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At least 127 records · Page 7

Monolithic microcircuit techniques and processes

Brief discussions of the techniques used to make dielectric and metal thin film depositions for monolithic circuits are presented. Silicon nitride deposition and the properties of silicon nitride films are discussed. Deposition of dichlorosilane and thermally grown silicon dioxide are reported. The deposition and thermal densification of borosilicate, aluminosilicate, and phosphosilicate glasses are discussed. Metallization for monolithic circuits and the characteristics of thin films are also included.

Kennedy, B. W.↗

Activated sintering of ThO2 and ThO2-Y2O3 with NiO.

Scanning electron microscopy and isothermal shrinkage measurements were used to study the effects of additives on the sintering of Thoria-Yttria compacts and loose powders. Small amounts of the oxides of Ni, Zn, Co, and Cu were found to reduce the sintering temperature (which is normally above 2000 C). In particular, NiO, at a concentration of 0.8 wt %, was found to yield high-density bodies at temperatures below 1500 C. Densification occurs very rapidly, and is followed by a much slower sintering process typical of volume diffusion.

Halbfinger, G. P.↗

Are the lunar seismic signals compatible with a deep layer of fine powder.

It is shown that a sudden change in the seismic wave velocity at 25 km can be interpreted in terms of a single type of material, namely the fine rock powder that is so abundant on the lunar surface. An investigation conducted by Toksoz et al. (1972) is considered. Toksoz et al. rule out a deep powder layer and derive a velocity profile for powders from laboratory data. Differences regarding powder densification between laboratory tests and actual lunar conditions due to much longer compression times are pointed out.

Jones, B. W.↗

Sintering and hot pressing of Fra Mauro composition glass and the lithification of lunar breccias.

It is proposed that Apollo 14 type breccias lithify by sintering of particles of matrix glass under stress-free conditions. Meteorite impacts generate the heat necessary for sintering. Compacted angular particles of glass with the composition of an Apollo 14 rock were sintered experimentally. Loose clods of sub 37 micron grains form in several days at 700 C. Synthetic rocks, which texturally resemble the breccias, were produced at 795 C and above in 7.5 hours. Glass devitrified with increasing temperature. At 850 C, devitrification prevents much further densification of the synthetic breccias after 2 hours. Experiments compressing glass at 500 bars at 600 C produced dense vitreous masses which did not resemble lunar breccias. Confining pressure does not play a major role in lithifying the breccias. It is concluded that Apollo 14 type lunar breccias form at shallow depths at 800 C+ in a period of minutes to days.

Simonds, C. H.↗

Grain boundary mobility in anion doped MgO

Certain anions OH(-), F(-) and Gl(-) are shown to enhance grain growth in MgO. The magnitude of their effect decreases in the order in which the anions are listed and depends on their location (solid-solution, second phase) in the MgO lattice. As most anions exhibit relatively high vapor pressures at sintering temperatures, they retard densification and invariably promote residual porosity. The role of anions on grain growth rates was studied in relation to their effect on pore mobility and pore removal; the atomic process controlling the actual rates was determined from observed kinetics in conjunction with the microstructural features. With respect to controlling mechanisms, the effects of all anions are not the same. OH(-) and F(-) control behavior through creation of a defect structure and a grain boundary liquid phase while Cl(-) promotes matter transport within pores by evaporation-condensation. Studies on an additional anion, S to the minus 2nd power gave results which were no different from undoped MgO, possibly because of evaporative losses during hot pressing. Hence, the effect of sulphur is negligible or undetermined.

Kapadia, C. M.↗

Powder compaction in systems of bimodal distribution

The compaction of mixtures involving different particle sizes is discussed. The various stages of the compaction process include the rearrangement of particles, the filling of the interstices of the large particles by the smaller ones, and the change in particle size and shape upon further densification through the application of pressure. Experimental approaches and equipment used for compacting material are discussed together with the theoretical relations of the compacting process.

Chattopadhyay, A. K.↗

Magnetic pinch compression of silica glass

SiO2 glass has been irreversibly densified by pressures up to 250 kbar produced in a magnetic pinch apparatus. The threshold for significant densification was about 60 kbar. The recovered densities agree better with published shock wave results than with static results.

Bless, S. J.↗

Low-cost methods for fabrication of aluminum-boron shapes

Deformation processing has not been seriously considered as applicable to composite fabrication, particularly if the filament (e.g., boron) lacks plasticity. When, however, the brittle filament is clad with a ductile matrix such as 6061 Al, the underlying filament is protected from damage even when cold worked severely as in drawing and rolling. These two metal-working processes have been applied successfully to produce seven ply aluminum 50 vol % boron tubes up to 2 in. O.D. by 3 feet in length and flats 1 in. in width by 2 feet in length respectively. Although adequate densification is achieved via drawing and rolling, the former has been given major emphasis. Mechanical properties of rolled and drawn flats and tubes compare favorably with those prepared by static methods. However, the objective of the presentation is to focus on lower processing costs. In specific terms, 2 in. tubes in lengths up to 12 feet can be produced for as little as $150/lb. This is possible only because standard drawbench and carbide dies can be utilized. Furthermore, the major steps including cladding, preform preparation and drawing are conducive to automation.

Divecha, A. P.↗

Microstructure of hot-pressed Al2O3-Si3N4 mixtures as a function of holding temperature

Powder mixtures of 40 m/o Si3N4-60 m/o Al2O3 were hot-pressed at 4000 psi at various holding temperatures from 1100 C to 1700 C. Scanning Electron Microscopy and Transmission Electro Microscopy results were correlated to X-ray phase analysis and density measurements. The progressively developed microstructure was used to interpret the densification behavior of SiAlON. Photomicrographs of microstructures are shown.

Yeh, H. C.↗

Pressure sintering of Si3N4-Al2O3 /Sialon/

Essentially pore-free Sialon bodies were obtained by pressure sintering for three blends (mol ratios of 4:1, 2:3, and 3:2) of Si3N4 and Al2O3 powders under the conditions of 27.6 MN/sq m and a temperature of 1700 C for 2 h. These dense bodies consist mainly of a Sialon solid solution with a minor amount of a particular second phase. The higher the Al2O3 content (20 to 60 mol% range) in Sialon, the higher the densification rate. Fully dense bodies can be obtained at temperatures as low as 1500 C at 27.6 MN/sq m for 2 h with no second phase detectable by X-ray diffraction. A 100% dense body can be obtained by heating at 1700 C at 27.6 MN/sq m without a holding time.

Yeh, H. C.↗

Friction and wear of several compressor gas-path seal movements

Rub interaction experiments were conducted on a series of sintered and plasma sprayed compressor gas path seal materials in contact with Ti-6Al-4V blade tip and knife edge rotors. The most rub tolerant materials investigated were sintered Nichrome and plasma sprayed nickel 25 percent graphite. The effectiveness of providing a compliant substrate for dense seal material coatings was also demonstrated. In general, it was observed that rotor wear and high frictional energy generation rates accompanied smearing or surface densification of the materials investigated. The onset of smearing was sensitive to rub interaction parameters and seal geometry. Two complementary models were proposed to account for the smearing trends. One is based on thermal effects, the other on particulate escape effects. They were shown to be consistent with the experimental evidence at hand, and together they predict that smearing, with the onset of high energy rub conditions, is favored when incursion rates (radial motion) are low, incursion depths are high, the seal geometry is of a knife-edge character, and the seal particle size is small.

Bill, R. C.↗

Effects of pressure and temperature on hot pressing a sialon

Mixed powders (60 m/o Al2O3-40 m/o Si3N4) were hot pressed at temperatures and pressures from 1360 to 1750 C and 3.5 to 27.5 MPa (0.5 to 4.0 ksi). Fully dense sialon bodies are obtainable at temperatures and pressures as low as 1550 C and 0.5 ksi. The fully dense bodies contain Beta prime and x-phase. There is some evidence that plastic deformation has contributed to densification.

Yeh, H. C.↗

Microstructure of hot-pressed Al2O3-Si3N4 mixtures as a function of holding temperature

Powder mixtures of 40 m/o Si3N4-60 m/o Al2O3 were hot-pressed at 4000 psi at various holding temperatures from 1100 C to 1700 C. Scanning and transmission electron microscopy results were correlated to X-ray phase analysis and density measurements. The progressively developed microstructure was used to interpret the densification behavior of SiAlON.

Yeh, H. C.↗

Detection of horizontal crustal movements by photogrammetric methods

The photogrammetric methods can be applied only if the horizontal displacements of the ground are of the order of several centimeters, because the standard error of the points so determined cannot, at the present time, be smaller than two centimeters. The procedure to be adopted, which has already been applied with satisfactory results for the densification of geodetic nets, is the aerial analytical triangulation. The taking can be executed with wide-angle cameras (f = 15 cm), or normal-angle cameras (f = 30 cm) and format 23 x 23 cm. Since the average scale of photos must be chosen in relation with the desired accuracy and then is independent of the principal distance of the cameras, the number of photos is constant, whereas the flying height varies according to the focal length.

Solaini, L.↗

Polar Environmental Monitoring

The present and projected benefits of the polar regions were reviewed and then translated into information needs in order to support the array of polar activities anticipated. These needs included measurement sensitivities for polar environmental data (ice/snow, atmosphere, and ocean data for integrated support) and the processing and delivery requirements which determine the effectiveness of environmental services. An assessment was made of how well electromagnetic signals can be converted into polar environmental information. The array of sensor developments in process or proposed were also evaluated as to the spectral diversity, aperture sizes, and swathing capabilities available to provide these measurements from spacecraft, aircraft, or in situ platforms. Global coverage and local coverage densification options were studied in terms of alternative spacecraft trajectories and aircraft flight paths.

Nagler, R. G.↗

"Densified" tiles form stronger bonds

Application of colloidal silica more than doubles bond strength of ceramic tile/substrate attachments. "Densification" process strengthens surface where tile attaches to felt strain-isolator pad, redistributing stresses and preventing failures at that point. First, isopropyl alcohol is applied to bottom tile surface. Second, aqueous mixture of cementing colloidal silica and reinforcing ball-milled silica particles is painted on tile. Finally, after drying, tile is rewaterproofed by exposure to vapors or methyltrimethoxysilane and acetic acid.

Dotts, R. L.↗

Shock effects in olivine and implications for Hugoniot data

New observations of shock deformation in single-crystal olivine are presented for the range in peak pressures from about 16 to 75 GPa. A nonequilibrium model is suggested for the behavior of olivine under shock which explains the densification associated with a mixed-phase region and which is consistent with all available observations, yet which bears little similarity to the equilibrium behavior of olivine at high pressure.

Jeanloz, R.↗

Structural tests on space shuttle thermal protection system constructed with nondensified and densified Li 900 and LI 2200 tile

Structural tests were conducted on thermal protection systems (TPS) LI 900 and LI 2200 tiles and .41 cm and .23 cm thick strain isolation pads. The bond surface of selected tiles was densified to obtain improved strength. Four basic types of experiments were conducted including tension tests, substrate mismatch (initial imperfection) tests, tension loads eccentrically applied, and pressure loads applied rapidly to the tile top surface. A small initial imperfection mismatch (2.29 m spherical radius on the substrate) did not influence significantly the ultimate failure strength. Densification of the tile bond region improved the strength of TPS constructed both of LI 900 tile and of LI 2200 tile. Pressure shock conditions studied did not significantly affect the TPS strength.

Williams, J. G.↗