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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

The Science Goals of the Constellation-X Mission

The Constellation-X mission will address the questions: "What happens to matter close to a black hole?" and "What is Dark Energy?" These questions are central to the NASA Beyond Einstein Program, where Constellation-X plays a central role. The mission will address these questions by using high throughput X-ray spectroscopy to observe the effects of strong gravity close to the event horizon of black holes, and to observe the formation and evolution of clusters of galaxies in order to precisely determine Cosmological parameters. To achieve these primary science goals requires a factor of 25-100 increase in sensitivity for high resolution spectroscopy. The mission will also perform routine high- resolution X-ray spectroscopy of faint and extended X-ray source populations. This will provide diagnostic information such as density, elemental abundances, velocity, and ionization state for a wide range of astrophysical problems. This has enormous potential for the discovery of new unexpected phenomena. The Constellation-X mission is a high priority in the National Academy of Sciences McKee-Taylor Astronomy and Astrophysics Survey of new Astrophysics Facilities for the first decade of the 21st century.

White, Nicholas E.↗
NASA NTRS2005

Planar diode multiplier chains for THz spectroscopy

High-resolution laboratory spectroscopy is utilized as a diagnostic tool to determine noise and harmonic content of balanced [9]-[11] and unbalanced [12]-[14] multiplier designs. Balanced multiplier designs suppress unintended harmonics more than -20dB. Much smaller values were measured on unbalanced multipliers.

high-resolution spectroscopy↗
NASA NTRS1980

A 10 micron heterodyne receiver for ultra high resolution astronomical spectroscopy

An improved CO2 laser heterodyne spectrometer is examined. The present system uses reflective optics to eliminate refocusing at different wavelengths, and the local oscillator is a line-center-stabilized isotopic CO2 laser. A tunable diffraction grating makes possible easy and rapid selection of over 50 transitions per isotope of CO2. The IF (0 to 1.6 GHz) from the HgCdTe photomizer is analyzed by a 128-channel filter bank, consisting of 64 tunable 5-MHz filters and 64 fixed 25-MHz RF filters. These filters provide resolving powers of about 1,000,000 to 10,000,000 and velocity resolution of 50 to 250 m/sec; their output is synchronously detected, integrated, multiplexed and stored in a buffer memory for the desired integration period. Kitt Peak observations show the wide spectral coverage, wide mixer and electronics bandwidth, and high sensitivity of the system.

Buhl, D.↗
NASA NTRS2003

High Spectral Resolution Spectroscopy of Mars from 2 to 4 Microns: Surface Mineralogy and the Atmosphere

The composition of the Martian surface and atmosphere on a global scale has been discovered in great part from spectroscopic measurements in the visible through infrared. Spectroscopic observations on Mars however require careful analysis from both atmospheric and mineralogical perspectives. The 2-4 m region contains diagnostic absorption features indicative of water such as the 3 m bound water band and cation-OH stretches between 2-2.5 m. Carbonate minerals also have absorption features in these wavelength range. However, this wavelength region also has atmospheric signatures from CO, CO2, water vapor, clouds, and atmospheric dust that complicate direct mineralogical interpretations. Several absorption features have been identified in the in the 2.0 - 2.5 m (e.g. Clark et al. 1990, Murchie et al. 1993, Bell et al. 1994) at moderate resolution. These features, while intriguing, are weak, narrow, and frequently at the edge of instrumental and observational limits. Spectroscopic observations at high spectral resolutions can aid in the separation of weak surface and atmospheric absorptions that at lower resolution overlap. This paper focuses on understanding the atmospheric spectral signatures so that the underlying surface mineralogy can be understood.

Diana Blaney↗
DOE OSTI2023

High resolution electronic spectroscopy of uranium mononitride, UN

The isoelectronic molecules UN and UO + are known to have Ω = 3.5 and Ω = 4.5 ground states, respectively (where Ω is the unsigned projection of the electronic angular momentum along the internuclear axis). A ligand field theory model has been proposed to account for the difference [Matthew and Morse, J. Chem. Phys. 138, 184303 (2013)]. The ground state of UO + arises from the U 3+ (5f 3 ( 4 I 4.5 ))O 2− configuration. Owing to the higher nominal charge of the N 3− ligand, the U 3+ ion in UN is stabilized by promoting one of the 5f electrons to the more polarizable 7s orbital, reducing the repulsive interaction with the ligand and rendering U 3+ (5f 2 7s( 4 H 3.5 ))N 3− the lowest energy configuration. In the present work, we have advanced the characterization of the UN ground state through studies of two electronic transitions, [18.35]4.5-X(1)3.5 and [18.63]4.5-X(1)3.5, using sub-Doppler laser excitation techniques with fluorescence detection. Further, spectra were recorded under field-free conditions and in the presence of static electric or magnetic fields. The ground state electric dipole moment [μ = 4.30(2) D] and magnetic g e -factor [2.160(9)] were determined from these data. These values were both consistent with the 5f 2 7s configurational assignment. Dispersed fluorescence measurements were used to determine vibrational constants for the ground and first electronically excited states. Electric dipole moments and magnetic g e -factors are also reported for the higher-energy electronically excited states.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
NASA NTRS1977

High resolution stellar spectroscopy in the balloon ultraviolet

The JSC/SRL Balloon-borne Ultraviolet Stellar Spectrometer (BUSS) comprises a 40 cm telescope, an echelle spectrograph and a SEC Vidicon detector. Operating at an altitude of 40 km this instrument provides spectra of stars with 0.1 A resolution in the 2000-3400 A region. Observations made on 19 May 1976, are discussed.

De Jager, C.↗
NASA NTRS1980

Trace constituents in the middle atmosphere by high resolution UV spectroscopy

An array of 5 autonomous spectrometers, the imaging spectrometric observatory covers a broad wavelength range (approximately 200 to 12,000 A), has a resolution selectable down to approximately 0.5 A, and a dynamic range of approximately 10 to the 7th power and is designed to select experiment measurement sequences by software control. Because current models of thermospheric ionic processes produce too much N2(+) ionization, the N2(+) reaction with O and the chemistry of metastable (N(+) ions and of O2(+) ions are objects of study on Spacelab 1.

Torr, D. G.↗
NASA NTRS1982

A calibration line list for 807-1167 cm -1 from high resolution Fourier spectroscopy of the 14NH3 nu sub 2 band

A calibration list of 295 lines observed over the 800 to 1170 cm to the -1 power region is presented. This list is intended for use as a calibration reference for calibrating diode laser spectra. The transition frequencies were calibrated against the well established laser frequencies of CO2. The estimated uncertainty in the corrected frequencies is + or - 1x.0001 cm to the -1 power.

Hillman, J. J.↗
NASA NTRS1982

High resolution atmospheric spectroscopy using a diode laser heterodyne spectrometer

Ultrahigh resolution (0.007 per cm) atmospheric solar absorption spectra that have been obtained from a tunable infrared heterodyne radiometer are discussed. The radiometer was developed for ground based observations in the 8-12 micron region, and tunability is achieved through the use of Pb-salt semiconductor laser local oscillators. Spectra have been obtained in a piecewise fashion from 9.1 to 11.1 microns using laser emission modes that exhibit characteristics suitable for local-oscillator operation. Spectra showing absorption features of HNO3, O3, CO2, and H2O are presented along with comparisons of experimental and synthetic spectra calculated using a line-by-line atmospheric transmission model.

Hoell, J. M., Jr.↗
NASA NTRS1982

High resolution EUV spectroscopy of 56 Pegasi (KO 2p + wd)

The hypothesis that X-ray and UV emission by 56 Pegasi (K0II p + wd) originates in a conventional chromosphere, transition region and corona, as opposed to Schindler's hypothesis of accretion of the cool stellar wind onto the white dwarf companion, is discussed. Analysis of IUE data indicates that within the uncertainties associated with determining the stellar radius and abundances, the chromosphere, transition region, and corona of 56 Peg are similar to that of Beta Draconis both in structure and energy balance. The accretion hypothesis is not a unique explanation of the observed spectral properties and the white dwarf companion may not play a direct role. Furthermore, 56 Peg, according to current values of V-R and luminosity class, is on the nonsolar side of the Linsky-Haisch dividing line whereas Beta Draconis is on the solar side.

Jordan, C.↗
NASA NTRS1988

High resolution FTIR spectroscopy of the ClO radical

The chlorine monoxide radical, ClO, plays a significant role in the catalytic destruction of ozone in the Earth's stratosphere. Because of its atmospheric importance, ClO has been the subject of numerous observational attempts. In order to deduce ClO concentrations from stratospheric infrared measurements, the infrared spectroscopy of ClO must be well characterized. Approximately 830 individual lines were measured form ClO imfrared spectra with the ClO concentration between 1 x 10 to the 13th power and 6 x 10 to the 13th power molecules per cu cu. The lines were then averaged and fit to a function of m (where m = O, -J or J+1 for the Q,P and R branches respectively) to obtain the band strength, S sub v and the first Herman-Wallis coefficient, alpha. The total S sub v for the two main isotopmers was 13.11 plus or minus 1 cm(-2) atm(-1) while alpha was 0.00412 plus or minus .00062.

Lang, Valerie↗
NASA NTRS1989

High-resolution infrared spectroscopy of Io and possible surface materials

A comparison of new spectra of Io with laboratory-simulated frosts confirms that the dominant materials on Io are SO2 frost in conjunction with a spectrally neutral material presumed to be sulfur. While the 4-micron region spectra are largely explainable in these terms, attention is drawn to a shoulder in the spectrum at 4.04 microns that is suggestive of adsorbed SO2 gas; two shallow, unidentified bands are also noted at 3.85 and 3.91 microns. The isotopic ratios of oxygen and sulfur appear to be normal. The absence of distinct bands in the new spectra in the 5-micron region limits the abundance of sulfate and sulfite compounds.

Howell, Robert R.↗
NASA NTRS1987

High resolution infrared spectroscopy of the sun and the earth's atmosphere from space

The FFT spectrometer used in the atmospheric trace molecule spectroscopy (ATMOS) experiment, flown for the first time aboard the Shuttle Spacelab 3 mission (in April 1985), is described together with the instrument's design parameters, the ATMOS's science objectives, and observational techniques used. The ATMOS experiment acquired more than 1000 atmospheric spectra with an equal number of 'solar only' scans, yielding absorption spectra of some 400 different atmospheric constituents. Data were obtained on such key reservoir species as COF2, HNO4, and N2O5; simultaneous vertical distributions of the minor gases from 5 to 140 km; the entire odd-nitrogen family in the stratosphere; and on most of the halogen-source gases with their corresponding reservoir and sink species.

Farmer, Crofton B.↗