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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Factors Limiting Li+ Charge Transfer Kinetics in Li-ion Batteries

Understanding the factors limiting Li+ charge transfer kinetics in Li-ion batteries is essential in improving the rate performance, especially at lower temperatures. The Li+ charge transfer process involved in the lithium intercalation of graphite anode includes the step of de-solvation of the solvated Li+ in the liquid electrolyte and the step of transport of Li+ in the preformed solid electrolyte interphase (SEI) on electrodes until the Li+ accepts an electron at the electrode and becomes a Li in the electrode. Whether the de-solvation process or the Li+ transport through the SEI is a limiting step depends on the nature of the interphases at the electrode and electrolyte interfaces. Several examples involving the electrode materials such as graphite, lithium titanate (LTO), lithium iron phosphate (LFP), lithium nickel cobalt aluminum oxide (NCA) and solid Li+ conductor such as lithium lanthanum titanate or Li-Al-Ti-phosphate are reviewed and discussed to clarify the conditions at which either the de-solvation or the transport of Li+ in SEI is dominating and how the electrolyte components affect the activation energy of Li+ charge transfer kinetics. How the electrolyte additives impact the Li+ charge transfer kinetics at both the anode and the cathode has been examined at the same time in 3-electrode full cells. The resulting impact on Li+ charge transfer resistance, Rct, and activation energy, Ea, at both electrodes are reported and discussed.

Delp, Samuel A.↗

Voice interactive electronic warning systems (VIEWS) - An applied approach to voice technology in the helicopter cockpit

The cockpit has been one of the most rapidly changing areas of new aircraft design over the past thirty years. In connection with these developments, a pilot can now be considered a decision maker/system manager as well as a vehicle controller. There is, however, a trend towards an information overload in the cockpit, and information processing problems begin to occur for the rotorcraft pilot. One approach to overcome the arising difficulties is based on the utilization of voice technology to improve the information transfer rate in the cockpit with respect to both input and output. Attention is given to the background of speech technology, the application of speech technology within the cockpit, voice interactive electronic warning system (VIEWS) simulation, and methodology. Information subsystems are considered along with a dynamic simulation study, and data collection.

Voorhees, J. W.↗

Experimental Investigation of Pool Boiling Heat Transfer Enhancement in Microgravity in the Presence of Electric Fields

Boiling is an effective mode of heat transfer since high heat flux levels are possible driven by relatively small temperature differences. The high heat transfer coefficients associated with boiling have made the use of these processes increasingly attractive to aerospace engineering. Applications of this type include compact evaporators in the thermal control of aircraft avionics and spacecraft environments, heat pipes, and use of boiling to cool electronic equipment. In spite of its efficiency, cooling based on liquid-vapor phase change processes has not yet found wide application in aerospace engineering due to specific problems associated with the low gravity environment. After a heated surface has reached the superheat required for the initiation of nucleate boiling, bubbles will start forming at nucleation sites along the solid interface by evaporation of the liquid. Bubbles in contact with the wall will continue growing by this mechanism until they detach. In terrestrial conditions, bubble detachment is determined by the competition between body forces (e.g. buoyancy) and surface tension forces that act to anchor the bubble along the three phase contact line. For a given body force potential and a balance of tensions along the three phase contact line, bubbles must reach a critical size before the body force can cause them to detach from the wall. In a low gravity environment the critical bubble size for detachment is much larger than under terrestrial conditions, since buoyancy is a less effective means of bubble removal. Active techniques of heat transfer enhancement in single phase and phase change processes by utilizing electric fields have been the subject of intensive research during recent years. The field of electrohydrodynamics (EHD) deals with the interactions between electric fields, flow fields and temperature fields. Previous studies indicate that in terrestrial applications nucleate boiling heat transfer can be increased by a factor of 50 as compared to values obtained for the same system without electric fields. Imposing an external electric field holds the promise to improve pool boiling heat transfer in low gravity, since a phase separation force other than gravity is introduced. The goal of our research is to experimentally investigate the potential of EHD and the mechanisms responsible for EHD heat transfer enhancement in boiling in low gravity conditions.

Herman, Cila↗

Energetics of the midlatitude thermosphere

Thermospheric energetics is examined from the point of view of atomic and molecular processes which convert solar EUV radiative energy into kinetic energy of the ambient electron, ion, and neutral gases. The energy flow from photon to photoelectron-ion pair through energy loss and ion-molecule transfer to eventual electron-ion recombination is traced in detail. Upper and lower bounds are placed on the efficiency of conversion of radiative to thermal energy. Implications for the question of consistency of measured solar EUV fluxes and ionospheric models are discussed.

Stolarski, R. S.↗

Submicron area NbN/MgO/NbN tunnel junctions for SIS mixer applications

The development of submicron area mixer elements for operation in the submillimeter wave range is discussed. High-current-density NbN/MgO/NbN tunnel junctions with areas down to 0.1 sq microns have been fabricated in both planar and edge geometries. The planar junctions were fabricated from in situ deposited trilayers using electron-beam lithography to pattern submicron area mesas. Modifications of fabrication techniques used in larger-area NbN tunnel junctions are required and are discussed. The NbN/MgO/NbN edge junction process using sapphire substrates has been transferred to technologically important quartz substrates using MgO buffer layers to minimize substrate interactions. The two junction geometries are compared and contrasted in the context of submillimeter wave mixer applications.

Leduc, H. G.↗

Float zone processing in a weightless environment

Results are given for investigations into: (1) the physical limits which set the maximum practical diameters of Si crystals that can be processed by the float-zone method in a near weightless environment, and (2) the economic impact of large, space-produced Si crystals on the electronics industry. The stability of the melt is evaluated. Heat transfer and fluid flow within the melt as dependent on the crystal size and the degree and type of rotation imparted to the melt are studied. Methods of utilizing the weightless environment for the production of large, stress-free Si crystals of uniform composition are proposed. The economic effect of large size Si crystals, their potential applications, likely utilization and cost advantages in LSI, integrated circuits, and power devices are also evaluated. Foreseeable advantages of larger diameter wafers of good characteristics and the possibilities seen for greater perfection resulting from stress-free growth are discussed.

Fowle, A. A.↗

Optical glow spectra arising from low-energy N2, N2(+) and electron bombardment of MgF2 surfaces

Photon emission spectra resulting from the impact of N2, N2(+), and electron beams on magnesium fluoride in an ultrahigh vacuum environment were measured and compared for beam energies in the range 200-2000 eV. Unexpectedly, only the ion- and electron-induced spectra exhibited broad fluorescence. The observed data suggest that the broad fluorescence arising from low-energy ion bombardment is due primarily to the transfer of electronic energy to the surface by resonance or Auger neutralization. Since molecular nitrogen is a major constituent of the atmosphere at orbital altitudes, these measurements bear directly on radiation-induced glow and erosion processes on surfaces of spacecraft in low-earth orbit.

Qi, J.↗

Assessment of the Mars Helicopter Thermal Design Sensitivities Using the Veritrek Software

The Mars Helicopter will be a technology demonstration conducted during the Mars 2020 mission. The primary mission objective is to achieve several 90-second flights and capture visible light images via forward and nadir mounted cameras. These flights could possibly provide reconnaissance data for sampling site selection for other Mars surface missions. The helicopter is powered by a solar array, which stores energy in secondary batteries for flight operations, imaging, communications, and survival heating. The helicopter thermal design is driven by minimizing survival heater energy while maintaining compliance with allowable flight temperatures in a variable thermal environment. Due to the small size of the helicopter and its complex geometries, along with the fact that it operates with very low power and small margins, additional care had to be paid while planning thermal tests and designing the thermal system. A Thermal Desktop® model has been developed to predict the thermal system’s performance. A reduced-order model (ROM) created with the Veritrek software has been utilized to explore the sensitivities of the thermal system’s drivers, such as electronics dissipations, gas gaps, heat transfer coefficients, etc., as well as to assess and verify the final thermal design. This paper presents the performance of the Veritrek software products and the details of the ROM creation process. The results produced by Veritrek were utilized to study the effect of the major thermal design drivers and Mars environment on the Mars Helicopter in as little as 10 days, an effort that would have taken over 4 months using traditional thermal analysis techniques.

Hengeveld, Derek W.↗

Electron Energy Interplay in the Geomagnetic Trap Below the Auroral Acceleration Region

This publication addresses the collisional superthermal electron dynamics below the auroral acceleration region (AAR). This region is the portion of an auroral field line with a field-aligned electric field that leads to the formation of precipitating monoenergetic keV electron fluxes that produce the discrete auroral displays observable from the ground. It is assumed that these precipitating electron fluxes are monoenergetic and accelerated through a potential drop, V, such that these electrons are peaked at an energy E0 = eV, where e is the electron charge. Monoenergetic electrons precipitating into the upper atmosphere degrade to lower energies via many different collisional processes and produce the secondary electron population with energies of 10–100s eV which escapes back to magnetospheric altitudes and becomes geomagnetically trapped between the AAR and the upper ionosphere. The secondary electrons in this geomagnetic trap transfer energy via elastic Coulomb collisions to the thermal electrons. That energy is then returned to the topside ionosphere as heat flux carried by the electron thermal conduction which is essential to maintaining the topside electron temperature.

George V Khazanov↗

Imaging Electron Spectrometer (IES) Electron Preprocessor (EPP) Design

The Aerospace Corporation developed the Electron PreProcessor (EPP) to support the Imaging Electron Spectrometer (IES) that is part of the RAPID experiment on the ESA/NASA CLUSTER mission. The purpose of the EPP is to collect raw data from the IES and perform processing and data compression on it before transferring it to the RAPID microprocessor system for formatting and transmission to the CLUSTER satellite data system. The report provides a short history of the RAPID and CLUSTER programs and describes the EPP design. Four EPP units were fabricated, tested, and delivered for the original CLUSTER program. These were destroyed during a launch failure. Four more EPP units were delivered for the CLUSTER II program. These were successfully launched and are operating nominally on orbit.

Fennell, J. F.↗

Solution of the comoving-frame equation of transfer in spherically symmetric flows. IV - Frequency-dependent source functions for scattering by atoms and electrons

A numerical method is presented of solving the radiative transfer equation in the comoving frame of a spherically symmetric expanding atmosphere in which both the line and the electron-scattering source function can depend on frequency (i.e., when there is partial frequency redistribution in the scattering process). This method is used to assess the adequacy of various assumptions regarding frequency redistribution in the comoving frame and to discuss the effects of electron scattering more accurately than previously possible. The methods developed here can be used in realistic model atmospheres to account for the (major) effects of electron scattering upon emergent flux profiles.

Mihalas, D.↗

Downlink Data Multiplexer

A multiplexer/demultiplexer system has been developed to enable the transmission, over a single channel, of four data streams generated by a variety of sources at different (including variable) bit rates. In the original intended application, replicas of this multiplexer/demultiplexer system would be incorporated into the spacecraft-to-ground communication systems of the space shuttles. The multiplexer of each system would be installed in the spacecraft, where it would acquire and process data from such sources as commercial digital camcorders, video tape recorders, and the spacecraft telemetry system. The demultiplexer of each system would be installed in a ground station. Purely terrestrial systems of similar design could be attractive for use in situations in which there are requirements to transmit multiple streams of high-quality video data and possibly other data over single channels. The figure is a block diagram of the multiplexer as configured to process data received via three fiber-optic channels like those of the International Space Station and one electrical-cable channel that conforms to the Institute of Electrical and Electronic Engineers (IEEE) 1394 standard. (This standard consists of specifications of a high-speed serial data interface, the physical layer of which includes a cable known in the art as "FireWire." An IEEE 1394 interface can also transfer power between the components to which it is connected.) The fiber-optic channels carry packet and/or bit-stream signals that conform to the standards of the Consultative Committee for Space Data Systems (CCSDS). The IEEE 1394 interface accepts an isochronous signal like that from a digital camcorder or a video tape recorder. The processing of the four input data streams to combine them into one output stream is governed by a statistical multiplexing algorithm that features a flow-control capability and makes it possible to utilize the transmission channel with nearly 100-percent efficiency. This algorithm allocates the available bandwidth of the transmission channel to the data streams according to a combination of data rates and preassigned priorities. Incoming data streams that demand too much bandwidth are blocked. Bandwidth not needed for a transmission of a given data stream is allocated to other streams as available. Priority is given to the IEEE 1394 stream. In addition to the four incoming data streams, the multiplexer transmits data on the status of the system. An operator can monitor and control the multiplexer via displays and controls on the multiplexer housing. The output of the multiplexer is connected via a coaxial cable with an impedance of 50 Ohms to an interface circuit compatible with the space-shuttle high-speed digital downlink, which operates at a rate of 48 Mb/s.

Holland, Douglas↗

Heat Transfer and Thermal Stability Research for Advanced Hydrocarbon Fuel Technologies

In recent years there has been increased interest in the development of a new generation of high performance boost rocket engines. These efforts, which will represent a substantial advancement in boost engine technology over that developed for the Space Shuttle Main Engines in the early 1970s, are being pursued both at NASA and the United States Air Force. NASA, under its Space Launch Initiative s Next Generation Launch Technology Program, is investigating the feasibility of developing a highly reliable, long-life, liquid oxygen/kerosene (RP-1) rocket engine for launch vehicles. One of the top technical risks to any engine program employing hydrocarbon fuels is the potential for fuel thermal stability and material compatibility problems to occur under the high-pressure, high-temperature conditions required for regenerative fuel cooling of the engine combustion chamber and nozzle. Decreased heat transfer due to carbon deposits forming on wetted fuel components, corrosion of materials common in engine construction (copper based alloys), and corrosion induced pressure drop increases have all been observed in laboratory tests simulating rocket engine cooling channels. To mitigate these risks, the knowledge of how these fuels behave in high temperature environments must be obtained. Currently, due to the complexity of the physical and chemical process occurring, the only way to accomplish this is empirically. Heated tube testing is a well-established method of experimentally determining the thermal stability and heat transfer characteristics of hydrocarbon fuels. The popularity of this method stems from the low cost incurred in testing when compared to hot fire engine tests, the ability to have greater control over experimental conditions, and the accessibility of the test section, facilitating easy instrumentation. These benefits make heated tube testing the best alternative to hot fire engine testing for thermal stability and heat transfer research. This investigation used the Heated Tube Facility at the NASA Glenn Research Center to perform a thermal stability and heat transfer characterization of RP-1 in an environment simulating that of a high chamber pressure, regenerative cooled rocket engine. The first step in the research was to investigate the carbon deposition process of previous heated tube experiments by performing scanning electron microscopic analysis in conjunction with energy dispersive spectroscopy on the tube sections. This analysis gave insight into the carbon deposition process and the effect that test conditions played in the formation of deleterious coke. Furthermore, several different formations were observed and noted. One other crucial finding of this investigation was that in sulfur containing hydrocarbon fuels, the interaction of the sulfur components with copper based wall materials presented a significant corrosion problem. This problem in many cases was more life limiting than those posed by the carbon deposition process. The results of this microscopic analysis was detailed and presented at the December 2003 JANNAF Air-Breathing Propulsion Meeting as a Materials Compatibility and Thermal Stability Analysis of common Hydrocarbon Fuels (reference 1).

DeWitt, Kenneth↗

TPSAS-NF1676L-11045-DND

The International TOVS Working Group (ITWG) is convened as a sub-group of the International Radiation Commission (IRC) of the International Association of Meteorology and Atmospheric Physics (IAMAP). The ITWG continues to organize international TOVS study conferences which have met approximately every 18 months since 1983. The most recent conference, the seventeenth International TOVS Study Conference (ITSC-XVII) was held in Monterey, California from 12 to 20 April 2010. This report will cover the current ITWG status, objectives, activities, along with recommendations formulated during the recent ITSC conference to be forwarded to space agencies, operational NWP centers and the scientific community on issues ranging from data processing methods, derived products, and the impacts of radiances and inferred atmospheric temperature and moisture fields on numerical weather prediction, and weather and climate studies. Also to be reported on are activities of the technical sub-groups which meet informally to coordinate ATOVS processing software, radiative transfer models, sounding data for climate studies, use of sounding data in data assimilation/NWP, international issues, and future systems and frequency protection issues relevant to ATOVS. As the result of ITSC-XVII, a paper report and electronic proceedings are being formulated and will soon be published and distributed. The conference Working Group Report will summarize the recommendations and actions of these working sub-groups. Technical Proceedings of the scientific presentations and posters will also published. The ITWG web site (http://cimss.ssec.wisc.edu/itwg/) contains electronic versions of the conference papers, presentations and posters from earlier ITSCs. Together, these documents and web pages reflect the conduct of highly successful international collaborations.

Steve English↗

Modeling of Radiative Transfer in Protostellar Disks

This program implements a spectral line, radiative transfer tool for interpreting Spitzer Space Telescope observations by matching them with models of protostellar disks for improved understanding of planet and star formation. The Spitzer Space Telescope detects gas phase molecules in the infrared spectra of protostellar disks, with spectral lines carrying information on the chemical composition of the material from which planets form. Input to the software includes chemical models developed at JPL. The products are synthetic images and spectra for comparison with Spitzer measurements. Radiative transfer in a protostellar disk is primarily affected by absorption and emission processes in the dust and in molecular gases such as H2, CO, and HCO. The magnitude of the optical absorption and emission is determined by the population of the electronic, vibrational, and rotational energy levels. The population of the molecular level is in turn determined by the intensity of the radiation field. Therefore, the intensity of the radiation field and the population of the molecular levels are inter-dependent quantities. To meet the computational challenges of solving for the coupled radiation field and electronic level populations in disks having wide ranges of optical depths and spatial scales, the tool runs in parallel on the JPL Dell Cluster supercomputer with C++ and Fortran compiler with a Message Passing Interface. Because this software has been developed on a distributed computing platform, the modeling of systems previously beyond the reach of available computational resources is possible.

VonAllmen, Paul↗

F layer positive response to a geomagnetic storm - June 1972

A circulation model of neutral thermosphere-ionosphere coupling is used to interpret in situ spacecraft measurements taken during a topside midlatitude ionospheric storm. The data are measurements of electron density taken along the circular polar orbit of Ariel 4 at 550 km during the geomagnetically disturbed period June 17-18, 1972. It is inferred that collisional momentum transfer from the disturbed neutral thermosphere to the ionosphere was the dominant midday process generating the positive F-layer storm phase in the summer hemisphere. In the winter hemisphere the positive storm phase drifted poleward in the apparent response to magnetospheric E x B drifts. A summer F-layer positive phase developed at the sudden commencement and again during the geomagnetic main phase; a winter F-layer positive phase developed only during the geomagnetic main phase. The observed seasonal differences in both the onsets and the magnitudes of the positive phases are attributed to the interhemispheric asymmetry in thermospheric dynamics.

Miller, N. J.↗

Major Pathways to Electron Distribution Function Formation in Regions of Diffuse Aurora

This paper discusses the major pathways of electron distribution function formation in the region of diffuse aurora. The diffuse aurora accounts for about of 75% of the auroral energy precipitating into the upper atmosphere, and its origin has been the subject of much discussion. We show that an earthward stream of precipitating electrons initially injected from the Earth's plasma sheet via wave-particle interactions degrades in the atmosphere toward lower energies and produces secondary electrons via impact ionization of the neutral atmosphere. These electrons of magnetospheric origin are then reflected back into the magnetosphere along closed dipolar magnetic field lines, leading to a series of reflections and consequent magnetospheric interactions that greatly augment the initially precipitating flux at the upper ionospheric boundary (700-800 km). To date this, systematic magnetosphere-ionosphere coupling element has not been included in auroral research models, and, as we demonstrate in this article, has a dramatic effect (200-300%) on the formation of the precipitating fluxes that result in the diffuse aurora. It is shown that wave-particle interaction processes that drive precipitating fluxes in the region of diffuse aurora from the magnetospheric altitudes are only the first step in the formation of electron precipitation at ionospheric altitudes, and they cannot be separated from the atmospheric collisional machine that redistributes and transfers their energy inside the magnetosphere-ionosphere-atmosphere coupling system.

magnetospheric↗

Adiabatic criteria for outer-sphere bimolecular electron-transfer reactions

A model is presented for outer-sphere bimolecular electron-transfer reactions which is correct in the adiabatic, nonadiabatic, and intermediate dynamical regimes for an overdamped solvent coordinate. From this model, the conditions for the transfer to be adiabatic or nonadiabatic are deduced. The time-scale separations needed to adequately describe the process as an average over (distant dependent) unimolecular rates are described.

Onuchic, Jose Nelson↗