a third metallic element into the γ-brass lattice further perturbs the catalytic active site ensembles. Here, in this work, we introduce coinage metallic elements M (M = Cu, Ag, and Au) into the Pd–Zn γ-brass phase and investigate the site occupation factors of each element in the γ-brass lattice. The CALculation of PHAse Diagrams (CALPHAD) modeling approach supported by energetics predicted by the density functional theory and X-ray and neutron diffraction with Rietveld refinement were used to identify the SOF on each Wyckoff site for various M amounts alloyed into the Pd–Zn γ-brass phase. The present analysis unveils the strong preference for Pd occupying the outer tetrahedral (OT) site in the γ-brass lattice, while the coinage metallic elements tend to substitute for Zn on the octahedral (OH) site. The determination of site occupancy in the bulk M–Pd–Zn γ-brass phase provides opportunities to investigate and tailor potential catalytically active site ensembles in the γ-brass phase materials.

36 MATERIALS SCIENCE↗

Siting Analysis of a Solar-Nuclear-Desalination Integrated Energy System

Nuclear power is typically deployed as a baseload generator. Increased penetration of variable renewables motivates combining nuclear and renewable technologies into Integrated Energy Systems (IES) to improve dispatchability, component synergies and, through cogeneration, address multiple markets. However, combining multiple energy resources heavily depends on the proper selection of each system’s location and design limitations. In this paper, co-siting options for IES that couple nuclear and concentrating solar power (CSP) with thermal desalination are investigated. A comprehensive siting analysis is performed that utilizes global information survey data to determine possible co-siting options for nuclear and solar thermal generation in the United States. Viable co-siting options are distributed across the Southwestern U.S., with the greatest concentration of siting options in the southern Great Plains, although siting with higher solar direct normal irradiance is possible in other states such as Arizona and New Mexico. Brackish water desalination is also attractive across the southwest U.S. due to high water stress, but for brackish water desalination reverse osmosis (an electricity driven process) is most cost- and energy-efficient, which does not require co-siting with the thermal generator. The most attractive state for nuclear and thermal desalination (which is more attractive when using seawater) is Texas, although other areas may become attractive as water stress increases over the coming decades. Co-siting of all CSP and thermal desalination is challenging as attractive CSP sites are not coastal.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Restructuring of the Lewis Acid Sites in Y-Modified Dealuminated Beta-Zeolite by Hydrothermal Treatment

Yttrium-modified dealuminated Betazeolite (Y-BEA) represents a type of Lewis acid zeolite that has gained attention for its potential to efficiently catalyze the conversion of biomass-derived oxygenates. The structure of the Y active sites and their dynamics during biomass conversion reactions, which normally involve substantial amounts of water, necessitate thorough investigation for the rational design of more active and stable catalysts. Here, we conducted a study where a series of Y-BEA catalysts with different yttrium loadings (1–7 wt.%) were subjected to hydrothermal treatment (450 °C, 20% water) and investigated for their structural and catalytic activity changes through a combination of multiple characterizations and kinetic measurements. The number of acid sites of Y-BEA decreased without a change in acid strength following the hydrothermal treatment, which was confirmed by the results of acid site titration, infrared spectroscopy of probe molecules, and kinetic measurements for probe reactions (acetone aldol condensation). Structural analysis using X-ray diffraction (XRD), specific surface area measurement, X-ray absorption spectroscopy (XAS), and X-ray photoelectron spectroscopy (XPS) demonstrated that both the zeolite structure and the isolation status of the Y site remain intact after hydrothermal treatment. Further, the Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) spectra, thermogravimetric analysis (TGA), and operando 1 H and 29 Si magic-angle spinning (MAS) nuclear magnetic resonance (NMR) revealed the dehydroxylation of Y-BEA induced by hydration-rearrangement-condensation restructuring during the high-temperature steam treatment. Dehydroxylation affects the structure of Y sites by reducing their vicinal silanol sites. In conclusion, this conversion of Lewis acidic Y sites into nonacidic sites is the primary factor behind the change in acid site quantity and catalytic activity on Y-BEA.

36 MATERIALS SCIENCE↗

AmeriFlux FLUXNET-1F US-Ne2 Mead - irrigated maize-soybean rotation site

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-Ne2 Mead - irrigated maize-soybean rotation site. This is the FLUXNET version of the carbon flux data for the site US-Ne2 Mead - irrigated maize-soybean rotation site produced by applying the standard ONEFlux (1F) software. Site Description - The study site is one of three fields (all located within 1.6 km of each other) at the University of Nebraska Eastern Nebraska Research, Extension and Education Center near Mead, Nebraska. This site is irrigated with a center pivot system. Prior to the initiation of the study, the irrigated site had a 10-yr history of maize-soybean rotation under no-till management. A tillage operation (disking) was done just prior to the 2001 planting to homogenize the top 0.1 m of soil, incorporate P and K fertilizers, as well as previously accumulated surface residues. Since this tillage operation, the site has been under no-till management in a maize-soybean rotation (maize odd years and soybean even years). There was a brief period due to an intercomparison study from 2010 to 2013 when fall conservation tillage was performed and maize (not soybean) was planted in 2010 and 2012. The management reverted to a strictly no-till maize-soybean crop rotation after 2014.

Suyker, Andy [University of Nebraska - Lincoln]↗

AmeriFlux FLUXNET-1F US-RC4 Moscow Mountain on-farm site

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-RC4 Moscow Mountain on-farm site. This is the FLUXNET version of the carbon flux data for the site US-RC4 Moscow Mountain on-farm site produced by applying the standard ONEFlux (1F) software. Site Description - The Moscow Mountain On-farm site operated 2012-2016 as part of a cluster of 5 towers (RC1 to RC5) operated for the Regional Approaches to Climate Change (REACCH) USDA-supported research project. The site is located in the high precipitation agroecological zone of the Columbia Plateau’s dryland cropping region, near Moscow, Idaho. The site was managed with conventional (reduced) tillage. The crop rotation was spring barley, spring field peas, winter wheat, and spring wheat. Soils are silt loam mollisols including the Latahco, Thatuna, Southwick, and Larkin soil series. The site topography is sloping and is situated within the rolling hills of the Palouse region.

Chi, Jinshu [The Hong Kong University of Science a↗

AmeriFlux FLUXNET-1F CA-TPA Ontario Turkey Point Observatory Agricultural Site

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site CA-TPA Ontario Turkey Point Observatory Agricultural Site. This is the FLUXNET version of the carbon flux data for the site CA-TPA Ontario Turkey Point Observatory Agricultural Site produced by applying the standard ONEFlux (1F) software. Site Description - This agricultural flux tower site is located about 15 km southwest of Simcoe in southern Ontario, Canada. It was planted with corn (Zea mays) in 2020 and 2021, sweet potato (Ipomoea batatas) in 2022 and tobacco (Nicotiana tabacum) in 2023. The site is part of Turkey Point Environmental Observatory (TPEO). The establishment of the agricultural site has allowed TPEO to become representative of the major biomes in the Great Lakes region, encompassing coniferous and deciduous forests, as well as agricultural crops. The soil at this agricultural site is well-drained fine sandy loam. The area has a humid continental climate and has one of the longest-growing seasons in Canada with at least 150–160 frost-free days in a year.

Arain, M. Altaf [McMaster University]↗

AmeriFlux FLUXNET-1F US-VT1 Vermillion Tributary Paired Cropland – Site 1 (Corn/Soy; No Cover Crops)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-VT1 Vermillion Tributary Paired Cropland – Site 1 (Corn/Soy; No Cover Crops). This is the FLUXNET version of the carbon flux data for the site US-VT1 Vermillion Tributary Paired Cropland – Site 1 (Corn/Soy; No Cover Crops) produced by applying the standard ONEFlux (1F) software. Site Description - US-VT1 is located on flat, actively managed farmland operated by working farmers, following a conventional no-till corn–soybean rotation in the U.S. Midwest. US-VT1 is one of two paired working farm sites on the same property; both are managed using similar conventional practices, with the key difference being that the paired site (US-VT2) incorporates cover crops into its rotation. This paired design enables direct site-to-site comparisons to assess the impacts of cover cropping on carbon, water, and energy fluxes.

Key, Kesondra [Indiana University - Bloomington]↗

AmeriFlux FLUXNET-1F US-VT2 Vermillion Tributary Paired Cropland – Site 2 (Corn/Soy; Cover Crops)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-VT2 Vermillion Tributary Paired Cropland – Site 2 (Corn/Soy; Cover Crops). This is the FLUXNET version of the carbon flux data for the site US-VT2 Vermillion Tributary Paired Cropland – Site 2 (Corn/Soy; Cover Crops) produced by applying the standard ONEFlux (1F) software. Site Description - US-VT2 is located on flat, actively managed farmland operated by working farmers, following a conventional no-till corn–soybean rotation in the U.S. Midwest that uses cover crops. US-VT2 is one of two paired working farm sites on the same property; both are managed using similar conventional practices, with the key difference being that the paired site (US-VT1) does not incorporate cover crops into its rotation. This paired design enables direct site-to-site comparisons to assess the impacts of cover cropping on carbon, water, and energy fluxes.

Key, Kesondra [Indiana University - Bloomington]↗

AmeriFlux FLUXNET-1F US-SD2 Shatto Ditch Paired Cropland - Site 2 (Corn/Soy; Cover Crops)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-SD2 Shatto Ditch Paired Cropland - Site 2 (Corn/Soy; Cover Crops). This is the FLUXNET version of the carbon flux data for the site US-SD2 Shatto Ditch Paired Cropland - Site 2 (Corn/Soy; Cover Crops) produced by applying the standard ONEFlux (1F) software. Site Description - US-SD2, located on gently sloped terrain, is an actively managed farmland operated by working farmers following a conventional no-till corn–soybean rotation in the U.S. Midwest. US-SD2 is one of two paired working farm sites which are relatively close by; both are managed using similar conventional practices with the key difference being that the paired site (US-SD1) incorporates cover crops into its rotation, along with minor differentiating terrain and soil type, where US-SD1 is located on mostly flat terrain with some gentle hills. This paired design enables direct site-to-site comparisons to assess the impacts of cover cropping on carbon, water, and energy fluxes.

Key, Kesondra [Indiana University - Bloomington]↗