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Monitoring Direct Effects of Delta, Atlas, and Titan Launches from Cape Canaveral Air Station

Launches of Delta, Atlas, and Titan rockets from Cape Canaveral Air Station (CCAS) have potential environmental effects that could arise from direct impacts of the launch exhaust (e.g., blast, heat), deposition of exhaust products of the solid rocket motors (hydrogen chloride, aluminum oxide), or other effects such as noise. Here we: 1) review previous reports, environmental assessments, and environmental impact statements for Delta, Atlas, and Titan vehicles and pad areas to clarity the magnitude of potential impacts; 2) summarize observed effects of 15 Delta, 22 Atlas, and 8 Titan launches; and 3) develop a spatial database of the distribution of effects from individual launches and cumulative effects of launches. The review of previous studies indicated that impacts from these launches can occur from the launch exhaust heat, deposition of exhaust products from the solid rocket motors, and noise. The principal effluents from solid rocket motors are hydrogen chloride (HCl), aluminum oxide (Al2O3), water (H2O), hydrogen (H2), carbon monoxide (CO), and carbon dioxide (CO2). The exhaust plume interacts with the launch complex structure and water deluge system to generate a launch cloud. Fall out or rain out of material from this cloud can produce localized effects from acid or particulate deposition. Delta, Atlas, and Titan launch vehicles differ in the number and size of solid rocket boosters and in the amount of deluge water used. All are smaller and use less water than the Space Shuttle. Acid deposition can cause damage to plants and animals exposed to it, acidify surface water and soil, and cause long-term changes to community composition and structure from repeated exposure. The magnitude of these effects depends on the intensity and frequency of acid deposition.

Schmalzer, Paul A.↗

Tailoring Cementitious Materials Towards Value-Added Use of Large CO 2 Volumes

Hydraulic cements with alternative chemistries were developed for large-volume and value-added use of carbon dioxide. The hydraulic cements were processed using the energy-efficient mechanochemical technique at room temperature and atmospheric pressure. Carbon dioxide was captured directly from combustion emissions during processing. For this purpose, mechanochemical processing of hydraulic cements was accomplished under a flow of combustion emissions prior to the release of emissions to the atmosphere. The process removed a significant fraction of carbon dioxide from combustion emissions. The hydraulic cements captured carbon dioxide at about 10% of their weight. Two hydraulic cement chemistries were developed, and their mechanochemical processing was successfully scaled-up. The characteristic feature of one chemistry was its relatively low (near-neutral) pH where the integration of carbon dioxide yielded clear value. The second cement chemistry was based on alkali activation of industrial wastes. This chemistry could make value-added use of carbon dioxide, but it had to be refined to control the pH drop caused by CO 2 integration. These two cements render binding effects upon hydration by forming a combination of stable carbonates and aluminosilicates or phosphates. Efforts to develop cement chemistries based solely on carbonates were not successful. The mechanochemical process was found to integrate carbon dioxide into the alternative cement chemistries in the form of disordered and metastable carbonates. During hydration reactions, the disordered/metastable carbonates are either transformed into stable carbonate phases with desired binding efforts, or carbonates get integrated into the primary inorganic binders (hydrates). When compared with mechanochemical processing in pure carbon dioxide, mechanochemical processing in combustion emissions produced hydraulic cements with improved engineering properties. The mechanochemical process was scaled-up, and its variables as well as the raw materials formulations were optimized for implementation at pilot scale. Scale-up was found to enhance the carbon capture potential and the engineering qualities of the resulting hydraulic cements. This was because scale-up raises the intensity of mechanical energy input to raw materials. Certain mechanochemical phenomena cannot be induced, irrespective of the cumulative mechanical energy input, unless the intensity of impact is raised above a minimum level that cannot be achieved in laboratory-scale implementation of the process. Due to this effect, the duration of the mechanochemical process as well as its energy demand could be reduced significantly (by an order of magnitude) upon transition from laboratory to pilot scale, with the hydraulic cements produced at pilot scale offering engineering properties that were superior to those realized in laboratory-scale mechanochemical processing. The hydraulic cements produced at pilot scale via mechanochemical processing under a flow of combustion emissions were thoroughly characterized. They were found to meet standard requirements for ‘General Use’ hydraulic cements. They were compatible with the industrial-scale concrete production and construction practices that are used with the currently prevalent hydraulic cements. The new hydraulic cements with integrated carbon dioxide were found to offer distinct advantages over the currently prevalent Portland cement in terms of net carbon footprint and energy content. The combined raw materials and energy costs of the new hydraulic cements are competitive, and major cost savings can be realized because of the simplified production process that significantly lowers the capital investment in cement production plants. Mechanochemical processing of the new hydraulic cements under a flow of combustion emissions can be implemented using some existing components of cement manufacturing plants; this facilitates adoption of the technology by the cement industry.

36 MATERIALS SCIENCE↗

Proposed Potential Mitigation of Wastewater Disposal Through Treated Produced Water in Bakken Formation

The recent global expansion in the development of unconventional oil and gas assets has also resulted in a tremendous increase in the number of extended horizontal drilling and hydraulic fracturing projects in the Bakken. The United States is presently the largest global crude oil producer, and the Bakken Formation in North Dakota is one of the major contributors to this achievement. However, the wastewater produced from these increased oilfield activities are highly saline (∼170,000 to 350,000 ppm TDS) and no technology currently available can satisfactorily treat it. As a result, more than 90% of wastewater in the Bakken is disposed of by deep injection into disposal wells. However, there are growing environmental and operational concerns about the sustainability and impacts of this approach. Research has shown that cumulative wastewater injection in some areas could increase the chances of earthquakes in those areas. However, if this produced water is efficiently treated, it could be reused in hydraulic fracturing operations or to support coal mining and irrigation activities. All these applications would reduce the need for wastewater injection and reduce the demand for fresh water used in hydraulic fracturing operations across North Dakota. For this purpose, we propose an enhanced supercritical technology we call Supercritical Water Extraction – Enhance Targeted Recovery to handle the issue of high TDS of flowback and produced water in the Bakken.

04 OIL SHALES AND TAR SANDS↗

Dynamic land use implications of rapidly expanding and evolving wind power deployment

Abstract The expansion of wind power poses distinct and varied geographic challenges to a sustainable energy transition. However, current knowledge of its land use impacts and synergies is limited by reliance on static characterizations that overlook the role of turbine technology and plant design in mediating interactions with the environment. Here, we investigate how wind technology development and innovation have shaped landscape interactions with social and ecological systems within the United States and contribute to evolving land area requirements. This work assesses trends in key land use facets of wind power using a holistic set of metrics to establish an evidence base that researchers, technology designers, land use managers, and policymakers can use in envisioning how future wind-intensive energy systems may be jointly optimized for clean energy, social, and environmental objectives. Since 2000, we find dynamic land occupancy patterns and regional trends that are driven by advancing technology and geographic factors. Though most historical U.S. wind deployment has been confined to the temperate grassland biome in the nation’s interior, regional expansion has implicated diverse land use and cover types. A large percentage of the typical wind plant footprint (∼96% to > 99%) is not directly impacted by permanent physical infrastructure, allowing for multiple uses in the spaces between turbines. Surprisingly, turbines are commonly close to built structures. Moreover, rangeland and cropland have supported 93.4% of deployment, highlighting potential synergies with agricultural lands. Despite broadly decreasing capacity densities, offsetting technology improvements have stabilized power densities. Land use intensity, defined as the ratio of direct land usage to lifetime power generation of wind facilities, has also trended downwards. Although continued deployment on disturbed lands, and in close proximity to existing wind facilities and other infrastructure, could minimize the extent of impacts, ambitious decarbonization trajectories may predispose particular biomes to cumulative effects and risks from regional wind power saturation. Increased land-use and sustainability feedback in technology and plant design will be critical to sustainable management of wind power.

17 WIND ENERGY↗

Horizontal transport of the regolith, modification of features, and erosion rates on the lunar surface

Impact-ejecta systematics are developed for the smaller cratering events which, with cumulative crater populations observed in young mare regions and on Copernicus ejecta fields, yield rates and a range distribution for the horizontal transport of material by impact processes. The deposition rate for material originating more than 1 m away is found to be about 8 mm per million years. Material from 10 km away accumulates at a rate of about 0.08 mm per million years, providing a steady influx of foreign material. From the degradation of boulder tracks, a rate of 5 plus or minus 3 cm per million years is computed for the filling of shallow lunar depressions on slopes. Mass wastage and downslope movement of bedrock outcroppings on Hadley Rille seem to be proceeding at a rate of about 8 mm per million years. The Camelot profile is suggestive of a secondary impact feature.

Arvidson, R.↗

Northwest Africa 773: Lunar Mare Breccia with a Shallow-formed Olivine-Cumulate Component, Very-Low-Ti Heritage, and a KREEP Connection

Northwest Africa 773 is one of the more unusual lunar meteorites found in recent years because it contains a prominent clast lithology, which appears to be an olivine-rich cumulate and because it is a very-low-Ti (VLT) mare breccia with relatively high incompatible-trace-element concentrations and LREE/HREE enrichment. A lunar origin was verified by Fagan and coworkers on the basis of noble-gas contents, oxygen isotopes, and mineral compositions. Fagan et al. described two lithologies: (1) heterolithic impact breccia with a regolith component and (2) cumulus olivine gabbronorite. Here, we refer to these as the breccia (Bx) lithology and the olivine-cumulate (OC) lithology. The impact breccia components are predominantly volcanic (basaltic), and, in this context, the occurrence of the cumulus lithology is especially significant: is it related to the volcanic components or does it represent a deep-seated rock entrained by the basaltic magma as it rose to the surface? Elevated incompatible-element concentrations with more or less KREEP-like inter-element ratios and very-low-Ti concentrations distinguish both lithologies of this meteorite from Apollo mare basalts. Here, we summarize key compositional information (bulk and mineral), especially related to the OC lithology, to show that it formed at shallow depth and comes from a VLT ultramafic precursor that mixed with a KREEP-like trace-element component deep in the crust or upper mantle.

Jolliff, B. L.↗

Petrology of Diogenite NWA 5480, A Pristine Olivine-Rich Deformed Harzburgite

Diogenites are achondrites that are part of the HED (howardite, eucrite, diogenite) meteorite group thought to originate from asteroid Vesta. This suite of igneous rocks offers a glimpse of early planetary differentiation and subsequent igneous processes. While eucrites represent asteroidal basaltic crust and howardites the impact brecciated surface, diogenites are samples of the mantle and lower crust. Most of them are orthopyroxene (Opx) dominated cumulates, although harzburgites and rare dunites have also been found. The majority of diogenites are impact breccias. This study describes NWA 5480, a pristine, i.e. hardly altered and minimally shocked, harzburgitic diogenite.

Peslier, A. H.↗

Assessing precipitation, evapotranspiration, and NDVI as controls of US Great Plains plant production

Productivity throughout the North American Great Plains grasslands is generally considered to be water limited, with the strength of this limitation increasing as precipitation decreases. We hypothesize that cumulative actual evapotranspiration water loss (AET) from April to July is the precipitation-related variable most correlated to aboveground net primary production (ANPP) in the U.S. Great Plains (GP). We tested this by evaluating the relationship of ANPP to AET, precipitation, and plant transpiration (Tr). We used multi-year ANPP data from five sites ranging from semiarid grasslands in Colorado and Wyoming to mesic grasslands in Nebraska and Kansas, mean annual NRCS ANPP, and satellite-derived normalized difference vegetation index (NDVI) data. Results from the five sites showed that cumulative April-to-July AET, precipitation, and Tr were well correlated (R2: 0.54–0.70) to annual changes in ANPP for all but the wettest site. AET and Tr were better correlated to annual changes in ANPP compared to precipitation for the drier sites, and precipitation in August and September had little impact on productivity in drier sites. April-to-July cumulative precipitation was best correlated (R2 = 0.63) with interannual variability in ANPP in the most mesic site, while AET and Tr were poorly correlated with ANPP at this site. Cumulative growing season (May-to-September) NDVI (iNDVI) was strongly correlated with annual ANPP at the five sites (R2 = 0.90). Using iNDVI as a surrogate for ANPP, we found that county-level cumulative April–July AET was more strongly correlated to ANPP than precipitation for more than 80% of the GP counties, with precipitation tending to perform better in the eastern more mesic portion of the GP. Including the ratio of AET to potential evapotranspiration (PET) improved the correlation of AET to both iNDVI and mean county-level NRCS ANPP. Accounting for how different precipitation-related variables control ANPP (AET in drier portion, precipitation in wetter portion) provides opportunity to develop spatially explicit forecasting of ANPP across the GP for enhancing decision-making by land managers and use of grassland ANPP for biofuels.

Maosi Chen↗

Effects of global atmospheric perturbations on forest ecosystems: Predictions of seasonal and cumulative effects

The physical effects of certain large events, such as giant impacts, explosive volcanism, or combined nuclear explosions, have the potential of inducing global catastrophes in our terrestrial environment. Such highly energetic events can inject substantial quantities of material into the atmosphere. In turn, this changes the amount of sunlight reaching the Earth's surface and modifies atmospheric temperatures to produce a wide range of global effects. One consequence is the introduction of serious stresses in both plants and animals throughout the Earth's biosphere. For example, recent studies predict that forest lands, crop lands, and range lands would suffer specific physical and biological degradations if major physical and chemical disruptions occurred in our atmosphere. Forests, which cover over 4 times 10 to the 9th power hectares (4 times 10 to the 7th power sq km) of our planet, or about 3 times the area now cultivated for crops, are critical to many processes in the biosphere. Forests contribute heavily to the production of atmospheric oxygen, supply the major volume of biomass, and provide a significant percentage of plant and animal habitats.

Tinus, R. W.↗

Hypervelocity impact tests on Space Shuttle Orbiter RCC thermal protection material

It is noted that the Shuttle Orbiter will be more subject to meteoroid impact than previous spacecraft, due to its greater surface area and longer cumulative time in space. The Orbiter structural material, RCC, a reinforced carbon-carbon laminate with a diffused silicon carbide coating, is evaluated in terms of its resistance to hypervelocity impact. It was found that the specimens (disks with a mass of 34 g and a thickness of 5.0 mm) were cratered only on the front surface when the impact energy was 3 J or less. At 3 J, a trace of the black carbon interior was exposed. The specimens were completely penetrated when the energy was 34 J or greater.

Humes, D. H.↗

Petrogenesis of lunar troctolites

Models of petrogenesis for lunar troctolites are severely constrained by the high Mg(*) (greater than 88) values of the most primitive members of the Mg-rich suite. Melts derived by partial melting of olivine cumulates to the lunar magma ocean have high Mg(*) but are strongly undersaturated with respect to plagioclase. Assimilation of lunar crust cannot bring these melts to the plagioclase liquious without unduly reducing the Mg(*) values of olivine. Partial melts derived by melting a lherzolite primitive interior have higher normative plagioclase contents but require sources with Mg(*) greater than 90. More terrestrial-like Mg(*) (approximately 88) values are permitted if rising thermal plumes are capable of entraining the most Mg-rich cumulates of the magma ocean. The Mg(*) values of lunar troctolites may, therfore, reflect a hybrid source composed of primitive mantle and Mr-rich cumulates of the magma ocean. Higher Mg(*) values may also arise from the reducction of small amounts of FeO to Fe. Alternatively, the parent magmas to lunar troctolites may be impact melts of the anorthositic crust and the Mg-rich dunites cumulates of the magma ocean; the latter were brought to the upper mantle during the overturn of the unstable cumulate pile of the magma ocean.

Hess, Paul C.↗

The morphological evolution of mare-highland contacts - A potential measure of relative mare surface age

The uniform breaks in slopes along many mare-highland contacts may be debris aprons transported primarily by impact erosion at relatively slow rates. Other suggestions, such as the 'high lava mark' hypothesis, appear inadequate to explain all of the unique characteristics of these widespread features. There is a reasonable correlation of overall slope form (profile) and apron distribution with established mare age provinces. Distinctive debris aprons in the younger maria could represent the initial stages of lunar slope degradation produced mainly by the postmare impact flux. The growth of debris aprons must be qualitatively related to the impact flux recorded on adjacent mare surfaces and could provide an approximate means of extrapolating relative mare ages to highland scarps and crater walls. By combining detailed measurements of lunar slopes with development of a realistic model for impact modification of these features, approximate limits for the cumulative lunar flux distribution through time might be derived.

Young, R. A.↗

Impact experiments. III - Catastrophic fragmentation of aggregate targets and relation to asteroids

An experimental study is conducted of collisions employing artificial aggregates as targets, in order to ascertain the fragmentation characteristics of weakly bonded bodies that consist of stronger constituent particles, such as loosely aggregated planetesimals. It is established that weakly bonded aggregate bodies may exhibit unexpectedly high impact strengths due to constituent particles' energy dissipation. The cumulative size distributions of fragments that are larger than the constituent grains form power-law segments resembling those formed by the fragmentation of homogeneous targets.

Ryan, Eileen V.↗

I’ve Looked at Clouds from Both Sides, Now: Viewpoints from Surface and Spaceborne Lidar Systems

Clouds play a critical role in the Earth’s climate system because they are inextricably linked to the hydrological cycle and radiation budget. Information about cloud height, thickness, occurrence, and amount are critical inputs for a host of numerical applications involving climate research. Therefore, it is important to have highly accurate and quantitative data records of cloud properties that span several years and geographic regions. Verification of even the most basic modeling processes demands long term and continuous observations of global cloud occurrence, if there is to be any confidence in their fidelity. For a number of reasons, however, it is impossible to gauge the complexities of clouds from a single source. Fundamentally, an array of remote sensing methods is needed in order to provide a complete picture. Within the Micropulse Lidar Network (MPLNET), we have developed a new algorithm to improve the quality of our cloud products. The largest impact of the changes to the cloud detection algorithm is evident with high clouds (those with cloud base > 5 km). Furthermore, polarized measurements enable us to determine the cloud thermodynamic phase. Naturally, the next step is to investigate how these improvements compare with observations from spaceborne lidars (e.g. CALIOP) which have a better (unobstructed) view of high clouds. Recent advances in remote sensing have revealed that cirrus clouds are the most common cloud genus observed in the atmosphere. Furthermore, cirrus skew highly towards relatively low cloud optical depths, as observed from both surface and spaceborne viewpoints. The radiative impacts of these findings are quite significant, considering the cumulative effect cirrus exhibit when compared to low clouds.

Jasper R Lewis↗

Directed Acyclic Graph Guidance Documentation

For over a decade, the National Aeronautics and Space Administration (NASA) has tracked and configuration-managed approximately 30 risks to astronaut health and performance that occur before, during and after spaceflight. The Human System Risk Board (HSRB), a Health and Medical Technical Authority (HMTA) Board at NASA Johnson Space Center, is the entity responsible for identifying, assessing, analyzing, and monitoring the official understanding of the risk or risk posture for each of the Human System Risks and determining – based on evaluation of the available evidence – when that risk posture changes. The ultimate purpose of tracking and researching these risks is to find ways to reduce the risk that astronaut crews face during spaceflight. Historically, research, development and operations relevant to one risk have been conducted in isolation from other risks; these individual risk ‘silos’ enabled initial characterization of each specific risk. In spaceflight however, the impact of exposure to risk for astronaut crews is cumulative, and not independent of exposures or other risks, as all the adverse effects of the spaceflight environment begin at launch, continue throughout the duration of the mission and in some cases across the lifetime of the crews. In January of 2020, the HSRB at NASA embarked on a pilot project designed to assess the potential value of causal diagramming as a tool to facilitate understanding these cumulative and interdependent effects as applied within Human System Risk management. This process uses directed acyclic graphs as a means of formalizing a shared mental model of the causal flow of risk among Risk Board stakeholders. Initially this model was to improve communication among those stakeholders, but the potential value exceeds communication alone. Formalization of the process for creating these causal diagrams will enable the creation of a composite risk network that is vetted by members of the NASA community and configuration managed. The causal diagrams are formulated as directed acyclic graphs (DAGs) to function as a type of knowledge graph for reference for the board and its stakeholders. This document outlines the pilot process, the standardized approaches, and guidance for risk custodian teams when creating and updating DAGs as a part of the NASA Human System Risk Management process.

Risk↗

Directed Acyclic Graphs: A Tool for Understanding the NASA Human Spaceflight System Risks - Human System Risk Board

For over a decade, the National Aeronautics and Space Administration (NASA) has tracked and configuration-managed approximately 30 risks to astronaut health and performance that occur before, during and after spaceflight. The Human System Risk Board (HSRB), a Health and Medical Technical Authority (HMTA) Board at NASA Johnson Space Center, is the entity responsible for identifying, assessing, analyzing, and monitoring the official understanding of the risk or risk posture for each of the Human System Risks and determining – based on evaluation of the available evidence – when that risk posture changes. The ultimate purpose of tracking and researching these risks is to find ways to reduce the risk that astronaut crews face during spaceflight. Historically, research, development and operations relevant to one risk have been conducted in isolation from other risks; these individual risk ‘silos’ enabled initial characterization of each specific risk. In spaceflight however, the impact of exposure to risk for astronaut crews is cumulative, and not independent of exposures or other risks, as all the adverse effects of the spaceflight environment begin at launch, continue throughout the duration of the mission and in some cases across the lifetime of the crews. In January of 2020, the HSRB at NASA embarked on a pilot project designed to assess the potential value of causal diagramming as a tool to facilitate understanding of these cumulative and interdependent effects as applied within Human System Risk management. This process uses directed acyclic graphs as a means of formalizing a shared mental model of the causal flow of risk among Risk Board stakeholders. Initially this model was to improve communication among those stakeholders, but the potential value exceeds communication alone. The causal diagrams are formulated as directed acyclic graphs (DAGs) to function as a type of knowledge graph for reference for the board and its stakeholders. This document is a sister document to NASA/TM 20220006812 Directed Acyclic Graph Guidance Documentation (1). In that document, the basic guidance for creating and standardizing directed acyclic graphs as tools for cross-risk analysis is provided. This document contains the initial configuration managed DAGs that were created as a result of applying those principles. These initial versions were accepted by the HSRB in January of 2022. Each of the Human System Risks are represented by a DAG that has been reviewed by the larger Human Health and Performance community at NASA including life scientists, physical scientists, physicians, nurses, pharmacists, exercise specialists and more. These results show the starting point for Human System Risk DAGs as shared mental models and communication aids across the boundaries of the various expertise needed to understand and mitigate the human risks in spaceflight. Because they are a starting point, each of these DAGs can be expected to change over time as new or refined evidence becomes available. The process for updating these DAGs can be found in the JSC-66705 Human System Risk Management Plan (2) that is publicly available on the NASA Technical Reports Server.

Erik L. Antonsen↗

Investigating the Effects of Space Weathering in Ryugu Samples Using Coordinated Microanalyses

Airless planetary surfaces are characterized by a distinct lack of an atmosphere or magnetic field, leading to direct exposure to the effects of hypervelocity micrometeoroid impacts and solar wind ion irradiation [1]. These processes, cumulatively known as space weathering, gradually alter the microstructural and chemical properties of the grains on airless surfaces. Signatures of space weathering include vesiculated textures, amorphous grain rims (upper ~100 nm), solar flare tracks, and Fe-bearing nanoparticles (npFe) [2,3]. The accumulation of these microstructural space weathering characteristics, particularly the presence of npFe, alters the spectral properties of airless regoliths resulting in changes in spectral slope and reflectance of the surfaces, and the attenuation of characteristic absorption bands in the visible to near-infrared (Vis-NIR) wavelengths. These spectral changes complicate our ability to accurately interpret the mineralogy of airless bodies via remote sensing spectroscopy [1,4]. Studies of space weathering have primarily focused on anhydrous silicate minerals, reflecting the main components of the available returned samples from the Moon and S-type asteroid Itokawa [3,5,6]. However, our understanding of space weathering of primitive, organic-rich carbonaceous materials is still a work in progress. The Japan Aerospace Exploration Agency (JAXA)’s Hayabusa2 mission offered the first opportunity to directly investigate carbonaceous asteroids by returning samples from C-type asteroid (162173) Ryugu. Initial studies of Ryugu samples show mineralogical similarities to CI chondrites along with surface modifications consistent with space weathering. These surface modifications are primarily in the form of μm-thick silicate melts, amorphized phyllosilicates, glassy spherules, and burst vesicles [3,7]. Here, we report results from coordinated microanalytical techniques to further our understanding of the mineralogy and space weathering of carbonaceous materials.

L E Melendez↗

A study of lunar impact crater size-distributions

In view of the discrepancies in published crater frequency data, effects modifying production size distributions of impact craters are discussed. The resulting criteria are applied to the determination of the size distributions of unmodified impact crater populations in selected lunar regions of different ages. The measured cumulative crater frequencies are used to obtain a general calibration size distribution curve by a normalization procedure. Deviations of measured size distributions from the calibration distribution are strongly suggestive of the existence of processes having modified the primary impact crater population.

Neukum, G.↗