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One of the important issues for technological application of the high temperature superconductors is their behavior in a magnetic field. A variety of experiments including electrical transport, mechanical oscillators, and magnetic decoration have suggested that these magnetic properties will make applications more difficult than originally anticipated. These experiments and their results are briefly discussed.
In our NIAC Phase I study, awarded September 2011, the MIT Space Systems Lab (MIT SSL) began investigating a new structural and mechanical technique aimed at reducing the mass and increasing the stowed-to-deployed ratio of spacecraft systems. This technique uses the magnetic fields from current passing through coils of high temperature superconductors (HTSs) to support spacecraft structures and deploy them to operational configurations from their positions as stowed inside a launch vehicle fairing. These electromagnetic coils are tethered or hinged together in such a way that their motion in some directions or around some axes is constrained, as in Figure 1. Our Phase II study,awarded in Fall 2012, continued this work on electromagnetic structures, with an added focus on developing a new thermal system, investigating additional, non-structural electromagnet functions, and creating a maturation roadmap and plan for addressing barriers to feasibility of the technology. We now call the project MAGESTIC, or Magnetically Enabled STructures using Interacting Coils.
Melt processing of RE123 superconductors has gained importance in recent years. While the first high temperature superconductors (HTSCs) were made using traditional ceramic press and sinter technology, recent fabrication efforts have employed alternate processing techniques including laser ablation and ion beam assisted deposition for thin film fabrication of tapes and wires and melt growth for bulk materials. To optimize these techniques and identify other potential processing strategies, phase relation studies on HTSCs have been conducted on a wide variety of superconducting compounds using numerous processing strategies. This data has enhanced the understanding of these complex systems and allowed more accurate modeling of phase interactions. All of this research has proved useful in identifying processing capabilities for HTSCs but has failed to achieve a breakthrough for wide spread application of these materials. This study examines the role of full to partial substitution of Nd in the Y123 structure under rapid solidification conditions. Aero-acoustic levitation (AAL) was used to levitate and undercool RE123 in pure oxygen binary alloys with RE = Nd an Y along a range of compositions corresponding to Y(x)Nd(1-x) Ba2Cu3O(7-delta) (0 = or < x < or = 0.7) which were melted by a CO2 laser. Higher Y content spheres could not be melted in the AAL and were excluded from this report. Solidification structures were examined using scanning electron microscopy, electron dispersive spectroscopy, and powder x-ray diffraction to characterize microstructures and identify phases.
The objective of this project was to determine to what extent (as a function of distance from the Sun) our “Solar White” coatings could passively chill a high temperature superconductor (HTS) and maintain it in a superconducting state. The end goal is to enable the use of superconductors in space for active radiation shielding and highly efficient energy storage and retrieval. The best we were able to demonstrate during this testing was a coating with a solar absorptivity of 2.6%, which is sufficient to keep the superconductor we chose cold enough for these purposes at distances of 1.25 astronomical units (AU) from the Sun. Computations and modeling show that we would need samples with solar absorptivities of less than 1.5% for 1 AU and beyond operation. Our best tile to date was measured as having 1% absorption, which is still an order of magnitude higher than our theoretical limit. This should be achievable once manufacturing consistency is achieved. We are in the process of commercializing production of Solar White, and are hopeful that more consistent and improved results will be achieved within the coming year.
The material requirements, material manufacturing and magnetic properties that are relevant to fabrication of High Temperature Superconductor (HTS) magnetic bearings have been discussed. It is found that the seeded-melt-texturing method can be used to fabricate the single domain material that is required to achieve the best magnetic properties. Trapped-field mapping has been used as a non-destructive tool to determine the single-domain nature of the HTS material and quantity of the HTS disks. Both the trapped field and the levitation force of the Y-Ba-Cu-O disks are found to be strongly sensitive to the oxygen content.
During the past two years, one of the most exciting research fields in science has been the study of the newly discovered high-T(sub c) metal oxide superconductors. Although many theoretical models were proposed, there is no general agreement on any theory to explain these materials. One of the peculiar features of these high-T(sub c) materials is the noninteger number of oxygen atoms. The oxygen content is extremely critical to the superconductive properties. Take YBa2Cu3O(7-x) as an example. Its superconductive properties disappear whenever x is larger than 0.5. The existence of Cu(+ 3) was considered to account for x less than 0.5. However, results from mass spectroscopy of laser desorbed species indicate that significant quantities of oxygen molecules are trapped in the bulk of these high-T(sub c) superconductors. It appears that these trapped oxygen molecules may play key roles in superconductive properties. Preparation of superconductive thin films are considered very important for the applications of these new superconductors for the electronics industry. Fluorescence spectra and ion spectra following laser ablation of high-temperature superconductors were obtained. A real time monitor for preparation of superconductive thin films can possibly be developed.
During the past two years, one of the most exciting research fields in science has been the study of the newly discovered high-T(sub c) metal oxide superconductors. Although many theoretical models were proposed, there is no general agreement on any theory to explain these materials. One of the peculiar features of these high-T(sub c) materials is the noninteger number of oxygen atoms. The oxygen content is extremely critical to the superconductive properties. Take YBa2Cu3O(7-x) as an example. Its superconductive properties disappear whenever x is larger than 0.5. The existence of Cu(+ 3) was considered to account for x less than 0.5. However, results from mass spectroscopy of laser desorbed species indicate that significant quantities of oxygen molecules are trapped in the bulk of these high-T(sub c) superconductors. It appears that these trapped oxygen molecules may play key roles in superconductive properties. Preparation of superconductive thin films are considered very important for the applications of these new superconductors for the electronics industry. Fluorescence spectra and ion spectra following laser ablation of high-temperature superconductors were obtained. A real time monitor for preparation of superconductive thin films can possibly be developed.
The recent discovery of high temperature superconductors (HTS) has generated a substantial amount of interest in microstrip antenna applications. However, the high permittivity of substrates compatible with HTS results in narrow bandwidths and high patch edge impedances of such antennas. To investigate the performance of superconducting microstrip antennas, three antenna architectures at K and Ka-band frequencies are examined. Superconducting microstrip antennas that are directly coupled, gap coupled, and electromagnetically coupled to a microstrip transmission line were designed and fabricated on lanthanum aluminate substrates using YBa2Cu3O7 superconducting thin films. For each architecture, a single patch antenna and a four element array were fabricated. Measurements from these antennas, including input impedance, bandwidth, patterns, efficiency, and gain are presented. The measured results show usable antennas can be constructed using any of the architectures. All architectures show excellent gain characteristics, with less than 2 dB of total loss in the four element arrays. Although the direct and gap coupled antennas are the simplest antennas to design and fabricate, they suffer from narrow bandwidths. The electromagnetically coupled antenna, on the other hand, allows the flexibility of using a low permittivity substrate for the patch radiator, while using HTS for the feed network, thus increasing the bandwidth while effectively utilizing the low loss properties of HTS. Each antenna investigated in this research is the first of its kind reported.
The recent discovery of high-temperature superconductors (HTSs) has generated a substantial amount of interest in microstrip antenna applications. However, the high permittivity of substrates compatible with HTS causes difficulty in feeding such antennas because of the high patch edge impedance. Two methods for feeding HTS microstrip antennas at K- and Ka-band are examined. Superconducting microstrip antennas that are directly coupled and gap-coupled to a microstrip transmission line have been designed and fabricated on lanthanum aluminate substrates using Y-Ba-Cu-O superconducting thin films. Measurements from these antennas, including input impedance, bandwidth, efficiency, and patterns, are presented and compared with published models. The measured results demonstrate that usable antennas can be constructed using either of these architectures, although the antennas suffer from narrow bandwidths. In each case, the HTS antenna shows a substantial improvement over an identical antenna made with normal metals.
The recent discovery of high-temperature superconductors (HTSs) has generated a substantial amount of interest in microstrip antenna applications. However, the high permittivity of substrates compatible with HTS causes difficulty in feeding such antennas because of the high patch edge impedance. Two methods for feeding HTS microstrip antennas at K- and Ka-band are examined. Superconducting microstrip antennas that are directly coupled and gas-coupled to a microstrip transmission line have been designed and fabricated on lanthanum aluminate substrates using Y-Ba-Cu-O superconducting thin films. Measurements from these antennas, including input impedance, bandwidth, efficiency, and patterns, are presented and compared with published models. The measured results demonstrate that usable antennas can be constructed using either of these architectures, although the antennas suffer from narrow bandwidths. In each case, the HTS antenna shows a substantial improvement over an identical antenna made with normal metals
A hybrid superconductor magnet bearing system has been developed based on passive magnetic levitation and the flux pinning effect of high-temperature superconductivity. The rationale lies in the unique capability of a high-temperature superconductor (HTS) to enhance system stability passively without power consumption. Characterization experiments have been conducted to understand its dynamic behavior and to estimate the required motor torque for its driving system design. These experiments show that the hybrid HTS-magnet bearing system has a periodic oscillation of drag torque due mainly to the nonuniform magnetic field density of permanent magnets. Furthermore, such a system also suffers from a small superimposed periodic oscillation introduced by the use of multiple HTS disks rather than a uniform annulus of HTS material. The magnitude of drag torque is velocity independent and very small. These results make this bearing system appealing for high-speed application. Finally, design guidelines for superconducting bearing systems are suggested based on these experimental results.
A new type of telescope pointing system designed specifically for space and lunar applications will be discussed, based upon a prototype advanced technology telescope under investigation. The focus here will be the system of hybrid superconductor magnetic bearings (HSMB) used to provide isolation support and steering functions. HSMB's are combinations of high temperature superconductors, permanent magnets, and coils, being passive (requiring no power), noncontact, and essentially frictionless. These also are well suited to long-term unattended operation in the space environment. The characteristics of these subsystems, their expected behavior under space vacuum, and thermal and radiation environments are discussed.
Several NASA programs designed to monitor the Earth's atmosphere from space utilize infrared detectors which operate at or below 4.2 K for optimum performance. At present, the detectors are maintained at cryogenic temperatures by a stored volume of liquid helium. These detectors must be electrically linked to amplification electronics data storage instruments maintained at 80 K. The electrical connections over the temperature gradient account for approximately 20% of the total heat load on the Dewar for some systems, accelerating the boil-off of liquid helium cryogen and reducing the operational lifetime of the space-borne instruments. The recent discovery of high temperature superconductors has provided an opportunity to develop electrically conductive, thermally insulating links to bridge this thermal gradient. This paper describes the modelling of the thermal transport properties of thick film, high T(sub c) electrical bridges across a 4.2-80 K temperature gradient and the impact of such devices on a spaceborne remote sensing system.
High temperature superconductors(HTS) and microwaves devices form the ideal partnership. The application of superconductors in microwave devices, components and systems allows the reduction in size, power consumption and insertion loss. The surface resistance of high-Tc superconductors has been found to be two orders of magnitude lower than normal conducting copper materials. The reduction in size and power requirements, which together both lead to a reduction in system mass, coupled with reasonably accessible operating temperatures, suggest that HTS microwave components should find ready application in satellite communications systems. At present, multi- channeling communication networks demand filters with narrow bandwidth in order to allow the available RF frequency spectrum to be partitioned into small frequency bands, -and possible variation of dielectric constant from substrate to substrate is undesirable. Microwave multiplexers demand the fabrication of two identical filters in each channel. Thus, the filter with tuning function is preferable. Tunable filters are the critical component for phased array antennas in order to electronically steer the radiated beam. To fabricate a tunable filter that uses an electric field for operation, one would like a material that provides a large change on dielectric constant for a given electric field, yet has a relatively low tangent in order to minimize the insertion loss of the device. Ferroelectrics have been the materials of choice. Their large dielectric constant sufficiently increases the coupling between microwave resonators and its dependence on electric field provides timability. Development of technology promises to diminish tangent loss. The use of thin ferroelectric films sufficiently decreases insertion losses keeping considerable potential for applications. NASA Lewis Research Center is the one of the leading centers in investigation of superconductors/ferroelectric tunable components for microwave devices. A large number of possible microwave devices were fabricated and tested on the basis of thin film multilayer superconductor-ferroelectric structures. In major cases the systems with edge-coupling scheme were investigated. Dr. Genkin has recently focused on the new potentialities which implements the using of thin ferroelectric films in filters fabricated with end-coupled microstrip lines. Numerical modeling shows that these systems have large potential for application in tunable narrow- and wide-bandpass filters in the frequency range 10-20 GHz. The phase shifter with end-coupled resonant sections was fabricated and tested. Experimental results show large tunability, particular in low voltages. The possible optimization of this structure promises to improve the obtained result and to reach the low level of insertion losses.
The excellent microwave properties of the High-Temperature-Superconductors (HTS) have been amply demonstrated in the laboratory by techniques such as resonant cavity, power transmission and microstrip resonator measurements. The low loss and high Q passive structures made possible with HTS, present attractive options for applications in commercial, military and spacebased systems. However, to readily insert HTS into these systems improvement is needed in such areas as repeatability in the deposition and processing of the HTS films, metal-contact formation, wire bonding, and overall film endurance to fabrication and assembly procedures. In this paper we present data compiled in our lab which illustrate many of the problems associated with these issues. Much of this data were obtained in the production of a space qualified hybrid receiver-downconverter module for the Naval Research Laboratory's High Temperature Superconductivity Space Experiment 2 (HTSSE-2). Examples of variations observed in starting films and finished circuits will be presented. It is shown that under identical processing the properties of the HTS films can degrade to varying extents. Finally, we present data on ohmic contacts and factors affecting their adhesion to HTS films, strength of wire bonds made to such contacts, and aging effects.
The excellent microwave properties of the High-Temperature-Superconductors (HTS) have been amply demonstrated in the laboratory by techniques such as resonant cavity, power transmission and microstrip resonator measurements. The low loss and high Q passive structures made possible with HTS, present attractive options for applications in commercial, military and space-based systems. However, to readily insert HTS into these systems, improvement is needed in such areas as repeatability in the deposition and processing of the HTS films, metal-contact formation, wire bonding, and overall film endurance to fabrication and assembly procedures. In this paper, we present data compiled in our lab which illustrate many of the problems associated with these issues. Much of this data were obtained in the production of a space qualified hybrid receiver-downconverter module for the Naval Research Laboratory's High Temperature Superconductivity Space Experiment II (HTSSE-II). Examples of variations observed in starting films and finished circuits will be presented. It is shown that under identical processing the properties of the HTS films can degrade to varying extents. Finally, we present data on ohmic contacts and factors affecting their adhesion to HTS films, strength of wire bonds made to such contacts, and aging effects.
We report on persistent field in a quasi-permanent magnet made of high temperature superconductor. The material has an average of 40 percent molar excess of Y, relative to Y1Ba2Cu3O7 and has been irradiated with high energy light ions at 200 MeV. The magnet, which traps 1.52 T at 77.3 K, traps nearly 4 T at 64.5 K. No evidence of giant flux jump or sample cracking was observed.
A highly reflective spray-on coating and tile material has been under development at Kennedy Space Center (KSC) that scatters away most of the Sun’s energy, thereby allowing coated objects to remain cool in space. The best performing tile material has achieved 1% solar absorptivity while the best performing spray-on coating has achieved around 4%. Both versions passively maintain cryogenic temperatures below 120 K at 1 astronomical unit (AU) from the Sun, but the tile material consistently sustains temperatures below 90 K, which is low enough to preserve oxygen and methane in a liquid state. Besides keeping propellants cold, this “solar white” material has the potential to passively maintain high-temperature superconductors (HTS) in a superconducting state without the support of liquid nitrogen cooling. If superconductors can be operated without the added infrastructure of liquid nitrogen cooling, it may enable them to be used in space for applications like magnetic radiation shielding and efficient energy management. Long duration exposure to both galactic cosmic radiation and coronal mass ejections can pose health risks for the astronauts and increase the potential for damage to electronics. This makes shielding essential to accomplish long duration missions, particularly when astronauts are onboard. The objective of this project was to determine the extent we could keep a high-temperature superconducting (HTS) material passively chilled to maintain its superconducting state. Both the tile and spray-on versions of solar white were investigated. We focused on finding a version that could support passive cooling at 1 AU from the Sun and determined the closest operating distances for samples that were unable to perform at 1 AU. Early in the project, we selected bismuth strontium calcium copper oxide (BSCCO) as the HTS to test based on its reputable usage in superconducting wires. The version we selected was Bi-2223, which has a critical temperature of about 108 K. Sample bars with contacts for a four-point probe were obtained from Quantum Levitation: https://quantumlevitation.com/product/superconductor-bar-for-4-point-tc-experiment/.