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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Profiles of stratospheric chlorine nitrate (ClONO2) from atmospheric trace molecule spectroscopy/ATLAS 1 infrared solar occultation spectra

Stratospheric volume mixing ratio profiles of chlorine nitrate (ClONO2) have been retrieved from 0.01/cm resolution infrared solar occultation spectra recorded at latitudes between 14 deg N and 54 deg S by the atmospheric trace molecule spectroscopy Fourier transform spectrometer during the Atmospheric Laboratory for Applications and Science (ATLAS) 1 shuttle mission (March 24 to April 2, 1992). The results were obtained from nonlinear least squares fittings of the ClONO2 nu(sub 4) band Q branch at 780.21/cm with improved spectroscopic parameters generated on the basis of recent laboratory work. The individual profiles, which have an accuracy of about +/- 20%, are compared with previous observations and model calculations.

Rinsland, C. P.↗
NASA NTRS1994

Infrared spectroscopic measurements of the total column abundance of ethan (C2H6) above Lauder, New Zealand

Total vertical column aboundances of atmospheric ethane (C2H6) have been retrieved form more than 350 high-resolution infrared solar spectra recorded on 129 days between December 1992 and March 1994 at the Network for the Detection of Stratospheric Change (NDSC) station in Lauder, New Zealand (latitude 45.04 deg S, 169.68 deg E, 0.37 km altitude). The results are based on nonlinear least squares fits to narrow spectral intervals containing the unresolved C2H6 nu (sub 7) band (P)Q(sub 3) and (R)Q(sub 0) subbranches at 2976.8 and 2986.7/cm. The measured Lauder column abundances show a pronounced seasonal cycle with a maximum value of (8.6 +/- 0.5) x 10(exp 15) molecules/sq cm in September and a minimum value of (3.8 +/- 0.5) x 10 (exp 15) molecules/sq cm in February. Assuming a realistic vertical distribution for C2H6, these values correspond to surface level volume-mixing ratios of 0.52 and 0.23 ppbv (parts per billion by volume), respectively. The phase and relative amplitude of the Lauder C2H6 seasonal cycle are similar to corresponding values determined from infrared measurements at the Jungfraujoch (46.55 deg N, 7.98 deg E, 3.58 km altitude) and Mauna Loa (latitude 19.5 deg N, longitude 155.6 deg W, 3.5 km altitude) NDSC stations, but the inferred absolute magnitudes of the Lauder surface level mixing ratios during the same season are significantly lower. The Lauder C2H6 measurements are also compared with published southern hemisphere surface level sampling measurements and two-dimensional model calculations.

Rinsland, Curtis P.↗
NASA NTRS1994

An improved solution to the 'Rankine-Hugoniot' problem

This paper presents an extension of the nonlinear least squares fitting technique of Vinas and Scudder (1986) (VS), which finds the physical and geometrical properties of nondissipational magnetohydrodynamic (MHD) shocks. The new method incorporates plasma temperature observations in the form of normal momentum flux and energy density flux conservation as well as plasma density, velocity, and magnetic field data. The new technique is capable of using known standard deviations in the individual measurement points to properly weight the fitting procedure. The new fitting code is validated through the analysis of synthetic shocks with known physical and geometrical properties. Finally, it is compared to the original VS method and the preaveraged velocity coplanarity technique.

Szabo, A.↗
NASA NTRS1996

Modeling of Aircraft Unsteady Aerodynamic Characteristics/Part 3 - Parameters Estimated from Flight Data: Parameters Estimated from Flight Data - Part 3

A nonlinear least squares algorithm for aircraft parameter estimation from flight data was developed. The postulated model for the analysis represented longitudinal, short period motion of an aircraft. The corresponding aerodynamic model equations included indicial functions (unsteady terms) and conventional stability and control derivatives. The indicial functions were modeled as simple exponential functions. The estimation procedure was applied in five examples. Four of the examples used simulated and flight data from small amplitude maneuvers to the F-18 HARV and X-31A aircraft. In the fifth example a rapid, large amplitude maneuver of the X-31 drop model was analyzed. From data analysis of small amplitude maneuvers ft was found that the model with conventional stability and control derivatives was adequate. Also, parameter estimation from a rapid, large amplitude maneuver did not reveal any noticeable presence of unsteady aerodynamics.

Klein, Vladislav↗
NASA NTRS1996

Polarization Signals of Common Spacecraft Materials

This is the final report documenting the results of the polarization testing of near-planar objects with various reflectance properties. The purpose of this investigation was to determine the portion of the reflected signal which is polarized for materials commonly used in space applications. Tests were conducted on several samples, with surface characteristics ranging from highly reflective to relatively dark. The measurements were obtained by suspending the test object in a beam of collimated light. The amount of light falling on the sample was controlled by a circular aperture placed in the light field. The polarized reflectance at various phase angles was then measured. A nonlinear least squares fitting program was used for analysis. For the specular test objects, the reflected signals were measured in one degree increments near the specular point. Otherwise, measurements were taken every five degrees in phase angle. Generally, the more diffuse surfaces had lower polarized reflectances than their more specular counterparts. The reflected signals for the more diffuse surfaces were spread over a larger phase angle range, while the signals from the more specular samples were reflected almost entirely within five degrees of angular deviation from the specular point. The method used to test all the surfaces is presented. The results of this study will be used to support the NASA Orbital Debris Optical Signature Tests. These tests are intended to help better understand the reflectance properties of materials often used in space applications. This data will then be used to improve the capabilities for identification and tracking of space debris.

Gravseth, Ian↗
NASA NTRS1996

Spectroscopy Made Easy: A New Tool for Fitting Observations with Synthetic Spectra

We describe a new software package that may be used to determine stellar and atomic parameters by matching observed spectra with synthetic spectra generated from parameterized atmospheres. A nonlinear least squares algorithm is used to solve for any subset of allowed parameters, which include atomic data (log gf and van der Waals damping constants), model atmosphere specifications (T(sub eff, log g), elemental abundances, and radial, turbulent, and rotational velocities. LTE synthesis software handles discontiguous spectral intervals and complex atomic blends. As a demonstration, we fit 26 Fe I lines in the NSO Solar Atlas (Kurucz et al.), determining various solar and atomic parameters.

Valenti, J. A.↗
NASA NTRS1996

Examination of Biomass Fire Temperature and Areal Extent from Calibrated AVIRIS Spectra

Biomass burning is an important process on the Earth at the local, regional and global scales. To investigate issues related to biomass burning, a range of remotely acquired data were measured as part of the NASA Smoke Cloud Aerosol and Radiation experiment in Brazil, 1995. As part of this experiment, images of calibrated spectral radiance from 400 to 2500 nm at 10 nm intervals were acquired by AVIRIS. To investigate the expression of biomass fires in AVIRIS spectra, a model of the upwelling radiance from a burning fire was developed. This spectral model accounts for four components in the 20 by 20 m AVIRIS spatial resolution element. These are: (1) the atmospheric path radiance, (2) the solar reflected radiance from unburnt vegetation and soil, (3) the apparent temperature and area of a primary fire, and (4) the apparent temperature and area of a secondary fire. A nonlinear least squares spectral fitting algorithm was developed to invert this model for the AVIRIS spectra. The derived biomass burning parameters from this algorithm are presented for AVIRIS spectral images acquired over Cuiaba, Brazil on 25 August 1995.

Green Robert O.↗
NASA NTRS1996

Retrieval of Surface Snow Grain Size and Melt Water from AVIRIS Spectra

The Earth's energy balance and hydrology are affected by the distribution and characteristics of snow cover on the surface. Snow grain size and snow melt influence surface albedo and hydrology. A model of snow reflectance that depends on both grain size and surface melt water was developed to derive these parameters from remote spectral measurements. This reflectance model is based on a discrete ordinate radiative transfer approach that uses Mie calculations of snow optical properties, which are based on the complex refractive index of ice and water. This snow model was linked to an atmospheric radiative transfer code and a nonlinear least squares fitting algorithm. The resulting combined algorithm was applied to an AVIRIS snow data set acquired over Mammoth Mountain, California. Maps of grain size and surface snow melt were generated that are consistent with the expected ranges and distributions for conditions at the site.

Green Robert O.↗
NASA NTRS1999

Wind Speed Measurement from Bistatically Scattered GPS Signals

Instrumentation and retrieval algorithms are described which use the forward, or bistatically scattered range-coded signals from the Global Positioning System (GPS) radio navigation system for the measurement of sea surface roughness. This roughness is known to be related directly to the surface wind speed. Experiments were conducted from aircraft along the TOPEX ground track, and over experimental surface truth buoys. These flights used a receiver capable of recording the cross correlation power in the reflected signal. The shape of this power distribution was then compared against analytical models derived from geometric optics. Two techniques for matching these functions were studied. The first recognized the most significant information content in the reflected signal is contained in the trailing edge slope of the waveform. The second attempted to match the complete shape of the waveform by approximating it as a series expansion and obtaining the nonlinear least squares estimate. Discussion is also presented on anomalies in the receiver operation and their identification and correction.

Garrison, James L.↗
NASA NTRS1985

Tentative Identification of the 780/cm nu(sub 4) Band Q Branch of Chlorine Nitrate in High-Resolution Solar Absorption Spectra of the Stratosphere

Absorption by the Q branch of the nu(sub 4), band of ClONO2 at 780.2/cm has been tentatively identified in a series of 0.02/cm resolution balloon-borne solar absorption spectra of the stratosphere. The spectral data were recorded at sunset from a flot altitude of 33.5 km during a balloon flight from Holloman Air Force Base (32.8deg N, 106.0 deg W) near Alamogordo, New Mexico, on March 23 1998. A preliminary ClONO2 vertical profile has been determined from the stratospheric spectra by using the technique of nonlinear least squares spectral curve fitting and new spectroscopic parameters deduced from high-resolution laboratory spectra of ClONO2 and O3.

Rinsland, C. P.↗
NASA NTRS1992

Mt. Pinatubo SO2 Column Measurements From Mauna Loa

Absorption features of the nu(sub 1) band of SO2 have been identified in high resolution infrared solar absorption spectra recorded from Mauna Loa, Hawaii, on July 9 and 12, 1991, shortly after the arrival of the first eruption plume from the Mt. Pinatubo volcano in the Phillipines. A total SO2 vertical column amount of (5.1 +/- 0.5) x 10(exp 16) molecules/sq cm on July 9 has been retrieved based on nonlinear least- squares spectral fittings of 9 selected SO2 absorption features with an updated set of SO2 spectral parameters. A SO2 total column upper limit of 0.9 x 10(esp 16) molecules/sq cm deduced from measurements on September 20-24, 1991, is consistent with the dispersion of the SO2 cloud and the rapid conversion of the SO2 vapor into volcanic aerosol particles.

Goldman, A.↗
NASA NTRS1994

Extraction of Dry Leaf Spectral Features from Reflectance Spectra of Green Vegetation

Reflectance spectra of green vegetation in the 1.4-2.5 micrometer region are dominated by liquid water absorptions. In this article, we describe the analysis of a set of reflectance spectra of green vegetation, dry vegetation, and liquid water measured in a laboratory using a nonlinear least squares spectral matching technique. We conclude that both the liquid water and the dry materials contribute to the reflectance spectra of green vegetation in the 1.0-2.5 micrometer region. Our matching of data acquired with the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) over two vegetated areas in Oregon Transect with a pure water spectrum also shows a residual absorption feature near 1.72 micrometers.

Gao, Bo-Cai↗
NASA NTRS1991

Case Studies of Water Vapor and Surface Liquid Water from AVIRIS Data Measured Over Denver, CO and Death Valley, CA

High spatial resolution column atmospheric water vapor amounts and equivalent liquid water thicknesses of surface targets are retrieved from spectral data collected by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). The retrievals are made using a nonlinear least squares curve fitting technique. Two case studies from AVIRIS data acquired over Denver-Platteville area, Colorado and over Death Valley, California are presented. The column water vapor values derived from AVIRIS data over the Denver-Platteville area are compared with those obtained from radiosondes, ground level upward-looking microwave radiometers, and geostationary satellite measurements. The column water vapor image shows spatial variation patterns related to the passage of a weather front system. The column water vapor amounts derived from AVIRIS data over Death Valley decrease with increasing surface elevation. The derived liquid water image clearly shows surface drainage patterns.

Gao, B.-C.↗
NASA NTRS2001

Properties of Stratospheric Aerosol Estimated from HALOE Data

Extinction coefficients for stratospheric aerosols at 8 HALOE (HALogen Occultation Experiment) wavelengths are determined by comparing transmittances data for two adjacent solar occultation measurements, where one limb path is loaded with aerosols but the other path is free of aerosols. These extinction coefficients are used to infer the aerosol properties such as composition and size distribution parameters. Mie theory has been used to calculate the extinction coefficients, and a nonlinear least square method is applied to determine the aerosol properties. Sixteen cases are selected for the retrieval in southern hemisphere at latitudes from 21 to 48 deg S for the period of 29 Mar - 31 May 1992. Retrieved size width ranges from 1.1 to 1.5 and radius ranges from 0.25 to 0.45 micrometers. These size parameters are within the ranges of in situ measurements at Laramie, Wyoming. Retrieved weight percent of H2SO4 is larger than the equilibrium value by about 5 to approximately 10 weight percent, similar to the results for northern hemisphere at latitudes 20 to 55 deg N for the period from Nov 1991 to Feb. 1992.

Lee, Kwang-Mog↗
NASA NTRS2002

Paralinear Oxidation of Silicon Nitride in a Water Vapor/Oxygen Environment

Three silicon nitride materials were exposed to dry oxygen flowing at 0.44 cm/s at temperatures between 1200 and 1400 C. Reaction kinetics were measured with a continuously recording microbalance. Parabolic kinetics were observed. When the same materials were exposed to a 50% H2O - 50% O2 gas mixture flowing at 4.4 cm/s, all three types exhibited paralinear kinetics. The material is oxidized by water vapor to form solid silica. The protective silica is in turn volatilized by water vapor to form primarily gaseous Si(OH)4. Nonlinear least squares analysis and a paralinear kinetic model were used to determine both parabolic and linear rate constants from the kinetic data. Volatilization of the protective silica scale can result in accelerated consumption of Si3N4. Recession rates under conditions more representative of actual combustors are compared to the furnace data.

Fox, Dennis S.↗
NASA NTRS2003

High Resolution Spectroscopy to Support Atmospheric Measurements

Spectroscopic parameters (such as line position, intensity, broadening and shifting coefficients and their temperature dependences, line mixing coefficients etc.) for various molecular species of atmospheric interest are determined. In order to achieve these results, infrared spectra of several molecular bands are obtained using high-resolution recording instruments such as tunable diode laser spectrometer and Fourier transform spectrometers. Using sophisticated analysis routines (Multispectrum nonlinear least squares technique) these high-resolution infrared spectra are processed to determine the various spectral line parameters that are cited above. Spectra were taken using the McMath-Pierce Fourier transform spectrometer (FTS) at the National Solar Observatory on Kitt Peak, Arizona as well as the Bruker FTS at the Pacific Northwest National Laboratory (PNNL) at Richland, Washington. Most of the spectra are acquired not only at room temperature, but also at several different cold temperatures. This procedure is necessary to study the variation of the spectral line parameters as a function of temperature in order to simulate the Earth's and other planetary atmospheric environments. Depending upon the strength or weakness of the various bands recorded and analyzed, the length(s) of the absorption cells in which the gas samples under study are kept varied from a few centimeters up to several meters and the sample temperatures varied from approximately +30 C to -63 C. Research on several infrared bands of various molecular species and their isotopomers are undertaken. Those studies are briefly described.

Venkataraman, Malathy Devi↗
NASA NTRS2004

Monitoring space shuttle air quality using the Jet Propulsion Laboratory electronic nose

A miniature electronic nose (ENose) has been designed and built at the Jet Propulsion Laboratory (JPL), Pasadena, CA, and was designed to detect, identify, and quantify ten common contaminants and relative humidity changes. The sensing array includes 32 sensing films made from polymer carbon-black composites. Event identification and quantification were done using the Levenberg-Marquart nonlinear least squares method. After successful ground training, this ENose was used in a demonstration experiment aboard STS-95 (October-November, 1998), in which the ENose was operated continuously for six days and recorded the sensors' response to the air in the mid-deck. Air samples were collected daily and analyzed independently after the flight. Changes in shuttle-cabin humidity were detected and quantified by the JPL ENose; neither the ENose nor the air samples detected any of the contaminants on the target list. The device is microgravity insensitive.

manned↗
NASA NTRS1999

CARES/Life Ceramics Durability Evaluation Software Enhanced for Cyclic Fatigue

The CARES/Life computer program predicts the probability of a monolithic ceramic component's failure as a function of time in service. The program has many features and options for materials evaluation and component design. It couples commercial finite element programs--which resolve a component's temperature and stress distribution--to reliability evaluation and fracture mechanics routines for modeling strength-limiting defects. The capability, flexibility, and uniqueness of CARES/Life have attracted many users representing a broad range of interests and has resulted in numerous awards for technological achievements and technology transfer. Recent work with CARES/Life was directed at enhancing the program s capabilities with regards to cyclic fatigue. Only in the last few years have ceramics been recognized to be susceptible to enhanced degradation from cyclic loading. To account for cyclic loads, researchers at the NASA Lewis Research Center developed a crack growth model that combines the Power Law (time-dependent) and the Walker Law (cycle-dependent) crack growth models. This combined model has the characteristics of Power Law behavior (decreased damage) at high R ratios (minimum load/maximum load) and of Walker law behavior (increased damage) at low R ratios. In addition, a parameter estimation methodology for constant-amplitude, steady-state cyclic fatigue experiments was developed using nonlinear least squares and a modified Levenberg-Marquardt algorithm. This methodology is used to give best estimates of parameter values from cyclic fatigue specimen rupture data (usually tensile or flexure bar specimens) for a relatively small number of specimens. Methodology to account for runout data (unfailed specimens over the duration of the experiment) was also included.

Nemeth, Noel N.↗