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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Numerical recovery of certain discontinuous electrical conductivities

The inverse problem of recovering an electrical conductivity of the form Gamma(x) = 1 + (k-1)(sub Chi(D)) (Chi(D) is the characteristic function of D) on a region omega is a subset of 2-dimensional Euclid space from boundary data is considered, where D is a subset of omega and k is some positive constant. A linearization of the forward problem is formed and used in a least squares output method for approximately solving the inverse problem. Convergence results are proved and some numerical results presented.

Bryan, Kurt↗
NASA NTRS1994

Electrically conductive, thermally insulating cryogenic current leads

An electrically conductive, thermally insulating current lead assembly has been developed for cryogenic systems. This lead assembly consists of thick film elements of high temperature superconductive materials deposited onto a low thermal conductivity substrate. The superconductor elements provide current transport but minimize heat transfer. The substrate provides the mechanical durability necessary for cryogenic and other environments.

Wise, Stephanie A.↗
DOE OSTI2020

Valence-Dependent Electrical Conductivity in a 3D Tetrahydroxyquinone-Based Metal–Organic Framework

Electrically conductive metal–organic frameworks (cMOFs) have become a topic of intense interest in recent years because of their great potential in electrochemical energy storage, electrocatalysis, and sensing applications. Most of the cMOFs reported hitherto are 2D structures, and 3D cMOFs remain rare. Herein we report FeTHQ, a 3D cMOF synthesized from tetrahydroxy-1,4-quinone (THQ) and iron(II) sulfate salt. FeTHQ exhibited a conductivity of 3.3 ± 0.55 mS cm –1 at 300 K, which is high for 3D cMOFs. The conductivity of FeTHQ is valence-dependent. Additionally, a higher conductivity was measured with the as-prepared FeTHQ than with the air-oxidized and sodium naphthalenide-reduced samples.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1976

Electrical conductivity measurements on silicate melts using the loop technique

A new method is described for measurement of the electrical conductivity of silicate melts under controlled oxygen partial pressure at temperatures to 1550 C. The melt samples are suspended as droplets on platinum-rhodium loops, minimizing iron loss from the melt due to alloying with platinum, and providing maximum surface exposure of the melt to the oxygen-buffering gas atmosphere. The latter provides extremely rapid equilibration of the melt with the imposed oxygen partial pressure. The loop technique involves a minimum of setup time and cost, provides reproducible results to within + or - 5% and is well suited to electrical conductivity studies on silicate melts containing redox cations.

Waff, H. S.↗
DOE OSTI2024

Redox Chemistry Mediated Control of Morphology and Properties in Electrically Conductive Coordination Polymers: Opportunities and Challenges

Coordination polymers (CPs) and metal–organic frameworks (MOFs) have attracted significant research interest in the past several decades due to their reticular structures and modularity. However, realizing electrically conductive CPs or MOFs with comparable properties to classic conducting organic polymers has only been a recent development. This emerging class of materials has found wide appli-cation in many fields due to combined features of structural rigidity, chemical tunability, porosity, and charge transport. Alongside many studies revealing myriad design approaches to access these materials, the role that redox chemistry plays in both material synthesis and modulation of electronic properties has been an emerging theme. This perspective provides a brief overview of select examples where redox chemistry medi-ates control of morphology and properties in electrically conductive CPs/MOFs. Here, the challenges and limitations in this area are also discussed. Particular challenges include the characterization of redox states in these materials and measuring and understanding highly correlated elec-tronic properties and other unusual physical phenomena which may be important for potential applications.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Electrical conductivity of Jupiter's shallow interior and the formation of a resonant of a resonant planetary-ionospheric cavity

The present consideration of hydrogenic atmospheric reactions on Jupiter, to a depth of 4000 km, notes the primary ion constituents at these depths to be both positive and negative ions of molecular hydrogen contributing less than 20 percent to total electrical conductivity by free electrons. An electrical surface defined by the boundary beneath which the interior is electrically conducting exists at depths which vary according to EM wave frequency, from 1100 km for 1 mHz to 3000 for 1 MHz. The presence of a lower electrical boundary within the shallow interior suggests that a planetary-ionosphere resonant cavity analogous to the earth-ionosphere cavity may exist.

Sentman, D. D.↗
NASA NTRS1988

Electrically-Conductive Polyaramid Cable And Fabric

Tows coated with metal provide strength and conductance. Cable suitable for use underwater made of electrically conductive tows of metal-coated polyaramid filaments surrounded by electrically insulating jacket. Conductive tows used to make conductive fabrics. Tension borne by metal-coated filaments, so upon release, entire cable springs back to nearly original length without damage.

Orban, Ralph F.↗
DOE OSTI2021

Ultrafast multi-cycle terahertz measurements of the electrical conductivity in strongly excited solids

Key insights in materials at extreme temperatures and pressures can be gained by accurate measurements that determine the electrical conductivity. Free-electron laser pulses can ionize and excite matter out of equilibrium on femtosecond time scales, modifying the electronic and ionic structures and enhancing electronic scattering properties. The transient evolution of the conductivity manifests the energy coupling from high temperature electrons to low temperature ions. Here we combine accelerator-based, high-brightness multi-cycle terahertz radiation with a single-shot electro-optic sampling technique to probe the evolution of DC electrical conductivity using terahertz transmission measurements on sub-picosecond time scales with a multi-undulator free electron laser. Our results allow the direct determination of the electron-electron and electron-ion scattering frequencies that are the major contributors of the electrical resistivity.

36 MATERIALS SCIENCE↗
NASA NTRS1978

Velocity, temperature, and electrical conductivity profiles in hydrogen-oxygen MHD duct flows

Two-dimensional duct flow computations for radial distributions of velocity, temperature, and electrical conductivity are reported. Calculations were carried out for the flow conditions representative of a hydrogen-oxygen combustion driven MHD duct. Results are presented for: profiles of developing flow in a smooth duct, and for profiles of fully developed pipe flow with a specified streamwise shear stress distribution. The predicted temperature and electrical conductivity profiles for the developing flows compare well with available experimental data.

Greywall, M. S.↗
DOE OSTI2020

Effect of Off-Stoichiometry on Electrical Conductivity in Ni-Fe and Mn-Co Spinel Systems

This study seeks to clarify the effects of off-stoichiometry on the electrical conductivity of spinels in the (Ni,Fe) 3 O 4 and (Mn,Co) 3 O 4 systems. Spinels with the compositions Ni x Fe 3–x O 4 (where x = 0.85, 0.875, 0.9, 1.0, 1.05, and 1.15) and Mn x Co 3–x O 4 (where x = 1.0, 1.2, 1.35, 1.5, 1.75, and 2.0) were prepared using conventional solid-state process. Electrical conductivity measurements were taken between 500 °C and 800 °C using the 4-point DC method. The conductivity in Ni-Fe spinels increased with increasing Fe content. Similarly, the conductivity of Mn-Co spinels increased drastically with increasing Co content. The coefficients of thermal expansion (CTEs) of these samples were also evaluated. All the (Ni,Fe) 3 O 4 spinels were found to exhibit excellent CTE matching with prospective stack components. However, thermal expansion characteristics were highly dependent on the composition in the (Mn,Co) 3 O 4 system, and only a narrow range of compositions was well-matched in CTE with prospective stack components. The significant effect of cation off-stoichiometry and sample preparation on the electrical behavior of spinels was discussed as a possible explanation for the large discrepancies in reported conductivity values for both systems.

08 HYDROGEN↗
NASA NTRS1991

Electrically conducting polymers for aerospace applications

Current research on electrically conducting polymers from 1974 to the present is reviewed focusing on the development of materials for aeronautic and space applications. Problems discussed include extended pi-systems, pyrolytic polymers, charge-transfer systems, conductive matrix resins for composite materials, and prospects for the use of conducting polymers in space photovoltaics.

Meador, Mary Ann B.↗
NASA NTRS1993

Simultaneous solution for core magnetic field and fluid flow beneath an electrically conducting mantle

The effects of laterally homogeneous mantle electrical conductivity were included in steady, frozen-flux core surface flow estimation along with refinements in method and weighting. The refined method allows simultaneous solution for both the initial radial geomagnetic field component at the core-mantle boundary (CMB) and the sub-adjacent fluid motion; it also features Gauss' method for solving the non-linear inverse problem associated with steady motional induction. The tradeoff between spatial complexity of the derived flows and misfit to the weighted Definitive Geomagnetic Reference Field models (DGRF's) is studied for various mantle conductivity profiles. For simple flow and a fixed initial geomagnetic condition, a fairly high deep-mantle conductivity performs better than either insulating or weakly conducting profiles; however, a thin, very high conductivity layer at the base of the mantle performs almost as well. Simultaneous solution for both initial geomagnetic field and flow reduces the misfit per degree of freedom even more than does changing the mantle conductivity profile. Moreover, when both core field and flow are estimated, the performance of the solutions and the derived flows become insensitive to the conductivity profile.

Voorhies, Coerte V.↗
NASA NTRS1994

Simultaneous solution for core magnetic field and fluid flow beneath an electrically conducting mantle

The effects of laterally homogeneous mantle electrical conductivity have been included in steady, frozen-flux core surface flow estimation along with refinements in method and weighting. The refined method allows simultaneous solution for both the initial radial geomagnetic field component at the core-mantle boundary and the subadjacent fluid motion; it also features Gauss' method for solving the nonlinear inverse problem associated with steady motional induction. The trade-off between spatial complexity of the derived flows and misfit to the weighted Definitive Geomagnetic Reference Field models is studied for various mantle conductivity profiles. For simple flow and a fixed initial geomagnetic condition a fairly high deep-mantle conductivity performs better than either insulating or weakly conducting profiles; however, a thin, very high conductivity layer at the base of the mantle performs almost as well. Simultaneous solution for both initial geomagnetic field and fluid flow reduces the misfit per degree of freedom even more than does changing the mantle conductivity profile. Moreover, when both core field and flow are estimated, the performance of the solutions and the derived flows become insensitive to the conductivity profile.

Voorhies, Goerte V.↗
DOE OSTI2025

Statistical Analysis of Intertube Tunneling Contacts in the Macroscopic Electrical Conductivity of Carbon Nanotube Fibers

Here, this study investigates the influence of tunneling contact resistances between carbon nanotubes (CNTs) on electron transport and electrical conductivity of macroscopic carbon nanofibers (CNFs), which profoundly impacts the performance of CNT thin film electronics, CNF electron emitters and cathodes, and energy conversion and storage devices. Utilizing a self-consistent electrical contact model coupling a transmission line model with tunneling current, we calculate the contact resistances of a plethora of CNT-CNT contacts within a CNF fiber, which consists of aligned, densely packed CNTs. A statistical analysis is conducted, using Gaussian distributions to account for variations in contact lengths, tunneling gap distances, and single CNT aspect ratios, to calculate the CNT-CNT contact resistance and the overall resistance of CNT fiber. By scaling our model to a macroscopic level, our results are in good agreement with experimental measurements. Our calculation suggests that while increasing the contact overlap length diminishes individual CNT-CNT contact resistance, it could paradoxically increase macroscopic CNT fiber resistance for a given constant CNF mass density, which is due to that fact that a larger overlap length allows more CNTs to pack along an electrical conduction path per unit length, leading to more tunneling contact junctions connected in series and thus less number of parallel conduction paths within the fiber cross section. Increasing tunneling gap distance increases both individual contact and overall fiber resistance. This research provides a simple design tool for tailoring CNT fiber electrical properties to promote real-world applications using CNTs or similar low-dimensional materials.

36 MATERIALS SCIENCE↗