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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Hydrogen utilization and alternatives

The historical uses of hydrogen are described along with potential new uses which could develop as a result of the diminishing supply of conventional fossil fuels such as natural gas. A perspective view of hydrogen, both as a chemical feedstock and as a fuel, is necessary to understand its relationship to the overall national energy projections. These projections, which show energy usage in terms of use sectors, forms of energy, and sources of energy, do not specifically identify hydrogen as a component of the energy system. By superimposing the traditional roles upon the new opportunities for hydrogen on the energy projections, the role of hydrogen and future projections is developed within the context of the national energy projections. Use, supply, and other factors affecting application are interrelated and are discussed.

Manvi, R.↗
NASA NTRS1976

Preliminary assessment of systems for deriving liquid and gaseous fuels from waste or grown organics

The overall feasibility of the chemical conversion of waste or grown organic matter to fuel is examined from the technical, economic, and social viewpoints. The energy contribution from a system that uses waste and grown organic feedstocks is estimated as 4 to 12 percent of our current energy consumption. Estimates of today's market prices for these fuels are included. Economic and social issues are as important as technology in determining the feasibility of such a proposal. An orderly program of development and demonstration is recommended to provide reliable data for an assessment of the viability of the proposal.

Graham, R. W.↗
NASA NTRS1976

Experimental clean combustor program, phase 2

The alternate fuels investigation objective was to experimentally determine the impacts, if any, on exhaust emissions, performance, and durability characteristics of the hybrid and vorbix low pollution combustor concepts when operated on test fuels which simulate composition and property changes which might result from future broadened aviation turbine fuel specifications or use of synthetically derived crude feedstocks. Results of the program indicate a significant increase in CO and small NOX increase in emissions at idle for both combustor concepts, and an increase in THC for the vorbix concept. Minimal impact was observed on gaseous emissions at high power. The vorbix concept exhibited significant increase in exhaust smoke with increasing fuel aromatic content. Altitude stability was not affected for the vorbix combustor, but was substantially reduced for the hybrid concept. Severe carbon deposition was observed in both combustors following limited endurance testing with No. 2 home heat fuel. Liner temperature levels were insensitive to variations in aromatic content over the range of conditions investigated.

Roberts, R.↗
NASA NTRS1975

Hydrogen energy systems technology study

The paper discusses the objectives of a hydrogen energy systems technology study directed toward determining future demand for hydrogen based on current trends and anticipated new uses and identifying the critical research and technology advancements required to meet this need with allowance for raw material limitations, economics, and environmental effects. Attention is focused on historic production and use of hydrogen, scenarios used as a basis for projections, projections of energy sources and uses, supply options, and technology requirements and needs. The study found more than a billion dollar annual usage of hydrogen, dominated by chemical-industry needs, supplied mostly from natural gas and petroleum feedstocks. Evaluation of the progress in developing nuclear fusion and solar energy sources relative to hydrogen production will be necessary to direct the pace and character of research and technology work in the advanced water-splitting areas.

Kelley, J. H.↗
NASA NTRS1976

A preliminary assessment of the feasibility of deriving liquid and gaseous fuels from grown and waste organics

An estimate is obtained of the yearly supply of organic material for conversion to fuels, the energy potential is evaluated, and the fermentation and pyrolysis conversion processes are discussed. An investigation is conducted of the estimated cost of fuel from organics and the conclusions of an overall evaluation are presented. It is found that climate, land availability and economics of agricultural production and marketing, food demand, fertilizer shortage, and water availability combine to cast doubts on the feasibility of producing grown organic matter for fuel, in competition with food, feed, or fiber. Less controversial is the utilization of agricultural, industrial, and domestic waste as a conversion feedstock. The evaluation of a demonstration size system is recommended.

Graham, R. W.↗
NASA NTRS1976

Benefits of hydrogen production research

An economic analysis of total monetary benefits arising from increased volume and efficiency of hydrogen production from various primary energy sources is carried out. The analysis is based on NASA's projections of future hydrogen demand in terms of both established industrial-chemical uses and new energy system applications, along with the mix of primary energy sources needed to meet this demand. A cost methodology model is worked out with the basic cost elements being plant construction costs, feedstock and energy costs, and operating and labor-related costs. A computer simulation technique was developed and a set of model calculations was performed. Some representative outputs of the computer analysis are displayed and conclusions are drawn on major factors determining the overall savings possible in hydrogen production and on its technological and economic impact.

Manvi, R.↗
NASA NTRS1976

Hydrogen production by water decomposition using a combined electrolytic-thermochemical cycle

A proposed dual-purpose power plant generating nuclear power to provide energy for driving a water decomposition system is described. The entire system, dubbed Sulfur Cycle Water Decomposition System, works on sulfur compounds (sulfuric acid feedstock, sulfur oxides) in a hybrid electrolytic-thermochemical cycle; performance superior to either all-electrolysis systems or presently known all-thermochemical systems is claimed. The 3345 MW(th) graphite-moderated helium-cooled reactor (VHTR - Very High Temperature Reactor) generates both high-temperature heat and electric power for the process; the gas stream at core exit is heated to 1850 F. Reactor operation is described and reactor innards are illustrated. A cost assessment for on-stream performance in the 1990's is optimistic.

Farbman, G. H.↗
NASA NTRS1977

Low cost silicon solar array project silicon materials task: Establishment of the feasibility of a process capable of low-cost, high volume production of silane (step 1) and the pyrolysis of silane to semiconductor-grade silicon (step 2)

Extended operation of a small process-development unit routinely produced high quality silane in 97+% yield from dichlorosilane. The production rate was consistent with design loadings for the fractionating column and for the redistribution reactor. A glass fluid-bed reactor was constructed for room temperature operation. The behavior of a bed of silcon particles was observed as a function of various feedstocks, component configurations, and operating conditions. For operating modes other than spouting, the bed behaved in an erratic and unstable manner. A method was developed for casting molten silicon powder into crack-free solid pellets for process evaluation. The silicon powder was melted and cast into thin walled quartz tubes that sacrificially broke on cooling.

Breneman, W. C.↗
NASA NTRS1977

High velocity continuous-flow reactor for the production of solar grade silicon

The feasibility of a high volume, high velocity continuous reduction reactor as an economical means of producing solar grade silicon was tested. Bromosilanes and hydrogen were used as the feedstocks for the reactor along with preheated silicon particles which function both as nucleation and deposition sites. A complete reactor system was designed and fabricated. Initial preheating studies have shown the stability of tetrabromosilane to being heated as well as the ability to preheat hydrogen to the desired temperature range. Several test runs were made and some silicon was obtained from runs carried out at temperatures in excess of 1180 K.

Woerner, L.↗
NASA NTRS1979

Laser-zone Growth in a Ribbon-to-ribbon (RTR) Process Silicon Sheet Growth Development for the Large Area Silicon Sheet Task of the Low Cost Solar Array Project

A technique for growing limited-length ribbons continually was demonstrated. This Rigid Edge technique can be used to recrystallize about 95% of the polyribbon feedstock. A major advantage of this method is that only a single, constant length silicon ribbon is handled throughout the entire process sequence; this may be accomplished using cassettes similar to those presently in use for processing Czochralski waters. Thus a transition from Cz to ribbon technology can be smoothly affected. The maximum size being considered, 3 inches x 24 inches, is half a square foot, and will generate 6 watts for 12% efficiency at 1 sun. Silicon dioxide has been demonstrated as an effective, practical diffusion barrier for use during the polyribbon formation.

Baghdadi, A.↗
NASA NTRS1979

Habitat and logistic support requirements for the initiation of a space manufacturing enterprise

A detailed scenario for the initiation of a space manufacturing enterprise using lunar materials to construct solar power satellites (SPS) was developed, with particular attention to habitat design and logistic support requirements. If SPS's can be constructed exclusively from lunar materials, the entire enterprise can be initiated in a 7 year period of launch activity (beginning as early as 1985) using the Space Shuttle and a low-cost, Shuttle-derived heavy lift vehicle. If additional chemical feedstocks must be imported from earth in significant quantities, it may be necessary to bring the next-generation launch vehicle (single-stage-to-orbit) into operation by 1991. The scenario presented features use of the mass-driver reaction engine for orbit-to-orbit transfer of cargos and makes extensive use of the expendable Shuttle external propellant tanks.

Vajk, J. P.↗
NASA NTRS1979

A geologic assessment of potential lunar ores

Although bulk lunar soil is not a suitable feedstock for extracting metals, certain minerals such as anorthite and ilmenite can be separated and concentrated. These minerals can be considered as potential ores of aluminum, silicon, titanium, andiron. A separation and metal extraction plant could also extract large amounts of oxygen and perhaps hydrogen from these minerals. Anorthie containing 19 percent aluminum and 20 percent silicon can be concentrated from some highland soils where it is present in amounts up to 60 percent. Ilmenite containing 32 percent titanium and 37 percent iron can be concentrated from some mare soils where it is present in amounts up to 10 percent. The ideal mining site would be located at the boundary between a high-titanium mare and a high-aluminum highlands. Such area may exist around the rims of some eastern maria, particularly Tranquilitatis. A location on Earth with raw materials as described above would be considered an economically valuable ore deposit if conventional terrestrial resources were not available.

Mckay, D. S.↗
NASA NTRS1979

Mining and beneficiation of lunar ores

The beneficiation of lunar plagioclase and ilmenite ores to feedstock grade permits a rapid growth of the space manufacturing economy by maximizing the production rate of metals and oxygen. A beneficiation scheme based on electrostatic and magnetic separation is preferred over conventional schemes, but such a scheme cannot be completely modeled because beneficiation processes are empirical and because some properties of lunar minerals have not been measured. To meet anticipated shipping and processing needs, the peak lunar mining rate will exceed 1000 tons/hr by the fifth year of operation. Such capabilities will be best obtained by automated mining vehicles and conveyor systems rather than trucks. It may be possible to extract about 40 kg of volatiles (60 percent H2O) by thermally processing the less than 20 micron ilmenite concentrate extracted from 130 tons of ilmenite ore. A thermodynamic analysis of an extraction process is presented.

Bunch, T. E.↗
NASA NTRS1978

Methods for the photochemical utilization of solar energy

The paper considers the 'ground rules' which govern the efficiency of photochemical solar energy conversion and then summarizes the most promising approaches in each of three categories: photochemically assisted thermal systems for the heating and/or cooling of structures; photogalvanic systems for the production of electrical power in applications, such as photorechargeable batteries or inexpensive 'solar cells'; and photochemical formation of fuels for combustion and for use as chemical feedstocks or foods. Three concepts for the photochemical utilization of solar energy in space are found to be particularly promising: (1) photochemical trans-cis isomerization of indigold dyes for photoassisted heating or cooling, (2) the redox stabilized photoelectrolysis cell for the production of hydrogen (and/or oxygen or other useful chemicals), and (3) the liquid-junction photovoltaic cell for the production of electrical power.

Schwerzel, R. E.↗
NASA NTRS1979

Overview of methods for extraterrestrial materials processing

A brief survey of processing systems suitable for conversion of lunar soil fractions to refined industrial feedstocks are given. Description of a 'baseline' process using hydrochemical or metallurgical separation of compounds of major and minor elements using HF acid leaching as the initial step is presented. Rough engineering parameters including power and heat rejection requirements, potential loss of earth supplied reagents during recycling, and mass: output ratios of equipment, reagent inventory, and associated power and radiator facilities are described. Minimal practical scales for such systems and manpower requirements are discussed.

Waldron, R. D.↗
NASA NTRS1979

Electrochemistry of lunar rocks

Electrolysis of silicate melts has been shown to be an effective means of producing metals from common silicate materials. No fluxing agents need be added to the melts. From solution in melts of diopside (CaMgSi2O6) composition, the elements Si, Ti, Ni, and Fe have been reduced to their metallic states. Platinum is a satisfactory anode material, but other cathode materials are needed. Electrolysis of compositional analogs of lunar rocks initially produces iron metal at the cathode and oxygen gas at the anode. Utilizing mainly heat and electricity which are readily available from sunlight, direct electrolysis is capable of producing useful metals from common feedstocks without the need for expendable chemicals. This simple process and the products obtained from it deserve further study for use in materials processing in space.

Lindstrom, D. J.↗
NASA NTRS1979

Hydrogen in the U.S. energy picture

A study of hydrogen in the U.S. program performed by the Hydrogen Energy Systems Technology (HEST) investigation is reported. Historic production and use of hydrogen, hydrogen use projections, hydrogen supply, economics of hydrogen production and supply, and future research and development needs are discussed. The study found current U.S. hydrogen utilization to be dominated by chemical and petroleum industries, and to represent 3% of total energy consumption. Hydrogen uses are projected to grow by a factor of 5 to 20 during the remainder of this century, and new applications in synthetic fuel from coal manufacture and directly as energy storage or fuel are expected to develop. The study concluded that development of new methods of supplying hydrogen replacing natural gas and petroleum feedstocks with alternate sources such as coal and heavy oils, and electrolysis techniques is imperative.

Kelley, J. H.↗
NASA NTRS1979

The role of chemical engineering in space manufacturing

A survey of factors involved in space manufacturing is presented. It is shown that it will be more economical to obtain the necessary raw materials from the moon than from earth due to earth's greater gravity and atmosphere. Discussion covers what resources can be mined and recovered from the moon and what ranges of industrial feedstock can be provided from lunar materials, noting that metallurgy will be different in space due to the lack of key elements such as H, C, Na, Cl, etc. Also covered are chemical plant design, space environmental factors such as vacuum and zero gravity, recycling requirments, reagent and equipment mass, and unit operations such as materials handling and phase separation. It is concluded that a pilot plant in space could be an economic boon to mankind.

Waldron, R. D.↗