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NASA NTRS2006

Non-nebular Origin of Dark Mantles Around Chondrules and Inclusions in CM Chondrites

Our examination of nine CM chondrites that span the aqueous alteration sequence leads us to conclude that compact dark fine mantles surrounding chondrules and inclusions in CM chondrites are not discrete fine-grained rims acquired in the solar nebula as modeled by Metzler et al. [Accretionary dust mantles in CM chondrites: evidence for solar nebula processes. Geochim. Cosmochim. Acta 56, 1992, 2873-28971. Nebular processes that lead to agglomeration produce materials with porosities far higher than those in the dark mantles. We infer that the mantles were produced from porous nebular materials on the CM parent asteroid by impact-compaction (a process that produces the lowest porosity adjacent to chondrules and inclusions). Compaction was followed by aqueous alteration that formed tochilinite, serpentine, Ni-bearing sulfide, and other secondary products in voids in the interchondrule regions. Metzler et al. reported a correlation between mantle thickness and the radius of the enclosed object. In Yamato 791 198 we find no correlation when all sizes of central objects and dark lumps are included but a significant correlation (r(sup 2) = 0.44) if we limit consideration to central objects with radii >35 microns; a moderate correlation is also found in QUE 97990. We suggest that impact-induced shear of a plum-pudding-like precursor produced the observed "mantles"; these were shielded from comminution during impact events by the adjacent stronger chondrules and inclusions. Some mantles in CM chondrites with low degrees of alteration show distinct layers that may largely reflect differences in porosity. Typically, a gray, uniform inner layer is surrounded by an outer layer consisting of darker silicates with BSE-bright speckles. The CM-chondrite objects characterized as "primary accretionary rocks" by Metzler et al. did not form in the nebula, but rather on the parent body. The absence of solar-flare particle tracks and solar-wind-implanted rare gases in these clasts reflect their lithified nature and low surface/volume ratios during the period when they resided in the regolith and were subject to irradiation by solar particles. The clasts are analogous to the light-colored metamorphosed clasts in ordinary-chondrite regolith breccias (which also lack solar-flare particle tracks and solar-wind gas).

Trigo-Rodriquez, Josep M.↗

NASA NTRS2006

Turbulent Size Selection and Concentration of Chondrule-Sized Objects: Reynolds Number Invariance and Implications

It is generally agreed that individual chondrules formed as entities in a gaseous nebula prior to being accumulated into a meteorite parent body, within which they incur various forms of modification before arriving in our labs. While there are major unanswered questions about the properties of the nebula environment in which chondrules formed, the process by which the most primitive meteorites are formed overwhelmingly from chondrules must then be an aspect of "nebula processing". Textures in certain fragments of primitive meteorites might be summarized as being primarily chondrules and clastic, chondrule-sized, fragments of other minerals, each covered with a rim of fine dust with physical and chemical properties which are essentially independent of the composition and mineralogy of the underlying chondrule. This (unfortunately rather rare) texture was called "primary accretionary texture" to reflect their belief that it precedes subsequent stages in which fragmentation, comminution, mixing, heating, and other forms of alteration occur on the parent body(-ies). The size distribution of these chondrules and fragments, and the properties of their dusty rims, are key clues regarding the primary nebula accretion process. Even in the much more abundant meteorites which have clearly suffered internal mixing, abrasion, grinding, and even mineralogical alteration or replacement (due presumably to the collisional growth and heating process itself), key chondrule properties such as mean size and density remain relatively well defined, and well defined rims persist in many cases. It has been our goal to infer the key nebula processes indirectly from the properties of these very earliest primitive meteorites by making use of a theoretical framework in which the nebula possesses a plausible level of isotropic turbulence. We have shown that turbulence has the property of concentrating one particular particle size by orders of magnitude, where the preferentially concentrated size depends primarily on the intensity of the turbulent kinetic energy (represented by the Reynolds number of the nebula). Specifically, the preferentially concentrated particle is that which has a stopping time equal to the turnover time of the smallest eddy. The intensity level of turbulence implied by chondrule sizes can be maintained by even a small fraction of the energy released by the radially evolving disk (it must be noted that the details of how this transfer of energy actually occurs remain obscure, however).

Cuzzi, J. N.↗

NASA NTRS2007

Experimental Impacts into Chondritic Targets: Disruption of an L6 Chondrite by Multiple Impacts - Part 1

A fragment of an L6 chondrite (ALH 85017,13) with an initial mass (M(sub 0)) of 464.1 g was the target in a series of experimental impacts in which the largest remaining fragment (M(sub R)) after each shot was impacted by a 3.18-mm ceramic sphere at a nominal speed of 2 km/s. This continued until the mass of the largest remaining piece was less than half the mass of the target presented to that shot (M(sub S)). Two chunks of Bushveldt gabbro with similar initial masses were also impacted under the same conditions until M(sub R) was less than half M(sub 0). The two gabbro targets required a total of 1.51x10(exp 7) and 1.75x10(exp 7) erg/g to attain 0.27 and 0.33 M(sub R)/M(sub 0), respectively; the chondrite, however, was considerably tougher, reaching 0.40 and 0.21 M(sub R)/M(sub 0) only after receiving 2.37x10(exp 7) and 3.10x10(exp 7) erg g-1, respectively. The combined ejecta and spallation products from the gabbro impacts were coarser than those from the chondrite and in sufficient quantities that the new surface areas exceeded those from the meteorite until the fifth shot in the chondrite series, which was the number of impacts required to disrupt each gabbro target (i.e., MR/M0 = 0.5). Unlike the behavior shown in previous regolith-evolution series, neither gabbro target produced an enhancement in the size fraction reflecting the mean size of the crystals composing the rock (about 3 mm), an effect possibly related to the width of the shock pulse. The original chondrite was so fine-grained and fractured, and the variance in its grain-size distribution so large, that effects related to grain-size were relegated to the <63- m fraction. Impacts into ALH 85017 produced abundant, fine-grained debris, but otherwise the slopes of its size distributions were comparable to those from other experiments involving natural and fabricated terrestrial targets. The characteristic slopes of the chondrite's size distributions, however, were notably more constant over the entire nine-impact series than those from any of the terrestrial targets, a testament to the control over comminution apparently exerted by pre-existing fractures and other, microscopic damage in the meteorite. The enhancement in the finer fraction of debris from ALH 85017 indicates that ordinary chondrites in solar orbit would be very efficient contributors to the cosmic-dust complex. At the same time, the greater resistance to disruption displayed by ordinary chondrites relative to that exhibited by igneous rocks indicates that a selection effect could be operative between the annealed, ordinary-chondritic breccias and relatively weaker, differentiated meteorites. Preferential survival from their time in the regoliths of their parent bodies through their transit to Earth and passage through the atmosphere suggests that meteorite collections could be biased in favor of the ordinary chondrites.

Cintala, Mark J.↗

NASA NTRS2009

The Lunar Regolith

A thick layer of regolith, fragmental and unconsolidated rock material, covers the entire lunar surface. This layer is the result of the continuous impact of meteoroids large and small and the steady bombardment of charged particles from the sun and stars. The regolith is generally about 4-5 m thick in mare regions and 10-15 m in highland areas (McKay et al., 1991) and contains all sizes of material from large boulders to sub-micron dust particles. Below the regolith is a region of large blocks of material, large-scale ejecta and brecciated bedrock, often referred to as the "megaregolith". Lunar soil is a term often used interchangeably with regolith, however, soil is defined as the subcentimeter fraction of the regolith (in practice though, soil generally refers to the submillimeter fraction of the regolith). Lunar dust has been defined in many ways by different researchers, but generally refers to only the very finest fractions of the soil, less than approx.10 or 20 microns. Lunar soil can be a misleading term, as lunar "soil" bears little in common with terrestrial soils. Lunar soil contains no organic matter and is not formed through biologic or chemical means as terrestrial soils are, but strictly through mechanical comminution from meteoroids and interaction with the solar wind and other energetic particles. Lunar soils are also not exposed to the wind and water that shapes the Earth. As a consequence, in contrast to terrestrial soils, lunar soils are not sorted in any way, by size, shape, or chemistry. Finally, without wind and water to wear down the edges, lunar soil grains tend to be sharp with fresh fractured surfaces.

Noble, Sarah↗

NASA NTRS2010

The Epiregolith

The physical properties of the lunar regolith were originally inferred from remotely sensed data, first from the Earth and later from orbiting spacecraft. The Surveyor landings and the Apollo surface explorations produced a more concrete characterization of the macroscopic properties. In general, the upper regolith consists of a loosely consolidated layer centimeters thick underlain by a particulate but extremely compacted layer to depths of meters or tens of meters. The median particle size as determined by mechanical sieving in terrestrial laboratories is several tens of micrometers. However, the comminuting processes that form the layer produce particles in all sizes down to manometers. The smallest particles, having a high surface to volume ratio, tend to be electrostatically bound to larger particles and are quite difficult to separate mechanically in the laboratory. Particle size distributions determined from lunar soil samples often group particles smaller than 10 micrometers.

Mendell, Wendell W.↗

NASA NTRS2004

Evidence for Differential Comminution/Aeolian Sorting and Chemical Weathering of Martian Soils Preserved in Mars Meteorite EET79001

Impact-melt glasses containing Martian atmospheric gases in Mars meteorite EET79001 are formed from Martian soil fines that had undergone meteoroid-comminution and aeolian sorting accompanied by chemical weathering near Mars surface. Using SiO2 and SO3 as proxy for silicates and salts respectively in Mars soils, we find that SiO2 and SO3 correlate negatively with FeO and MgO and positively with Al2O3 and CaO in these glasses, indicating that the mafic and felsic components are depleted and enriched relative to the bulk host (Lith A/B) respectively as in the case of Moon soils. Though the overall pattern of mineral fractionation is similar between the soil fines on Mars and Moon, the magnitudes of the enrichments/depletions differ between these sample-suites because of pervasive aeolian activity on Mars. In addition to this mechanical processing, the Martian soil fines, prior to impact-melting, have undergone acid-sulfate dissolution under oxidizing/reducing conditions. The S03 content in EET79001,507 (Lith B) glass is approx.18% compared to < 2% in EET79001, 506 (Lith A). SiO2 and SO3 negatively correlate with each other in ,507 glasses similar to Pathfinder soils. The positive correlation found between FeO and SO3 in ,507 glasses as well as Pathfinder rocks and soils is consistent with the deposition of ferric-hydroxysulfate on regolith grains in an oxidizing environment. As in the case of Pathfinder soils, the Al 2O3 vs SiO2 positive correlation and FeO VS S102 negative correlation observed in ,507 glasses indicate that SiO2 from the regolith is mobilized as soluble silicic acid at low pH. The large off-set in the end-member FeO abundance ( SO3=0) between Pathfinder soil-free rock and sulfur-free rock in ,507 glass precursors suggests that the soils comprising the ,507 glasses contain much larger proportion of fine-grained Martian soil fraction that registers strong mafic depletion relative to Lith B. This inference is strongly supported by the Al2O3 - SO3 negative correlation observed in both ,507 glasses and pathfinder soils. Furthermore, the flat MgO-SO3 correlation observed in the case of ,507 glasses shows that the solubilized MgSO4 is mobilized by the aqueous solutions leaving behind the rock-residue with approx.2-3% MgO. This value is similar to the approx.2% MgO found for the soil-free rock at the Pathfinder site. The EET79001 ,506 glasses, in contrast, show that Al2O3 and CaO positively correlate with SO3 indicating that Al is precipitated as amorphous hydroxysulfate at relatively high pH. The FeO - SO3 negative correlation observed in ,506 glasses yields an end-member FeO abundance of approx.21% for the sulfur-free rock, which is consistent with the 22% FeO deduced for the Viking soil-free rock. Further, the FeO and MgO negative correlation with S03 observed in ,506 glasses indicates that the divalent Fe and Mg released from ferromagnesian minerals by acid sulfate dissolution are mobilized away from the reaction sites as soluble sulfates under reducing environment. A similar negative correlation between FeO and SO3 and a positive correlation between Al2O3 and SO3 found in Viking soils suggest that they also had undergone acid-sulfate dissolution under relatively reducing conditions.

Rao, M. N.↗

NASA NTRS2013

Space Weathering of Lunar Rocks and Regolith Grains

The exposed surfaces of lunar soil grains and lunar rocks become modified and coated over time with a thin rind of material (patina) through complex interactions with the space environment. These interactions encompass many processes including micrometeorite impacts, vapor and melt deposition, and solar wind implantation/sputtering effects that collectively are referred to as "space weathering". Studies of space weathering effects in lunar soils and rocks provide important clues to understanding the origin and evolution of the lunar regolith as well as aiding in the interpretation of global chemical and mineralogical datasets obtained by remote-sensing missions. The interpretation of reflectance spectra obtained by these missions is complicated because the patina coatings obscure the underlying rock mineralogy and compositions. Much of our understanding of these processes and products comes from decades of work on remote-sensing observations of the Moon, the analysis of lunar samples, and laboratory experiments. Space weathering effects collectively result in a reddened continuum slope, lowered albedo, and attenuated absorption features in reflectance spectra of lunar soils as compared to finely comminuted rocks from the same Apollo sites. Space weathering effects are largely surface-correlated, concentrated in the fine size fractions, and occur as amorphous rims on individual soil grains. Rims on lunar soil grains are highly complex and span the range between erosional surfaces modified by solar wind irradiation to depositional surfaces modified by the condensation of sputtered ions and impact-generated vapors. The optical effects of space weathering effects are directly linked to the production of nanophase Fe metal in lunar materials]. The size of distribution of nanophase inclusions in the rims directly affect optical properties given that large Fe(sup o) grains (approx 10 nm and larger) darken the sample (lower albedo) while the tiny Fe(sup o) grains (<5nm) are the primary agent in spectral "reddening". More recent work has focused on the nature and abundance of OH/H2O in the lunar regolith using orbital data and samples analyses. Advances in sample preparation techniques have made possible detailed analyses of patina-coated rock surfaces. Major advances are occurring in quantifying the rates and efficiency of space weathering processes through laboratory experimentation.

Keller, L. P.↗

NASA NTRS2016

The Microstructure of Lunar Micrometeorite Impact Craters

The peak of the mass flux of impactors striking the lunar surface is made up of objects approximately 200 micrometers in diameter that erode rocks, comminute regolith grains, and produce agglutinates. The effects of these micro-scale impacts are still not fully understood. Much effort has focused on evaluating the physical and optical effects of micrometeorite impacts on lunar and meteoritic material using pulsed lasers to simulate the energy deposited into a substrate in a typical hypervelocity impact. Here we characterize the physical and chemical changes that accompany natural micrometeorite impacts into lunar rocks with long surface exposure to the space environment (12075 and 76015). Transmission electron microscope (TEM) observations were obtained from cross-sections of approximately 10-20 micrometers diameter craters that revealed important micro-structural details of micrometeorite impact processes, including the creation of npFe (sup 0) in the melt, and extensive deformation around the impact site.

Noble, S. K.↗