Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “determinant”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Application of Raman Spectroscopy to Determine Uranium Content in ADUN Solution

The work presented in this report is part of the ongoing efforts to address the nuclear material control and accounting needs for advanced reactor fuel fabrication facilities. This work was supported by the Materials Protection, Accounting, and Control Technologies (MPACT) program under the US Department of Energy Office of Nuclear Energy‘s Nuclear Fuel Cycle and Supply Chain program. The activities and engagements under the MPACT program are designed to support a robust US civilian nuclear energy enterprise. In the work described in this report, we supported MPACT objectives by developing measurement techniques that could be used for material accounting and process monitoring and by working with industry partners to identify existing gaps and areas for improvement. Oak Ridge National Laboratory has been working with commercial tristructural isotropic (TRISO) fuel fabricators such as Standard Nuclear to develop technology for rapid and cost-effective uranium content assessment. This work has focused on demonstrating advanced measurement techniques (e.g., Raman spectroscopy) that can be used for rapid, reliable, and cost-effective routine measurements of uranium content in feed solutions and liquid waste streams as well as for monitoring in-line process measurements and product streams. Specifically, this report explores techniques for accurately determining uranium content in acid-deficient uranyl nitrate (ADUN) solutions and detecting low uranium concentrations in ammonia solutions. Developing such measurement techniques will benefit TRISO fuel fabrication facilities, facilities involved in other parts of the fuel cycle that require online monitoring of aqueous solutions, and potentially molten salt fuel reactors. This work supports developing Raman spectroscopy procedures to determine uranium concentrations in ADUN solutions, which are used as feedstock in the sol–gel process for creating TRISO fuel. Some additional benefits of using Raman spectroscopy for uranium quantification in fabrication facilities include enabling online monitoring of the chemical process, which would provide near real-time feedback; eliminating the need for sample transfers, preparation, or dilution; providing nondestructive measurements; and user friendliness. In this fiscal year, FY25, we determined the identity of the unknown Raman band at approximately 853 cm−1 that was discovered in ADUN Raman spectra in FY24, created calibration curves and determined uranium concentrations of two ADUN solutions, and compared the Raman results to results obtained from inductively coupled plasma mass spectrometry and Davies–Gray titration. Furthermore, we have identified focus areas for experimentation in future fiscal years. A key result is that the accuracy of using Raman can provide accuracy comparable to destructive analysist techniques, With a well-developed calibration curve, using standards and a large number of samples (more than five samples), uncertainty on the order of 1%–3% is achievable. Given that the uncertainties achieved by Raman spectroscopy were on the order of the uncertainties achieved using ICP-MS, we conclude that with a well-developed procedure Raman spectroscopy can be used to determine uranium concentrations in ADUN solutions for NMC&A applications. The benefits of such an approach are that the time and effort will be less than that of comparable destructive analysis techniques, with approximately the same level of technical expertise. This will be attractive to operators of fuel fabrication facilities as it will lower costs and improve efficiencies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Tetrafluoroboric Acid Digestion for Accurate Determination of Rare Earth Elements in Coal and Fly Ash by ICP-MS Analysis

Coal and coal-related fly ash often contain rare earth elements (REEs) that have the potential to be utilized as valuable mineral resources. Accurately determining the REE content in coal and fly ash is crucial for resource evaluation. The conventional approach involves using hydrofluoric acid (HF) to dissolve silicates and release REEs, which, however, prolongs the digestion process due to the additional step of complexing fluoride ions (F−) with boric acid (H3BO3). Determining the correct amount of H3BO3 for neutralization can be challenging, and in some instances, the binding of fluoride ions with certain lanthanides (Lns) hampers the accurate determination of all 14 naturally occurring rare earth elements in a single digestion batch by inductively coupled plasma mass spectrometry (ICP-MS). In this study, we present an alternative method that achieves the accurate determination of all 14 naturally occurring REEs using tetrafluoroboric acid (HBF4) followed by ICP-MS analysis. This approach eliminates the need for an F− complexing step. We tested this method on certified REE reference materials, including NIST 1632e (coal) and NIST 1633c (fly ash), as well as the REE geological reference material USGS AGV-1 (andesite). Our results demonstrated excellent recovery rates (relative standard deviation, RSD < ±10%), with a correlation coefficient (r2) exceeding 0.99. Using this method, we investigated the concentrations of all 14 REEs in coal and fly ash samples collected from various locations in the southwestern USA. This improved digestion technique streamlines the analysis process and enhances the accuracy of REE determination, facilitating a more comprehensive evaluation of REE-rich coal and fly ash deposits for resource exploration.

58 GEOSCIENCES↗
NASA NTRS1974

The geoid: Definition and determination

The determination of the geoid has been one of the prime goals of geodesy. Knowledge of geoid undulations with respect to some reference surface was needed for the determination of the figure of the earth, for the precise reduction of distance measurements to a reference ellipsoid, and for the determination of the geocentric location of points on the surface of the earth. Currently and in the future, undulation information can also be used in geophysical studies related to crustal structures and in oceanographic studies related to sea surface topography. The actual determination of global geoids has been carried out by using gravimetric data, satellite‐derived information related to the gravitational field of the earth, or a combination of the two techniques. Regional geoid determinations have been made by astrogeodetic techniques. For some applications of undulation information, undulation standard deviations of the order of ±5 m would be sufficient. Such an accuracy can be obtained by using data currently available. In the past few years, renewed interest in the geoid arose when the concept of satellite altimetry was proposed to measure the distance from the satellite to some area on the ocean surface.

Richard H. Rapp↗
NASA NTRS1978

Determination of boron and lithium by recording the products from (n, alpha) reactions

Irradiation with thermal neutrons in the VVR-S reactor provides a nondestructive method for determining the presence of boron and lithium in solids. The charged particles produced in the reactions Li-6(n,alpha)H-3 and B-10(n,alpha)Li-7 were detected using CsI single crystal. For alpha-particle spectrometry in the boron determination, an ionization chamber (W and Sn electrodes, 99% Ar + 1% H2) was developed allowing both absolute and relative measurements. In determining boron in lithium-containing samples, both scintillation and ionization chambers are used. In determining lithium in minerals, the error was 1.5%, and the sensitivity 0.00005 wt.%. In the determination of boron in SiC with a concentration of boron approximately (3 plus or minus 2) the error given by the alpha-range uncertainty was 15%.

Lobanov, Y. M.↗
NASA NTRS1978

The GEOS-3 orbit determination investigation

The nature and improvement in satellite orbit determination when precise altimetric height data are used in combination with conventional tracking data was determined. A digital orbit determination program was developed that could singly or jointly use laser ranging, C-band ranging, Doppler range difference, and altimetric height data. Two intervals were selected and used in a preliminary evaluation of the altimeter data. With the data available, it was possible to determine the semimajor axis and eccentricity to within several kilometers, in addition to determining an altimeter height bias. When used jointly with a limited amount of either C-band or laser range data, it was shown that altimeter data can improve the orbit solution.

Pisacane, V. L.↗
NASA NTRS1978

On-board Attitude Determination System (OADS)

The requirements, capabilities and system design for an on-board attitude determination system (OADS) to be flown on advanced spacecraft missions were determined. Based upon the OADS requirements and system performance evaluation, a preliminary on-board attitude determination system is proposed. The proposed OADS system consists of one NASA Standard IRU (DRIRU-2) as the primary attitude determination sensor, two improved NASA Standard star tracker (SST) for periodic update of attitude information, a GPS receiver to provide on-board space vehicle position and velocity vector information, and a multiple microcomputer system for data processing and attitude determination functions. The functional block diagram of the proposed OADS system is shown. The computational requirements are evaluated based upon this proposed OADS system.

Carney, P.↗
NASA NTRS1979

Feasibility of determining flat roof heat losses using aerial thermography

The utility of aerial thermography for determining rooftop heat losses is investigated. Actual rooftop heat losses were obtained both from in-situ instrumentation of test roofs with known thermal resistances and aerial thermography obtained from overflights at an altitude of 305 m. It is found that the roof heat losses calculated using the remotely determined roof temperature agreed to within 17% of those calculated from ground measurements. However it is noted that an acceptable quantitative determination of roof heat losses using aerial thermography is only feasible when the convective term is accurately known or minimized. In addition, the sensitivity of the heat loss determination to environmental conditions is also evaluated. Finally, the analysis shows that the most reliable determinations can probably be obtained under conditions of total cloud cover with low wind speeds and at low ambient temperatures.

Bowman, R. L.↗
NASA NTRS1980

Incorporation of star measurements for the determination of orbit and attitude parameters of a geosynchronous satellite: An iterative application of linear regression

Currently on NOAA/NESS's VIRGS system at the World Weather Building star images are being ingested on a daily basis. The image coordinates of the star locations are measured and stored. Subsequently, the information is used to determine the attitude, the misalignment angles between the spin axis and the principal axis of the satellite, and the precession rate and direction. This is done for both the 'East' and 'West' operational geosynchronous satellites. This orientation information is then combined with image measurements of earth based landmarks to determine the orbit of each satellite. The method for determining the orbit is simple. For each landmark measurement one determines a nominal position vector for the satellite by extending a ray from the landmark's position towards the satellite and intersecting the ray with a sphere with center coinciding with the Earth's center and with radius equal to the nominal height for a geosynchronous satellite. The apparent motion of the satellite around the Earth's center is then approximated with a Keplerian model. In turn the variations of the satellite's height, as a function of time found by using this model, are used to redetermine the successive satellite positions by again using the Earth based landmark measurements and intersecting rays from these landmarks with the newly determined spheres. This process is performed iteratively until convergence is achieved. Only three iterations are required.

Phillips, D.↗
NASA NTRS1983

Multisatellite attitude determination/optical aspect bias determination (MSAD/OABIAS) system description and operating guide. Volume 1: Introduction and analysis

The Multisatellite Attitude Determination/Optical Aspect Bias Determination (MSAD/OABIAS) System, designed to determine spin axis orientation and biases in the alignment or performance of optical or infrared horizon sensors and Sun sensors used for spacecraft attitude determination is described. MSAD/OABIAS uses any combination of eight observation models to process data from a single onboard horizon sensor and Sun sensor to determine simultaneously the two components of the attitude of the spacecraft, the initial phase of the Sun sensor, the spin rate, seven sensor biases, and the orbital in-track error associated with the spacecraft ephemeris information supplied to the system. In addition, the MSAD/OABIAS System provides a data simulator for system and performance testing, an independent deterministic attitude system for preprocessing and independent testing of biases determined, and a multipurpose data prediction and comparison system.

Joseph, M.↗
NASA NTRS1983

Multisatellite attitude determination/optical aspect bias determination (MSAD/OABIAS) system description and operating guide. Volume 3: Operating guide

The Multisatellite Attitude Determination/Optical Aspect Bias Determination (MSAD/OABIAS) System, designed to determine spin axis orientation and biases in the alignment or performance of optical or infrared horizon sensors and Sun sensors used for spacecraft attitude determination, is described. MSAD/OABIAS uses any combination of eight observation models to process data from a single onboard horizon sensor and Sun sensor to determine simultaneously the two components of the attitude of the spacecraft, the initial phase of the Sun sensor, the spin rate, seven sensor biases, and the orbital in-track error associated with the spacecraft ephemeris information supplied to the system. In addition, the MSAD/OABIAS system provides a data simulator for system and performance testing, an independent deterministic attitude system for preprocessing and independent testing of biases determined, and a multipurpose data prediction and comparison system.

Joseph, M.↗
NASA NTRS1983

Voyager orbit determination at Jupiter

This paper summarizes the Voyager 1 and Voyager 2 orbit determination activity extending from encounter minus 60 days to the Jupiter encounter, and includes quantitative results and conclusions derived from mission experiences. The major topics covered include an identification and quantification of the major orbit determination error sources and a review of salient orbit determination results from encounter, with emphasis on the Jupiter approach phase orbit determination. Special attention is paid to the use of combined spacecraft-based optical observations and earth-based radiometric observations to achieve accurate orbit determination during the Jupiter encounter approach phase.

Campbell, J. K.↗
NASA NTRS1985

Dynamic characteristics of statically determinate space-truss platforms

The geometry of a class of statically determinate platforms is developed and vibration frequencies determined. Such configurations would allow shape control by changing member lengths to be accomplished with small forces. An additional advantage of a statically determinate structure is being free of thermal stress under any temperature distribution. Frequency comparisons between statically determinate and more conventional redundant platforms are presented. Vibration of curved platforms that could be used as antenna concepts is also investigated. Alternate concepts incorporating the statically determinate design but having improved dynamic characteristics are suggested.

Anderson, M. S.↗
NASA NTRS1986

Determination of band oscillator strengths of atmospheric molecules from high resolution vacuum ultraviolet cross section measurements

An account is given of progress in work on (1) the determination of band oscillator strengths of the Schumann-Runge absorption bands of (16)O2 and (18)O2 from cross section measurements conducted at 79 K; (2) the determination of the absolute absorption cross section of the Schumann-Runge bands of (16)O(18)O from optical depth measurements performed on mixtures of (16)O2, (18)O2 and (16)O(18)O at 79K; and (3) the influence of Schumann-Runge linewing contributions on the determination of the Herzberg continuum absorption cross section of (16)O2 in the wavelength region 194 to 204 nm. The experimental investigations are effected at high resolution with a 6.65 m scanning spectrometer which is, by virtue of its small instrumental width (EWHM = 0.0013 nm), uniquely suitable for cross section measurements of molecular bands with discrete rotational structure. Absolute cross sections, which are independent of the instrumental function and from which band oscillator strengths are directly determined, are measured for the absorption bands that are most predissociated. Such measurements are needed for (1) accurate calculations of the stratospheric production of atomic oxygen and heavy ozone formed following the photopredissociation of (18)O(16)O by solar radiation penetrating between the absorption lines of (16)O2; (2) elucidation of the mechanism of predissociation of the upper state of the Schumann-Runge bands; and (3) determination of the true shape of the Herzberg continuum cross section.

Parkinson, W. H.↗
NASA NTRS1985

Assisting extrasolar planetary detection through the determination of stellar space orientations

Various methods outlined for indirect planetary detection would greatly benefit (in some cases require) the determination of the planetary orbital plane, which is theoretically equivalent to the stellar equatorial plane. Determining the stellar space orientation, therefore, would greatly benefit extrasolar planetary detection. Stellar rotation periods determined from short-term variations in Ca II H and K sunspot emission are utilized together with both stellar radii measurements and Doppler-broadened spectral line profiles to get the stellar inclination to the line of sight. The clocklike on-the-plane-of-the-sky component determination utilizes the concentration of sunspot-associated plage areas at central stellar latitudes when viewed in Ca II H or K emission. One can perform Ca II H and K emission speckle interferometry to measure the clocklike angle of this stellar Ca II H and K emission band, modeling it as an elliptical intensity distribution. Both components should be determinable to within 10 deg for at least the resolvable fifth magnitude stars.

Doyle, L. R.↗
NASA NTRS1986

Orbit determination using synthetic aperture radar

The use of synthetic aperture radar (SAR) images to estimate orbital parameters is studied. The SAR image formation process which requires the ability to repeatedly transmit identical signals and accurately sense the return echoes from a region of terrain is described. The orbit determination capabilities of the SAR system's observables are investigated. Five SAR observations were collected from a simulated shuttle orbit, which was circular with a latitude of 220 km and along-track velocity of 7.7 km/sec, to obtain along-track and line-of-sight direction position measurements; the simulation reveals that only three SAR observations were required to determine the position of the spacecraft to within 100 m. A prototype SAR orbit determination system was developed. The system consists of a VAX 11/780 time-shared computer, a frame buffer, topographic maps, and software for line-pixel location of an object within a SAR image and for orbit determination. The prototype is applied to the processing of a single short arc of Shuttle Imaging-Radar-B (SIR-B) data. It is observed that the SAR data is useful as orbit determination or tracking data; however, the low SNRs in the SIR-B data made feature identification difficult.

Taber, W. L.↗
NASA NTRS1989

Determination of longitudinal aerodynamic derivatives using flight data from an icing research aircraft

A flight test was performed with the NASA Lewis Research Center's DH-6 icing research aircraft. The purpose was to employ a flight test procedure and data analysis method, to determine the accuracy with which the effects of ice on aircraft stability and control could be measured. For simplicity, flight testing was restricted to the short period longitudinal mode. Two flights were flown in a clean (baseline) configuration, and two flights were flown with simulated horizontal tail ice. Forty-five repeat doublet maneuvers were performed in each of four test configurations, at a given trim speed, to determine the ensemble variation of the estimated stability and control derivatives. Additional maneuvers were also performed in each configuration, to determine the variation in the longitudinal derivative estimates over a wide range of trim speeds. Stability and control derivatives were estimated by a Modified Stepwise Regression (MSR) technique. A measure of the confidence in the derivative estimates was obtained by comparing the standard error for the ensemble of repeat maneuvers, to the average of the estimated standard errors predicted by the MSR program. A multiplicative relationship was determined between the ensemble standard error, and the averaged program standard errors. In addition, a 95 percent confidence interval analysis was performed for the elevator effectiveness estimates, C sub m sub delta e. This analysis identified the speed range where changes in C sub m sub delta e could be attributed to icing effects. The magnitude of icing effects on the derivative estimates were strongly dependent on flight speed and aircraft wing flap configuration. With wing flaps up, the estimated derivatives were degraded most at lower speeds corresponding to that configuration. With wing flaps extended to 10 degrees, the estimated derivatives were degraded most at the higher corresponding speeds. The effects of icing on the changes in longitudinal stability and control derivatives were adequately determined by the flight test procedure and the MSR analysis method discussed herein.

Ranaudo, R. J.↗
NASA NTRS1989

Automation of orbit determination functions for National Aeronautics and Space Administration (NASA)-supported satellite missions

The Flight Dynamics Facility (FDF) at Goddard Space Flight Center (GSFC) provides spacecraft trajectory determination for a wide variety of National Aeronautics and Space Administration (NASA)-supported satellite missions, using the Tracking Data Relay Satellite System (TDRSS) and Ground Spaceflight and Tracking Data Network (GSTDN). To take advantage of computerized decision making processes that can be used in spacecraft navigation, the Orbit Determination Automation System (ODAS) was designed, developed, and implemented as a prototype system to automate orbit determination (OD) and orbit quality assurance (QA) functions performed by orbit operations. Based on a machine-resident generic schedule and predetermined mission-dependent QA criteria, ODAS autonomously activates an interface with the existing trajectory determination system using a batch least-squares differential correction algorithm to perform the basic OD functions. The computational parameters determined during the OD are processed to make computerized decisions regarding QA, and a controlled recovery process isactivated when the criteria are not satisfied. The complete cycle is autonomous and continuous. ODAS was extensively tested for performance under conditions resembling actual operational conditions and found to be effective and reliable for extended autonomous OD. Details of the system structure and function are discussed, and test results are presented.

Mardirossian, H.↗
NASA NTRS1990

A comparison of operationally determined atmospheric densities from satellite orbit solutions and the exospheric temperature from the Jacchia-Roberts model

Operational orbit determination by the Flight Dynamics Division at the Goddard Space Flight Center has yielded a data base of orbit solutions covering the onset of solar cycle 22. Solutions for nine satellites include an estimated drag adjustment parameter (rho sub 1) determined by the Goddard Trajectory Determination System (GTDS). The rho sub 1 is used to evaluate correlations between density variations and changes in the following: 10.7-centimeter wavelength solar flux (F sub 10.7), the geomagnetic index A sub p, and two exospheric temperatures (T sub c and T sub infinity) adapted from the Jacchia-Roberts atmospheric density model in GTDS. T sub c depends on the daily and 81-day centered mean F sub 10.7; T sub infinity depends on T sub c and the geomagnetic index K sub p values. The highest correlations are between density and T sub infinity. Correlations with T sub c and F sub 10.7 are lower by 9 and 10 percent, respectively. For most cases, correlations with A sub p are considerably lower; however, significant correlations with A sub p were found for some high-inclination, moderate-altitude orbits. Results from this analysis enhance the understanding of the drag model and the accommodation of atmospheric density variations in the operational orbit determination support. The degree of correlation demonstrates the sensitivity of the orbit determination process to drag variations and to the input parameters that characterize aspects of the atmospheric density model. To this extent, the degree of correlation provides a measure of performance for methods of selecting or modeling the thermospheric densities using the solar F sub 10.7 and geomagnetic data as input to the process.

Ward, D. T.↗