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NASA NTRS1980

SCATHA observations of space plasma composition during a spacecraft charging event

During an Earth eclipse of the SCATHA spacecraft, the spacecraft charged to potentials greater than 1KV for about 30 minutes with extended excursions greater than 4KV. The composition of the hot plasma was obtained in the 0.1 to 32 keV energy range with an ion mass spectrometer aboard the spacecraft. Prior to the onset of the charging event, H(+) was the principal plasma ion, and during the event O(+) was the principal ion. The composition was energy dependent and varied significantly on a time scale of 4 minutes. An assumption that the ion flux was all H(+) led to computed number densities that were in error by more than a factor of two for several time intervals during the event.

Johnson, R. G.↗

NASA NTRS1990

Comparison of plasma wave measurements in the bow shocks at Earth, Jupiter, Saturn, Uranus and Neptune

Plasma wave measurements from the Voyager 2 crossing of Neptune's bow shock are presented and compared with measurements from the bow shocks of Earth, Jupiter, Saturn, and Uranus. The wave amplitudes above 0.01fp, when normalized to the solar wind ion thermal energy density at each planet, are significantly higher at the outer planets than at Earth. Despite the differences in amplitude, the shock spectra of all the planets can be fitted to curves of similar form in this frequency range. The total normalized electric field energy densities exhibit an exponential dependence on ion thermal Mach number, Magnetosheath wave energies are comparable at all of the planets when normalized to the downstream plasma pressure.

Moses, S. L.↗

NASA NTRS1989

Incoherent scatter radar observations of the ionosphere

Incoherent scatter radar (ISR) has become the most powerful means of studying the ionosphere from the ground. Many of the ideas and methods underlying the troposphere and stratosphere (ST) radars have been taken over from ISR. Whereas the theory of refractive index fluctuations in the lower atmosphere, depending as it does on turbulence, is poorly understood, the theory of the refractivity fluctuations in the ionosphere, which depend on thermal fluctuations, is known in great detail. The underlying theory is one of the most successful theories in plasma physics, and allows for many detailed investigations of a number of parameters such as electron density, electron temperature, ion temperature, electron mean velocity, and ion mean velocity as well as parameters pertaining to composition, neutral density and others. Here, the author reviews the fundamental processes involved in the scattering from a plasma undergoing thermal or near thermal fluctuations in density. The fundamental scattering properties of the plasma to the physical parameters characterizing them from first principles. He does not discuss the observation process itself, as the observational principles are quite similar whether they are applied to a neutral gas or a fluctuating plasma.

Hagfors, Tor↗

NASA NTRS2003

Ion Velocity Distributions Within LLBL and Their Possible Implication to Multiple Reconnections

We analyze two LLBL crossings made by Interball Tail satellite under southward or variable magnetosheath magnetic field: one crossing on the flank of the magnetosphere, and another one closer to the subsolar point. Three different types of ion velocity distributions within LLBL are observed: (a) D-shaped distributions, (b) ion velocity distributions consisting of two counter-streaming components of magnetosheath-ty and (c) distributions with three components one of which has nearly zero parallel velocity and two counter-streaming components. Only the (a) type fits to the single magnetic flux tube formed by reconnection between magnetospheric and magnetosheath magnetic fields. We argue that two counter-streaming magnetosheath-like ion components observed by Interball within LLBL cannot be explained by the reflection of the ions from the magnetic mirror deeper within magnetosphere. Types (b) and (c) ion velocity distributions would form within spiral magnetic flux tube consisting of a mixture of alternating segments originating from the magnetosheath and from magnetospheric plasma. The shapes of ion velocity distributions and their evolution with decreasing number density in LLBL indicate that a significant part of LLBL is located on magnetic field lines of long spiral flux tube islands at the magnetopause, as has been proposed and found to occur in magnetopause simulations. We consider these observations as evidence for multiple reconnection X-ray lines between magnetosheath and magnetospheric flux tubes.

Vaisberg, O. L.↗

NASA NTRS2010

Solar Wind Sputtering of Lunar Surface Materials: Role and Some Possible Implications of Potential Sputtering

Solar-wind induced sputtering of the lunar surface includes, in principle, both kinetic and potential sputtering. The role of the latter mechanism, however, in many focused studies has not been properly ascertained due partly to lack of data but can also be attributed to the assertion that the contribution of solar-wind heavy ions to the total sputtering is quite low due to their low number density compared to solar-wind protons. Limited laboratory measurements show marked enhancements in the sputter yields of slow-moving, highly-charged ions impacting oxides. Lunar surface sputtering yields are important as they affect, e.g., estimates of the compositional changes in the lunar surface, its erosion rate, as well as its contribution to the exosphere as well as estimates of hydrogen and water contents. Since the typical range of solar-wind ions at ~1 keV/amu is comparable to the thickness of the amorphous rim found on lunar soil grains, i.e. ~ few 10s nm, lunar simulant samples JSC-1A AGGL are specifically enhanced to have such rims in addition to the other known characteristics of the actual lunar soil particles. However, most, if not all laboratory studies of potential sputtering were carried out in single crystal targets, quite different from the rim s amorphous structure. The effect of this structural difference on the extent of potential sputtering has not, to our knowledge, been investigated to date.

Barghouty, A. F.↗

NASA NTRS2012

Current Density Measurements of an Annular-Geometry Ion Engine

The concept of the annular-geometry ion engine, or AGI-Engine, has been shown to have many potential benefits when scaling electric propulsion technologies to higher power. However, the necessary asymmetric location of the discharge cathode away from thruster centerline could potentially lead to non-uniformities in the discharge not present in conventional geometry ion thrusters. In an effort to characterize the degree of this potential non-uniformity, a number of current density measurements were taken on a breadboard AGI-Engine. Fourteen button probes were used to measure the ion current density of the discharge along a perforated electrode that replaced the ion optics during conditions of simulated beam extraction. Three Faraday probes spaced apart in the vertical direction were also used in a separate test to interrogate the plume of the AGI-Engine during true beam extraction. It was determined that both the discharge and the plume of the AGI-Engine are highly uniform, with variations under most conditions limited to +/-10% of the average current density in the discharge and +/-5% of the average current density in the plume. Beam flatness parameter measured 30 mm from the ion optics ranged from 0.85 - 0.95, and overall uniformity was shown to generally increase with increasing discharge and beam currents. These measurements indicate that the plasma is highly uniform despite the asymmetric location of the discharge cathode.

Shastry, Rohit↗

NASA NTRS1975

The 10 sheath-accelerated electrons and ions

A model is presented that suggests that plasma sheaths form between the ionospheric plasma moving with Io and the ambient plasma corotating with Jupiter. Potentials across these sheaths could be as high as 580 kV which is the motional emf across Io's ionosphere. Electrons and ions can be accelerated across these sheaths. The sheaths may exist at the top of the Io ionosphere with characteristic thicknesses of 1/4 kilometers. The model is consistent with the Pioneer observations of 0.15 MeV electrons at the inner edge of Io's L-shell and the enhanced number density of low-energy protons at the outer edge. Ion sputtering of the Io surface is discussed and may explain the presence of atomic hydrogen and sodium in the vicinity of Io. Also these accelerated particles may be important to the formation of the Io ionosphere. High electron flux which may lead to decametric radio emissions, Jovian atmospheric heating and optical and X-ray emissions is also discussed.

Shawhan, S. D.↗

NASA NTRS1981

Ion composition and energy distribution during 10 magnetic storms

Data from the plasma composition experiment of ISEE 1 are used to investigate the relative quantities and energy characteristics of H(+), He(++), He(+), and O(+) ions in the near-equatorial magnetosphere during magnetic storm conditions. The ions in the study had energies between 0.1 and 17 keV/e and pitch angles between 45 and 135 deg. The data were obtained during 10 storms, for the most part at or immediately following the peak Dst, covering all major local time sectors and geocentric distances between 2 and 15 earth radii. The ion fluxes are averaged over the spacecraft spin angle and over time for periods ranging from about 20 min close to the earth to more than an hour in most distant regions. The inferred 'isotropic' number densities are characterized by a large to dominant fraction of terrestrial ions throughout the energy range covered. The data are found to be consistent with a terrestrial origin for all of the O(+), most of the He(+), and a large but varying fraction of the H(+), whereas the He(++) and part of the H(+) appear to be of solar wind origin.

Lennartsson, W.↗

NASA NTRS1977

Optimization of confinement in a toroidal plasma subject to strong radial electric fields

A preliminary report on the identification and optimization of independent variables which affect the ion density and confinement time in a bumpy torus plasma is presented. The independent variables include the polarity, position, and number of the midplane electrode rings, the method of gas injection, and the polarity and strength of a weak vertical magnetic field. Some characteristic data taken under condition when most of the independent variables were optimized are presented. The highest value of the electron number density on the plasma axis is 3.2 x 10 to the 12th power/cc, the highest ion heating efficiency is 47 percent, and the longest particle containment time is 2.0 milliseconds.

Roth, J. R.↗

NASA NTRS1976

An analysis of auroral E region neutral winds based on incoherent scatter radar observations at Chatanika

The physical origin of auroral E-region neutral winds during geomagnetic disturbances is investigated by comparing incoherent-backscatter radar observations made at Chatanika, Alaska, during such disturbances with detailed theoretical calculations of neutral velocities for these conditions. In the analysis, an ion-drag collisional-coupling model is adopted as the primary driving force for the neutral winds. Electric fields and electron number densities observed by the radar facility are used in the calculations, and the coupled ion and neutral momentum equations are solved numerically as functions of altitude and time in the ion-drag approximation. The altitude structure of the velocity field is examined, and the detailed response of the neutral gas to the ion-drag mechanism is delineated. Weighted altitude averages of the calculated velocities are obtained, the accuracy of the procedure for deriving neutral winds from incoherent-scatter radar observations is evaluated, and the comparison is carried out. It is concluded that both ion drag and pressure gradients appear to be required to explain the neutral winds observed in the auroral E-region during geomagnetic disturbances.

Comfort, R. H.↗

DOE OSTI2023

Error-Field Penetration Thresholds in Ohmically Heated ITER and SPARC Plasmas

The critical n=1, n=2, and n=3 error-field amplitudes needed to trigger error-field penetration in ITER and SPARC, steady-state, ohmically heated plasmas are calculated using a standard asymptotic matching approach. The calculation incorporates plasma impurities, trapped particles, the bootstrap current, and neoclassical poloidal flow-damping. The energy confinement time is specified by the neo-Alcator scaling law in the low-density linear ohmic confinement (LOC) regime, and by the ITER-89P L-mode scaling law in the high-density saturated ohmic confinement regime (SOC) regime. The response of the plasma in the inner region is calculated using a linearized version of the four-field model. At the normal operating electron number density, diamagnetic levels of rotation are found to be sufficient to protect ITER and SPARC ohmically heated plasmas from m=2/n=1 error-field penetration. On other hand, SPARC, and especially ITER, ohmically heated plasmas may be vulnerable to n>1 error-field penetration. ITER and SPARC ohmically heated plasmas are also slightly more susceptible to error-field penetration when the electron fluid at the rational surface rotates in the ion diamagnetic direction, rather than the electron diamagnetic direction. At electron number densities that are sufficiently low that the plasma lies in the LOC confinement regime, the error-field penetration threshold increases with increasing density. However, as soon as the electron number density becomes large enough that the plasma enters the SOC regime, the increase in the error-field penetration threshold with increasing density levels off.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS1983

Particle and wave observations of low-altitude ionospheric ion acceleration events

Two sounding rockets were launched into the expansive phases of two auroral substorms and passed through source regions of transversely accelerated ionospheric ions. Energetic ion and electron, wave, and ambient plasma observations were made. The events were observed in the 400-600 km range and resulted in the ion energization of hundreds of electron volts. In the acceleration region the ionospheric ion velocity distribution function in the direction perpendicular to the local magnetic field showed a non-Maxwellian, high-energy tail. Plasma density was lower than theoretical quiescent values. Strong thermal ion drift was observed only in the perpendicular direction. Large-amplitude, low-frequency fluctuations in plasma density were present along with a number of different wave modes. The characteristics of the ion energy spectra agreed with a model of ion cyclotron acceleration and energy loss due to ion-neutral collisions.

Yau, A. W.↗

DOE OSTI2022

Carboxylate binding prefers two cations to one

Almost all studies of specific ion binding by carboxylates (–COO - ) have considered only a single cation, but clustering of ions and ligands is a common phenomenon. We apply density functional theory to investigate how variations in the number of acetate ligands in binding to two monovalent cations affects ion binding preferences. We study a series of monovalent (Li + , Na + , K + , Cs + ) ions relevant to experimental work on many topics, including ion channels, battery storage, water purification and solar cells. We find that the preferred optimal structure has 3 acetates except for Cs + , which has 2 acetates. The optimal coordination of the cation by the carboxylate O atoms is 4 for both Na + and K + , and 3 for Li + and Cs + . There is a 4-fold coordination minimum just a few kcal mol -1 higher than the optimal 3-fold structure for Li+. For two cations, multiple minima occur in the vicinity of the lowest free energy state. Here we find that, for Li, Na and K, the preferred optimal structure with two cations is favored over a mixture of single cation complexes, providing a basis for understanding ionic cluster formation that is relevant for engineering proteins and other materials for rapid, selective ion transport.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1972

The relationship of theory and experiment in the D-region.

To monitor the descriptive parameters of the lower ionosphere and construct a model which predicts their temporal and spatial variations is a particularly difficult task. In a given situation simultaneous measurements should be conducted of ionization sources, the altitude distribution of all neutral atmospheric constituents, the identification, number density, and altitude distribution of different species of positive and negative ions and electrons. These results are compared with theoretical predictions to serve as boundary conditions and guides to modification of the theory. It has not been possible to realize this goal in lower ionosphere research because of the large number of parameters and since certain parameters, such as positive ion species distribution and nitric oxide, can only be measured with the aid of sounding rockets. To illustrate the difficulty, recent positive ion composition measurements are compared with predictions utilizing clustering of ions and neutrals to form hydrated ions.

Aikin, A. C.↗

NASA NTRS1999

Electrolytes for Li-Ion Cells in Low Temperature Applications

A number of upcoming NASA missions require energy storage devices which display high energy density and can effectively operate at low temperature. Lithium-ion batteries have been identified as the most promising technology which can meet these stringent requirements.

electrolytes↗

DOE OSTI2025

Spectral emission characteristics near 646 nm and plasma properties of laser-induced plasma of gaseous uranium hexafluoride

We present a detailed investigation of the temporal evolution of line and continuum emissions in laser-induced breakdown spectroscopy (LIBS) of gaseous uranium hexafluoride (UF 6 ), focusing on the spectral region near 646 nm. Spectral emission features, signal-to-background ratios (SBRs) of selected uranium lines, and spectral linewidths were examined under varying UF 6 pressures (15–60 Torr) and laser pulse energies (10–60 mJ). Higher pressures and pulse energies enhanced continuum emission and reduced SBRs but did not cause significant spectral congestion. Additional studies with the use of different laser systems, including nanosecond-pulsed Nd:YAG lasers (at fundamental and various harmonics) and a femtosecond-pulsed Ti:sapphire laser, revealed long-lived plasma continua in all cases. This persistent continuum is attributed to a pseudo-continuum from overlapping molecular emissions, as its intensity scales linearly with electron number density, deviating from the expected quadratic dependence of classical ion–electron interactions for free-free and free-bound continuum emission. Based on plasma persistence time, SBR, U II/U I intensity ratios, and electronic excitation temperature, no fundamental advantage was found for femtosecond-pulsed lasers over conventional nanosecond-pulsed ones for UF 6 enrichment assay with direct LIBS measurement.

Laser-induced breakdown spectroscopy↗

NASA NTRS1978

Electrical structure and ionizable constituent measurements

In-situ stratospheric ions showed typical characteristics. A Krypton lamp created large numbers of additional ions of remarkably high mobility with a product of number density and ionization cross section of the ionizable constituent(s) greater than 10 cm to the 9th power per cm.

Hale, L. C.↗

NASA NTRS1992

Inclusive inelastic scattering of heavy ions in the independent particle model

We consider the inclusive inelastic scattering of heavy ions using the Glauber (1959) model and the independent particle approximation. Inclusive inelastic distributions for projectile excitation of the target and total inelastic scattering, where all projectile and target excited states are summed, are discussed using closure. The total inelastic distribution, when integrated, is shown to be equivalent to the absorption cross section, found from applying the optical theorem to the elastic scattering amplitude in the coherent approximation. Calculations are presented for several heavy-ion pairs, using realistic nuclear densities in a large mass number approximation.

Cucinotta, Francis A.↗