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Results for “conditional neutrality”

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At least 127 records · Page 7

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NASA NTRS1988

Microbial reduction of manganese oxides - Interactions with iron and sulfur

Alteromonas putrefaciens (strain MR-1) is capable of rapid Mn(IV) reduction under conditions of neutral pH and temperatures characteristic of the Oneida Lake, New York, sediments from which it was isolated. MR-1 also reduces Fe(3+) to Fe(2+), and disproportionates thiosulfate to sulfide and sulfite; independently, the Fe(2+) and sulfide act as rapid reductants of Mn. The addition of Fe(3+) or thiosulfate to cultures of MR-1 in the presence of oxidized Mn increases the rate and the extent of Mn reduction relative to that observed in the absence of Fe(3+) or thiosulfate. Furthermore, when Fe(3+) and Mn oxides are present conjointly, Fe(2+) does not appear until the reduction of the oxidized Mn is complete. These results demonstrate that the observed rates of Fe(2+) and sulfide production may underestimate the total rates of Fe and sulfate reduction in those environments containing oxidized Mn. These results also demonstrate the potential impact that a single microbe can exert on sediment geochemistry, and provide the basis for preliminary models of the complexity of microbial and geochemical interactions that occur.

Myers, Charles R.↗

NASA NTRS1989

Interset: A natural language interface for teleoperated robotic assembly of the EASE space structure

A teleoperated robot was used to assemble the Experimental Assembly of Structures in Extra-vehicular activity (EASE) space structure under neutral buoyancy conditions, simulating a telerobot performing structural assembly in the zero gravity of space. This previous work used a manually controlled teleoperator as a test bed for system performance evaluations. From these results several Artificial Intelligence options were proposed. One of these was further developed into a real time assembly planner. The interface for this system is effective in assembling EASE structures using windowed graphics and a set of networked menus. As the problem space becomes more complex and hence the set of control options increases, a natural language interface may prove to be beneficial to supplement the menu based control strategy. This strategy can be beneficial in situations such as: describing the local environment, maintaining a data base of task event histories, modifying a plan or a heuristic dynamically, summarizing a task in English, or operating in a novel situation.

Boorsma, Daniel K.↗

NASA NTRS1990

High voltage interactions of a sounding rocket with the ambient and system-generated environments

EPSAT (environment power system analysis tool) is used to examine the design of SPEAR III, which is scheduled to fly in early 1991. It will test high-voltage designs in both ambient and system-generated environments. Two of the key questions that the experiment hopes to address are whether or not the earth's magnetic field can cause the current that a high-voltage object draws from the plasma to be far less than the current that would be drawn in the absence of the magnetic field and under what neutral environmental conditions a discharge from the high-voltage object to the plasma will occur. The EPSAT program makes it possible to perform a variety of analyses on a preliminary or conceptual-level description of a system in a short period of time. The calculations presented on SPEAR III are all done for a conceptual-level description. The calculations indicate that the experiment will produce the conditions necessary to address these questions.

Kuharski, Robert A.↗

NASA NTRS1991

Cold-air outbreak during GALE - Lidar observations and modeling of boundary layer dynamics

Two cold-air outbreaks were studied during the Genesis of Atlantic Lows Experiment. A lidar system was operated to observe the boundary layer evolution and the development of clouds. On the first day (January 30, 1986) boundary layer rise was less than 50 percent of the value for the second day (March 2, 1986). On the first day only a thin broken cloud cover formed, while on the second day a thick solid cloud deck formed - although the average moisture content was 60 percent of that on the first day. A trajectory slab model was employed to simulate the evolution of the layer over the ocean near the east Atlantic shore. The model allows for vertical gradients in conservative variables under neutrally buoyant conditions. The primary effect of these assumptions, which are based on observed thermodynamic profiles, is to reduce cloudiness to be more in line with observations. Boundary-layer depth was reasonably well predicted as was sensible and latent heat flux.

Boers, Reinout↗

NASA NTRS1992

Aerodynamic roughness measured in the field and simulated in a wind tunnel

This study evaluates how well values of aerodynamic surface roughness, z sub 0, measured over scale models in wind tunnels correlate with values of z sub 0 measured at full scale in the field. A field experiment was conducted in which values of z sub 0 and u* (wind friction speed) were measured over three arrays of non-erodible roughness elements on a dry lake bed. Wind profiles were measured by ten anemometers on a 15 m mast under thermally neutral atmospheric conditions. Values of z sub 0 increased from .00014 m (dry lake bed only) to .026 m with increasing roughness element density. The three roughness element arrays were simulated at 1/10 and 1/20 scale in an open-circuit atmospheric boundary-layer wind tunnel. Velocities were measured with a boundary-layer pitot-tube rake from the same relative position within the scale model arrays as the anemometers were relative to the field arrays. Each array at each scale was sampled three times at five freestream velocities. Average values of z sub 0 for each model array at each scale were compared with full-scale values of z sub 0 obtained in the field. The field vs. wind tunnel correspondence of z sub 0 is found to be z sub 0 field = 0.2661 x (z sub(0 model) x scale(exp -1))exp .8159.

Sullivan, Robert↗

NASA NTRS1953

Preliminary Results of Stability and Control Investigation of the Bell X-5 Research Airplane

During the acceptance tests of the Bell X-5 airplane, measurements of the static stability and control characteristics and horizontal-tail loads were obtained by the NACA High-Speed Flight Research Station. The results of the stability and control measurements are presented in this paper. A change in sweep angle between 20 deg and 59 deg had a minor effect on the longitudinal trim, with a maximum change of about 2.5 deg in elevator deflection being required at a Mach number near 0.85; however, sweeping the wings produced a total stick-force change of about 40 pounds. At low Mach numbers there was a rapid increase in stability at high normal-force coefficients for both 20 0 and 1100 sweepback, whereas a condition of neutral stability existed for 58 0 sweepback at high normal-force coefficients. At Mach numbers near 0.8 there was an instability at normal-force coefficients above 0.5 for all sweep angles tested. In the low normal-force-coefficient range a high degree of stability resulted in high stick forces which limited the maximum load factors attainable in the demonstration flights to values under 5g for all sweep angles at a Mach number near 0.8 and an altitude of 12,000 feet. The aileron effectiveness at 200 sweepback was found to be low over the Mach number range tested.

Finch, Thomas W↗

NASA NTRS1999

Mineral induced formation of pentose-2,4-bisphosphates

Formation of rac.-pentose-2,4-bisphosphates is demonstrated, starting from glycolaldehyde phosphate and glyceraldehyde-2-phosphate, and induced by mixed valence double layer metal hydroxide minerals. The reactions proceed from dilute aqueous reactant solutions (1.5 mM) at near neutral pH. Conditions have been established, where ribose-2,4-bisphosphate is the major product (approximately 48%) among the pentose-2,4-bisphosphates, which are formed with up to 25% yield.

Non-NASA Center↗

NASA NTRS2012

Timescale Correlation between Marine Atmospheric Exposure and Accelerated Corrosion Testing - Part 2

Evaluation of metals to predict service life of metal-based structures in corrosive environments has long relied on atmospheric exposure test sites. Traditional accelerated corrosion testing relies on mimicking the exposure conditions, often incorporating salt spray and ultraviolet (UV) radiation, and exposing the metal to continuous or cyclic conditions similar to those of the corrosive environment. Their reliability to correlate to atmospheric exposure test results is often a concern when determining the timescale to which the accelerated tests can be related. Accelerated corrosion testing has yet to be universally accepted as a useful tool in predicting the long-term service life of a metal, despite its ability to rapidly induce corrosion. Although visual and mass loss methods of evaluating corrosion are the standard, and their use is crucial, a method that correlates timescales from accelerated testing to atmospheric exposure would be very valuable. This paper presents work that began with the characterization of the atmospheric environment at the Kennedy Space Center (KSC) Beachside Corrosion Test Site. The chemical changes that occur on low carbon steel, during atmospheric and accelerated corrosion conditions, were investigated using surface chemistry analytical methods. The corrosion rates and behaviors of panels subjected to long-term and accelerated corrosion conditions, involving neutral salt fog and alternating seawater spray, were compared to identify possible timescale correlations between accelerated and long-term corrosion performance. The results, as well as preliminary findings on the correlation investigation, are presented.

Montgomery, Eliza L.↗

NASA NTRSDate not supplied

Apatite Nanoresponse to Acidic Dissolution

Phosphorus uptake by plants and organisms is one of the most important life-sustaining processes occurring in the critical zone (CZ). Because 95% of Earth’s reserves is relatively immobile in the form of apatite, plants and organisms rely on molecular scale solubilization process to extract available P. As the world experiences a global P shortage, influencing food production, it becomes increasingly important to understand apatite dissolution. The detailed study of chemically weathered apatite surfaces at the μm to nm-scale is key to understanding P solubilization and uptake in the CZ, allowing for better crop management and efficient fertilization. Apatite weathering is generally viewed in terms of a pH-dependent process where protons weaken atomic bonds, this leading to the disintegration of the apatite structure. A general feature of apatite weathering in acid and near neutral pH conditions is an apparent non-stoichiometric dissolution characterized by [Ca/P]aq > 1.66 in both fluorapatites (FAP) and hydroxyapatites (HAP). This process leads to the formation of a surface altered layer (SAL) with a different composition from the bulk, which many have argued is a Ca-depleted “leached layer.” We investigated apatite weathering at the nanoscale using FIB-prepared TEM-foils. Our preliminary results based on laboratory-altered FAP at ambient T and pH 3 show the formation of amorphous SALs with a maximum thickness of ~10 nm. High resolution chemical mapping and profiling using STEM-EELS and STEM-EDXS indicate that the SALs are generally, but not always, depleted in Ca and enriched in P. These results provide an alternate view of the mechanism of apatite dissolution with stoichiometric breakdown of the apatite structure, followed by the reprecipitation of an amorphous surface layer depleted in Ca. This mechanism can be described in terms of coupled interfacial dissolution-reprecipitation (CIDR), which is increasingly viewed as a universal mechanism of silicate mineral and glass dissolution. Our observation that apatite may dissolve similarly to silicates implies not only that apatite weathering may be more complex than originally thought, but also that the CIDR mechanism may extend beyond silicates.

mineralogy↗

DOE OSTI2020

The distribution of neutral hydrogen in the colour–magnitude plane of galaxies

ABSTRACT We present the conditional H i (neutral hydrogen) mass function (HIMF) conditioned on observed optical properties, Mr (r-band absolute magnitude), and Cur (u − r colour), for a sample of 7709 galaxies from Arecibo Legacy Fast ALFA (40 per cent data release – α.40) which overlaps with a common volume in SDSS DR7. Based on the conditional HIMF, we find that the luminous red, luminous blue, and faint blue populations dominate the total HIMF at the high-mass end, knee, and the low-mass end, respectively. We use the conditional HIMF to derive the underlying distribution function of ΩH i (H i density parameter), p(ΩH i), in the colour–magnitude plane of galaxies. The distribution, p(ΩH i), peaks in the blue cloud at $\mathit{ M_{{r}}}^{\text{max}}=-19.25, \mathit{ C_{{ur}}}^{\text{max}}=1.44$ but is skewed. It has a long tail towards faint blue galaxies, and luminous red galaxies. We argue that p(ΩH i) can be used to reveal the underlying relation between cold gas, stellar mass, and the star formation rate in an unbiased way, that is, the derived relation does not suffer from survey or sample selection.

Dutta, Saili (ORCID:0000000288585845)↗

NASA NTRS1982

A survey of interstellar neutral potassium. I - Abundances and physical conditions in clouds toward 188 early-type stars

Observations of interstellar absorption in the resonance doublet 7664, 7698 A of neutral potassium toward 188 early-type stars at a spectral resolution of 8 km/s are reported. The 7664 A line is successfully separated from nearly coincident telluric O2 absorption for all but a few of the 165 stars for which K I absorption is detected, making possible an abundance analysis by the doublet ratio method. The relationships between the potassium abundances and other atomic abundances, the abundance of molecular hydrogen, and interstellar reddening are investigated.

Chaffee, F. H., Jr.↗

NASA NTRS2017

Smectite Formation in Acid Sulfate Environments on Mars

Phyllosilicates of the smectite group detected in Noachian and early Hesperian terrains on Mars were hypothesized to form under aqueous conditions that were globally neutral to alkaline. These pH conditions and the presence of a CO2-rich atmosphere should have been favorable for the formation of large carbonate deposits. However, large-scale carbonate deposits have not been detected on Mars. We hypothesized that smectite deposits are consistent with perhaps widespread acidic aqueous conditions that prevented carbonate precipitation. The objective of our work was to investigate smectite formation under acid sulfate conditions in order to provide insight into the possible geochemical conditions required for smectite formation on Mars. Hydrothermal batch incubation experiments were performed with Mars-analogue, glass-rich, basalt simulant in the presence of sulfuric acid of variable concentration.

Peretyazhko, T. S.↗

DOE OSTI2025

Rapid Crystallization of Zeolites with Controllable Defects: Disentangling Fluoride Concentration and pH Using NH 4 F

Zeolite synthesis is typically conducted either under basic conditions or in neutral fluoride media using hydrofluoric acid (HF). While basic (OH − ) conditions generally result in faster zeolite crystallization, they can also increase the likelihood of framework defects and crystal intergrowths. In contrast, synthesis in neutral fluoride media tends to produce fewer defects because fluoride balances positive charges from structure-directing agents. However, this method often requires significantly longer crystallization times and involves the handling of dangerous HF. In the present study, we pursue the best of both synthesis conditions, rapid syntheses with controllable defect concentrations, by disentangling of mineralizing agent and chargebalancing agent using ammonium fluoride (NH 4 F) as an alternative to HF. We have investigated the use of NH 4 F in the syntheses of siliceous and aluminum-containing zeolite A (LTA, small pore), ZSM-5 (MFI, medium pore), and siliceous Beta(*BEA, large pore). The crystallization times of all four zeolites decreased substantially with an increasing NH 4 F concentration. Crystallization times were reduced from 24 to 4 h (Si-LTA), 96 to 36 h (Al-LTA), 240 to 6 h (ZSM-5), and 24 to 3 h (Si-*BEA). Additionally, increasing the NH 4 F concentration in the synthesis mixtures decreases the defect densities of siliceous zeolites. Raman spectroscopy, along with 29 Si MAS NMR, 19 F MAS NMR, 13 C MAS NMR, and fluorine elemental analysis of Si-LTA samples confirms that the reduction in charged defects (Si−O − ) is due to the higher incorporation of F − within the double four-membered ring (D4R) present in the LTA samples. We show that the accelerated crystallization is due to the role of F − in enhancing the silica mineralization rate (formation of silicon hexafluoride species) and stabilizing D4Rs under basic conditions. As a result, combining basic and fluoride-mediated synthesis could therefore be advantageous for faster zeolite production and improved control over structural properties for a wide variety of zeolite structures.

Anions↗

NASA NTRS2011

The Formation of Fe/Mg Smectite Under Mildly Acidic Conditions on Early Mars

The detection of Fe/Mg smectites and carbonate in Noachian and early Hesperian terrain of Mars suggests that neutral to mildly alkaline conditions prevailed during the early history of Mars. If early Mars surface geochemical conditions were neutral to moderately alkaline with a denser CO2 atmosphere than today, then large carbonates deposits should be more widely detected in Noachian terrain. Why have so few carbonate deposits been detected compared to Fe/Mg smectites? Fe/Mg smectites on early Mars formed under mildly acidic conditions, which would preclude the extensive formation of carbonate deposits. The goal of the proposed work is to evaluate the formation of Fe/Mg smectites under mildly acidic conditions.

Sutter, B.↗

DOE OSTI2026

The solubility of ErPO 4 and Er speciation in hydrothermal fluids at varying pH and salinity between 350 and 450 °C

The rare earth elements (REE) are important for the green-energy transition and can be incorporated into the REE phosphates, such as xenotime-(Y), which also hosts heavy REE (Tb– Lu). Xenotime-(Y) is a common accessory mineral in metamorphic rocks and a range of mineral deposits where it controls the mobility of heavy REE, however, the impact of high temperature aqueous fluids on the behavior of heavy REE is largely unknown. Thermodynamic modeling can be utilized as a tool to predict the mobility of REE in hydrothermal aqueous fluids, but must be supported by accurate experimental data. Here, we measured the solubility of endmember synthetic xenotime-structured ErPO4 in NaCl-HCl-NaOH-bearing aqueous solutions at 350 °C and water vapor saturation pressure, at 400 and at 450 °C and 500 bar using batch-type Inconel reactors. Erbium speciation was investigated as a function of pH from 2.8 to 8, where Er chloride species are predominant at acidic conditions (pH <3) and Er hydroxyl complexes are predominant at near- neutral to alkaline conditions (pH >3). At pH 7–9, the measured ErPO 4 solubility (-9.8 to -7.5 log m Er ) is up to 2.5 orders of magnitude lower than thermodynamic predictions (-9.4 to -6.7 log m Er ) using existing thermodynamic databases. At pH 2–3, the predicted ErPO 4 solubility is ~0.5 orders of magnitude higher at 350 °C and ~1 order of magnitude lower at 450 °C compared to experimentally measured Er concentrations. The thermodynamic properties of aqueous Er species were therefore revised in this study. The partial molal Gibbs energy of formation (Δ f G 0 T,P ) for aqueous Er hydroxyl and chloride species are optimized using GEMSFITS and the logarithmic formation constants (logβ n ( Cl,OH) ) were derived at each experimental temperature and pressure. The updated thermodynamic properties for Er hydroxyl species (Er(OH) +2 , Er(OH) 2 + , and Er(OH) 3 0 ) show that their stability shifts to more acidic conditions at and below 400 °C. The Er chloride species (ErCl +2 and ErCl 2 + ) show increased stability compared to Er hydroxyl species at temperatures of 450 °C and 0.01 mol/kg NaCl. The updated thermodynamic properties are implemented into the GEM-Selektor modeling package to investigate the mobility of Er in saline hydrothermal fluids in equilibrium with alkaline rocks. Importantly, the updated properties for Er hydroxyl species result in low Er solubility at rock equilibrated pH conditions due to an expanded hydroxyl predominance zone, but lower aqueous complex stability overall, whereas previous models suggest greater stability for aqueous Er species. Furthermore, ErPO 4 solubility increases with decreasing temperature due to the deprotonation of HCl, which increases the acidity of hydrothermal fluids and the availability of Cl - to complex with the REE. These simulations highlight how fluid-rock reaction and temperature affect the mobility of REE in hydrothermal ore-forming systems.

58 GEOSCIENCES↗

NASA NTRS1973

Turbulent shear flow of continuum plasma.

The turbulence structure of weakly ionized, continuum plasma is analyzed with emphasis on the turbulent fluctuation and the transport properties of the ionized species. The mean gradients of the velocity and ionized-species concentrations are considered to be uniform. It is assumed that the turbulence Reynolds number is small and that the turbulence field is homogeneous in order to close the dynamic equations of turbulence. It was found that the ratio of the Debye shielding length to the local integral scale of turbulence must be sufficiently small in order for the detailed quasi-neutrality to prevail. The condition of the detailed quasi-neutrality is necessary, in addition to the equal mean concentrations of electrons and ions, in order for the turbulence properties involving the electrons to be the same as those involving the ions.

Chung, P. M.↗

DOE OSTI2025

Insights into oxygen diffusion in rare earth disilicate environmental barrier coatings

Environmental barrier coatings (EBC) are crucial for the use of SiC-based ceramic matrix composites in high-temperature combustion environments, yet knowledge of oxygen diffusion in these coatings is limited. This study investigates oxygen diffusion dynamics in the β-RE 2 Si 2 O 7 system to minimize oxygen penetration in rare earth disilicates. We analyze defect formation energy under varying oxygen conditions, identifying key diffusion mechanisms. In oxygen-rich environments, the most favorable neutral interstitial oxygen diffuses along the [110] direction. In oxygen-poor conditions, neutral oxygen vacancies rotate around Y and Si atoms, exhibiting a diffusivity of 6.59×10 −22 m 2 /s at 1500 K for β-Yb 2 Si 2 O 7 . Under intermediate oxygen levels, charged interstitial oxygen diffuses via concerted interstitialcy along the [001] direction with a diffusivity of 6.21×10 −17 m 2 /s. Additionally, alloying rare earth Y with Er and Yb increases diffusion barriers, contributing to improved EBC performance in extreme environments. The insights gained provides valuable guidance for designing robust coatings tailored to withstand extreme operational environments.

36 MATERIALS SCIENCE↗

NASA NTRS1975

Exospheric temperature inferred from the Aeros-A neutral composition measurement

The derivation of exospheric temperature from satellite drag measurements is based on an assumption of invariant conditions of the neutral atmosphere at 120 km. Since it has been established that atomic oxygen, which is usually the major neutral constituent in the region of drag measurements, is subject to considerable variability with season, latitude, and solar and geomagnetic activity in the altitude region of 120 km, its value as an indicator of exospheric temperature is questionable. Ogo 6 neutral mass spectrometer measurements revealed that molecular nitrogen is a better indicator of exospheric temperature, since it is not subject to changes caused by eddy mixing and is therefore relatively less variable near the turbopause. However, theoretical arguments show that argon, even though it is a minor constituent, is relatively less variable with respect to changes in eddy diffusion coefficient and hence a better indicator of exospheric temperature than O and N2. In this paper the relative merits of these gases for deriving exospheric temperature are investigated by using observational data from the Aeros-A Nate experiment.

Chandra, S.↗