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At least 127 records · Page 7

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DOE OSTI2022

2020 Component Innovation Awardee: Windurance LLC

Currently, there is no wind system power-conversion component available to wind turbine OEMs that is certified to applicable standards for use in the U.S. distributed wind energy market. Off-the-shelf industrial drives have features that are not needed by distributed wind OEMs and lack other features that would be valuable for the operation and control of wind turbine generating systems. In addition to adding costs for OEMs, these industrial drives increase uncertainty and risk for project developers and prospective owners. All of this presents barriers and increases costs for the development of distributed wind in the United States. With funding from CIP, Windurance plans to develop an industry-specific power-conversion component that will offer application-specific features at lower cost for distributed wind OEMs.

CIP↗

DOE OSTI2023

2022 Prototype Design Development Awardee: RRD Engineering

The innovative BladeRunner distributed wind turbine concept from RRD Engineering will address the need for dependable, efficient, and affordable midsize turbines to power operations in the commercial, industrial, agricultural, military, governmental, and institutional sectors. The inventive design funded by this Competitiveness Improvement Project (CIP) award reduces LCOE by using materials and components that cost and weigh less than those found in conventional turbines, while delivering savings related to manufacturing and maintenance requirements.

CIP↗

DOE OSTI2023

2022 Prototype Installation and Testing Awardee: Windward Engineering

The 60-kilowatt (kW) Zephyr 21/60 wind turbine from Windward Engineering uses a low-cost, full-span independent pitch system that can act as a redundant aerodynamic braking system. This design uses a relatively simple pneumatic rotary vane actuator, allowing each of the turbine's three blades to be pitched independently and any single blade to activate emergency braking for the entire turbine. A previous Competitiveness Improvement Project (CIP) funding award enabled Windward Engineering to design and develop the Zephyr 21/60 wind turbine's aeroelastic model and pitch system. At the end of this current Competitiveness Improvement Project award, a fully validated aeroelastic model will make it possible to certify Windward Engineering's Zephyr 21/60 design and quantify the technology's levelized cost of energy in preparation for certification and entry into the distributed wind market. The Zephyr 21/60 will feature an attractive levelized cost of energy, improved reliability, and a full-span pitch system for safe and redundant protection against rotor overspeed (which occurs when the rotor turns beyond its design limit).

CIP↗

DOE OSTI2023

2022 Component Innovation Awardee: Carter Wind Turbines

Carter Wind Turbines will develop a competitively priced, portable, ultra-lightweight, self-erecting turbine that will expand the viability of wind energy systems for commercial and residential customers in areas far from population centers. The new turbine is a taller version of the Carter Model 300, which was developed with funding from previous Competitiveness Improvement Project (CIP) awards. Compared to conventional turbines, the new assembly is cheaper to ship, can be erected in one day without any cranes or heavy excavation equipment, and is compatible with the wide range of grid configurations and site conditions found in remote areas.

CIP↗

DOE OSTI2023

2022 Small Turbine Certification Awardee: NPS Solutions

Inverters convert the direct current power generated by wind turbines into the alternating current needed to serve local loads and feed onto the electricity grid. Although distributed wind systems typically supply electricity for homes and businesses near the turbines, these systems can also provide clean power to strengthen grid resilience. Certification to UL 1741 SA ensures that inverters will enable distributed wind turbines to provide grid support services and stay online when the grid experiences stability issues. Small companies often find the electrical listing process too complex and expensive to undertake on their own, so few distributed wind turbine inverters are certified to this standard. A U.S. Department of Energy (DOE) Competitiveness Improvement Project (CIP) award is helping NPS Solutions (NPS) secure this critical certification for the inverter in its 100-kilowatt NPS 100C wind turbine, which is optimized for on-site generation at farms, businesses, schools, hospitals, and remote locations.

CIP↗

DOE OSTI2023

2022 Product Commercialization and Market Development Awardee: Bergey Windpower

In 2023, consumers will finance more than 80% of the residential solar energy systems they purchase, which they use as collateral (called "non-recourse loans"). Similar loans are not yet offered to fund distributed wind energy systems. To accelerate deployment of small wind systems, which power individual rural homes and farms, the United States will need to make consumer loans available at reasonable rates with modest downpayments and collateral requirements. A team led by Bergey Windpower Co. is creating new consumer financing options to reduce or eliminate the upfront cash needed to buy distributed wind energy systems. This new financing structure would decrease purchase costs for small wind turbines produced by Bergey Windpower and possibly other manufacturers. Product financing is instrumental in growing wind power market share, clean energy manufacturing, and installation jobs while reducing greenhouse gas emissions. Bergey Windpower's previous Competitiveness Improvement Project (CIP) awards have led to the development of affordable, high-performance wind turbines, microgrids, and components.

CIP↗

DOE OSTI2024

2022 System Optimization Awardee: XFlow Energy Company

Vertical-axis wind turbines offer several cost-saving advantages over traditional horizontal-axis wind turbines, including lower blade manufacturing costs and a simpler mechanical design. Unfortunately, until now, vertical configurations have not been able to match the power production and durability of more conventional horizontal-axis models. XFlow Energy Company (XFlow Energy) plans to improve the design and reduce the production costs of its 25-kilowatt (kW) vertical-axis wind turbine, delivering a levelized cost of energy that is competitive with that of U.S. retail electricity generated by coal-fired power plants. XFlow Energy's efficient turbine also is designed to maximize power production and longevity. Two previous Competitiveness Improvement Project (CIP) awards funded XFlow Energy's development of a 10-meter vertical-axis turbine prototype.

CIP↗

DOE OSTI2025

Grid Communications: Digital Assurance and Supply Chain Challenges and Emerging Regulation Session Two

The TADA Grid Communications Workshops are designed to strengthen cybersecurity and digital assurance across the energy sector by focusing on secure deployment and management of grid communications technologies. These workshops bring together state energy offices, utilities, and technology suppliers to explore the intersection of communications infrastructure, supply chain risks, and emerging regulatory requirements. Participants will apply Cyber-Informed Engineering (CIE) principles to reduce risks in communications systems, engage with INL’s procurement guidance, and explore future tools. Through scenario-based exercises and peer exchange, attendees will develop risk-based security strategies and actionable compliance roadmaps tailored to their grid communications projects. The workshops also help participants navigate evolving regulatory frameworks such as FEOC rules in the OBBB, NERC CIP-013, and NDAA 2024, while identifying compliance gaps in mixed-technology environments. A key outcome is the formation of a practitioner network with ongoing access to INL expertise and resources, fostering long-term resilience in the digital energy ecosystem. This is Session 2 of 3 (Full Version).

29 - ENERGY PLANNING, POLICY AND ECONOMY↗

DOE OSTI2025

Grid Communications: Cybersecurity and Supply Chain Challenges and Emerging Regulation Session Three

29 - ENERGY PLANNING, POLICY AND ECONOMY↗

DOE OSTI2025

Grid Communications Supply Chain & Emerging Regulation Challenges Session 1

29 - ENERGY PLANNING, POLICY AND ECONOMY↗

DOE OSTI2024

Boron and lithium aqueous thermochemistry to model crud deposition in pressurized water reactors

Here, a comprehensive database of boron and lithium aqueous thermochemistry has been developed for use at elevated temperatures. The Helgeson-Kirkham-Flowers (HKF) formalism provides a framework to describe thermodynamic properties over a broad range of temperatures and pressures. Accuracy at high temperatures is vital to modeling nickel oxide and ferrite fuel deposits that occur in pressurized water nuclear reactors (PWRs). CALPHAD (CALculation of PHAse Diagrams) calculations are performed at PWR crud conditions to predict the stability regions of the solid lithium metaborate (LiBO 2 ) and lithium tetraborate (Li 2 B 4 O 7 ) precipitates. In addition, similar calculations are performed using sodium and potassium instead of lithium in order to assess the thermodynamics associated with preventing the formation of such precipitates. This database contributes to understanding of crud formation and composition and will aid in the prediction of phenomena such as Crud-Induced Power Shifts (CIPS).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Understanding fluorine-free electrolytes via small-angle X-ray scattering

Fluorine-free electrolytes have attracted great attention because of its low-cost and environmental friendliness. However, so far, little is known about the solution structures of these electrolytes. Here, we compare the solvation phenomenon of sodium tetraphenylborate (NaBPh 4 ) salt dissolved in organic solvents of propylene carbonate (PC), 1,2-dimethoxyethane (DME), acetonitrile (ACN) and tetrahydrofuran (THF). Small-angle X-ray scattering (SAXS) reveals a unique two-peak structural feature in this salt concentrated PC electrolyte, while solutions using other solvents only have one scattering peak. Molecular dynamics (MD) simulations further reveal that there are anion-based clusters in addition to the short-range charge ordering in the concentrated NaBPh4/PC electrolyte. Raman spectroscopy confirms the existence of considerable contact ion pairs (CIPs). Here, this work emphasizes the importance of global and local structural analysis, which will provide valuable clues for understanding the structure performance relationship of electrolytes.

25 ENERGY STORAGE↗

DOE OSTI2022

High-pressure CO 2 permeation properties and stability of ceramic-carbonate dual-phase membranes

CO 2 permeation properties and stability of ceramic-carbonate dual-phase membranes at high pressures/temperatures are critical to their CO 2 separation and membrane reactor applications, but such data are not available in the literature. Here, this work aims to study the effect of high transmembrane pressure on CO 2 permeation flux and the stability of molten carbonate in the dual-phase samarium-doped ceria (SDC) and molten-carbonate (MC) membranes. Dead-end porous SDC tubular supports were made by a cold isostatic press (CIP)/sintering method with a low porosity (below 7%), and gas-tight SDC-MC membranes were prepared by direct infiltration of molten lithium and sodium carbonate mixture into SDC pores, with a MC volume fraction less than 7%. CO 2 permeation/separation tests were performed on the SDC-MC membranes using feed gas of equal molar CO 2 /N 2 mixture at feed pressures up to 15 atm and sweep gas of helium at 1 atm. CO 2 permeation flux for the SDC-MC membranes depends logarithmically on feed/permeate CO 2 pressure ratio in 660–810°C. The temperature dependence of CO 2 permeation shows activation energy of 30 kJ/mol. Due to the small MC volume fraction and hence low effective carbonate conductivity, CO 2 permeation of the SDC-MC membranes is dominated by the carbonate ionic conduction in the MC phase. The SDC-MC membranes remain in the same structure, morphology, and gas-tightness after CO 2 separation tests at high feed pressures and temperatures, showing high stability of SDC-MC membranes for high-temperature, high-pressure separation and chemical reaction applications.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Factors Influencing Preferential Anion Interactions during Solvation of Multivalent Cations in Ethereal Solvents

Most multivalent secondary batteries have employed electrolytes composed of cyclic ether solvents such as tetrahydrofuran or linear glycol ether solvents (glymes) such as 1,2-dimethoxyethane (G1). A robust understanding of multivalent cation solvation tendencies in these classes of solvents provides insight into corresponding structure–property relationships which, in turn, promotes the design and discovery of improved electrolytes. In this work, our goal is to systematically address how electrolyte constituent properties, namely, ether solvent structure and dication size, direct the solvation interactions of divalent electrolytes and their resultant properties. This study utilizes pulsed-field gradient (PFG) nuclear magnetic resonance (NMR) spectroscopy in conjunction with Raman spectroscopy and ionic conductivity measurements to elucidate the preferential interactions between multivalent cations, anions, and solvent molecules along with their correlated ion dynamics. These investigations incorporate two representative divalent cations (Ca 2+ and Zn 2+ ) as well as two ethereal solvent representatives from both the cyclic ether and glyme structural classes. The results reveal that anions coordinate more readily with divalent cations in cyclic ethers than in glymes. Furthermore, the coordination of the anions with Ca 2+ , i.e., contact-ion pair (CIP) formation is more pronounced than with Zn 2+ in a glyme solvent of limited chain length (G1), providing insight into cation size effects that are important for translating solvation behavior across various multivalent electrolytes. Importantly, we find that specific anion coordination is more strongly controlled by solvent structure than by salt concentration in the practical range of 0.1–0.5 M. However, simply reducing these inner-sphere inter-ionic interactions by changing solvent structure does not necessarily de-correlate ionic motion. Instead, concentration-dependent changes in molar ionic conductivity suggest that second-shell interactions, i.e., solvent separated ion pairs (SSIPs), are prevalent in these electrolytes and that the solution dielectric constant, which is increased by the presence of dipolar ion pairs, is critical for controlling these interactions. These findings thus provide a basis for understanding the physical chemistry of multivalent battery electrolytes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2015

Solvate Structures and Computational/Spectroscopic Characterization of LiPF6 Electrolytes

Raman spectroscopy is a powerful method for identifying ion-ion interactions, but only if the vibrational band signature for the anion coordination modes can be accurately deciphered. The present study characterizes the PF6- anion P-F Raman symmetric stretching vibrational band for evaluating the PF6-...Li+ cation interactions within LiPF6 crystalline solvates to create a characterization tool for liquid electrolytes. To facilitate this, the crystal structures for two new solvates—(G3)1:LiPF6 and (DEC)2:LiPF6 with triglyme and diethyl carbonate, respectively—are reported. The information obtained from this analysis provides key guidance about the ionic association information which may be obtained from a Raman spectroscopic evaluation of electrolytes containing the LiPF6 salt and aprotic solvents. Of particular note is the overlap of the Raman bands for both solvent-separated ion pair (SSIP) and contact ion pair (CIP) coordination in which the PF6- anions are uncoordinated or coordinated to a single Li+ cation, respectively.

crystal structure↗

DOE OSTI2026

Prediction and Experimental Verification of Electrolyte Solvation Structure from an OMol25-Trained Interatomic Potential

A molecular-level understanding of electrolyte solvation structure and ion–ion correlations is critical to developing next-generation battery chemistries. Atomistic simulation capabilities with sufficient accuracy, speed, and transferability to deliver reliable structural insights while avoiding arduous system-specific reparameterization are thus highly desirable. Machine learning interatomic potentials (MLIPs) trained on large, chemically diverse data sets are revolutionizing computational chemistry, enabling molecular dynamics simulations of battery electrolytes with near-DFT accuracy over 10,000× faster than DFT. While previous MLIP training data sets with suitable elemental coverage for electrolytes have been based on inorganic materials, the Open Molecules 2025 (OMol25) data set provides large-scale molecular DFT MLIP training data with broad elemental coverage and specifically samples tens of millions of electrolyte configurations. Here, we integrate computational modeling with experimental validation to systematically assess the ability of large-scale MLIPs pretrained on materials data or on OMol25 to accurately resolve nanoscale structural organization and ion-solvation characteristics in Na-ion battery electrolytes across diverse physicochemical conditions and compositional regimes. We find that the OMol25-trained Universal Model of Atoms (UMA-OMol) predicts experimentally measured densities and X-ray structure factors in substantially better agreement compared to state-of-the-art models trained only on inorganic materials data. Using UMA-OMol, we further analyze systematic trends in solvation structure as a function of cation identity, anion chemistry, salt concentration, and solvent topology. We observe that increasing system temperature amplifies the heterogeneity within the solvation environment, perturbing cation–solvent interactions and promoting the formation of contact ion pairs (CIPs). Moreover, subtle variations in the solvent topology of glyme-based electrolytes cause pronounced changes in ion correlations and solvation structure. The experimental agreement and microscopic insights shown here position OMol25-trained MLIPs as a practical route to predictive, high-throughput electrolyte simulations beyond the limits of classical force fields and direct DFT molecular dynamics, serving as a powerful tool for accelerating the design of next-generation Na-ion battery electrolytes and beyond.

MLIPs↗

DOE OSTI2026

Mixed-anion electrolytes: from bulk speciation to interfacial dynamics in divalent metal electrodeposition

Mixing anions is emerging as a promising strategy for multivalent electrolyte design, allowing for adjustment of the solvation structure of bulk cations and enhancing the efficiency of electrochemical processes (e.g. metal deposition for batteries and catalysis). Further progress in electrolyte development requires a fundamental understanding of how tailored electrolyte speciation in mixed anion systems can modify the dynamic electrochemical interface during metal cycling. In this study, we present an anode-focused mechanistic study of exemplar Mg electrolytes containing three different secondary anions, correlating electrochemical behavior with bulk speciation and operando interfacial dynamics. Electrospray Ionization-Mass Spectrometry (ESI-MS) results reveal a general trend of forming mixed anion contact ion pairs (CIPs) across various anions, with the extent of ion pairing influenced by the association strength of the secondary anion. Operando multiharmonic electrochemical quartz crystal microbalance with dissipation (EQCM-D) reveals how these bulk species influence interfacial mass uptake, viscoelasticity, and solvent-coupled hydrodynamic behavior during deposition and stripping. The results indicate that Mg-containing ion pairs and solvated complexes shape adsorption, nucleation, and deposit growth, leading to distinct anion-dependent interphases ranging from more permeable, solvent-coupled layers to relatively compact and rigid deposits. This work establishes a quantitative link between bulk speciation and interfacial dynamics in divalent metal electrodeposition and provides mechanistic guidance for electrolyte design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2015

Microsolvation of sodium acetate in water: Anion photoelectron spectroscopy and ab initio calculations

To understand the microsolvation of sodium acetate (CH{sub 3}COONa, NaOAc) in water, we studied NaOAc(H{sub 2}O){sub n}{sup −} (n = 0–3) clusters by photoelectron spectroscopy. We also investigated the structures of NaOAc(H{sub 2}O){sub n}{sup −} (n = 0–5) anions and NaOAc(H{sub 2}O){sub n} (n = 0–7) neutrals by quantum chemistry calculations. By comparing the theoretical results with the photoelectron experiment, the most probable structures of NaOAc(H{sub 2}O){sub n}{sup −/0} (n = 0–3) were determined. The study also shows that, with increasing n, the solvent-separated ion pair (SSIP) structures of NaOAc(H{sub 2}O){sub n}{sup −} anions become nearly energetically degenerate with the contact ion pair (CIP) structures at n = 5, while the SSIP structures of the neutral NaOAc(H{sub 2}O){sub n} clusters appear at n = 6 and become dominant at n = 7.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗