Super 40 Ar- super 40 K ages of silicate inclusions in iron meteorites.
Argon and potassium in silicate inclusions of iron meteorites analyzed, determining radioactive age
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Argon and potassium in silicate inclusions of iron meteorites analyzed, determining radioactive age
Ru isotopic compositions of magmatic iron meteorites and chondrites overlap with terrestrial Ru at the 0.3 to 0.9 (epsilon) level. Additional information is contained in the original extended abstract.
Physical and chemical properties of iron meteorite and mesosiderite fusion crusts, and cosmic spherule production
The characteristics of the sulfide and metal phases of Derrick Peak, Cape York, Grant, Gibeon, and Santa Clara iron meteorite samples are examined. The textures and mineralogies of the samples are described. The effects of thermal and shock events on the distribution of Ag, and the relationship between Ag-107 and Pd are investigated. The correlation between the thermal histories and metal and sulfide nodules of the Gibeon and Santa Clara specimens is analyzed. It is noted that the Pd-107-Ag107 systematics involve the isotopic chemistry and cooling history of iron meteorites, the intensity of late extraterrestrial shock occurrences, and thermal processing.
Trace element analyses using proton induced X-ray emission and synchrotron X-ray fluorescence have been made on metal and troilite from nine iron meteorites representing five geochemical groups. Nickel and copper distribution coefficients D (troilite/metal) vary by factors of 600 and 20, respectively, correlate positively with kamacite bandwidth and correlate negatively with bulk nickel content. Meteorites with bulk Ni of less than 10 percent have Cu-enriched troilite while those with Ni greater than 10 percent have Cu-depleted troilite. Since magmatic evolution and partial melting will produce Cu-enriched troilite only, the observation of Cu-depleted troilite in Ni-rich meteorites is evidence for subsolidus reequilibration, a process which reduces D(Cu) by transfer of Cu to exsolving metal. Elemental redistribution may have played an important role in establishing the present chemical trends in iron meteorites.
The intensity, relative stability and directional behavior in alternating field demagnetization of natural, saturation, thermal and spontaneous magnetization were studied for a variety of iron meteorites. Results show that remanence and relative stability increase from the coarser to the finer-grained samples. In addition, natural remanent magnetization coercivity spectra are found to soften with coarsening of the grain size. The link between fine structure and magnetization direction in octahedrites is also discussed. The combined effect of magnetocrystalline- and shape-anisotropy of the crystallographically ordered ferromagnetic kamacite alpha-phase renders the iron meteorites of little use for the study of ancient solar system fields.
Platinum and palladium distribution in iron meteorites and ordinary chondrite metal phase spectrographically determined
Cooling rates for Widmanstatten pattern formation in iron meteorites used to obtain data on parent meteorite bodies
Several low Ni-iron meteorites previously classified with group IAB are reclassified with group IIICD because of lower Ge, Ga, W, and Ir concentrations and higher As concentrations. The low Ni extreme of IIICD is now 62 mg/g, and that of IAB is 64 mg/g. It is proposed that the meteorites of both groups formed as individual shock melts on a chondritic parent body. The differences in log element-log Ni slopes of the daughter irons demonstrate that there were detailed differences in the composition and size of phases in the parental material (e.g., more Ni in the sulfides or metal of IAB, or more Ge and Ir in the oxides of IIICD).
Octahedrite Woodbine meteorite with inclusions of silicate minerals chemically analyzed and compared with meteorites of similar composition
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Computed tomography (CT) imaging and electron-probe microanalysis (EPMA) have been used to study samples of the Mundrabilla and Colomera iron meteorites in order to perform structural, textural, and mineralogical analysis. Both gamma-ray (Co-60 source, essentially monochromatic 1.25MeV avg.) and x-ray (420 KeV, continuous) sources have been used, with effective resolution of approximately 1 mm and 0.25 mm, respectively. The gamma-ray source provides approx. 15 cm penetration through steel and is used for larger samples, whereas the x-ray source provides superior resolution at reduced penetration but exhibits beam hardening artifacts. Here we present a combined approach where CT and EPMA imaging and microanalysis aid in the identification of structural and compositional features in iron meteorites.
Measurements of solid metal/liquid metal trace element partition coefficients, which are used to interpret the crystallization history of magmatic iron meteorite groups differ greatly between different research groups, using different experimental techniques. Specifically, partition coefficients measured utilizing 'static' experiments which approach equilibrium cannot be reconciled with the results of 'dynamic' experiments which mimic fractional crystallization. We report new tests of our 'static' experimental technique and demonstrate that our methodology yields reliable equilibrium values for Ni, P and Ge partition coefficients. Partition coefficients in the Fe-Ni-S-P system are well matched by interpolation between the Fe-Ni-S and Fe-Ni-P subsystems. In contrast, the predictions of 'dynamic' experiments do not agree with our measurements and, consequently, the ability of 'dynamic' experiments to reproduce iron meteorite Ge vs. Ni fractionation trends successfully must be regarded as fortuitous.
X ray diffraction studies of kamacite /alpha-iron/ from iron meteorites indicating shock induced alteration and unstable polymorph influence
Mossbauer spectra of shocked and unshocked iron meteorite and fayalite
Analyses of magmatic iron meteorites, plotted on LogC(sub i) vs LogC(sub Ni) diagrams, often form linear arrays. Traditionally, this linearity has been ascribed to fractional crystallization under the assumption of constant partition coefficients (i.e., Rayleigh fractionation). Paradoxically, however, partition coefficients in the Fe-Ni-S-P system are decidedly not constant. This contribution provides a rationale for understanding how trends on LogC(sub i) vs LogC(sub Ni) diagrams can be linear, even when partition coefficients are changing rapidly.
IIE iron meteorites contain silicate inclusions whose characteristics suggest a parent body similar to that of H-chondrites. However, these silicates show a wide range of alteration, ranging from Netschadvo and Techado, whose inclusions are little altered. to highly differentiated silicates like-those in Kodaikanal, Weekeroo Station and Colomera, which have lost metal and sulfur and are enriched in feldspar. We find these inclusions to show varying degrees of shock alteration. Because only a limited amount of data on - isotopic ages of HE silicates were available, we made Ar-39 - Ar-40 age determinations of Watson, Techado, miles Colomera, and Sombrerete. Watson has an Ar-Ar age of 3.653 +/- 0.012 Gyr, similar to previously reported ages for Kodaikanal and Netschadvo. We suggest that the various determined radiometric ages of these three meteorites were probably reset by a common impact event. The space exposure ages for these three meteorites are also similar to each other and are considerably younger than exposure ages of other IIEs. Ar-39 - Ar-40 ages inferred for the other four meteorites analyzed are considerably older than Watson and are: Techado =4.49 +/- 0.01 Gyr, Miles =4.412 +/- 0.016 Gyr, Colomera =4.469 +/- 0.012 Gyr, and Sombrerete =4.535 +/- 0.005 Gyr. These ages are in fair agreement with previously reported Rb-Sr isochron ages for Colomera and Weekeroo Station. Although several mechanisms to form HE meteorites previously were suggested, it is not obvious that a single mechanism could produce a suite of meteorites with very different degrees of silicate differentiation and with isotopic ages that differ by >0.8 Gyr. We suggest that those IIEs with older isotopic ages are a product of partial melting and differentiation within the parent body, followed by mixing of silicate and metal while both were relatively hot. Netschadvo and Watson may have formed by this same process or by impact mixing about 4.5 Gyr ago, but their isotopic ages were subsequently reset by shock heating. Kodaikanal apparently is required to have formed more recently, in which case impact melting and differentiation seems the only viable process. We see no compelling reasons to believe that IIE silicate and metal derived from different parent bodies or that the parent body of IIEs was the same as that of H-chondrites.
We have studied IAB iron meteorites and their silicate-bearing inclusions to elucidate the origin of their parent body. We have divided IAB irons into five categories which best describe the inclusions and other properties of the irons.