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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

Thermal Constraints from Siderophile Trace Elements in Acapulcoite-Lodranite Metals

A fundamental process in the formation of differentiated bodies is the segregation of metal-sulfide and silicate phases, leading to the formation of a metallic core. The only known direct record of this process is preserved in some primitive achondrites, such as the acapulcoite-lodranites. Meteorites of this clan are the products of thermal metamorphism of a chondritic parent. Most acapulcoites have experienced significant partial melting of the metal-sulfide system but not of silicates, while lodranites have experienced partial melting and melt extraction of both. The clan has experienced a continuum of temperatures relevant to the onset of metal mobility in asteroidal bodies and thus could yield insight into the earliest stages of core formation. Acapulcoite GRA 98028 contains relict chondrules, high modal sulfide/metal, has the lowest 2-pyroxene closure temperature, and represents the least metamorphosed state of the parent body among the samples examined. Comparison of the metal-sulfide component of other clan members to GRA 98028 can give an idea of the effects of metamorphism.

Herrin, Jason S.↗
NASA NTRS2024

Formation and Interior Evolution of Mars

The formation and earliest evolution of Mars involved core formation followed by magma ocean solidification and primordial crust formation. Here, we review the formation and early interior evolution of Mars as understood through meteorite studies. Martian meteorites exhibit ages that span the entire history of the Solar System, but most derive from compositionally distinct sources that formed early in the history of Mars. Geochemical and isotopic studies of Martian meteorites have provided critical information on Mars’ building blocks, bulk composition, and its differentiation into a core, mantle and crust. Radiogenic isotope systems provide vital insights into the petrogenesis of Martian meteorite source regions and into the nature and timescales of primordial differentiation on Mars. Application of short-lived isotope chronometers to Martian meteorites indicates that the Martian core formed early within <10 million years (Ma), while magma ocean differentiation and crust formation occurred soon thereafter, within the first tens of Ma of Solar System history. Bulk silicate Mars is variably depleted in moderately volatile elements relative to chondrites, but to a lesser extent than the Earth. The nature and evolution of more volatile elements and volatile species on Mars (e.g., H 2 O, C, S, halogens) remains an active area of investigation, but overall suggest that Mars is more enriched in volatile elements than the Moon but less than the Earth. While geochemical exploration of Mars coupled with new discoveries of Martian meteorites has provided a wealth of information, the compositional and lithologic diversity on Mars significantly exceeds that seen in the suites of Martian meteorites currently studied. This implies that our current perspective on the planet’s evolution is very likely biased, highlighting the need for future sample return missions to Mars.

Accretion↗
NASA NTRS1973

Gravitational energy sources in Jupiter

Gravitational sources of the intrinsic luminosity of Jupiter are examined in the context of current hydrogen-helium models. When no gravitational separation of matter occurs, the amount of heat which can be released over the remaining lifetime of the planet is necessarily limited by the size of its existing reservoir of thermal energy. This conclusion rests only on the assumption that its interior is relatively cold and degenerate. If gravitational unmixing occurs, the size of the thermal reservoir does not necessarily limit the heat output. If core formation occurs, for example, then the size of the core formed will be a limiting factor. The energy released with the formation of a helium core is computed for Jupiter. A core growth rate, averaged over several billion years, of 20 trillionths of Jupiter's mass per year is required if gravitational separation is to play a significant role in the thermal evolution.

Flasar, F. M.↗
NASA NTRS2016

Hydrophilic-Core Microcapsules and Their Formation

Hydrophilic-core microcapsules and methods of their formation are provided. A hydrophilic-core microcapsule may include a shell that encapsulates water with the core substance dissolved or dispersed therein. The hydrophilic-core microcapsules may be formed from an emulsion having hydrophilic-phase droplets dispersed in a hydrophobic phase, with shell-forming compound contained in the hydrophilic phase or the hydrophobic phase and the core substance contained in the hydrophilic phase. The shells of the microcapsules may be capable of being broken down in response to being contacted by an alkali, e.g., produced during corrosion, contacting the shell.

Calle, Luz M.↗
NASA NTRS2016

Hydrophobic-Core Microcapsules and Their Formation

Hydrophobic-core microcapsules and methods of their formation are provided. A hydrophobic-core microcapsule may include a shell that encapsulates a hydrophobic substance with a core substance, such as dye, corrosion indicator, corrosion inhibitor, and/or healing agent, dissolved or dispersed therein. The hydrophobic-core microcapsules may be formed from an emulsion having hydrophobic-phase droplets, e.g., containing the core substance and shell-forming compound, dispersed in a hydrophilic phase. The shells of the microcapsules may be capable of being broken down in response to being contacted by an alkali, e.g., produced during corrosion, contacting the shell.

Calle, Luz M.↗
NASA NTRS1982

Prebiotic organic matter - Possible pathways for synthesis in a geological context

Models for the accretion of the earth, core formation, differentiation of the planet into core, mantle, crust, and atmosphere, and prebiotic synthesis of organic materials are reviewed. The development of the Haldane-Oparin and Urey models is traced, and the effect of accretion time on the outgassing process and the composition of the consequent atmosphere is examined. Model prebiotic atmospheres are calculated, the extent of equilibration of the primitive atmosphere is studied and the evolution of the atmosphere prior to organic chemical evolution is reviewed. Finally, experimental progress in synthesis of biological monomers and polymers under presumed early earth conditions is covered.

Chang, S.↗
NASA NTRS2014

Core-Mantle Partitioning of Volatile Elements and the Origin of Volatile Elements in Earth and Moon

Depletions of siderophile elements in mantles have placed constraints on the conditions on core segregation and differentiation in bodies such as Earth, Earth's Moon, Mars, and asteroid 4 Vesta. Among the siderophile elements there are a sub-set that are also volatile (volatile siderophile elements or VSE; Ga, Ge, In, As, Sb, Sn, Bi, Zn, Cu, Cd), and thus can help to constrain the origin of volatile elements in these bodies, and in particular the Earth and Moon. One of the fundamental observations of the geochemistry of the Moon is the overall depletion of volatile elements relative to the Earth, but a satisfactory explanation has remained elusive. Hypotheses for Earth include addition during accretion and core formation and mobilized into the metallic core, multiple stage origin, or addition after the core formed. Any explanation for volatile elements in the Earth's mantle must also be linked to an explanation of these elements in the lunar mantle. New metal-silicate partitioning data will be applied to the origin of volatile elements in both the Earth and Moon, and will evaluate theories for exogenous versus endogenous origin of volatile elements.

Righter, K.↗
DOE OSTI2024

Formation and interior evolution of Mars

The formation and earliest evolution of Mars involved core formation followed by magma ocean solidification and primordial crust formation. Here, in this study, we review the formation and early interior evolution of Mars as understood through meteorite studies. Martian meteorites exhibit ages that span the entire history of the Solar System, but most derive from compositionally distinct sources that formed early in the history of Mars. Geochemical and isotopic studies of Martian meteorites have provided critical information on Mars’ building blocks, bulk composition, and its differentiation into a core, mantle and crust. Radiogenic isotope systems provide vital insights into the petrogenesis of Martian meteorite source regions and into the nature and timescales of primordial differentiation on Mars. Application of short-lived isotope chronometers to Martian meteorites indicates that the Martian core formed early within <10 million years (Ma), while magma ocean differentiation and crust formation occurred soon thereafter, within the first tens of Ma of Solar System history. Bulk silicate Mars is variably depleted in moderately volatile elements relative to chondrites, but to a lesser extent than the Earth. The nature and evolution of more volatile elements and volatile species on Mars (e.g., H 2 O, C, S, halogens) remains an active area of investigation, but overall suggest that Mars is more enriched in volatile elements than the Moon but less than the Earth. While geochemical exploration of Mars coupled with new discoveries of Martian meteorites has provided a wealth of information, the compositional and lithologic diversity on Mars significantly exceeds that seen in the suites of Martian meteorites currently studied. This implies that our current perspective on the planet's evolution is very likely biased, highlighting the need for future sample return missions to Mars.

Kruijer, Thomas S.↗
NASA NTRS1985

Implications of Convection in the Moon and the Terrestrial Planets

The early evolution of the Moon and its implications for the early evolution of the Earth was studied. The study is divided into two parts: (1) studies of core formation. Cosmochemical studies strongly favor a near-homogeneous accretion of the Earth. It is shown that core segregation probably occurred within the first 10,000 years of Earth history. It is found that dissipative heating may be a viable mechanism for core segregation if sufficiently large bodies of liquid iron can form; (2) early thermal evolution of the Earth and Moon. The energy associated with the accretion of the Earth and the segregation of the core is more than sufficient to melt the entire Earth. The increase in the mantle liquidus with depth (pressure) is the dominant effect influencing heat transfer through the magma ocean. It is found that a magma ocean with a depth of 100 km would have existed as the Earth accreted. It is concluded that this magma ocean zone refined the earth resulting in the simultaneous formation of the core and the atmosphere during accretion. The resulting mantle was a well-mixed solid with a near pyrolite composition.

Turcotte, D. L.↗
NASA NTRS1974

Models of the giant planets

Models of the giant planets were constructed based on the assumption that the hydrogen to helium ratio is solar in these planets. This assumption, together with arguments about the condensation sequence in the primitive solar nebula, yields models with a central core of rock and possibly ice surrounded by an envelope of hydrogen, helium, methane, ammonia, and water. These last three volatiles many be individually enhanced due to condensation at the period of core formation. Jupiter was found to have a core of about 40 earth masses and a water enhancement in the atmosphere of about 7.5 times the solar value. Saturn was found to have a core of 20 earth masses and a water enhancement in the atmosphere of about 25 times the solar value. Rock plus ice constitute 75-85% of the mass of Uranus and Neptune.

Podolak, M.↗
NASA NTRS1981

Models of the earth's core

Combined inferences from seismology, high-pressure experiment and theory, geomagnetism, fluid dynamics, and current views of terrestrial planetary evolution lead to models of the earth's core with five basic properties. These are that core formation was contemporaneous with earth accretion; the core is not in chemical equilibrium with the mantle; the outer core is a fluid iron alloy containing significant quantities of lighter elements and is probably almost adiabatic and compositionally uniform; the more iron-rich inner solid core is a consequence of partial freezing of the outer core, and the energy release from this process sustains the earth's magnetic field; and the thermodynamic properties of the core are well constrained by the application of liquid-state theory to seismic and labroatory data.

Stevenson, D. J.↗
NASA NTRS1983

Impact versus internal origins for mesosiderites

The textures, mineral compositions, and thermal history of mesosiderites are examined to see whether they are compatible with any kind of impact process or internal process which might produce stony-iron breccias. It was proposed that cratering by metal projectiles is not an adequate origin mechanism since it would not deposit enough metal in the stony-iron breccias. It was also proposed that such mechanisms as accretion of differentiated planitesimals must be considered for mesosiderite origins. But no single model for origins is fully satisfactory. Disruption and reassembly of two colliding bodies could form stony-iron breccias at depth, but, as with the previous models, the easiest way to explain the low olivine of mesosiderites is to postulate derivation from olivine-poor chondritic material. Turbulent metal-crust mixing during core formation and crustal blocks sinking into the core withhold olivine from the breccia but do not explain how the silicate and metal liquids in subgroup IV could have failed to segregate.

Hewins, R. H.↗
NASA NTRSDate not supplied

Multi-Anvil Experimentation Applied to Planetary Differentiation

Planets undergo differentiation that includes segregation of metal from silicate at high temperatures and pressures ranging from deep planetary core pressures (>300 GPa for Earth)to very shallow conditions of asteroids (<100 MPa).The multi-anvil solid media apparatus accesses the middle part of this range from 3 to 30 GPa –pressure relevant to the interior of Mercury, Venus, Earth, Earth’s Moon, and Mars. Early planets are thought to have experienced high temperatures from a combination of heat sources including radioactive decay, gravitational and accretional heating, and impact processes. These heating events led to melting of mantles and cores, thus requiring an understanding of solid-liquid equilibria in metal-silicate systems. In 2006 we established a multi-anvil facility at NASA-JSC combining an 880 ton press and a Kawai/Walker type module from Rockland Research. Our high PT work has been greatly facilitated by use of the COMPRES multi-anvil assemblies (1). Our recent work has included studies of element partitioning between liquid metal and liquid silicate(e.g., 2), as well as between minerals and melts(e.g., 3), both of which have led to better constraints on the timing and conditions of planetary differentiation(e.g. 4). Several examples involving sustained efforts will be summarized below and for the presentation. The distribution of siderophile (iron-loving) elements between core and mantle is controlled by metal-silicate equilibrium across a wide range of pressures. Therefore, experimentation across this pressure range helps to calibrate elemental partitioning models that can be applied to planets, and used to predict mantle chemistry and composition during planetary differentiation. Our studies have focused on a wide range of siderophile elements (refractory Ni, Co, W, Mo; volatile P, Ga, Cu, Sn, Sb; highly siderophile Au, Pd) that have constrained partitioning, valence, and isotopic fractionation, and applied to Earth, Moon, and Mars. When molten mantles (magma oceans) cool enough to initiate crystallization, the solids precipitate at depth and in large planets this involves high pressure phases like garnet, majorite, akimotoite, and ringwoodite. As these solids precipitate they can segregate from liquid by density contrasts, thus causing elemental fractionation which can be used to decipher timing of differentiation. Mineral/melt and metal/silicate equilibria in our lab have helped to better understand high pressure fractionation of isotopic parent/daughter pairs Hf/W, Mn/Cr, Pd/Ag, Pt/Os, Re/Os, and U/Pb, and their application to Earth, Moon and Mars. There remains great potential for multi-anvil experimentation to shed light on many pressure–dependent aspects of planetary evolution such as core formation, high pressure phase equilibria, redox equilibria, and volatile evolution and storage. References1. Leinenweber, K., et al.(2012) American Mineralogist,97, 353–368. 2.Righter, K., et al.(2020) Geochem. Persp. Lett.15, 1-6.3. Righter, K., et al.(2020) Met. Planet. Sci 55, 2741-2757.4. Righter, K., et al.(2020)Earth and Planetary Science Letters,552, 116590.

pressure↗
DOE OSTI2020

Activity coefficients of siderophile elements in Fe-Si liquids at high pressure

Metallic core formation in differentiated bodies in the inner solar system can take place between low pressures (near 1 bar) to much higher pressures (up to 100 GPa). Most thermodynamic models of metal-silicate equilibria utilise activity coefficients for metallic tracers in Fe liquids, nearly all of which have been carried out at low pressures. This study focuses on the effect of pressure on activity coefficients for Au, P, V, Mn, Ga, Zn, Cd, Sn, W, Pb, and Nb in liquid Fe-Si alloys. From a series of experiments at 10 GPa, 2373 K containing variable Si content in a metallic liquid we have derived epsilon interaction parameters in Fe-Si liquids ($ε^{Si}_{M}$). Comparison of 1 GPa and 10 GPa data shows no difference except for Nb. Epsilon parameters derived from low pressure experiments can thus be used to calculate activity coefficients for application to higher pressure processes (at least to 10 GPa).

58 GEOSCIENCES↗
NASA NTRSDate not supplied

Metal-silicate Partitioning of Re, Ru, Pt, Os, Ti, Nb, and Ta in Reduced Differentiated Planetary Bodies

Siderophile (iron-loving) elements are strongly fractionated during differentiation of planetary bodies into core and mantle [1]. Because the fractionation is controlled by the pressure, temperature, redox conditions, and composition, this group of elements can provide important constraints on the conditions of accretion and core formation in early solar system bodies (planetesimals) and planets (Earth, Mercury, Venus)[2]. At the reducing conditions thought to prevail in the early solar system, Si is known to alloy with FeNi metallic liquids (e.g., [3]) affecting the activity coefficients of siderophile elements in FeNi liquids and thus ultimately their detailed partitioning between metal and silicate melt. The effect of Si can be significant for some siderophile elements, as demonstrated previously by (e.g., [4]: Ni, Co; [5,6]: Ge, As, Sb, Pd, Pt, Au). The effect of Si has not yet been determined for several key groups of siderophile elements including the highly siderophile Re, Ru and Os, and the weakly siderophile Ta, Nb, and Ti. Here, we report new experiments designed to quantify the effect of Si on the partitioning of Re, Pt, Os, Ru, Ti, Ta and Nb between metal and silicate melts. The results will be used to evaluate metal/silicate equilibrium for Nb, Ta, Ti and Nb/Ta ratios in planetary mantles, mantle concentrations of Ru, Re, Pt, Os during accretion, the evolution of Re/Os, Pt/Os ratios in magma oceans, and the role of late veneer in establishing Re and Ru abundances in the terrestrial mantle.

core formation↗
NASA NTRS1985

Origin of life

The pathways of organic chemical synthesis, the chemical evolution on the early Earth leading to life was constrained by the development of the planet by accretion and core formation. The accretion and differentiation into the core-mantle-crust-atmosphere system strongly influenced the temperature and composition of the atmosphere, surface, and interior; but large gaps persist in our understanding of these processes. The time-span over which Earth acquired its volatiles, the composition of these volatiles, and the conditions under which outgassing of volatiles occurred to form the atmosphere, are unknown. Uncertainties in existing models for Earth accretion and early planetary development allows a wide range of possible prebiotic atmospheric compositions at the time and temperature when liquid water appeared and thermally-labile organic compounds could survive. These compositions range from strongly reducing atmospheres to mildly reducing ones.

Chang, S.↗
DOE OSTI2022

Water‐Induced Diamond Formation at Earth's Core‐Mantle Boundary

Abstract The carbon and water cycles in the Earth's interior are linked to key planetary processes, such as mantle melting, degassing, chemical differentiation, and advection. However, the role of water in the carbon exchange between the mantle and core is not well known. Here, we show experimental results of a reaction between Fe 3 C and H 2 O at pressures and temperatures of the deep mantle and core‐mantle boundary (CMB). The reaction produces diamond, FeO, and FeH x , suggesting that water can liberate carbon from the core in the form of diamond (“core carbon extraction”) while the core gains hydrogen, if subducted water reaches to the CMB. Therefore, Earth's deep water and carbon cycles can be linked. The extracted core carbon can explain a significant amount of the present‐day mantle carbon. Also, if diamond can be collected by mantle flow in the region, it can result in unusually high seismic‐velocity structures.

Ko, Byeongkwan↗
NASA NTRS2010

In Situ Determination of Siderophile Trace Elements in Metals and Sulfides in Enstatite Achondrites

Enstatite meteorites are identified by their extremely reduced mineralogy (1) and similar oxygen isotope composition (2). The enstatite meteorite clan incorporates both EH and EL chondrites, as well as a wide variety of enstatite achondrites, such as aubrites or anomalous enstatite meteorites (e.g. Mt. Egerton, Shallowater, Zaklodzie, NWA 2526). The role of nebular versus planetary processes in the formation of enstatite meteorites is still under debate (e.g. 3-5). Past studies showed a significant influence of metal segregation in the formation of enstatite achondrites. Casanova et al. (6) suggested incomplete metal-silicate segregation during core formation and attributed the unfractionated siderophile element patterns in aubrites metals to a lack of fractional crystallization in a planetary core. Recent studies suggest a significant role of impact melting in the formation of primitive enstatite chondrites (7) and identified NWA 2526 as a partial melt residue of an enstatite chondrite (8). To understand the nature of siderophile element-bearing phases in enstatite achondrites, establish links between enstatite achondrites and enstatite chondrites (9), and constrain planetary differentiation on their respective parent bodies and their petrogenetic histories, we present laser ablation ICP-MS measurements of metal and sulfide phases in Shallowater, Mt. Egerton, and the aubrites Aubres, Cumberland Falls, and Mayo Belwa.

vanAcken, D.↗