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At least 127 records · Page 7

Evaluation of tantalum-alloy-clad uranium mononitride fuel specimens from 7500-hour, 1040 C pumped-lithium-loop test

Simulated nuclear fuel element specimens, consisting of uranium mononitride (UN) fuel cylinders clad with tungsten-lined T-111, were exposed for up to 7500 hr at 1040 C (1900 F) in a pumped-lithium loop. The lithium flow velocity was 1.5 m/sec (5 ft/sec) in the specimen test section. No evidence of any compatibility problems between the specimens and the flowing lithium was found based on appearance, weight change, chemistry, and metallography. Direct exposure of the UN to the lithium through a simulated cladding crack resulted in some erosion of the UN in the area of the defect. The T-111 cladding was ductile after lithium exposure, but it was sensitive to hydrogen embrittlement during post-test handling.

Watson, G. K.↗

Nuclear Engine System Simulation (NESS). Version 2.0: Program user's guide

This Program User's Guide discusses the Nuclear Thermal Propulsion (NTP) engine system design features and capabilities modeled in the Nuclear Engine System Simulation (NESS): Version 2.0 program (referred to as NESS throughout the remainder of this document), as well as its operation. NESS was upgraded to include many new modeling capabilities not available in the original version delivered to NASA LeRC in Dec. 1991, NESS's new features include the following: (1) an improved input format; (2) an advanced solid-core NERVA-type reactor system model (ENABLER 2); (3) a bleed-cycle engine system option; (4) an axial-turbopump design option; (5) an automated pump-out turbopump assembly sizing option; (6) an off-design gas generator engine cycle design option; (7) updated hydrogen properties; (8) an improved output format; and (9) personal computer operation capability. Sample design cases are presented in the user's guide that demonstrate many of the new features associated with this upgraded version of NESS, as well as design modeling features associated with the original version of NESS.

Pelaccio, Dennis G.↗

Transmission of Images on High-Temperature Nuclear-Grade Metallic Pipe with Ultrasonic Elastic Waves

Transmission of information using elastic ultrasonic waves on existing metallic pipes provides an alternative communication option for a nuclear facility. The advantages of this approach consist of transmitting information through barriers, such as the containment building wall, with minimal modification of the existing hardware. Because bit rates on the order of kilobits per second are achievable, relatively large volumes of data, such as images, can be transmitted. A viable candidate for an ultrasonic communication channel is a stainless steel pipe of the chemical volume control system (CVCS) that penetrates through the reactor containment building wall through a sealed tunnel. To study ultrasonic communication under simulated nuclear facility conditions of high temperature, a test article was developed by installing heating tapes, temperature controllers, and thermal insulation on a laboratory CVCS-like stainless steel pipe. High temperature and radiation-resilient lithium niobate ultrasonic transducers were utilized for information transmission on the heated pipe. The amplitude shift keying (ASK) digital communication protocol was developed and implemented in a GNU Radio software-defined radio environment. A root-raised-cosine filter was introduced to suppress ultrasonic transducer ringing and thus reduce inter-symbol interference. This resulted in the enhancement of the data transmission bit rate compared to information encoding with square pulses. Demonstrations of communication at high temperature included transmission of a 90-KB image at the bit rate of 10 Kbps with a bit error rate of 10 -3 across a 6-ft-long straight pipe heated up to 230 degrees C. Additional preliminary studies were conducted to evaluate ultrasonic communication system resilience to environmental degradation and damage.

42 ENGINEERING↗

Composition Measurements of the LAW Phase 4 Glasses

In this report, the Savannah River National Laboratory provides results from the analyses of glass compositions for a series of simulated nuclear waste glasses fabricated at the Pacific Northwest National Laboratory. The series included quenched versions of the glasses. The resulting data will be used in the development of enhanced property/composition models for waste vitrification at Hanford. Chemical analyses were performed on a representative sample of each of the quenched glasses to allow for comparisons with the targeted compositions. For the quenched glasses from Set 1, measured concentrations of B 2 O 3 and SiO 2 were generally above the targeted values. Measured concentrations for MgO and P 2 O 5 were generally low for glasses. Measured concentrations of ZrO 2 were both below and above the targeted values for glasses. For the quenched glasses from Set 2, measured concentrations of AL 2 O 3 , B 2 O 3 , P 2 O 5 , SiO 2 , and ZrO 2 were generally below the targeted values. Measured concentrations of Na 2 0 were both below and above the targeted values for glasses. The measured concentrations of chlorine, fluorine, and SO 3 were below the targeted values for most of the study glasses, likely because of volatility during melting. Overall, there were no indications of errors in batching of the simulated waste glasses. These results can be used in further characterization of this series of glasses, including the normalization of Product Consistency Test results.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development of Shielding Benchmarks Using the Godiva IV Assembly

The Nuclear Criticality Safety Program (NCSP) is developing a shielding benchmark using the Godiva IV assembly as a source. Its present status is reviewed herein. Even eight decades into the nuclear era, substantial work remains to develop a database of shielding benchmarks to support future nuclear development. A nuclear simulation is only as good as its supporting data, inputs, and validation basis. Uncertainty in these areas is addressed using conservatism, which adds margin and, occasionally, cost. In many shielding situations, high accuracy is not necessary because additional material is not particularly expensive. After all, 1–2 cm of lead often reduces the gamma ray dose substantially. However, in certain areas, conservatism can add unnecessary cost. These areas include mobile shielding applications such as casks, ships, microreactors, and spacecraft, where weight and, thus, margin is expensive. Although these characteristics are side benefits for NCSP shielding benchmark development, the main driver is enabling more reliable placement of criticality accident alarm systems (CAASs) in nuclear material facilities, such as those dedicated to the production of advanced reactor fuels. CAAS placement relies on more than accurate data and code validation. It also relies on sufficiently accurate materials specifications, geometry specifications, and a well-defined, alarm-producing baseline accident. All these things require tacit knowledge and understanding of the problem being evaluated. Benchmarks can help ensure this understanding.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Performance of Microreactor Test Article with Embedded Sensors During Testing in The Single Primary Heat Extraction and Removal Emulator

The nuclear industry is pursuing microreactors that can be factory assembled and deployed to remote regions for reliable power generation. One class of microreactors uses a monolithic metal core block coupled to heat pipes that use passive heat flow, increasing the surface area for heat transfer without requiring active coolant flow through the reactor core. Additional experimental testing is required to understand the heat rejection limitations of heat pipes and thermal stresses in the monolithic core block due to significant temperature gradients. This report describes the initial characterization and testing of a stainless-steel test article that was fabricated with embedded sensors to measure heat pipe performance limits, as well as spatially distributed temperatures and strains during electrically heated thermal testing to simulate nuclear heating. The electrically heated testing was performed in the Single Primary Heat Extraction and Removal Emulator facility located at Idaho National Laboratory. The ultimate goals of this work are to (1) accurately monitor temperature and strain distributions that result from differential thermal expansion in the test articles and (2) quantify the heat rejection limits of heat pipes as a function of operating temperature and working fluid during steady-state and transient operations. Initial tests focused on the feasibility of using advanced fiber-optic sensors and other sensor technologies to improve the understanding of temperature and strain distributions within the electrically heated experiments. However, these sensing capabilities could benefit the broader microreactor community if the sensors could be used to monitor component and system health during nuclear operations to inform a limited number of microreactor operators, ultimately reducing operation and maintenance costs and moving toward semiautonomous operation.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

High sensitivity measurement of femtogram-level 238 Pu by thermal ionization mass spectrometry with correction of background 238 U

Low-concentration plutonium isotopic measurements provide a valuable fingerprint to identify possible material origins in the context of environmental contamination monitoring, environmental tracing, nuclear safeguards, nuclear forensics, and treaty monitoring. Thermal ionization mass spectrometry (TIMS) has long been recognized as one of the most sensitive techniques for plutonium isotopic measurement, but has not generally been utilized for 238 Pu determination, especially at low concentrations, due to an isobaric interference from 238 U, prevalent as background. Here, this work demonstrates a new analytical technique for correction of background 238 U from the 238 Pu counts collected during a TIMS analysis. The technique takes advantage of the higher ionization temperature of U relative to Pu and uses a 235 U tracer added after plutonium purification chemistry for 238 U semi-quantitative determination. This technique has been successfully applied to the determination of 238 Pu concentration and the 238 Pu/ 239 Pu ratio in sample types including single-isotope standards, isotopic certified reference materials, matrix-containing environmental reference materials, and simulated nuclear detonation debris. The results have been directly compared on a sample-by-sample basis to alpha spectrometry results. The detection limit by this new technique is 0.23 fg 238 Pu, which was previously unachievable by mass spectrometry and is possible in around 1 h of analysis time post-chemistry compared to weeks of required counting time by alpha spectrometry (at the same atom amount). We also present original, high precision data for Pu isotope concentrations in IAEA-384, Fangataufa Sediment, including 242 Pu results for the first time. The new technique allows measurement of a key isotope, 238 Pu, that was previously not measured in small environmental or nuclear forensics collections.

238Pu↗

The evolution of the Human Systems and Simulation Laboratory in nuclear power research

The events at Three Mile Island in the United States brought about fundamental changes in the ways that simulation would be used in nuclear operations. The need for research simulators was identified to scientifically study human-centered risk and make recommendations for process control system designs. This paper documents the human factors research conducted at the Human Systems and Simulation Laboratory (HSSL) since its inception in 2010 at Idaho National Laboratory. The facility’s primary purposes are to provide support to utilities for system upgrades and to validate modernized control room concepts. In the last decade, however, as nuclear industry needs have evolved, so too have the purposes of the HSSL. Thus, beyond control room modernization, human factors researchers have evaluated the security of nuclear infrastructure from cyber adversaries and evaluated human-in-the-loop simulations for joint operations with an integrated hydrogen generation plant. Lastly, our review presents research using human reliability analysis techniques with data collected from HSSL-based studies and concludes with potential future directions for the HSSL, including severe accident management and advanced control room technologies.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Examining phase separation and crystallization in glasses with X-ray nano-computed tomography

X-ray nano-computed tomography (nano-CT) is a powerful technique to characterize and visualize 3 dimensional (3D) phenomena in complex glasses at the nanoscale. This technique can offer a unique opportunity to explore the intricate morphology of multicomponent glass and glass-ceramic samples, due to its low X-ray energy and high spatial resolution (down to 50 nm). In the current demonstration paper, nano-CT provided insight into crystallization and phase separation, as well as a variety of other phenomena, including corrosion, fracture, and porosity. At scales ranging from 100 to 20 μm, the microstructures of phase separation in borosilicate, complex silicate, and chalcogenide glass compositions were examined. In addition, crystallites present in simulant nuclear waste glasses, volcanic glasses, and other related samples were explored. Nano-CT analysis can add to the understanding of (1) the formation processes, (2) distributions, interactions, and compositions of phases, and (3) the mechanisms, structures, and growth of crystallization and phase separation. Nano-CT offers wide potential in the field of glass science, especially when (1) common characterization methods are insufficient, (2) simple sample preparation is required, (3) 3D rendering is needed, or (4) compelling images of small, complex features are desired.

36 MATERIALS SCIENCE↗

Nautilus

A collection of useful utilities for simulating nuclear reactions and related applications.

Krueger, Brendan K. [Los Alamos National Laborator↗

Engineering Layer For System Analysis

ELSA offers various utility classes and methods to streamline the definition of regions, materials, and geometries in nuclear simulations. Key features include generating OpenMC regions, managing material properties, and providing convenient abstractions for complex geometrical and physical configurations. Additionally, ELSA supports the creation of submodels, enabling users to build modular and reusable components for their simulations. The codebase also includes robust extrusion and revolution capabilities, facilitating the efficient creation of 3D parametric geometries from 2D profiles through linear and rotational transformations.

Ferney, Paul [Idaho National Laboratory (INL), Ida↗

Product consistency test results for the LAW Phase 4 gases

In this report, the Savannah River National Laboratory provides chemical analysis of Product Consistency Test (PCT) leachates from a series of simulated nuclear waste glasses fabricated at the Pacific Northwest National Laboratory (PNNL). The series included quenched and canister-centerline cooled (CCC) versions of the glasses. The resulting data will be used in the development of enhanced property/composition models for waste vitrification at Hanford. For some of the glass leachates, minor scatter among the triplicate values of some analytes were observed. For other leachates, there were more significant differences among the triplicate values. A review of the PCT data noted that there was little difference between the normalized values based on targeted or measured glass composition. Several of the study glasses have normalized concentration of element “i” (NCi) values that are greater than the Hanford Tank Waste Treatment and Immobilization Plant immobilized low-activity waste constraint of 4 g/L for boron (B), sodium (Na), and silicon (Si). The results of these glasses will help ensure the ability of advanced glass performance models to appropriately predict acceptable compositions. For the study glasses with NCi values exceeding 4 g/L, the CCC heat treatment samples had generally lower NCi values than quenched samples. The samples of the Environmental Assessment (EA) reference glass included with each PCT set had generally consistent NCi values. The release rates for boron (B), potassium (K), lithium (Li), sodium (Na), and silicon (Si) were highly correlated for the study glasses.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Characterization of the Sulfur-Saturated Melt Versions of the LAW Phase 4 Glasses

In this report, results are provided from the analyses of a series of sulfur-saturated melt versions of simulated nuclear waste glasses, and chemical analysis of the wash solution resulting from the preparation of these glasses. The glasses were selected and fabricated by the Pacific Northwest National Laboratory as part of a broader study of the influence of glass composition on chemical durability, sulfur retention, and other properties. The resulting data will be used in the development of enhanced property/composition models for waste vitrification at Hanford. Chemical analyses were performed on a representative sample of each of the sulfur-saturated versions of the quenched glasses to allow for comparisons with the targeted compositions, as well as the measured compositions of the quenched glasses. The measured concentrations of chlorine, and fluorine were below the targeted values for most of the study glasses, likely because of volatility during the multiple melting steps. The measured concentrations of B 2 O 3 , K 2 0, and Li 2 0 were generally low relative to the targeted values. As expected, the measured concentrations of SO 3 in most of the glasses were higher than targeted due to the use of the sulfur saturation method in fabricating these glasses. The wash solutions contained mainly sodium and sulfur, with moderate concentrations of potassium.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization of the Sulfur-Saturated Melt Versions of the HFG1 Study Glasses

The U.S. Department of Energy (DOE) is responsible for building the Hanford Tank Waste Treatment and Immobilization Plant (WTP) at the Hanford Site in Washington to remediate 55 million gallons of radioactive waste that is temporarily stored in 177 underground tanks. The Office of River Protection (ORP) has requested that the Savannah River National Laboratory (SRNL) contribute to current glass studies to support successful startup of the WTP, due to SRNL’s recognized capabilities and expertise for glass waste form development. As part of this effort, the Pacific Northwest National Laboratory (PNNL) is developing, batching, and fabricating simulated high-level waste (HLW) glasses to generate the associated property data needed to validate or identify areas of potential characterization improvements in the current glass property/ composition models. Currently, the models cover only a small fraction of the waste compositions projected in the Hanford tank farm; therefore, the models must be expanded to include high fluoride compositions to successfully complete the WTP mission. SRNL support of this work is defined in the Task Technical and Quality Assurance Plan (TTQAP). This report provides results from the chemical analyses of a series of sulfur-saturated melt (SSM) versions of simulated nuclear waste glasses fabricated at PNNL. The glasses were selected as part of a broader study of the influence of glass composition on chemical durability, sulfur retention, and other properties. The glasses were designated the High Fluoride Glasses-1 (HLG1).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Product Consistency Test Results for the HFG1 Glasses

The U.S. Department of Energy (DOE) is responsible for building the Hanford Tank Waste Treatment and Immobilization Plant (WTP) at the Hanford site in Washington to remediate 55 million gallons of radioactive waste that is temporarily stored in 177 underground tanks. The Office of River Protection (ORP) has requested that the Savannah River National Laboratory (SRNL) contribute in areas of recognized capabilities and expertise for glass waste form development to support successful startup of the WTP. As part of this effort, the Pacific Northwest National Laboratory (PNNL) is developing, batching, and fabricating simulated high-level waste (HLW) glasses to generate the associated property data needed to validate or identify areas of potential characterization improvement in the current glass property/composition models. Currently, the models cover only a small fraction of the waste compositions projected in the Hanford tank farm; therefore, the models must be expanded to include high fluoride compositions to successfully complete the WTP mission. SRNL support of this work is defined in the Task Technical and Quality Assurance Plan (TTQAP). This report provides the results of the Product Consistency Test (PCT) leachates from the High Fluoride Glasses-1 (HFG1), a series of simulated nuclear waste glasses fabricated at PNNL. The series included quenched (Q) and canister-centerline cooled (CCC) versions of the glasses. The glasses were selected as part of a broader study of the influence of glass composition on chemical durability, sulfur retention, and other properties. These data will be used to validate or identify areas of potential characterization improvements in the current glass property/composition models.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Composition Measurements of the LAW Phase 5 Glasses

This report provides the results from the chemical analyses of glass compositions for the Low-Activity Waste Phase 5 study glasses, a series of simulated nuclear waste glasses fabricated at Pacific Northwest National Laboratory. These data will be used in the development of enhanced property/composition models for waste glass vitrification at Hanford. Chemical analyses were performed on a representative sample of each of the quenched glasses to allow for comparisons with targeted compositions. The relative differences between the targeted and measured concentrations of CaO, Cl - , K 2 O, Li 2 O, and SO 3 for some of the glasses were greater than 10%. Several of these glass samples were rerun to verify original measurements; however, there were no significant changes in the measurements to indicate errors in preparation or analysis of the samples. These results can be used in further characterization of this series of glasses, including the normalization of Product Consistency Test results.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Product Consistency Test Results for the LAW Phase 5 Glasses

This report provides the results of the Vapor Hydration Test solutions and the Product Consistency Test leachates from the Low-Activity Waste Phase 5 glasses, a series of simulated nuclear waste glasses fabricated at the Pacific Northwest National Laboratory. The series included quenched and canister-centerline cooled versions of the glasses. These data will be used in the development of enhanced property/composition models for waste glass vitrification at Hanford. Several of the blanks had detectable amounts of sodium and/or silicon. The measured concentrations (mg/L) of boron, sodium, and silicon for the low-activity test reference material glass included with the Product Consistency Tests were much lower than the expected low-activity test reference material test results. A review of the Product Consistency Test data indicated that there was generally little difference between the normalized values based on targeted or measured glass composition. Heat treatment had various impacts on the normalized concentration values. Most of the glasses had NC B , NC Na , and NC Si values that were greater than the Hanford Tank Waste Treatment and Immobilization Plant low-activity waste constraint of 4 g/L. The release rates for boron, sodium, and silicon were highly correlated for the study glasses.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗