Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “grazing incidence”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Crystallization of nanopore-confined imidazolium ionic liquids probed by temperature-resolved in situ grazing-incidence wide angle X-ray scattering (GIWAXS)

The crystallization behavior of ionic liquids (ILs) 1-butyl-3-methylimidazolium [BMIM] hexafluorophosphate [PF 6 ] and chloride [Cl] is investigated upon confinement in 2.3 or 8.2 nm diameter silica nanopore arrays, along with the effects of covalently modifying the pore walls with 1-(3-trimethoxysilylpropyl)3-methylimidazolium [TMS-MIM] + groups. In situ grazing-incidence wide angle x-ray scattering (GIWAXS) is performed during heating from as low as -110 °C to room temperature. Partially ordered “nanodomains” are observed in both ILs in the bulk molten state, but they are disrupted by nanoconfinement. Melting point depression consistent with capillary effects is observed for [BMIM][PF 6 ] in 2.3 nm pores. However, the melting point is elevated for [BMIM][PF 6 ] in 8.2 nm pores, which provide sufficient space to stabilize the crystalline phase. For [BMIM][Cl], crystallization is observed only in 8.2 nm bare silica pores, but the melting point is severely depressed. Tethering with IL-like [TMS-MIM + ] also promotes the crystallization of [BMIM][PF 6 ], resulting in elevated melting points. The combined effects of a larger pore size and pore surface tethering on [BMIM][PF 6 ] result in a single stable crystal phase that persists from -140 °C to 25 °C (vs. the bulk melting point of -11 °C). These results show that when ILs are used in confined systems, complex crystallization behavior can emerge depending on the counterion, pore size, and surface modification that require consideration of ion layering in the confined space in addition to surface free energy effects.

He, Yuxin [University of Kentucky, Lexington, KY (↗
DOE OSTI2020

In-situ Grazing-Incidence Wide-Angle Scattering Reveals Mechanisms for Phase Distribution and Disorientation in 2D Halide Perovskite Films

Two-dimensional (2D) hybrid halide perovskites with the formula (A') 2 (A) n-1 Pb n I 3n+1 have remarkable stability and promising efficiency in photovoltaic and optoelectronic devices, yet fundamental understanding of film formation, key to optimizing these devices, is lacking. In this study, in-situ grazing-incidence wide-angle X-ray scattering (GIWAXS) is used to monitor film formation during spin-coating. This elucidates the general film formation mechanism of 2D halide perovskites during one-step spin-coating. There are three stages of film formation: sol-gel, oriented 3D, and 2D. Three precursor phases form during the sol-gel stage and transform to perovskite, first giving a highly oriented 3D-like phase at the air/liquid interface followed by subsequent nucleations forming slightly less oriented 2D perovskite. Furthermore, heating before crystallization leads to fewer nucleations and faster removal of the precursors, improving orientation. This outlines the primary causes of phase distribution and perpendicular orientation in 2D perovskite films and paves the way for rationally designed film fabrication techniques.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Structure Development of the Interphase between Drying Cellulose Materials Revealed by In Situ Grazing-Incidence Small-Angle X-ray Scattering

The nano- to microscale structures at the interface between materials can define the macroscopic material properties. These structures are extremely difficult to investigate for complex material systems, such as cellulose-rich materials. The development of new model cellulose materials and measuring techniques has opened new possibilities to resolve this problem. We present a straightforward approach combining micro-focusing grazing-incidence small-angle X-ray scattering and atomic force microscopy (AFM) to investigate the structural rearrangements of cellulose/cellulose interfaces in situ during drying. Based on the results, we propose that molecular interdiffusion and structural rearrangement play a major role in the development of the properties of the cellulose/cellulose interphase; this model is representative of the development of the properties of joint/contact points between macroscopic cellulose fibers.

36 MATERIALS SCIENCE↗
NASA NTRS1989

The design and evaluation of grazing incidence relay optics

X-ray astronomy, both solar and celestial, has many needs for high spatial resolution observations which have to be performed with electronic detectors. If the resolution is not to be detector limited, plate scales in excess of 25 microns arc/sec, corresponding to focal lengths greater than 5 m, are required. In situations where the physical size is restricted, the problem can be solved by the use of grazing incidence relay optics. A system was developed which employs externally polished hyperboloid-hyperboloid surfaces to be used in conjunction with a Wolter-Schwarzschild primary. The secondary is located in front of the primary focus and provides a magnification of 4, while the system has a plate scale of 28 microns arc/sec and a length of 1.9 m. The design, tolerance specification, fabrication and performance at visible and X-ray wavelengths of this optical system are described.

Davis, John M.↗
NASA NTRS1988

The flight test of a grazing incidence relay optics telescope for solar X-ray astronomy utilizing a thinned, back-illuminated CCD detector

The new AS&E Ultrahigh Resolution Soft X-ray Solar Research Rocket Payload has been successfully flown twice on Black Brant IX Sounding Rockets from White Sands Missile Range. These flights, conducted on 15 August 1987 and 11 December 1987, provided the first test of the new payload which consists of 3.8X magnifying hyperboloid-hyperboloid grazing incidence relay optic used in conjunction with an existing Wolter-I primary mirror. An RCA SID 500 series CCD detector was utilized in a thinned, back-illuminated configuration for recording the images. The 5.4 m effective focal length of the compound optics system resulted in a plate scale of 1 arc second per pixel which is comparable to the inherent resolution of the primary mirror. These flights represent the first use in X-ray astronomy of either of these two new technologies. These observations are presented with comparison to laboratory measurements and theoretical expectations of the instrument performance.

Moses, J. Daniel↗
NASA NTRS2014

Mounting for Fabrication, Metrology, and Assembly of Full Shell Grazing Incidence Optics

Future x-ray telescopes will likely require lightweight mirrors to attain the large collecting areas needed to accomplish the science objectives. Understanding and demonstrating processes now is critical to achieving sub-arcsecond performance in the future. Consequently, designs not only of the mirrors but of fixtures for supporting them during fabrication, metrology, handling, assembly, and testing must be adequately modeled and verified. To this end, MSFC is using finite-element modeling to study the effects of mounting on full-shell grazing-incidence mirrors, during all processes leading to flight mirror assemblies. Here we report initial results of this study.

Roche, Jacqueline M.↗
DOE OSTI2022

Film formation mechanisms in mixed-dimensional 2D/3D halide perovskite films revealed by in situ grazing-incidence wide-angle X-ray scattering

We report mixed dimensionality 2D/3D hybrid halide perovskites retain the stability of 2D perovskites (formula (A')2(A)n-1PbnI3n+1) and long diffusion lengths of the 3D materials (formula AMX3), thereby affording solar cells with extended stability as well as state of the art efficiencies approaching that of the 3D materials. These films are made by spin coating precursor solutions with arbitrarily large average layer thickness n ($\langle$n$\rangle$ > 7) to give films with both 2D and 3D phases present. While the 2D and 3D perovskite film formation mechanisms have been studied previously, little is understood about composite 2D/3D film formation. We used in situ grazing-incidence wide-angle scattering (GIWAXS) with synchrotron radiation to fully characterize films fabricated from precursor solutions with stoichiometries of (BA) 2 (MA) n-1 Pb n I 3n+1 ($\langle$n$\rangle$ = 3, 4, 5, 7, “12,” “50,” and ∞ (MAPbI 3 )). Four different mechanisms are seen depending on the stoichiometry in the precursor solution. When $\langle$n$\rangle$ = 3, oriented perovskite grows directly. For $\langle$n$\rangle$ = 4-5, the needle-shaped solvate (MA) 2 Pb 3 I 8 ·2DMF forms concomitantly with the oriented perovskite which leads to 2D/3D composite films. For $\langle$n$\rangle$ ≥ 7, this solvate dominates and unoriented perovskite grows in secondarily. For 3D perovskite, the solvate is the only phase formed. Kinetic analysis shows faster and earlier growth of the solvate with increasing $\langle$n$\rangle$. Using this knowledge, we show that the undesirable solvate mechanism can be reduced by addition of excess ammonium iodide in the precursor solution to give highly oriented films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1999

Effectiveness of Near-Grazing Incidence Reflection in Creating the Rotationally Modulated Lanes in the Jovian Hectometric Radio Emission Spectrum

The Galileo plasma wave instrument has identified a narrow (in frequency) attenuation band in the hectometric emission that varies in frequency with system 3 longitude. It is possible to model this emission band assuming a high-latitude cyclotron source region with emission that is efficiently attenuated when the ray path is nearly tangent to an L shell that is close to the Io flux tube. The data suggest that the mechanism for attenuating the emission is very efficient, with the ratio of attenuated to unattenuated emission I/I(sub o) < 0.02, and not a strong function of frequency. In this paper we demonstrate that incoherent scattering alone cannot explain the attenuation lane, which does not preclude coherent scattering by uncertain processes. We find rather that the source of attenuation is consistent with near-grazing incidence reflection of emission from an L shell that is near the Io flux tube (a caustic surface).

Menietti, J. D.↗
NASA NTRS1984

Proposed design class of grazing incidence echelle spectrometers - Critical analysis and reevaluation

The class of miltibounce grazing spectrometers proposed by Cash (1982) and by McClintock and Cash (1982) is analyzed, and performance values significantly lower than asserted by these authors are found. Ray tracing calculations used to examine the design parameters given in the above papers are reported, as is the efficiency which results from use of accepted reflectance data. Several schemes which can improve some of the performance parameters are indicated.

Hettrick, M. C.↗
NASA NTRSDate not supplied

Evaluation of a Variable Facesheet Liner Configuration in Grazing Incidence for Broadband Noise Reduction

Tests were conducted in the NASA Langley Grazing Flow Impedance Tube (GFIT) to determine the broadband noise reduction capability of a variable facesheet liner. Three uniform liners were designed to achieve sound absorption over distinct frequency regimes at Mach 0.0. Each liner was fabricated and tested in the GFIT at sound pressure levels of 120 and 140 dB, and at tangential flow velocities up to Mach 0.5. A variable facesheet liner was fabricated to combine the geometries of these three liners, such that the facesheet geometry (hole diameter and porosity) was varied across the liner surface. The Prony method was used to educe the impedance of each sample, and these impedances were input to the CHE (Convected Helmholtz Equation) propagation code to predict the acoustic pressure profiles in the GFIT. Comparisons of predicted and measured acoustic pressure profiles were used to confirm the uniformity of all four liners, and to demonstrate the suitability of the CHE code in the analysis of the variable facesheet concept. Results showed good comparison at no flow and at Mach 0.3, and acceptable comparison at Mach 0.5. The variable facesheet liner provided enhanced broadband noise reduction at the no-flow condition for which it was designed, but further optimization is needed to target flow conditions.

acoustic↗
NASA NTRSDate not supplied

Evaluation of a Variable Facesheet Liner Configuration in Grazing Incidence for Broadband Noise Reduction

Abstract Tests were conducted in the NASA Langley Grazing Flow Impedance Tube (GFIT) to determine the broadband noise reduction capability of a variable facesheet liner. Three uniform liners were designed to achieve sound absorption over distinct frequency regimes at Mach 0.0. Each liner was fabricated and tested in the GFIT at sound pressure levels of 120 and 140 dB, and at tangential flow velocities up to Mach 0.5. A variable facesheet liner was fabricated to combine the geometries of these three liners, such that the facesheet geometry (hole diameter and porosity) was varied across the liner surface. The Prony method was used to educe the impedance of each sample, and these impedances were input to the CHE (Convected Helmholtz Equation) propagation code to predict the acoustic pressure profiles in the GFIT. Comparisons of predicted and measured acoustic pressure profiles were used to confirm the uniformity of all four liners, and to demonstrate the suitability of the CHE code in analysis of the variable facesheet concept. Results showed good comparison at no flow and Mach 0.3, and acceptable comparison at Mach 0.5. The variable facesheet liner provides enhanced broadband noise reduction at the no-flow condition for which it was designed, but further optimization is needed to target flow conditions.

acoustic↗
NASA NTRS1988

Design of the Extreme Ultraviolet Explorer long-wavelength grazing incidence telescope optics

Designing optics for photometry in the long-wavelength portion of the EUV spectrum (400-900) A) poses different problems from those arising for optics, operating shortward of 400 A. The available filter materials which transmit radiation longward of 400 A are also highly transparent at wavelengths shortward of 100 A. Conventional EUV optics, with grazing engles of less than about 10 deg, have very high throughput in the EUV, which persists to wavelengths shortward of 100 A. Use of such optics with the longer-wavelength EUV filters thus results in an unacceptably large soft X-ray leak. This problem is overcome by developing a mirror design with larger graze angles of not less than 20 deg, which has high throughput at wavelengths longer than 400 A but at the same time very little throughput shortward of 100 A.

Finley, David S.↗
NASA NTRS1988

Electromagnetic wave scattering at near-grazing incidence from a gently undulating, rough surface

Models to estimate the reflection coefficient of a statistically rough surface, for example the works of Beckmann, Smith, and Vesecky are discussed. Bistatic radar experiments carried out during the Apollo 16 mission provide a data set with which to compare theoretical models and experimental data. These bistatic S-band radar experiments provide experimental estimates of the Moon's bistatic, forward scatter, reflection coefficient for grazing angles of 2.5 to 78 deg. Theoretical expressions for the reflection coefficient are developed for comparison with these experimental data. At grazing angles below 10 deg the models of Smith and Vesecky compare favorably with the data. Beckmann's model falls significantly more rapidly with decreasing grazing angle than does the data.

Vesecky, J. F.↗
NASA NTRS1986

An analysis of two classes of grazing incidence mirrors for use with Rowland circle spectrometers

Results are presented of a comparative analysis of Hettrick Bowyer Type II (HBII) and Wolter-Schwarzschild Type II (WSII) optics for use with Rowland circle spectrometers. The HBII can substitute, with few exceptions, for a WSII in any Rowland circle with little change in spectrometer performance or design. However, the HBII telescope offers several clear advantages over the WSII in these configurations. Because the HBII employs a virtual focus, it requires a much shorter instrument length than a WSII. For example, a 3-m Rowland circle spectrometer, fed by an optimized, f/10, 1-m diameter WSII, has a total instrument length of 6 m. If a HBII is used to feed the identical spectrometer, the entire instrument length can be as little as 3 m. In addition, the improved imaging gained with the larger graze angles of the HBII design results in better resolution in slitless operation modes.

Green, James↗
DOE OSTI2021

Electrochemistry of Thin Films with In Situ/Operando Grazing Incidence X-Ray Scattering: Bypassing Electrolyte Scattering for High Fidelity Time Resolved Studies

Electroactive polymer thin films undergo repeated reversible structural change during operation in electrochemical applications. While synchrotron X-ray scattering is powerful for the characterization of stand-alone and ex situ organic thin films, in situ/operando structural characterization has been underutilized-in large part due to complications arising from supporting electrolyte scattering. This has greatly hampered the development of application relevant structure property relationships. Therefore, a new methodology for in situ/operando X-ray characterization that separates the incident and scattered X-ray beam path from the electrolyte is developed. As a proof of concept, the operando structural characterization of weakly-scattering, organic mixed conducting thin films in an aqueous electrolyte environment is demonstrated, accessing previously unexplored changes in the $\pi-\pi$ peak and diffuse scatter, while capturing the solvent swollen thin film structure which is inaccessible in previous ex situ studies. These in situ/operando measurements improve the sensitivity to structural changes, capturing minute changes not possible ex situ, and have multimodal potential such as combined Raman measurements that also serve to validate the true in situ/operando conditions of the cell. Finally, new directions enabled by this in situ/operando cell design are examined and state of the art measurements are compared.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗