Calculated ion distributions in a helium negative glow.
Ion distributions in helium negative glow assuming diffusion from cathode, conversion to molecular ions and recombination
HELIUM AFTERGLOW↗
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The role of unneutralized surface ions in negative potential arcing
The observed arcing on negatively biased solar arrays exposed to plasma environments is shown to be due to an effective charge layer on the interconnect formed by ion collection from the plasma. Time scales to form this layer are shown to be in agreement with experimental observations. A quantitative theory is presented which predicts arcing threshold dependence on plasma density and external potentials. After breakdown, the discharge process is modeled as space charge limited transport to nearby coverslips. Peak currents and decay times predicted by this model are compared with experimental observations.
Jongeward, G. A.↗
Large Abundances of Polycyclic Aromatic Hydrocarbons in Titan's Upper Atmosphere
In this paper, we analyze the strong unidentified emission near 3.28 micron in Titan's upper daytime atmosphere recently discovered by Dinelli et al.We have studied it by using the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbons (PAHs), after absorbing UV solar radiation, are able to emit strongly near 3.3 micron. By using current models for the redistribution of the absorbed UV energy, we have explained the observed spectral feature and have derived the vertical distribution of PAH abundances in Titan's upper atmosphere. PAHs have been found to be present in large concentrations, about (2-3) × 10(exp 4) particles / cubic cm. The identified PAHs have 9-96 carbons, with a concentration-weighted average of 34 carbons. The mean mass is approx 430 u; the mean area is about 0.53 sq. nm; they are formed by 10-11 rings on average, and about one-third of them contain nitrogen atoms. Recently, benzene together with light aromatic species as well as small concentrations of heavy positive and negative ions have been detected in Titan's upper atmosphere. We suggest that the large concentrations of PAHs found here are the neutral counterpart of those positive and negative ions, which hence supports the theory that the origin of Titan main haze layer is located in the upper atmosphere.
PAH↗
Application of reversal electron attachment for ultrasensitive detection of thermal electron-attaching molecules - CCl4 and C6H5O2
A standard gas-dilution method was used to determine the selective response of the reversal electron attachment detector to carbon tetrachloride concentrations in nitrogen. Data are provided that determine the lowest concentration of sample detectable with the present instrumental configuration as being below 1.0 part per trillion by volume. The incorporation of a 90-deg electrostatic deflector with the quadrupole mass spectrometer is shown to be vital, and with it, negative-ion quadrupole mass spectrometry is used to characterize the ionization process. Observations are also made of the reversal electron attachment response to nitrobenzene. The analytical potential of reversal electron capture negative-ion mass spectrometry is examined, and areas for future development are discussed.
Bernius, Mark T.↗
Early time evolution of a chemically produced electron depletion
The early time evolution of an ionospheric electron depletion produced by a radially expanding electron attachment chemical release is studied with a two-dimensional simulation model. The model includes electron attachment chemistry, incorporates fluid electrons, particle ions and neutrals, and considers the evolution in a plane perpendicular to the geomagnetic field for a low beta plasma. Timescales considered are of the order of or less than the cyclotron period of the negative ions that result as a by-product of the electron attacment reaction. This corresponds to time periods of tenths of seconds during recent experiemts. Simulation results show that a highly sheared azimuthal electron flow velocity develops in the radially expanding depletion boundary. This sheared electron flow velocity and the steep density gradients in the boundary give rise to small-scale irregulatities in the form of electron density cavities and spikes. The nonlinear evolution of these irregularities results in trapping and ultimately turbulent heating of the negative ions.
Scales, W. A.↗
Rocket measurements of ion and electron densities in the D-region during sunrise.
Results from two rockets launched near sunrise at White Sands, N. Mex., when positive ion and electron densities were measured in the D-region for solar zenith angles of 91 and 79 deg. The measurements cover the height range 80 to 110 km and complement previous vlf observations and rocket measurements of electron density. It is shown that the majority of negative ions in this height range are detached near to after ground sunrise. On the basis of these measurements it is possible to discuss electron affinity of negative ions and ion production functions during twilight.
Pedersen, A.↗
Negative radiation in partially ionized gas
A stationary, nonlinear collisional-radiative model for high-temperature atomic oxygen is presented. Populations of negative ions, electrons, positive ions and excited atoms and intensities of spectral, continuum and dielectronic recombination radiation are calculated in a wide range of conditions. Calculated total continuum emission is in good agreement with existing measurements. The contribution of the negative ion emission to the total continuum emission is found to be significant.
Soon, W. H.↗
Effects of contaminants in CO2 lasers.
A theoretical model which includes the effects of contaminants is developed for the high flow electric discharge CO2-N2-He laser. The model couples the excitation and relaxation processes, CO2 dissociation, and negative ion formation with the flow processes. An analysis of the effects of CO, O2, NO, and N2O impurities on the average small signal gain is presented. CO decreases the gain by collisional depopulation of the upper laser level, and O2, NO, and N2O reduce the gain by decreasing the electron density by forming stable negative ions. In particular, N2O exhibits a strong quenching effect because of its large dissociation cross section for the formation of O(-).
Smith, N. S.↗
Uncertainty Analysis of Air Radiation for Lunar Return Shock Layers
By leveraging a new uncertainty markup technique, two risk analysis methods are used to compute the uncertainty of lunar-return shock layer radiation predicted by the High temperature Aerothermodynamic Radiation Algorithm (HARA). The effects of epistemic uncertainty, or uncertainty due to a lack of knowledge, is considered for the following modeling parameters: atomic line oscillator strengths, atomic line Stark broadening widths, atomic photoionization cross sections, negative ion photodetachment cross sections, molecular bands oscillator strengths, and electron impact excitation rates. First, a simplified shock layer problem consisting of two constant-property equilibrium layers is considered. The results of this simplified problem show that the atomic nitrogen oscillator strengths and Stark broadening widths in both the vacuum ultraviolet and infrared spectral regions, along with the negative ion continuum, are the dominant uncertainty contributors. Next, three variable property stagnation-line shock layer cases are analyzed: a typical lunar return case and two Fire II cases. For the near-equilibrium lunar return and Fire 1643-second cases, the resulting uncertainties are very similar to the simplified case. Conversely, the relatively nonequilibrium 1636-second case shows significantly larger influence from electron impact excitation rates of both atoms and molecules. For all cases, the total uncertainty in radiative heat flux to the wall due to epistemic uncertainty in modeling parameters is 30% as opposed to the erroneously-small uncertainty levels (plus or minus 6%) found when treating model parameter uncertainties as aleatory (due to chance) instead of epistemic (due to lack of knowledge).
Kleb, Bil↗
Design and Preliminary Testing Plan of Electronegative Ion Thruster
Electronegative ion thrusters are a new iteration of existing gridded ion thruster technology differentiated by their ability to produce and accelerate both positive and negative ions. The primary motivations for electronegative ion thruster development include the elimination of lifetime-limiting cathodes from a thruster system and the ability to generate appreciable thrust through the acceleration of both positive or negative-charged ions. Proof-of-concept testing of the PEGASES (Plasma Propulsion with Electronegative GASES) thruster demonstrated the production of positively and negatively-charged ions (argon and sulfur hexafluoride, respectively) in an RF discharge and the subsequent acceleration of each charge species through the application of a time-varying electric field to a pair of metallic grids similar to those found in gridded ion thrusters. Leveraging the knowledge gained through experiments with the PEGASES I and II prototypes, the MINT (Marshall's Ion-ioN Thruster) is being developed to provide a platform for additional electronegative thruster proof-of-concept validation testing including direct thrust measurements. The design criteria used in designing the MINT are outlined and the planned tests that will be used to characterize the performance of the prototype are described.
Schloeder, Natalie R.↗
An intercomparison technique for measuring thermal attachment cross sections and rate constants in distinct final channels
A new technique is introduced for comparing negative-ion signal rates in which a common ion is produced by dissociative attachment in a series of molecules. Measurements are carried out at electron energies less than 100 MeV and at resolutions of 6-8 MeV (FWHM). The technique is demonstrated by detection of the Cl(-) signal in CFCl3, CCl4, CF2Cl2, 1,1,2-C2Cl3F3, 1,1,1-C2Cl3F3 and C2Cl4. Measurements for 1,1,1-C2Cl3F3 show that there is a significant open channel, other than Cl(-) formation, which accounts for about 60 percent of negative-ion formation in thermal-multiple-collision (swarm) experiments. Channel cross sections and rate constants are given for the process Cl(-)/1,1,1-Cl2Cl3F3, as well as in C2Cl4, for the separate channels Cl(-)/C2Cl4 and C2Cl4(-)/C2Cl4.
Alajajian, S. H.↗
Mobilities of some positive and negative hydrogen ions in He and H2
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Wealton, J. H.↗
General features of the Comet Halley-solar wind interaction from plasma measurements
The Giotto Complete Positive ion, Electron and Ram Negative Ion measurements near Comet Halley plasma experiment identified regions in which the solar wind interaction with the cometary plasma displayed characteristic features. Beginning 4.6 million km from the comet there is an upstream region with sporadic connection to the comet. An electron foreshock is present up to 250,000 km away from the bow shock. A bow shock is detected at 1.15 million km. Between the bow shock and the cometopause the outer regions can be divided into three parts. A cometopause is found at 135,000 km, and a density decrease is detected at 45,000 km from the comet. The detailed plasma features associated with these regions are described.
Reme, H.↗
Electron distributions upstream of the Comet Halley bow shock - Evidence for adiabatic heating
Three-dimensional plasma electron (22 eV to 30 keV) observations upstream of Comet Halley bow shock, obtained by the RPA-1 COPERNIC (Reme Plasma Analyzer - Complete Positive Ion, Electron and Ram Negative Ion Measurements near Comet Halley) experiment on the Giotto spacecraft are reported. Besides electron distributions typical of the undisturbed solar wind and backstreaming electrons observed when the magnetic field line intersects the cometary bow shock, a new type of distribution, characterized by enhanced low energy (less than 100 eV) flux which peaks at 90-deg pitch angles is found. These are most prominent when the spacecraft is on field lines which pass close to but are not connected to the bow shock. The 90-deg pitch angle electrons appear to have been adiabatically heated by the increase in the magnetic field strength resulting from the compression of the upstream solar wind plasma by the cometary mass loading. A model calculation of this effect which agrees qualitatively with the observed 90-deg flux enhancements is presented.
Larson, D. E.↗
Electron plasma environment at comet Grigg-Skjellerup: General observations and comparison with the environment at comet Halley
The three-dimensional electron spectrometer of the Reme plasma analyzer-complete positive ion, electron and ram negative ion measurements near comet Halley (RPA-COPERNIC) experiment aboard the Giotto spacecraft, although damaged during the comet Halley encounter in March 1986, has provided very new results during the encounter on July 10, 1992, with the weakly active comet Grigg-Skjellerup (G-S). The main characteristic features of the highly structured interaction region extending from approximately 26,500 km inbound to approximately 37,200 km outbound are presented. These results are compared to the results obtained by the same instrument during the Giotto comet Halley fly-by. Despite the large difference in the size of the interaction regions (approximately 60,000 km for G-S, approximately 2000,000 km for Halley) due to 2 orders of magnitude difference in cometary neutral gas production rate, there are striking similarities in the solar wind interactions with the two comets.
Reme, H.↗
Investigations of negative and positive cesium ion species
A direct test is provided of the hypothesis of negative ion creation at the anode or collector of a diode operating under conditions simulating a cesium thermionic converter. The experimental technique involves using direct ion sampling through the collector electrode with mass analysis using a quadrupole mass analyzer. Similar measurements are undertaken on positive ions extracted through the emitter electrode. Measurements were made on a variety of gases including pure cesium, helium-cesium mixtures and cesium-hydrogen as well as cesium-xenon mixtures. The gas additive was used primarily to aid in understanding the negative ion formation processes. Measurements were conducted using emitter (cathode) temperatures up to about 1000 F. The major negative ion identified through the collector was Cs(-) with minor negative ion peaks tentatively identified as H(-), H2(-), H3(-), He(-) and a mass 66. Positive ions detected were believed to be Cs(+), Cs2(+) and Cs3(+).
Chanin, L. M.↗
Photodetachment of thermally relaxed CO3/-/
The CO3(-) ion is the most abundant negative ion species in the night-time D region (65-85 km above earth's surface). The absolute photodetachment cross section and the solar detachment rate of ground electronic and vibrational energy state of this ion have been determined by using an electron-detecting drift-tube method. The CO3(-) ion is identified by mass and mobility measurements and its cross section is obtained. The solar photodetachment rate is found to be 0.022. The experiment may be of interest to the modeling of the ionized atmosphere.
Hong, S. P.↗
Radionuclide measurements by accelerator mass spectrometry at Arizona
Over the past years, Tandem Accelerator Mass Spectrometry (TAMS) has become established as an important method for radionuclide analysis. In the Arizona system the accelerator is operated at a thermal voltage of 1.8MV for C-14 analysis, and 1.6 to 2MV for Be-10. Samples are inserted into a cesium sputter ion source in solid form. Negative ions sputtered from the target are accelerated to about 25kV, and the injection magnet selects ions of a particular mass. Ions of the 3+ charge state, having an energy of about 9MeV are selected by an electrostatic deflector, surviving ions pass through two magnets, where only ions of the desired mass-energy product are selected. The final detector is a combination ionization chamber to measure energy loss (and hence, Z), and a silicon surface-barrier detector which measures residual energy. After counting the trace iosotope for a fixed time, the injected ions are switched to the major isotope used for normalization. These ions are deflected into a Faraday cup after the first high-energy magnet. Repeated measurements of the isotope ratio of both sample and standards results in a measurement of the concentration of the radionuclide. Recent improvements in sample preparation for C-14 make preparation of high-beam current graphite targets directly from CO2 feasible. Except for some measurements of standards and backgrounds for Be-10 measurements to date have been on C-14. Although most results have been in archaeology and quaternary geology, studies have been expanded to include cosmogenic C-14 in meteorites. The data obtained so far tend to confirm the antiquity of Antarctic meteorites from the Allan Hills site. Data on three samples of Yamato meteorites gave terrestrial ages of between about 3 and 22 thousand years.
Jull, A. J. T.↗