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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Progressive and instantaneous nature of lithium nucleation discovered by dynamic and operando imaging

The understanding of lithium (Li) nucleation and growth is important to design better electrodes for high-performance batteries. However, the study of Li nucleation process is still limited because of the lack of imaging tools that can provide information of the entire dynamic process. We developed and used an operando reflection interference microscope (RIM) that enables real-time imaging and tracking the Li nucleation dynamics at a single nanoparticle level. This dynamic and operando imaging platform provides us with critical capabilities to continuously monitor and study the Li nucleation process. We find that the formation of initial Li nuclei is not at the exact same time point, and Li nucleation process shows the properties of both progressive and instantaneous nucleation. In addition, the RIM allows us to track the individual Li nucleus’s growth and extract spatially resolved overpotential map. The nonuniform overpotential map indicates that the localized electrochemical environments substantially influence the Li nucleation.

25 ENERGY STORAGE↗
DOE OSTI2023

Separation of K + and Bi 3+ displacements in a Pb-free, monoclinic piezoelectric at the morphotropic phase boundary

The best piezoelectric properties of any perovskite oxide known are found in the solid solution of the relaxor Pb (Mg 1/3 Nb 2/3 )O 3 and ferroelectric PbTiO 3 . Despite its impressive properties, this system has limited analogy. We present the compositional exploration of the Pb-free analogue (1-x)(K 1/2 Bi 1/2 )(Mg 1/3 Nb 2/3 )O 3 -x(K 1/2 Bi 1/2 )TiO 3 (KBMN-KBT). We locate the morphotropic phase boundary between x = 0.86 and 0.88 changing from Cm to Pm symmetry and the optimally performing composition at x = 0.88. We report a piezoelectric figure of merit (d 33 *) of 192 pm V —1 from strain measurements. Diffraction methods reveal disordered displacements of K + and Bi 3+ which persist from the KBMN endmember through multiple changes in symmetry. Rearrangement of the Bi 3+ displacements along the uncommon [011] c direction drives the physical response. Ferroelectric, dielectric, and piezoresponse force microscopy are used to study the progression of physical properties through the MPB and attribute the mechanism to a polarization rotation. Taking account for local, short-range, and average structural features yield a balanced perspective on the structure and properties of this system, isolating the driving force within this system to the Bi 3+ bonding configuration. This work yields a strong analogy to the Pb-based analogue, and provides strategies for further optimization.

36 MATERIALS SCIENCE↗
NASA NTRSDate not supplied

Measuring the Wear and Abrasive Resistance of Air Plasma Sprayed Aluminum Oxide for Lunar Exploration

Lunar regolith, especially finer dust particles traveling at high velocities, can cause significant wear and abrasive damage to structural components that ensure a prolongated presence on the surface of the Moon. With the absence of an atmosphere and lower gravity than on Earth, regolith particles maintain high velocities at large distances from where they were generated, for example next to lunar landers. Wear-resistant ceramic and ceramic composite materials can improve the durability of spacecraft components during long missions on the Moon’s surface. Aluminum oxide coatings are lightweight, have multifunctional properties, and have high strength including high hardness and wear resistance. These properties can help improve the durability of structures used in space exploration. Air plasma sprayed (APS) aluminum oxide coatings have demonstrated the potential to protect critical structures. This study investigated the abrasive wear resistance of APS aluminum oxide coatings via Taber abrasion experiments. Taber abrasion offers the advantage of quantifying the abrasive wear behavior of particles with different shapes on a surface. In this work, an abrasive wheel made of silicon carbide was utilized to evaluate wear properties of specimens progressively over 5000 cycles. This experiment focused on testing two series of specimens to determine whether a bond coat composed of nickel, chromium, aluminum, and yttrium (NiCrAlY) improved the protective behavior of the APS aluminum oxide coating. The specimens varied in topcoat thickness and were made with and without an approximately 100 µm bond coat layer. The mass of the specimens was measured at 400 cycles, 800 cycles, 3800 cycles, and 5000 cycles. Increasing thickness was found to result in higher wear for samples with and without a bond coat. Increased mass loss in samples with a bond coat was observed indicating a need for further studies on the overall impact of the use of a bond coat on the protective behavior of the coatings. To continue designing wear resistant coatings for structural protection in space missions, the multifunctional properties of the APS aluminum oxide coating will be studied. Future experiments will determine whether the APS aluminum oxide coating can protect the structures from other aspects of the harsh space environment, such as extreme temperature variations and ionizing radiation.

aluminum oxide↗
DOE OSTI2016

Fundamental Properties for Evaluation of Uranium-free TRU-Zr Metal Fuel Performance

FR (Fast Reactor) is widely recognized to effectively burn plutonium and MA (Minor Actinides) (i.e., TRU: Transuranic) due to its higher fission-to-neutron-capture ratio compared to LWR. When TRU in LWR (Light Water Reactor) spent fuel is recycled into FR cycle, the radiotoxicity of the residual nuclear wastes from LWR spent fuel is reduced to natural uranium level after several hundred years instead of more than hundreds of thousand years for no recycling case. It could significantly improve public perception to nuclear waste disposal and might reduce the burden of the disposal. However, U-TRU-fueled fast reactors also produce TRU while burning TRU because they use uranium together with TRU. For example, FR, even with low conversion ratio of 0.75, burns only 0.18 t TRU/GWe/y, while LWRs produces about 0.22 t TRU/GWe/y. It is not a realistic scenario which needs almost the same capacity of fast reactors as that of LWRs to continuously burn TRU at LWR-dominant era in the near term at least. Therefore, a FR system to burn TRU from LWR with the minimum reactor units is desirable. The most effective way is to use uranium-free TRU fuel since it does not produce any new TRU. It can reduce the capacity of the TRU burner units and the associated fuel cycle facilities to about 1/5 and 1/8 respectively. Metal fuel FR cycle is considered to be one of the most promising ways because uranium-free TRU metal fuel could be recycled by pyro-process for U-Pu-Zr metal fuel without large modifications. This paper shows the recent research progress on fundamental properties of uranium-free TRU metal fuel. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

1000 Soils Pilot Dataset, version 8, May 2025

This record hosts data generated by the 1000 Soils Pilot. Data will be updated as more become available. Please see the most recent data upload for current data. A beta visualization tool is available for some data types at https://shinyproxy.emsl.pnnl.gov/app/1000soils. Please submit any suggestions or comments through the 'contact' tab. We are actively working to improve visualizations and value all feedback. Data completed include: Geochemistry, texture, respiration, and enzyme activities FTICR-MS organic matter chemistry Microbial biomass C and N TOC/TDN of water-extractable OM X-ray computed tomography (derived metrics available here, raw data available upon request) Metagenomes; a variety of data formats are available upon request Soil hydraulic properties Data in progress: LC-MS/MS in development, timeline TBD, inquire for status 1000S_processed_BGC_summary.csv contains all available biogeochemical data; microbial biomass C and N; and TOC/TDN of water-extractable OM; and 1000S_Tomography.xslx contains a summary of data generated via X-ray computed tomography. icr_v2_corems2.csv contains FTICR-MS data processed by CoreMS version 2. These data are merged by formula across instrument runs to enable cross-sample comparisons. Technical replicates are merged by retaining peaks present in 2 out of 3 replicates. 1000Soils_Metadata_Site_Mastersheet_v1.csv contains site information. Soil Hydraulics_corrected_02042025.xlsx contains soil hydraulics information. Readme File_v4.xlsx is the readme file. Please contact the MONet project (monet.emsl@pnnl.gov) or Emily Graham (emily.graham@pnnl.gov) with questions. The following file and all raw data are available upon request: icr_by_mass_for_single_sample_analysis_only.csv contains FTICR-MS data processed by CoreMS and is intended for usage in the calculation of biochemical transformations within samples only. These data are not acceptable for cross-sample comparison of masses because they are from multiple instrument runs. For more information, please see: https://www.emsl.pnnl.gov/monet and https://sc-data.emsl.pnnl.gov/monet Acknowledgment: Soil data were provided by the Molecular Observation Network (MONet) at the Environmental Molecular Sciences Laboratory (https://ror.org/04rc0xn13), a DOE Office of Science user facility sponsored by the Biological and Environmental Research program under Contract No. DE-AC05-76RL01830. The work (proposal: 10.46936/10.25585/60008970) conducted by the U.S. Department of Energy, Joint Genome Institute (https://ror.org/04xm1d337), a DOE Office of Science user facility, is supported by the Office of Science of the U.S. Department of Energy operated under Contract No. DE-AC02-05CH11231. The Molecular Observation Network (MONet) database is an open, FAIR, and publicly available compilation of the molecular and microstructural properties of soil. Data in the MONet open science database can be found at https://sc-data.emsl.pnnl.gov/.

biogeochemistry↗
DOE OSTI2021

Materials Based on Technical Bulk Lignin

Lignin is the second most abundant biopolymer and the main source of aromatic structures on earth. Lignin has long been produced as a byproduct of the pulping process and utilized in low value-added applications like heat. However, lignin has received increased attention in recent years to improve its value through various chemical processes. This Review compiles recent progress in synthesis, properties, and applications of lignin-based materials. The lignin for material applications can often be classified into three categories: technical bulk lignin (TBL), lignin-derived oligomers (LDOs), and lignin-derived phenols (LDPs). Furthermore, this Review focuses on the chemical modifications of TBLs and their applications in novel smart materials like self-healing, stimulus responsive, and shape memory polymers. The conversion of TBL to polymers can be briefly divided into two steps: (1) introduction of polymerizable functional groups into the lignin backbone and (2) polymerization that achieves desired materials. Both lignin functionalization and polymerization approaches are discussed in detail. As such, this work attempts to provide a comprehensive overview that highlights the importance of these approaches for the utilization of the abundant but largely ignored biopolymer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Supervised learning of a chemistry functional with damped dispersion

Abstract Kohn–Sham density functional theory is widely used in chemistry, but no functional can accurately predict the whole range of chemical properties, although recent progress by some doubly hybrid functionals comes close. Here, we optimized a singly hybrid functional called CF22D with higher across-the-board accuracy for chemistry than most of the existing non-doubly hybrid functionals by using a flexible functional form that combines a global hybrid meta-nonseparable gradient approximation that depends on density and occupied orbitals with a damped dispersion term that depends on geometry. We optimized this energy functional by using a large database and performance-triggered iterative supervised training. We combined several databases to create a very large, combined database whose use demonstrated the good performance of CF22D on barrier heights, isomerization energies, thermochemistry, noncovalent interactions, radical and nonradical chemistry, small and large systems, simple and complex systems and transition-metal chemistry.

Liu, Yiwei (ORCID:0000000288126163)↗
DOE OSTI2014

Intergalactic medium emission observations with the cosmic web imager. I. The circum-QSO medium of QSO 1549+19, and evidence for a filamentary gas inflow

The Palomar Cosmic Web Imager (PCWI), an integral field spectrograph designed to detect and map low surface brightness emission, has obtained imaging spectroscopic maps of Lyα from the circum-QSO medium (CQM) of QSO HS1549+19 at redshift z = 2.843. Extensive extended emission is detected from the CQM, consistent with fluorescent and pumped Lyα produced by the ionizing and Lyα continuum of the QSO. Many features present in PCWI spectral images match those detected in narrow-band images. Filamentary structures with narrow line profiles are detected in several cases as long as 250-400 kpc. One of these is centered at a velocity redshifted with respect to the systemic velocity, and displays a spatially collimated and kinematically cold line profile increasing in velocity width approaching the QSO. This suggests that the filament gas is infalling onto the QSO, perhaps in a cold accretion flow. Because of the strong ionizing flux, the neutral column density is low, typically N(H I)∼10{sup 12}--10{sup 15} cm{sup −2}, and the line center optical depth is also low (typically τ{sub 0} < 10), insufficient to display well separated double peak emission characteristic of higher line optical depths. With a simple ionization and cloud model we can very roughly estimate the total gas mass (log M {sub gas} = 12.5 ± 0.5) and the total (log M {sub tot} = 13.3 ± 0.5). We can also calculate a kinematic mass from the total line profile (2 × 10{sup 13} M {sub ☉}), which agrees with the mass estimated from the gas emission. The intensity-binned spectrum of the CQM shows a progression in kinematic properties consistent with heirarchical structure formation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Effects of defects in composite wind turbine blades – Part 1: Characterization and mechanical testing

Abstract. The Montana State University Composite Material Technologies Research Group performed a study to ascertain the effects of defects that often result from the manufacture of composite wind turbine blades. The first step in this multiyear study was to systematically quantify and enter these defects into a database before embedding similar defects into manufactured coupons. Through the Sandia National Laboratories Blade Reliability Collaborative (BRC), it was determined that key defects to investigate were fiber waves and porosity. An inspection of failed commercial-scale wind turbine blades yielded metrics that utilized specific parameters to physically characterize a defect. Methods to easily and consistently discretize, measure, and assess these defects based on the identified parameters were established to allow for statistical analysis. Data relating flaw parameters to frequencies of occurrence were analyzed and found to fit within standard distributions. Additionally, mechanical testing of coupons with flaws based on these physical characterization data was performed to understand effects of these defects. Representative blade materials and manufacturing methods were utilized and both material properties and damage progression were measured. It was observed that flaw parameters directly affected the mechanical response. While the data gathered in this first step are widely useful, it was also intended for use as a foundation for the rest of the study, to perform probabilistic analysis and comparative analysis of progressive damage models.

Nelson, Jared W. (ORCID:0000000207736091)↗
NASA NTRS1985

Geology of icy satellites

The geology of the major icy satellites of Jupiter, Saturn, Uranus, and Neptune is discussed in terms of the four major processes that shape icy satellite surfaces: impact cratering, volcanism, tectonism, and interactions with planetary magnetospheres and solar radiation. The role of these processes in creating the differences that exist among the satellites, in particular the orderly progression of geological properties in the Jovian satellites, is emphasized. Important questions left open after the Voyager missions are summarized.

Mckinnon, W. B.↗
NASA NTRS1984

Determination of the ultrasonic properties of composites

The research described encompasses two facets of the propagation of ultrasonic waves in composite structures: imaging of delaminations and the temperature dependence of the acoustical properties of composites. Progress in each area is summarized.

Smith, B. T.↗
NASA NTRS1993

Pyroxene equilibration temperatures in metamorphosed ordinary chondrites

Ordinary chondrites are divided into petrographic types based on observed mineralogical and textural properties consistent with progressive thermal metamorphism from low grade (type 3) to high (type 7). Regardless of the exact cause of the metamorphism, higher-type chondrites should retain information concerning peak temperatures reached and for what duration. Using the two-pyroxene geothermometer of Lindsley, we have calculated the equilibration temperatures for 26H, L and LL type 5 and 6 ordinary chondrites, to investigate the relative peak temperatures and equilibration-states reached by these various meteorite classes. The Lindsley thermometer relies on a detailed accounting of non-quadrilateral components in pyroxenes, whose recalculated compositions are then plotted onto an empirically-derived polythermal diagram from which temperatures can be interpolated. The reported uncertainty of this method is plus or minus 50 C; in addition, close spacing of isotherms on the graph (particularly for orthopyroxene compositions) increase this uncertainty. We have parameterized the Lindsley polythermal quadrilateral for 1 atm pressure (less than 2 bar), and interpreted recalculated coordinates directly in terms of 25 C temperature intervals. Meteorites selected for this study include both relatively shocked and unshoked specimens; heavily weathered or visibly brecciated specimens were avoided. Temperatures were calculated from orthopyroxene (opx) and clinopyroxene (cpx) analyses within one relative percent of ideal sums and stoichiometry. Histograms summarizing the calculated temperatures for type 5 and 6 ordinary chondrites are shown.

Harvey, R. P.↗
NASA NTRS2019

Architecture and Dynamics of Kepler's Multi-Transiting Planet Systems.III. Comprehensive Investigation Using All Four Years of Kepler Mission Data

We study the orbital architectures of planetary systems orbiting within ∼1 AU of their stars by analyzing the ensemble of Kepler systems having two or more planet candidates. We use data from the entire Kepler mission, and in many cases we apply improved analysis techniques (e.g., replacing histograms by top-hat Kernel Density Estimators that avoid the loss of information resulting from choosing a particular phase for the bin boundaries) to extend and enhance the studies of Lissauer et al. (2011, ApJS 197, 8) and Fabrycky et al. (2014, ApJ 790, 146).These data show ~ 1700 transiting planet candidates in > 600 multiple-planet systems, far more than were available for our previous two studies. The increased numbers and better information about planetary radii and the properties of stellar hosts made possible by Gaia DR2 allow more statistically-robust analyses of the entire ensemble of Kepler multis as well as independent analyses of subsets of the population. We are thus able to contrast the dynamical configurations of small and large planets, short-period and longer-period planets, and planets orbiting various types of host stars. We reinforce our previous findings that most pairs of planets within the same system are neither in nor near low-order mean motion resonances and that there is a substantial excess of planets having period ratios slightly larger than those of first-order mean-motion resonances. However, neglecting three systems whose planets are locked in 3- body resonances and summing over all first-order mean motion resonances, the deficit of planet pairs with period ratios just narrow of resonance is as large as the excess of planets wide of resonance (within statistical uncertainties), suggesting that overall there is no overall excess of planet pairs in the vicinity of resonance. Other aspects of our study, including estimates of the typical relative inclinations of planetary orbits and their variations as functions of orbital period, planet sizes and stellar properties, are in progress, with results expected to be available for presentation by the time of the conference.

Lissauer, Jack↗
NASA NTRSDate not supplied

Monitoring the 2022 Hunga Tonga-Hunga Ha'apai Aerosol Cloud Using Space-Based Observations

- We will analyze the volcanic plume progression, spread and properties using space-based observations - OMPS LP, SAGE III/ISS, CALIPSO, TROPOMI - OMPS LP and SAGE III/ISS are limb instruments that measure the aerosol vertical profiles globally, while CALIPSO is a LIDAR that measures the backscatter and depolarization ratio of the aerosol profiles. -TROPOMI is a UV instrument that measures SO2 and absorbing aerosol total column - Volcanic plume in the upper stratosphere - The main plume in middle stratosphere - Volcanic aerosol transport to SH/NH - Volcanic aerosol optical properties

Atmospheric Science↗
DOE OSTI2022

Widespread opportunities for materials engineering of nanocrystals: Synthetically tailorable effects and methodologies

Since their initial development, semiconductor nanocrystals (NCs) and metal nanoparticles (NPs) have become widely utilized in a variety of applications, including solar energy harvesting, lighting, catalysis, biomedical imaging, and targeted cancer treatments. Because of their reduced dimensionality, NCs and NPs have vastly different optical and electronic properties than their bulk counterparts, and the properties often depend heavily on the NC or NP surface. Surface defects and ligands alter the optoelectronic properties of NCs and NPs and affect their interaction with the environment, allowing tailoring of their properties without changing the overall chemical composition. In this review, we discuss research progress focusing on optoelectronic properties of NPs and NCs and their respective applications. We highlight how different surface treatments and ligand functionalization of nanomaterials can influence these applications.

36 MATERIALS SCIENCE↗
NASA NTRS1987

A Jupiter Data Analysis Program (JDAP) research grant on wave accessibility and attributes

For more than thirty years the intense decametric radio emissions from Jupiter (DAM) and the corresponding auroral kilometric radiation from the Earth (AKR) have remained major radio science mysteries. Part of the problem, aside from their inherent complexity, has been the difficulty of measuring their source location and emission properties from limited observations. Progress has been made on this problem by locating the source directly, i.e., by analysis of the faraday rotation observed with Voyager as the wave path crossed the Io plasma torus, and indirectly by comparing the peak frequencies of the decametric emission with that at the foot of the Io flux tube. Progress was also made on the general question of how the emissions originate by finding properties of both the AKR and DAM which would imply emission by natural radio lasing.

Calvert, Wynne↗
DOE OSTI2021

Recent progress in understanding solid electrolyte interphase on lithium metal anode

Lithium (Li) metal batteries (LMBs) are among the most promising candidates of next-generation high-energy-density rechargeable batteries. Solid electrolyte interphase (SEI) on Li metal anode plays a significant role which influences the Li deposition morphology and the cycle life of LMBs. Although SEI is the most important part, a thorough understanding of SEI is inadequate. In this review, we focus on the progresses of understanding on structures, properties and influencing factors of SEI as well as efficient strategies of tailoring SEI. First, the compositions, models and recent progresses on characterizing atomic structure of SEI are summarized. Second, the properties of SEI, including electronic conduction, ionic conduction, stability and mechanical properties are elucidated. Structures and properties of SEI are greatly influenced by multiple factors such as solvent, salt, additive, solvation structure, impurity, current density, temperature, pressure and capacity utilization. Thus, interactions between these factors and SEI are comprehensively discussed. Correlations of SEI with Li deposition morphology, rate capability and cycle life are further summarized. Moreover, efficient strategies of tailoring SEI with desired properties, including in-situ SEI and ex-situ SEI are also reviewed. Despite the significant progresses that have been achieved in the researches of SEI, better understanding of SEI is still highly demand. Finally, future directions especially in-operando techniques, multi-modality approaches for characterization of SEI and artificial intelligence assisted understanding of correlation between electrolyte components and SEI properties are proposed.

Wu, Haiping↗